Sample Paper 2016

JEE ADVANCED EXAMINATION

(QUESTION PAPER - 2)

Avail Free Video Solutions of Experienced Faculty

www.etoosindia.com

Page # 2

PART - I [MATHEMATICS]
SECTION - A
[STRAIGHT OBJECTIVE TYPE]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1.

If a, b, c, d are sides of a quadrilateral, then find minimum value of

2
5

(A)

2.

(B)

5
3

(C)

1
3

(D)

a2 b2 c2
d2

2
3

Let Tr be rth terms of sequence for

r = 1, 2, 3 ......... . If 3Tr + 1 = Tr and
T4 =

1
find value of
Tr Tr 1
243

r 1

3.

(A)

1
217

(B)

1
215

(C)

1
216

(D) None of these

Given that for a, b, c, d R, If a sec 200 c tan (200) = d

b sec 200 + d tan (200) = c
a2 b2 c2 d2
sin 20
find value of

bd

ac

(A) 1
(B) 2
(C) 3
(D) 4

4.

If , are the roots of the quadratic equation

the value of 2 + + 2 is equal to
(A) 3
(B) 5

x2 3 2

log2 3

(C) 7

log3 2

x 2 3

log3 2

2log2 3 = 0, then

(D) 11

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 3

5.

The value of

(1) n 1 5n

equals

n 1

(A)

6.

5
12

(B)

5
24

(C)

5
36

(D)

5
16

1
sin
1
1
sin
The value of sin
1
sin
1
(A) can not equals three for atleast one value of R.
(B) is zero for some value of R.
(C) lies in [2, 4]
(D) lies in [1, 1]

7.

Let

{ 1 ,

0,

1}

1 x
f2 (x).f
= 64x then [|f(2)|] is.
1 x

8.

where [*] denotes GIF.

(A) 1
(B) 2
2
If x f(x) = 3 (f(x)) + 2
then

(A)

(C) 3

(D) 4

2x2 12xf(x) f(x)

dx
(6f(x) x)(x2 f(x))2

1
C
(6f(x) x)2

(B)

1
C
x f(x)
2

(C)

1
C
x xf(x)
2

(D) None

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

sat i sfi es

Page # 4

9.

3
Let f(x) = cos1 (4x3 3x) If f = and
5
4
f = q find |4p + q| is equal to
5

(A) 40
10.

(B) 15

(C) 10

(D) 20

Suppose f : R R+, and g : R R+ are differentiable functions such that

x g(f(x))f(g(x))g(x) = f(g(x))g(f(x))f(x) x R
Further

a
0

f(g(x)) dx = 1

(A) 12

e 2a
x R. Given that f(f(0)) = 1. If g(f(4)) = ek, then k is
2

(B) 2

(C) 16

(D) 8

[COMPREHENSION TYPE]
Q.11 to Q.16 are based upon a paragraph. Each questions has four choice (A), (B), (C), (D) out of which
ONLY ONE is correct
Paragraph for Question Nos. 11 to 12
Suppose you do not know the function f (x), however some information about f (x) is listed below.
Read

t he

f ol l owi n g

carefu l l y

attempting the questions

(i)

f (x) is continuous and defined for all real numbers

(ii)

f '(5) = 0 ; f '(2) is not defined and f '(4) = 0

(iii)

(5, 12) is a point which lies on the graph of f (x)

(iv)

f ''(2) is undefined, but f ''(x) is negative everywhere else.

(v)

the signs of f '(x) is given below

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

before

Page # 5

11.

On the possible graph of y = f (x) we have

(A) x = 5 is a point of relative minima.
(B) x = 2 is a point of relative maxima.
(C) x = 4 is a point of relative minima.
(D) graph of y = f (x) must have a geometrical sharp corner.

12.

Possible graph of y = f (x) is

(A)

(B)

(C)

(D)

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 6

Paragraph for Question Nos. 13 to 14

From a point 'P' three normals are drawn to the parabola y2 = 4x such that two of them make
angles with the abscissa axis, the product of whose tangents is 2. Suppose the locus of the point
'P' is a part of a conic 'C'. Now a circle S = 0 is described on the chord of the conic 'C' as diameter
passing through the point (1, 0) and with gradient unity. Suppose (a, b) are the coordinates of the
centre of this circle. If L1 and L2 are the two asymptotes of the hyperbola with length of its
transverse axis 2a and conjugate axis 2b (principal axes of the hyperbola along the coordinate
axes) then answer the following questions.
13.

