Supplementary Information PDF

1
Supplementary Information: PAH and OPAH Air and Water Exchange
during the Deepwater Horizon Incident
3
4
Lane G. Tidwell, Sarah E. Allan, Steven G. OConnell, Kevin A. Hobbie, Brian W. Smith, Kim A.
Anderson*.
5
6
Table of Contents:
Table 1.pg.S2
List 1pg.S2
List 2pg.S2-S3
10
Air concentration calculationpg.S3
11
Figure S1: Individual PAH in air....pg.S4-S6
12
Figure S2: Alkylation profiles of selected PAH......pg.S7
13
Figure S3: Individual OPAH in air and water.pg.S8-12
14
PCA Explanationpg.S12
15
Table 2: Individual PAH flux,.pg.S13-20
16
Table 3: PAH and OPAH LOD and LOQ ......pg.S21
17
Table 4: Concentrations OPAH in crude oilpg.S22
18
19
20
21
22
23
24
25
S1
26
27
Table 1: Sampling events and durations

May 2010
June-1
June-2
July
August
September
Winter
February
March
April
May 2011
May 10-13, 2010

June 8-11, 2010
June 11-July 7, 2010
July 7-August 5, 2010
August 5-September 8, 2010
September 8-October 13, 2010
October 13, 2010 February 9, 2011
February 9-March 15, 2011
March 15-April 25, 2011
April 25-April 29, 2011
April 29-June 8, 2011
28
29
30
31
32
33
Table 1: Sampling deployment times varied throughout the study due to scientific and logistical
considerations including degree of nearshore and shoreline oil, travel, weather, and site
accessibility. Because performance reference compounds were used to determine in situ uptake
rates to calculate water and air concentrations, a wide range of deployment times were feasible
and data from different deployment periods are directly comparable.
34
List 1: 33 PAH analyte method compounds
35
36
37
38
39
40
41
naphthalene, 1-methylnaphthalene, 2-methylnaphthalene, 1,2-dimethylnaphthalene, 1,6dimethylnaphthalene, acenaphylthene, acenaphthene, fluorene, dibenzothiophene, phenanthrene,
1-methylphenanthrene, 2-methylphenanthrene, 3,6-dimethylphenanthrene, anthracene, 2methylanthracene, 9-methylanthracene, 2,3-dimethylanthracene, 9,10-dimethylanthracene,
flouanthene, pyrene, 1-methylpyrene, retene, benz(a)anthracene, chrysene, 6-methylchrysene,
benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(e)pyrene, benzo(a)pyrene, indeno(1,2,3c,d)pyrene, dibenz(a,h)anthracene, benzo(g,h,i)perylene and dibenzo(a,l)pyrene.
42
43
44
Deuterated performance reference compounds (PRC): fluorene-D10, p,p-DDE-D8, and

benzo(b)fluoranthene-D10. Maximum differences between PRC log kow and target PAH and
OPAH log kow in water samples was 1.2 and 2.8 respectively.
45
46
47
The deuterated surrogate recovery standards: naphthalene-D8, acenaphthylene-D8,

phenanthrene-D10, fluoranthene-D10, pyrene-D10, benzo(a)pyrene-D12 and
benzo(g,h,i)perylene. Perylene-D12 was used as the instrumental internal standard.
48
List 2: 22 OPAH analyte method compounds
49
50
51
6H-benzo[cd]pyreneone, 1,4-phenanthrenedione, 1,4-benzo[c]phenanthrenequinone, 9fluorenone, 9,10-anthraquinone, 1,9-benzanthrone, benzo[a]pyrene-1,6-dione, benzo[a]pyrene7,8-dione, 1,4-benzoquinone, chromone, 9,10-phenanthrenequinone, 5,12-naphthacenequinone,
S2
52
53
54
benz[a]anthracene-7,12-dione, xanthone, 1,2-napthoquinone, 1,4-naphthoquinone,

perinaphthenone, pyrene-4,5-dione, aceanthrenequinone, benzo[a]fluorenone, 1,2acenaphthenequinone, 2-ethyl-9,10-anthraquinone, cyclopenta[def]phenanthrenedione.
55
56
Deuterated surrogate recovery standards: 9,10-anthraquinone-D8 and 9-fluorenone-D8. The

internal standard was 2-fluoro-fluorenone-13C.
57
Air concentration calculation.
58
59
60
61
62
63
64
65
66
67
68
Environmental vapor phase air concentrations were determined using an empirical

uptake model with sampling rates derived by measuring PRCs loss as described in Huckins et al.
2006.1 PRCs allow for an accurate assessment of in situ uptake rates for a wide range of analytes
under environmental conditions including variable wind speeds, temperatures and humidity
levels.2-4 The uptake calculation makes no assumptions about the analyte being at equilibrium or
in the linear uptake range, we used this model for air and water calculations for all compounds.
PRCs all share similar physical chemical properties with the analytes of interest in this study and
spanned a range of log Koa values from 6.58 to 10.35.3 Maximum differences between PRC log
koa and target PAH and OPAH log koa in air samples was 2.9 and 0.72 respectively. This
extrapolation is quite modest and well supported by the PRC literature.1-2 Air concentrations of
PAHs and oxygenated PAHs (OPAHs) were determined by:
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84

