Beruflich Dokumente
Kultur Dokumente
356
Archaeological background
357
358
359
b
Fig. 4a and b The layered structure of the beads is best visible when
parts of the outer layer are missing. The inner core shows characteristic
longitudinal fibrous striations, whereas the outer layer is much more
homogeneous. The silver layer is not visible any more on these two
beads but on the bead on fig. 4b (lower picture edge corresponds to
1.7 cm (a) and 2 cm (b) (S. Greiff, RGZM).
360
17.
18.
19.
20.
21.
361
28.
29.
30.
31.
See n. 24.
Ibid.
See n. 23.
R. Andrae, Mosaikaugenperlen. Untersuchungen... cit. n. 21,
p. 158.
32. M. Spaer, Gold-glass beads... cit. n. 1, p. 18.
33. G. C. Boon, Gold-in-glass beads from the Ancient World, in
Britannia, 8, 1977, p. 193-207, spec. p. 201.
34. For analyzing the bulk composition of the glass and the
metal layers we chose a Micro-XRF-system by
Roentgenanalytik Messtechnik GmbH (Taunusstein,
Germany), thus limiting the level of destruction of the
original substance. The system used is an Eagle III XXL
with an extra large sample chamber measuring
0,75 0,75 1,35 m. The device is equipped with a
Rhodium tube, with options for measurement in air or
vacuum and a nitrogen-cooled Oxford EDAX-system with a
Instrumentation
All analyses have been performed with a MicroX-ray-fluorescence technique Micro-XRF,
equipment especially designed for the investigation
of small spots on large samples 34. The X-ray beam is
reduced to a spot size of 0.3 mm, thus allowing
localized chemical analysis of very small patches of
material like the tiny rests of corroded metal foil on
the Albanian beads. In the case of the metal foils a
mere qualitative identification of the metal was
sufficient. For a reliable interpretation of glass
compositions used, we needed a full quantitative
analysis the compounds usually to be found in
antique glasses. For the purpose of quantification
the intensity of any chemical element gained from
the bead glasses is calculated against the intensity
of reference standard glasses with known
compositions 35. Glass corrosion effects the chemical
composition of excavated glassware lowering
sodium contents and rising silicon dioxide values,
362
The foils
Both the inherent structure of the core
material and the formation of corrosion layers on
the glass layers make it difficult to judge whether a
segmented bead was decorated by a metal foil or
not. Glass corrosion layers would reflect incident
light like metal leaf does. In the case of silver foil
the corrosion of the metal itself is a problem
(fig. 5). The adsorption of more or less opacifying
mobile soil compounds into the layered structure
Fig. 6 All foil particles investigated were made from silver as visible from the XRF-spectrum (peak labelled AgLa). The presence of iron and manganese
is due to the intrusion of soil fluids into the layered structure (S. Greiff).
363
Analytical results
Metal foils
In some cases, the metal layer was partly
exposed because the outer glass shell was
incomplete from the beginning or due to damage
during burial or after excavation. Around half a
dozen analyses of metal layers could be
accomplished. All results showed that silver had
been used (fig. 6). None of the beads carried a gold
foil as already indicated by the optical inspection
under the microscope.
Beside silver, some elements occur in the
XRF-spectrum that are specific for soil
constituents migrating into the sandwich
structure of the bead. During burial, silver turns
into silver chloride AgCl. Iron Fe and
manganese Mn are ions typical for soil fluids
and are absorbed on corroding surfaces on buried
artefacts of all kinds. Due to pronounced
corrosion it was not possible to attain quantitative
results from the silver.
Glass layers
Core and outer layer were analyzed separately.
The results are given in table 1.
Na2O
MgO
Al2O3
SiO2
P2O5
SO3
K 2O
CaO
TiO2
MnO
FeO
CuO
SrO
ZrO
Sample
D, St1
E, St3
Core
Core
15,29
15,77
3,55
3,88
2,98
3,03
65,90
64,95
0,21
0,24
0,29
0,37
2,98
2,76
6,10
6,05
0,12
0,12
1,70
1,94
0,81
0,82
0,01
0,00
0,04
0,05
0,01
0,02
F, St1
H, St1
Core
Core
14,99
13,78
3,98
3,70
3,53
3,52
64,46
66,51
0,27
0,29
0,23
0,24
2,81
2,77
6,06
5,69
0,16
0,12
2,37
2,39
1,06
0,91
0,01
0,01
0,04
0,05
0,01
0,02
I, St1
J, St4
Core
Core
15,64
10,91
3,93
4,38
2,98
2,53
65,30
72,61
0,24
0,19
0,27
0,36
2,65
2,14
6,39
5,68
0,14
0,08
1,52
0,53
0,87
0,53
0,01
0,01
0,04
0,04
0,02
0,01
K, St1
L, St2
Core
Core
16,04
14,90
3,75
3,81
3,11
3,07
65,24
64,69
0,23
0,27
0,27
0,31
2,52
2,51
6,30
7,06
0,12
0,14
1,49
2,23
0,86
0,92
0,01
0,01
0,04
0,04
0,02
0,02
D, St2
Outer layer
15,96
3,83
3,25
65,56
0,22
0,23
2,89
6,46
0,13
0,58
0,83
0,01
0,04
0,02
E, St1
E, St2
Outer layer
Outer layer
13,18
18,16
2,69
4,62
7,26
2,86
52,18
62,14
8,28
0,28
0,23
0,33
1,65
2,40
6,67
6,42
0,37
0,16
1,47
1,52
5,93
1,06
0,02
0,00
0,05
0,04
0,02
0,02
F, St3
F, St4
Outer layer
Outer layer
10,91
11,37
4,15
3,15
4,05
4,48
70,18
71,01
0,43
0,28
0,42
0,25
2,55
3,47
4,08
4,40
0,12
0,11
2,22
0,79
0,81
0,61
0,03
0,01
0,04
0,05
0,02
0,01
K, St2
N, St1
Outer layer
Outer layer
15,36
16,34
4,10
4,23
3,28
2,77
65,87
63,43
0,20
0,34
0,23
0,31
2,88
2,72
6,37
7,06
0,14
0,11
0,62
1,86
0,85
0,75
0,04
0,01
0,04
0,06
0,02
0,02
C, St1
C, St1b
Outer layer
Outer layer
15,64
16,49
4,83
5,10
1,93
1,93
66,20
65,26
0,15
0,19
0,33
0,36
2,38
2,33
6,77
6,60
0,11
0,11
0,85
0,83
0,71
0,70
0,01
0,01
0,05
0,05
0,02
0,02
364
365
Haithabu
The Viking Age settlement has been published
in great detail. 15% of the whole bead material
consists of foiled beads, some segmented, some
belong to the hollow type which is rare among the
Bukl samples plain segmented beads without
foil not included 46. Analyses of segmented beads
from the site have been published by
M. Dekwna 47. Like in the case of Borovce, some
of the samples yield higher PbO-contents around
2%, whereas the other components fit in the
general picture of a plant-ash glass.