Locus of P is a
(A) circle

14.

(B) parabola

(C) ellipse

(D) hyperbola

The angle (0, /2) between the two asymptotes of the hyperbola lies in the interval
(A) (0, 15)

(B) (30, 45)

(C) (45, 60) (D) (60, 75)

Paragraph for Question Nos. 15 to 16

x

Let y = f (x) satisfies the equation f (x) = (ex + ex)cos x 2x

( x t ) f ' ( t ) dt .
0

15.

y satisfies the differential equation

(A)

dy
+ y= ex(cos x sin x) ex(cos x + sin x)
dx

(B)

dy
y= ex(cos x sin x) + ex(cos x + sin x)
dx

(C)

dy
+ y= ex(cos x + sin x) ex(cos x sin x)
dx
(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 7

(D)

16.

dy
y= ex(cos x sin x) + ex(cos x sin x)
dx

f (x) as a function of x equals

(A) ex(cosx sinx) +

2
ex
(3 cosx + sinx) + ex
5
5

(B) ex(cosx + sinx) +

2
ex
(3 cosx sinx) ex
5
5

(C) ex(cosx sinx) +

2
ex
(3 cosx sinx) + ex
5
5

(D) ex(cosx + sinx) +

2
ex
(3 cosx sinx) ex
5
5

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 8

[MATCH THE COLUMN TYPE]

Q.17 to Q.20 contains 4 multiple choice questions. Each question has matching list. The codes of list have
choices (A), (B), (C) & (D) out of which only
17.
Column-I
Column-II
(P)

(Q)

(R)

x 2 y2

1
For an ellipse
9
4

(1) 2

with vertices A and A', tangent

drawn at the point P in the
first quadrant meets the y-axis
in Q and the chord A'P meets the
y-axis in M. If 'O' is the origin then
OQ2 MQ2 equals to
If the product of the
perpendicular distances from 2
x
y2
any point on the hyperbola 2 2 1
a
b
of eccentricity e = 3 from
its asymptotes is equal to 6, then the
length of the transverse axis of
the hyperbola is
The locus of the point of

(2) 3

(3) 4

intersection of the lines 3 x y 4 3 t = 0 and

(S)

3 tx + ty 4 3 = 0
(where t is a parameter) is a
hyperbola whose eccentricity is
If F1 & F2 are the feet of the
perpendiculars from the foci
S1 & S2 of an ellipse
is equal to
CODES :
P
(A)
4
(B)
3
(C)
3
(D)
1

Q
3
4
4
2

(4) 6

x 2 y2

=1 on the tangent at any point P on the ellipse, then (S1F1). (S2F2)

5
3
R
1
1
2
3

S
2
2
1
4

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 9

18.

P(0, 3, 2); Q(3, 7, 1) and R(1, 3, 1) are 3 given points. Let L1 be the line passing through
P and Q and L2 be the line through R and parallel to the vector

(P)

Column-I

Column-II

perpendicular distance

(1) 7 3

V i k .

of P from L2
(Q)

shortest distance

(2) 2

between L1 and L2
(R)

area of the triangle PQR

(S)

distance from (0, 0, 0)

(3) 6

to the plane PQR

(4)

19
147

CODES :
P

(A)

(B)

(C)

(D)

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 10

19.

MATCH THE COLUMN

Consider the following linear equations
ax + by + cz = 0
bx + cy + az = 0
cx + ay + bz = 0

Match the conditions/expressions in ColumnI with statements in ColumnII.

ColumnI

ColumnII

(P) a + b + c 0 and
a2+b2+c2

(1) the equation

= ab + bc+ca

represent planes
meeting only at a
single point.

(Q) a + b + c = 0 and
a2+b2+c2

(2) the equation

ab+bc+ca

represent the line

x=y=z

(R) a + b + c 0 and
a2+b2+c2

(3) the equation

ab+bc+ca

represent identical
planes

(S) a + b + c = 0 and
a2+b2+c2

(4) the equation

= ab+bc+ca

represent the
whole of the three
dimensional space.

