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1. Scope
1.1 This test method covers the determination of moisture in
the analysis sample of coal or coke. It is used for calculating
other analytical results to a dry basis. When used in conjunction with the air drying loss as determined in accordance with
Method D2013 or Practice D346, each analytical result can be
calculated to an as-received basis:
1.2 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:2
D346 Practice for Collection and Preparation of Coke
Samples for Laboratory Analysis
D2013 Practice for Preparing Coal Samples for Analysis
D3180 Practice for Calculating Coal and Coke Analyses
from As-Determined to Different Bases
D3302 Test Method for Total Moisture in Coal
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D3173 11
TABLE 1 Precision
Coal
Coke
Range
Repeatability
Limit
(r)
Reproducibility
Limit
(R)
1.0 21.9 %
0.181.87%
0.09 + 0.01xA
0.08
0.23 + 0.02xA
0.24
(1)
where:
A = grams of sample used and
B = grams of sample after heating.
10. Precision and Bias3
FIG. 2 Capsule for Use in Determining Moisture
10.1 PrecisionThe precision of this method for the determination of moisture in the analysis sample of coal and coke is
shown in Table 1 and Table A1.2. The precision characterized
by repeatability (Sr, r) and reproducibility (SR, R) is described
in Table A1.1 in Annex A1.
10.1.1 Repeatability Limit (r)The value below which the
absolute difference between two test results calculated to
separate consecutive test determinations, carried out on the
same sample in the same laboratory, by the same operator,
using the same apparatus on samples taken at random from a
single quantity of homogenous material, may be expected to
occur with a probability of approximately 95%.
10.1.2 Reproducibility Limit (R)The value below which
the absolute difference between two test results, carried out in
different laboratories, using samples taken at random from a
single quantity of material that is as nearly homogenous as
possible, may be expected to occur with a probability of
approximately 95%.
3
An interlaboratory study, designed consistent with Practice E691, was conducted in 1995. Twelve labs participated. Supporting data have been filed at ASTM
International Headquarters and may be obtained by requesting Research Report
RR:D05-1020. In addition, information for coke was calculated per Practice E 691
using 48 sets of data for 24 coke samples from a commercially available
inter-laboratory proficiency test program. The cokes used in this study included
furnace coke, foundry coke and coke breeze. Details and supporting information are
given in Research Report RR:D05-1039 .
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D3173 11
10.2 BiasCertified Reference Materials are not available
for the determination of bias by this test method.
NOTE 1One coke sample was analyzed in the interlaboratory study
which generated the first row of information in Table 1. The average
moisture of the coke sample was 0.36 %. The repeatability limit for this
sample is 0.10. The reproducibility limit for this sample is 0.15. The
repeatability standard deviation for this sample is 0.036. The reproducibility standard deviation for this sample is 0.053.
ANNEX
(Mandatory Information)
A1. PRECISION STATISTICS
NOTE 1The R-Squared statistic for both the repeatability (r) and
reproducibility (R) indicates that the model as fitted explains 62% of the
variability in the two variables.