Roman examples
A few Roman examples of gold-foil beads have
been analyzed. One example comes from
Caerleon in Wales and has been analyzed by
M. Dekwna 48 the other two are from Faras and
Panticapaeum. All three examples come from 2nd
to 3rd century contexts and all belong to the same
glass family of soda-glasses with mineral soda as a
flux. This was the predominant glass type of the
366
Fig. 7 The analytical results of the Albanian beads (red stars) together with reference data of other segmented beads taken from the literature
(magnesium oxide vs. calcium oxide). The areas of the different fluxes are given for comparison. It is obvious that all post-Roman segmented beads
are produced with plant-ashes (S. Greiff).
367
368
Fig. 8 The values for MgO and K2O were used by I. C. Freestone (see footnote 41) to define sub-groups of plant-ash glasses. The Albanian beads
fall into the field of Sassanian plant-ash recipes, as most literature data of segmented beads do (S. Greiff).
53. St. John Simpson, Sasanian beads : the evidence of art, texts and
archaeology, in I. C. Glover, H. H. Brock and J. Henderson
(ed.), Ornaments from the past-beads studies after Beck, London,
2003, p. 59-73, spec. p. 67.
54. See M. Jnsson, P. Hunner, Golf foil beads, in M. Rasmussen,
369
Fig. 9 X-ray radiograph from a choice of the beads from Bukl. The rather narrow string holes run through the length of the bead often limited by a
very fine light rim which corresponds to the iron-rich layer lining the holes (D. Bach, Winterbach).
Fig. 10 The outer layer could be lifted off and its thickness measured
(0.05-0.07 mm). The faint striations are the negative imprints inherited
from the striated inner core (lower picture edge corresponds to 0.9 cm)
(S. Greiff).
370
Fig. 11a This beads end was flattened by grinding thus exhibiting the difference between the clear outer glass skin and the structure of the
inhomogeneous core (lower picture edge corresponds to 0.9 cm); Fig. 11b : The outer layer of this bead shows only a few rounded bubbles (lower
picture edge corresponds to 1.1 cm) (S. Greiff).
371
Fig. 14 This bead differs from the majority of segmented beads by its
more homogeneous core and the fire-rounded rim of the outer skin
(lower picture edge corresponds to 1.35 cm) (S. Greiff).
372
373
perforation and its high absorption capacity for Xrays, it seems quite safe to assume the use of some
instrument like a point or a tapered wire probably
made of iron at least for the last step of
production. The surface of the iron was probably
kept in a corroded state so that the loose corrosion
products acted as a separator on heating. Brick
dust or a clay suspension used by modern bead
makers for a better separation of the finished bead
from the winding wire was not necessary 66.
Whether the next production step would be
the shaping into the rounded segments or if this
step is the last one to follow is not quite clear from
the evidence. At some time during the production
process, the Albanian beads were covered by
metallic silver. The extreme fineness of the metal
layers makes it difficult to imagine how molten
metal would cover the core in such a thin even
skin. Surface tension of a metal melt is so high
that coalescing is more probable than a
spontaneous coating of the core. The application
of metal as a foil seems to be more simple and
economic. The rough and striated structure of the
core offers a surface suitable to hold the thin foil in
place and acts as a good support for the silver
layer. A drying oil could be helpful for fixing, but
it is not absolutely necessary in order to achieve a
satisfactory result.
M. Spear suggests the two-tube process as the
most probable way of production. The evidence of
the Albanian beads from Bukl does not support
this model, but rather the application of glass
powder on the foiled surface with subsequent
careful heating or the dipping into some molten
glass. This conclusion here is based on the
observation that gas inclusions in the outer glass
layers are not elongated in a way that they are in
drawn glasses (see fig. 11b). Another hint is the
fineness of the outer glass layer which amounts
often to only a fraction of one mm. As even the
374
Fig. 15 The silver layer often did not cover the whole body of the
bead. Straight edges reveal that indeed a foil was applied instead of
immersing the core into molten metal (lower picture edge corresponds
to 0.9 cm) (S. Greiff).
375