CODES :
P

(A)

(B)

(C)

(D)

4
(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 11

20.

Column I

Column II

(P) sin 420 cos 390

(1) 0

+ cos (660) sin (330)

(Q) tan 315 cot (405)

(2) 1

+ cot 495 tan (585)

(R) The value of

(3) 2

(1 tan 8 )(1 tan 37 )

=
(1 tan 22 )(1 tan 23 )

2
(S) Value of sin x is
4 3

(4) 5

(where [.] represents greatest integer function)

CODES :
P

(A)

(B)

(C)

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 12

PART - III [CHEMISTRY]

SECTION - A
[STRAIGHT OBJECTIVE TYPE]
Q.1 to Q.10 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1.

An aqueous solution of (C2H5)3N is added slowly to an aqueous solutions of CH3COOH. The

variation in conductivity of this reaction is given as
G

(A)
Eq. Point

Vol. of WB added

(B)
Eq. Point

Vol. of WB added

(C)
Eq. Point

Vol. of WB added

(D)
Eq. Point

Vol. of WB added

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 13

2.

Which aqueous solution exhibits highest boiling point (A) 0.015 M glucose (B) 0.01 M KNO3
(C) 0.015 M urea
(D) 0.01M Na2SO4
a

3.

a
M

NH3 Cl NH
3
M

NH3
NH3
a a
Cl
(I)
(II)
Which of the following is incorrect related to I and II ?
(A) I exhibits geometrical isomerism (B) I exhibits optical isomerism
(C) II exihibits ionization isomerism (D) II exhibits geometrical isomerism
4.

Total vapour pressure of mixture of 1 mol volatile component A(p A = 100 mmHg) and
3 mol of volatile component B (pB = 60 mmHg) is 75 mm. For such case (A) there is positive deviation from Raoults law
(B) boiling point has been lowered
(C) force of attraction between A and B is smaller than that between A and A or between B and B
(D) All the above statements are correct

5.

In borax bead test, a colourless bead becomes coloured on being heated with a colourless metal
salt. This happends due to the formation of
(A) The borate and meta borate of the metal
(B) Boric acid
(C) The orthoborate of the metal
(D) The hexaborate of the metal
What is the minimum concentration of SO42 required to precipitate BaSO4 in a solution
containing 1.0 104 mole of Ba2+ ?
Ksp for BaSO4 = 4 1010
(A) 4 1010 M
(B) 2 107 M
(C) 4 106 M
(D) 2 103 M

6.

7.

Which of the following has been arranged in order of decreasing dipole moment ?
(A) CH3Cl > CCl4>CH2Cl2>CHCl3
(B) CH3Cl > CH2Cl2>CHCl3>CCl4
(C) CH3Cl>CHCl3>CH2Cl2>CCl4
(D) CH3Br>CH3Cl>CH3F>CH3I
(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 14

8.

Which of the following compounds will not show resonance ?

CH3
CH3
C
(A)

CH3

CH3

(B) CH2 = CH CH = CH CH2

H
H

(C)

(D)

9.

When one of the following molecules is expected to exhibit diamagnetic behaviour ?

(A) S2
(B) C2
(C) O2
(D) None

10.

Most stable conformer of given compound is :

CH3 CH3
(A)

CH2 = CH CH C CH3
CH3
CH3 CH3

(B)

CH3 CH = C C CH3
CH3

CH2 CH3
(C)

CH3 CH2 C C CH3

CH3

(D) None of these

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 15

Paragraph for Question Nos. 11 to 12

11.

Type of elimination reaction in which least substituted alkene is major product known as Hofmann's
elimination. Such reaction occur in following conditions.
(X) when base is bulky
(Y) when leaving group is very poor such as fluoride, ammonium group ( N R3 ) etc.
(Z) When alkyl halide contain one or more double bonds.
What is the major product of the following reaction?
CH3

CH3

CH3 CH CH C CH3
Br

Me3CO K

CH3
CH3 CH3

(A)

CH2 = CH CH C CH3
CH3

CH3 CH3
(B)

CH3 CH = C C CH3
CH3

CH2 CH3
(C)

CH3 CH2 C C CH3

CH3

(D) None of these

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 16

CH3
CH2 CH CH CH3

12.

