Beruflich Dokumente
Kultur Dokumente
1.
(a)
(i)
23
(ii)
in 12.(00)g of C
0.350
2
Moles O2 = 32 (= 1.09 10 mol)
(iii)
= 29 ( 1.09 10 )
[Accept answers via 4 separate mole calculations]
(1)
(= 0.0438 mol)
1
1
(b)
mRT
nRT
V
pV = nRT or pV =
or p = V
0.873 8.31 1100
nRT
1.00 10 3
V
p=
=
1
1
[11]
2.
(a) Na
Cl
21.6
23
33.3
35.5
45.1
16
0.9(39)
0.9(38)
2.8(2)
Hence:
1
1
1
[3]
3.
-3
(i)
(ii)
pV = nRT or n = pV/RT
pV
100000 1.22 10 4
8.31 298
moles O2 = n = RT = (1)
(1)
(i)
(ii)
45.9
39.1
16.5
14
37.6
16 (1)
1.17
1.18
2.35
KNO
(1)
(M3 tied to M2), (M3 can be transferred from equation if ratio correct
but EF not given) (if calc inverted, lose M2 and M3), (if used At N 1 /
wrong No for Ar then CE, lose M2 and M3) (if % of O missing,
award M2 only)
(c)
2 2
(accept 2KNO K N O + O )
Mill Hill High School
4.
0.0343 1000
1
vol HCl =
= 34.3 34.5 (cm3) (unless wrong unit)
2A1+ 3CuCl2
2A1C13 + 3Cu;
(accept multiples/fractions)
5.
OR
2A1+ 3Cu
2+
2A1
3+
+ 3Cu;
1
[1]
6.
(a)
moles HN03
=
175 X 10 1.5 = (0.2625 mol);
moles Pb(NO3 )2 =
0.2625 = (0.131 mol);
Mr Pb(NO3 )2
=
331(.2);
mass Pb(NO3 )2 =
331.2 x 0.131=43.5 g;
(accept 43.2 - 43.8)
(M1 & M2 are process marks. If error in M1, or in M2, do not
mark M4
consequentially, i.e. do not award M4)
(if atomic numbers used in M3, do not award M4)
1
1
1
1
(b)
(i)
pV = nRT;
pV 100000 1.5 10 4
n
RT
8.31 500
;
=
(ii)
3.61 X 10 ;
(If pressure not converted to Pa, max 2)
RT
(If n = pV used = CE; M2 = M3 = 0)
3
molesN02 =
4/5 3.61 10 ;
[mark is for use of 4/5]
3
1
3
= 2.89 10 OR 1.7810 ;
Mill Hill High School
1
3
Mr NO2
46;
1
3
massNO2 =
46 2.89l0
= 0.1.33(g) OR 0.0821 (g);
( if atomic numbers used, M3 = M4 = 0)
1
[11]
7.
(a)
(b)
(i)
(or multiples)
(ii)
Mg
16.2
(24)
16.2
24.3
18.9
14
64.9
16
(0.675)
0.667
1.37
4.06
1
1
1
2
6
MgN2O6
(Mark M1 first. If any wrong Ar used = CE = 0)
(Accept Mg(NO3)2 for M3 if above working shown)
[4]
8.
(a)
100 l0 0.500 =
(ii)
27.3 10 0.600 =
(iii)
1.64 10 (mol)
Mark conseq on (ii)
(iv)
(v)
5.00 10 (mol)
2
1.68 10 l32(.l)
Mark for Mr
or 1.39 10 132(.l)
= 2.22 g
or 1.83 g
n 0.143
17
pV = nRT
pV
T
nR
accept 5 10 / 0.05
(b)
(i)
1
3
8.4(1) 10 (mol)
100000 2.86 10 4
8.31 8.4 10 3
(1)
1
4
[11]
9.
[5]
10.
(a)
77
78 92.3
(b)
78
(CH has empirical mass of 13 and 13 = 6 ) C6H6
Correct answer 1 mark
4
[4]
11.
23
23/6.023 10 (1)
CE = 0 if inverted or multiplied
tied to M1 3.8(2) 10
23
2
[2]
12.
(a)
(b)
[4]
13.
(a)
0240 (1)
0 24
moles TiC14 = 4 = 006 (1)
mass = 006 190 = 114 (1)
(b)
moles NaOH
vol NaOH
moles
= conc (1)
0 12
3
= 1 1 = 109cm (1)
(c)
moles HC1
2
=
= 006 (1)
moles H2
(allow conseq)
nRT
= p (1) or PV = nRT
0 06 8 31 293
98 000
=
(1)
3
= 149 10 m (1)etc
(if chemical error on moles H2, max2) (2)
4
[11]
14.
(a)
10.0
moles of S = 32.1 ( = 0.3125)
10
allow 32 (1)
5.00
34.1
3
3
15.
(a)
(b)
Moles of X:
PV
110000 2.34 10 4
RT (1) =
8.31 473
3
= 6.55 10 (1)
6.5 to 6.6 10
RT
n
PV zero here, but can score Mr
If write
m
Relative molecular mass of X: Mr = n (1)
= 62 (1)
61.5 to 62.5
4
(c)
H = 9.68 / 1
O = 57.6(2) / 16
= 9.68
= 3.23
(1)
CH3O (1)
(d)
62
( 31 CH3O) = C2H6O2 (1)
1
[9]
16.