Material
Average
Sr
SR
91-2Ivb
91-1 hvAb
91-5 hvAb
89-4 hvCb
91-4 hvCb
90-1 subB
89-7 subA
91-6 subA
89-6 subC
0.9683
1.5689
3.1178
5.4428
9.6392
11.9
12.4556
15.1753
21.9461
0.0479
0.0569
0.0559
0.0601
0.0636
0.1252
0.0798
0.0577
0.1949
0.0853
0.1387
0.0977
0.1408
0.1004
0.2193
0.1188
0.1737
0.2843
0.1341
0.1593
0.1564
0.1682
0.1781
0.3505
0.2234
0.1615
0.5456
0.2388
0.3884
0.2736
0.3943
0.2811
0.614
0.3326
0.4865
0.796
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D3173 11
TABLE A1.2 Repeatability (Sr, r) and Reproducibility (SR, R)
Parameters Used for Calculation of Precision Statement for Coke
Samples
Material
CK980108 - Furnace
CK980312 - Furnace
CK980716 - Foundry
CKReference2 - Furnace
CKNIST01 - Foundry
CKNIST02 - Furnace
CK0303 - Foundry
CK9903 - Foundry
CK9904 - Furnace
CK0001 - Furnace
CK0401 - Furnace
CK0002 - Breeze
CK0302 - Breeze
CK0003 - Foundry
CK0101 - Furnace
CK0504 - Furnace
CK0701 - Furnace
CK0102 - Furnace
CK0301 - Furnace
CK0404 - Furnace
CK0103 - Furnace
CK0304 - Furnace
CK0601 - Furnace
CK0903 - Furnace
CK0104 - Furnace
CK0503 - Furnace
CK0201 - Furnace
CK0501 - Furnace
CK0802 - Furnace
CK0904 - Furnace
CK0202 - Furnace
CK0502 - Furnace
CK0603 - Furnace
CK0203 - Furnace
CK0403 - Furnace
CK0604 - Furnace
CK0801 - Furnace
CK0204 - Breeze
CK0402 - Breeze
CK0602 - Breeze
CK0704 - Breeze
CK0702 - Furnace
CK0902 - Furnace
CK0703 - Coke
CK0803 - Furnace
CK0804 - Furnace
CK0901 - Coke
CK1001 - Furnace
Average
Sr
SR
0.19
0.30
0.27
0.18
0.57
0.30
0.75
0.50
0.65
0.44
0.58
0.46
0.55
0.31
0.19
0.28
0.29
0.33
0.34
0.50
1.04
1.49
1.54
1.87
0.20
0.35
0.51
0.59
0.72
0.77
0.35
0.46
0.53
0.21
0.24
0.23
0.18
0.60
0.72
0.72
0.81
0.64
0.91
1.68
0.43
0.44
0.27
0.29
0.04
0.05
0.03
0.03
0.04
0.03
0.03
0.04
0.03
0.03
0.03
0.02
0.04
0.02
0.02
0.04
0.02
0.04
0.01
0.02
0.03
0.02
0.03
0.07
0.01
0.02
0.03
0.03
0.02
0.03
0.02
0.02
0.04
0.02
0.02
0.03
0.02
0.04
0.04
0.03
0.02
0.06
0.04
0.04
0.02
0.02
0.03
0.03
0.08
0.15
0.10
0.11
0.09
0.06
0.06
0.10
0.10
0.07
0.10
0.15
0.05
0.08
0.08
0.08
0.08
0.10
0.08
0.07
0.30
0.10
0.05
0.08
0.08
0.06
0.08
0.13
0.08
0.08
0.13
0.11
0.08
0.08
0.07
0.09
0.05
0.19
0.10
0.14
0.08
0.24
0.18
0.11
0.10
0.06
0.06
0.11
0.12
0.13
0.08
0.09
0.13
0.09
0.09
0.10
0.08
0.09
0.07
0.04
0.10
0.07
0.04
0.10
0.06
0.10
0.04
0.06
0.07
0.06
0.08
0.18
0.04
0.06
0.08
0.08
0.05
0.08
0.06
0.06
0.10
0.05
0.06
0.07
0.06
0.10
0.12
0.07
0.05
0.18
0.11
0.11
0.06
0.06
0.09
0.09
0.22
0.41
0.29
0.30
0.24
0.18
0.16
0.29
0.27
0.21
0.30
0.42
0.13
0.24
0.23
0.23
0.24
0.29
0.23
0.21
0.84
0.27
0.14
0.23
0.23
0.17
0.22
0.36
0.23
0.24
0.36
0.32
0.23
0.24
0.20
0.26
0.14
0.54
0.27
0.40
0.22
0.67
0.50
0.30
0.28
0.17
0.18
0.30
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