C2H5O

Br

CH3
(A)

CH = CH CH
CH3
CH3

(B)

CH 2CH=C
CH3

CH3
(C)

CH 2CHCH
OC2H5 CH3
OC2H5

(D)

CH2CH2CCH3
OC2H5

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 17

Paragraph for Question Nos. 13 to 14

(P)

KI(aq.)

aq.
NaOH

(Q)
Yellow
ppt.

BaCl2(aq.)

(R)
White
ppt.

NH4OH
(excess)

(T)
Brown ppt.

13.

14.

Solution of (S)

Here compound (P) can be:

(A) AgNO3
(B) Ca(NO3)2

(C) CuSO4

(D) Pb(NO3)2

Here yellow precipitate (Q) is of :

(A) CH3I
(B) CaI2

(C) AgI

(D) PbI2

Paragraph for Question Nos. 15 to 16

A solution of
salt containing 0.4 g of Cu2+ is electrolysed until all the Cu is deposited. The
electrolysis is continued for seven more minutes with the volume of solution kept of 100 ml and the
current at 1.2 ampere. (At. wt. of Cu = 63.6)
Cu2+

15.

Calculate the time in which all the Cu+2 is depositated

(A) 16.88 sec
(B) 16.88 min
(C) 1.67 sec
(D) None

16.

pH of resulting solutio
(A) 2 log12.5
(C) 9

(B) 4
(D) None

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 18

[MATCH THE COLUMN TYPE ]

Q.17 to Q.20 contains 4 multiple choice questions. Each question has matching list. The codes of list have
choices (A), (B), (C) & (D) out of which only
17.

Match the column

Column-I
(A) Rock salt
(B) Zinc blende
(C) Anti-fluorite
(D) CsCl type

Column-II
(P) Fraction of voids occupied = 1/3
(Q) Anions constitute lattice
(R) Cations in tetrahedral voids
(S) Coordination number of cation and
anion is same

(A) APQS ; BPQRS; CQR; DQS

(B) APS;BPQS; CQR; DQS
(C) APR;BPQR; CQR; DQS
(D) APQ; BQS; CQR; DQS

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India

Page # 19

18.

Match the following :

ColumnI

ColumnII
CHO

(A)

(P) Haloform reaction

(B) HCHO

(Q) Fehlings solution

(C) CH3CHO

(R) Cannizzaro reaction

(D) CH3 COCH3

(S) Aldol reaction

(A) APQ ;BQR; CQ, DR

(B) AR; BQR; CQ; DS
(C) AR; BQR; CPQS; DPS
(D) AQ,R; BP; CPQS; DPS
19.

Which of anions in the Column-I shows one or more observations from the column-II.
Column-I

Column-II

(A) [CoF3(H2O)3]

(P) sp3d2

(B) [Fe(edta)]

(Q) d2sp3

(C) [Fe(NH3)6]2+

(R) sp3

(D) [Ni(CN)2(PMe3)3]

(S) dsp2
(T) d3s

(A) AR, BQ, CS, DP

(B) AP, BQ, CR, DS
(C) AP, BQ, CP, DS
(D) AP, BS, CP, DR

(SPACE FOR ROUGH WORK)

Helpdesk 09214233303 (MON - SAT | 9 AM to 6 PM www.etoosindia.com

Page # 20

20.

Match the Column

Column-I

Column-II

(A) w 0

(P) Melting of ice at 0 & 1atm

(B) (G)T,P = 0

(Q) Freezing of CO2() at its melting point

(C) Ssys 0

(R) Reversible adiabatic process of ideal gas

where temperature increases

(D) q 0

(S) Compression of ideal gas at point

constant external pressure isothermally

(A) AQRS, BPQ, CQRS, DQR

(B) ARS, BQ, CQS, DQR
(C) APQS, BPQS, CQRS, DQRS
(D) AS, BPQR, CQRS, DQRS

(SPACE FOR ROUGH WORK)

Corporate Office - 3rd floor H.No 50 Rajeev Gandhi Nagar, Kota Rajasthan 324005, India