Beruflich Dokumente
Kultur Dokumente
05/14/2015
2
What is the minimum energy needed to eject an electron if it is ejected
by a green light photon at 500nm? (have to convert nm to m; multiple by
10=-9)
3.98 x 10-19 J
o c = v
o = hv
o h = 6.626 x 10-34 Js
o c = 3.00 x 108 m/s
A wavelength of 0.325 pm ejects an electron with an energy of 3.035 x
-19
10 J. What is the binding energy for the electron in Joules?
1 pm = 1x10-12 m
Total E = binding E +E of ejected e hc/ = binding E + 3.035 x 10-19 J
6.12 x 10-13 J = binding E
Magnetism
Paramagnetic it has unpaired electrons.
Diamagnetic has all electrons paired.
o Noble gases are not affected by magnetism.
Effective nuclear charge (Zelf) is the positive charge felt by an electron
Zelf =Z ; 0 < < Z ( = shielding constant)
Zelf Z number of inner or core electrons
This increases as you go to the right and down. This has an inverse
reaction to the radius.
Atomic Radii
Metallic radius: two atoms just next to each other. Not a lot of
orbital overlap. Nonbonding Radius.
Covalent Radius: Bonding Radius.
Which element would have the smallest radius? The one in the top
right.
If you add more electrons (ions) the Zelf is going to decrease and
the radius increases. Cations are drawn nearer to the nucleus and
anions are less attractive to the nucleus.
o Cations are always smaller than atom from which it is formed
o Anions are always larger than atom from which it is formed
Electron Affinity: the negative of the energy change that occurs when
an electron is accepted by an atom in the gaseous state tot form an anion.
X (g) + e- X- (g)
F (g) + e- X- (g) H = -328 kJ/mol
EA = +328 kJ/mol
The Halogens have the highest electron affinity
Alkali Metals: Group 1A Elements (ns1, n 2); stored away from air
Red-Ox
Reacts with water to form hydroxide bases
o 2Na(s) + 2H2)(l) 2NaOH(aq) + H2(g)
Oxidation to form metal oxides
Gases
Elements that exist as gases at 25oC and 1 atm
o Hydrogen
o Nitrogen
o Nobles
Physical Characteristics of Gases
Gases assume the volume and shape of their containers
Gases are the most compressible state of matter
Gases will mix evenly and completely when confined to the same
container
Gases have much lower densities than liquids and solids.
Boyles law: P a 1/V (at constant n and T)
Charles law: V a T (at constant n and P)
M = dRT/P
Kinetic Molecular Theory of Gases
A gas is composed of molecules that are separated from each other
by distances far greater than their own dimensions. The molecules
can be considered to be points, that is, they possess mass but have
negligible volume.
Gas molecules are in constant motion in random directions and they
frequently collide with one another. Collisions among molecules are
perfectly elastic.
Gas molecules exert neither attractive nor repulsive forces on one
another
The average kinetic energy of the molecules is proportional to the
temperature of the gas in kelvins. Any two gases at the same
temperature will have the same average kinetic energy.
o KE = m2 = 3/2 nRT
The lighter you are the faster you are flying.
Gas diffusion: the gradual mixing of molecules of one gas with
molecules of another by virtue of their kinetic properties
R1/r2 = sqrt(M2/M1)
Gas effusion: the process by which gas under pressure escapes from
one compartment of a container to another by passing through a small
opening.
Deviations from ideal behavior 1 mole of ideal gas. As the pressure
increases you see a deviation from the ideal gas
o Hydrogen bonding
o Ion-dipole forces
The strength of the intermolecular forces determines the physical
properties at a given temperature.
Intermolecular Forces
London Dispersion Forces
Very weak interactions due to the momentary changes in electron
density in a molecule
The change in electron density creates a temporary dipole
All covalent compounds exhibit London dispersion forces
The larger the molecule, the larger the attractive force, and the
stronger the intermolecular forces
The more polarizable the molecule, the greater the London
dispersion forces
Polarizability is the ease with which the electron distribution in the
atom or molecule can be distorted
Increase with:
o Greater number of electrons
o More diffuse electron cloud
Attractive forces between polar molecules
Positive to negative
Dipole-dipole interactions are the attractive forces between the
permanent dipoles of two polar molecules
Pa = (naRT)/V
Pb = (nbRT)/V
Pt = Pa + Pb
Molarity M = moles of solute/ liters of solution
Molality m = moles of solute/ mass of solvent (kg)
Colligative properties: depend only on the number of solute particles in
solution and not on the nature of the solute particles.
Van Hoff Factor
Boiling Point Elevation Tb = iKbm
Freezing Point Depression Tf = iKfm
Osmotic Pressure () = iMRT