Beruflich Dokumente
Kultur Dokumente
Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247 667, India
b
National Institute of Hydrology, Roorkee 247 667, India
Received 25 March 2003; accepted 6 May 2003
Abstract
The bagasse y ash, an industrial solid waste of sugar industry, was used for the removal of cadmium and nickel from
wastewater. As much as 90% removal of cadmium and nickel is possible in about 60 and 80 min, respectively, under the
batch test conditions. Effect of various operating variables, viz., solution pH, adsorbent dose, adsorbate concentration,
temperature, particle size, etc., on the removal of cadmium and nickel has been studied. Maximum adsorption of
cadmium and nickel occurred at a concentration of 14 and 12 mg l1 and at a pH value of 6.0 and 6.5, respectively. A
dose of 10 g l1 of adsorbent was sufcient for the optimum removal of both the metal ions. The material exhibits good
adsorption capacity and the adsorption data follow the Langmuir model better then the Freundlich model. The
adsorption of both the metal ions increased with increasing temperature indicating endothermic nature of the
adsorption process. Isotherms have been used to determine thermodynamic parameters of the process, viz., free energy
change, enthalpy change and entropy change.
r 2003 Elsevier Science Ltd. All rights reserved.
Keywords: Adsorption; Sugar industry; Bagasse y ash; Cadmium; Nickel
1. Introduction
The presence of trace metals in the aquatic environment has been of great concern because of their toxicity
and non-biodegradable nature [13]. Cadmium and
nickel are toxic and relatively widespread in the
environment [4]. These metals are used in a wide variety
of industries such as plating and cadmiumnickel
battery, phosphate fertilizers, mining, pigments, stabilizers and alloys [5], and nd their way to the aquatic
environment through wastewater discharges. Therefore,
a systematic study on the removal of cadmium and
nickel from wastewater is of considerable signicance
from an environmental point of view.
0043-1354/03/$ - see front matter r 2003 Elsevier Science Ltd. All rights reserved.
doi:10.1016/S0043-1354(03)00292-6
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2. Experimental methodology
All chemicals and reagents used were of analytical
grade and were obtained from E. Merck, India. Stock
solutions of cadmium and nickel were prepared using
cadmium nitrate and nickel nitrate in deionized water.
A pH meter (Hach, USA) was used for pH measurements. X-ray measurements were made using a Phillips
X-ray diffractometer employing nickel-ltered CuKa
radiations. The surface area of the adsorbent was
measured by a surface area analyser (Quantasorb Model
QS-7). IR spectra of the samples were recorded on an
infrared spectrophotometer (FTIR Perkin Elmer Model
1600). The porosity and density of the adsorbent were
determined by mercury porosimeter and specic gravity
bottles, respectively.
2.1. Adsorbent development
Baggase y ash, a solid waste material of the sugar
industry, was collected from a sugar factory at Iqbalpur,
UP, India. The material was treated with hydrogen
peroxide at 60 C for 24 h to oxidize the adhering organic
matter. It was then washed with de-ionized water, dried
at 100 C, powdered, and sieved to produce desired
particle size (100150, 150200 and 200250 mm). The
material was stored in a vacuum desiccator for further
use.
The stability of the adsorbent was determined by
keeping the material over night in different solvents
(water, dilute acids and bases of 0.10.2 N) and
determining the presence of its constituents in the
solvents. The loss of treatment was determined using
hydrogen peroxide. The constituents of the adsorbent
were determined following standard methods of chemical analysis [20].
2.2. Adsorption studies
Batch adsorption experiments were carried out in a
series of Erlenmeyer asks of 100 ml capacity covered
with Teon sheets to prevent contamination. The effect
of contact time (0150 min), concentration (2.0
20.0 mg l1), solution pH (2.09.0), adsorbent dose
(2.020.0 g l1), particle size (100150, 200250 and
300350 mm), and temperature (30 C, 40 C and 50 C)
were studied. Isotherms were obtained by adsorbing
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Cd
Ni
1.60
1.20
0.80
0.40
0.00
0
30
60
90
Time, min
120
150
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V.K. Gupta et al. / Water Research 37 (2003) 40384044
Ni
30 deg C
1.20
0.80
0.40
0.00
0
4
8
12
16
Initial concentration, mg/l
0.80
0.40
0.00
2
10
pH
Fig. 4. Effect of pH on adsorption of cadmium and nickel.
Cd
Ni
1.60
1.20
0.80
0.40
0.00
0
1.00
0.50
0.00
12
16
12
16
20
30 deg C
1.20
1.50
Ni
1.60
50 deg C
Cd
40 deg C
2.00
20
20
Dose, g/l
Fig. 5. Effect of adsorbent dose on adsorption of cadmium and
nickel.
Cd
1.60
4041
40 deg C
50 deg C
2.00
1.50
1.00
0.50
0.00
0
4
8
12
16
Initial concentration, mg/l
20
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Table 1
Langmuir and Freundlich constants for the uptake of cadmium
and nickel
Langmuir constants
Freundlich constants
Qo (mg/g)
KF
Cadmium
30oC
40oC
50oC
1.24
1.67
2.00
5.67
6.21
7.14
8.93
10.12
12.50
1.02
1.11
1.26
Nickel
30oC
40oC
50oC
1.12
1.35
1.70
6.42
7.21
8.66
10.04
12.31
14.00
0.90
1.05
1.17
0.10
y = 0.11x + 0.01
Cd
0.05
log qe
0.15
0.00
Ni
-0.05
-0.10
-0.15
-1.0
y = 0.1x - 0.04
-0.5
0.0
log Ce
0.5
1.0
1.60
y = 0.16x + 0.90
1/qe
1.40
Ni
1.20
1.00
Cd
0.80
following equation:
log qe log KF 1=n log Ce ;
2
1
y = 0.13x + 0.81
0.60
0.5
1.0
1.5
2.0
2.5
1/Ce
Fig. 8. Langmuir isotherm for cadmium and nickel.
3.0
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Table 2
Thermodynamic parameters for the uptake of cadmium and nickel
Adsorbate
Cadmium
Nickel
DS (J mol1)
30 C
40 C
50 C
30 C
40 C
50 C
30 C
40 C
50 C
4.37
4.69
4.60
4.98
4.95
5.44
7.18
9.28
11.74
15.41
9.39
12.19
9.27
15.15
22.81
33.32
14.55
20.89
Table 3
Values of B; Di ; Do ; Ea and DS# for the uptake of cadmium and nickel
B 104 (s1)
Cd
Ni
30 C
40 C
50 C
30 C
40 C
50 C
7.29
3.74
7.36
3.80
7.41
3.87
2.96
1.52
2.99
1.54
3.01
1.57
DG RT ln b;
DS o DG o DH o =T;
3.14
1.51
66.67
100.0
35.93
38.01
10
11
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4. Conclusions
Bagasse y ash obtained from the local sugar industry
is an inexpensive and effective adsorbent for the removal
of cadmium and nickel from wastewater. The removal of
the two metal ions takes place by a partial diffusion
mechanism. The adsorption data t very well to the
Langmuir model in comparison to the Freundlich
model. The adsorption was found to be endothermic
in nature.
Acknowledgements
Authors are thankful to the Council of Scientic and
Industrial research (CSIR), India, for providing nancial support to undertake the work.
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