(a)
mass
19.6
Moles HCl = M r = 36.5 (1) (= 0.537)
0.537
Concentration = 0.25 (1)
3
(b)
21.7
0.263
1000
= 5.7(1) 103 (mol) (1)
(i)
5.7 to 5.71 10
(ii)
5.71 10 3
3
2
= 2.85 10 (mol) (1)
Conseq
(iii)
0.394
2.85 10 3 = 138 (1)
Conseq
(iv)
6
[9]
17.
(a)
1.0078
mass of 1 mol
24
L = 1.6734 10
(1) or mass of 1 atom
must show working
23
= 6.0225 10 (1)
Ignore wrong units
NB answer only scores 1
2
(b)
equal (1)
Or same or 1:1
1
(c)
PV
PV = nRT (or n = RT ) (1)
98000 0.0352
8.31 298
=
(1)
= 1.39 (1)
Allow 1.390 to 1.395
ignore units even if incorrect
answer = 1.4 loses last mark
(d)
1000
3
0.732 250 = 2.93 (1) mol.dm (1)
3
OR M, mol/dm , mol.l
(e)
(i)
25
moles H2SO4 = 1000 1.24 = 0.0310
If use m1v1 = m2v2 scores 3 if answer is correct otherwise zero
3
1000
3
moles of NH3 in 1 dm = 0.620 30.8 = 2.01 (1) (mol dm )
3
(ii)
6
(f)
2
[16]
10
18.
mass of 1 atom of
(a)
12
12 (1)2
(b)
(c)
(i)
%O = 65.7 (1)
(d)
(ii)
C4 H2 O6 (1)
(i)
mass 1000
Mr
16
(1) = 62.5 (1)
0.0625 scores one
(ii)
100000
V= P
(1)
10 m
= 3.
(1)
6
[13]
19.
12
[1]
20.
(a)
Avogadros
(b)
(i)
pV=nRT (1)
nRT
m
P
Mr
allow {V=
etc., pV=
RT
(ii)
nRT
V= P
1 8 31 298
100 000
=
(1)
= 0.0248
m (1)
11
pV
RT
n=
500000 0.005
8.31 273
=
(1)
s
st
two marks
= 1.10mol (1)
(allow 1.1 to 1.11)
Mr (CO2)
= 44 (1)
mass
(allow 4849)
P1V1
3
st
(note can use calculation involving T and 22.4 dm instead of 1 mark requires same accuracy for full marks)
7
(c)
moles HC1
100
= 1000 5.0 = 0.5(0)(mol) (1)
moles H2
moles HC1
2
=
(1) = 0.25 (mol)
mass H2
(d)
(i)
O = 44.4 (1)
38.9
ratio Fe:C:O = 55.8 :
(or 50)
16.7 44.4
12.0 : 16.0 (if use At, CE)
=1:2:4
Fe C2 O4 (1)
(ii)
CO (1)
(mark independent of d (ii))
4
[15]
21.
(a)
moles of NH3
20.0
= 17.0 (1)
moles of HNO3
volume
1.18
= 2 (1)
3
4
12
(b)
(i)
PV
= nRT (1)
PV
95000 0.0500
= RT = 8.31 298
(1)
= 1.92 mol (1)
(ii)
1.92
1.5 (1) 1.28 mol
6
[10]
12
1.99 10 23 [[1] = 6.031023 (1)
22.
2
[2]
23.
(a)
or
81.7g 24 dm O2 (1)
81.7
24
g = 3.4lg 1 dm O2 (1)
24.
(a)
(b)
(c)
(i)
= 1.19 10 m (1)
(ii)
13
0.0384
3
3
vol HCl = 1.2 = 0.032 dm (1) (or 32 cm )
7
[9]
14
25.
percentage by mass of oxygen = 38.0% (1)
ratio of elements = 42.9/12 : 2.4/1 : 16.7/14 : 38.0/16 (1)
= 3.6 : 2.4 : 1.2 : 2.4
empirical formula is C3H2NO2 (1)
molecular formula is C6H4N2O4 (1)
4
[4]
26.
(a)
%H = 18.8 (1)
81.2 18.8
B : H = 10.8 : 1 (1)
= 2 : 5 : B2H5 (1)
(b)
B4H10 (1)
4
[4]
27.
(a)
(b)
= 6.02 10
23 (1)
1
[3]
28.
(b)
(i)
%F
= 428 (1)
I:F
57 2
42 8
= 127 = 19 (1)
= IF5 (1)
(ii)
4
[4]
15
29.
C 22.24/12 = 1.85 H 3.71/1 = 3.71 Br 74.05/79.9 = 0.927 (1)
ratio C:H:Br = 2:4:1 C2H4Br (1)
empirical mass = 107.9 mol formula = 215.8/107.9 C2H4Br = C4H8Br2 (1)
must use % to justify answer
or
C (22.24/100) 215.8 = 47.99 i.e. 48/12 = 4 carbon atoms (1)
H (3.71/100) 215.8 = 8.01 i.e. 8/1 = 8 hydrogen atoms (1)
Br (74.05/100) 215.8 = 159.8 i.e. 159.8/79.9 = 2 bromine atoms (1)
or
C (48/215.8) 100 = 22.24% (1)
H (8/215.8) 100 = 3.71 % (1)
Br (159.8/215.8) 100 = 74.05% (1)
3
[3]
16