V (1expV )
Eq. 1
Where Ca is the air concentration, Nanalyte is the mass of the compound of interest present in the
sampler, Vs is the sampler volume, Ksa is the sampler-air partition coefficient and is calculated
for each target analyte and PRC using a regression based on individual octanol-air partition
coefficients (Koa), Rs is the compound specific sampling rate, and t is the duration of sampling.
The sum of the vapor phase air concentrations of all 33 PAH analytes considered in this study
are denoted as 33air PAH. The sum of the vapor phase air concentrations and dissolved phase
water concentrations of all 22 OPAH analytes considered in this study are denoted as
22airOPAH and 22waterOPAH.The sampling rates of the PRCs were determined by using
equation 2.
=
ln( )
Eq. 2
Where N0 and N is the amount of PRC at the beginning and ending of sampling respectively.
The sampling rate Rs for individual analytes were calculated based on the Rs of the PRC with the
most similar Koa. By employing eq 3 from Huckins et al. 2006, a values can compensate for
compound-specific adjustments between the PRC and the target analyte.
, = ,
S3
Eq. 3
85
Figure S1: Individual PAH concentrations
Louisiana
5
4.5
PAHs ng/m in air
4
3.5
3
2.5
2
1.5
1
0.5
0
86
Mississippi
7
PAHs ng/m in air
6
5
4
3
2
1
0
87
88
S4
89
Figure S1 continued: Individual PAH concentrations
Alabama
2
1.8
PAHs ng/m in air
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
90
Florida
2.5
PAHs ng/m in air
2
1.5
1
0.5
0
91
92
S5
93
Figure S1 continued: Individual PAH concentrations
94
95
96
97
Figure S1: Individual parent PAH concentrations at four sampling sites across all time points in
the Gulf of Mexico. Individual concentrations are shown from left to right in the same order as
they are listed in the key.
98
99
100
101
102
103
104
105
106
107
108
S6
109
Figure S2: Selected PAH alkylation profiles
110
111
112
113
114
115
Figure S2. Alkylation profiles of phenanthrene and naphthalene. Profiles are predominantly
mixed. Evidence of petrogenic signature of phenanthrene in Grand Isle, LA during June-1
sampling.
S7
116
Figure S3: Individual OPAH concentrations
700
Louisiana
OPAH ng/L water
600
500
400
300
200
100
0
117
Louisiana
0.8
OPAHs ng/m^3 air
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
118
119
S8
120
Figure S3: Individual OPAH concentrations
400
Mississippi
350
OPAH ng/L water
300
250
200
150
100
50
0
121
Mississippi
3
OPAHs ng/m^3 air
2
2
1
1
0
122
123
S9
124
Figure S3 continued: Individual OPAH concentrations
Alabama
700
OPAH ng/L water
600
500
400
300
200
100
0
125
Alabama
0.25
OPAHs ng/m^3 air
0.2
0.15
0.1
0.05
0
126
127
S10
128
Florida
100
90
OPAH ng/L water
80
70
60
50
40
30
20
10
0
129
Florida
30
OPAHs ng/m^3 air
25
20
15
10
5
0
130
131
S11
132
133
134
135
Figure S3: Individual OPAH in air and water concentrations for four sampling sites across the
Gulf of Mexico.
136
PCA explanation
137
138
139
140
141
142
143
144
145
PCA using profile data was performed using PRIMER-E version 6.1.13. Profile analyte data
express the percent contribution of each analyte to the total for each sample. PCA is a multivariant variable reduction technique where principal components (PCs) are calculated as
combinations of the original variables to express the maximum total variation with a few
uncorrelated PCs. This modeling approach has been applied to many PAH fingerprinting and
allocation studies.5, 6 Assessment of samples using this approach allowed for recognition of
spatial and temporal trends in the chemical profile of Gulf of Mexico air that were not elucidated
by other data analysis tools. PCA loading vector plots show the direction of increase of the
individual analytes, as percentages, in terms of the first two principle components.
146
147
148
149
150
151
S12
152
Table 2: Individual PAH flux

Sampling
Location
event
May 2010
June -1
June -2
July
August
153
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
Compound
Air
ng/m
Water
ng/L
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1,2,3-c,d)pyrene
Dibenz(a,h)anthracene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
1.000
0.233
0.325
0.473
0.175
0.121
0.043
0.015
BDL
BDL
BDL
BDL
BDL
0.018
BDL
0.094
2.300
0.541
0.725
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.007
bdl
0.030
0.321
0.520
0.294
BDL
BDL
BDL
BDL
BDL
BDL
BDL
X
X
X
X
X
X
X
X
X
X
X
X
X
0.004
BDL
0.007
0.055
0.568
0.163
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.110
BDL
BDL
4.294
0.810
0.482
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
3.758
22.174
1.951
4.256
BDL
17.741
0.754
0.784
BDL
BDL
BDL
1.100
BDL
0.366
2.056
BDL
14.807
BDL
69.732
0.652
0.581
BDL
BDL
BDL
X
X
X
X
X
X
X
X
X
X
X
X
X
1.808
0.321
0.409
1.523
1.126
1.233
0.152
3.809
0.369
0.047
0.463
0.031
0.023
Water
Wind speed
Air temperature
temperature
m/s AVE
K
K
(max,min)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
299 (301,298)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
303 (305,302)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
300 (306,298)
X
X
X
X
X
X
X
X
X
X
X
X
X
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
302 (308,298)
301 (303,300) 4.5 (6.8,2.8)

301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
301 (303,300) 4.5 (6.8,2.8)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
06.5 (308.8,3052.8 (6.2,0.5)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
305 (311,301) 3.1 (7.5,0.1)
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
305 (308,301) 3.7 (8.7,0.1)
S13
Kw
Ka
MTC
Flux
SD
2.05E+00
2.07E+00
2.08E+00
2.05E+00
1.97E+00
2.03E+00
2.15E+00
1.96E+00
1.91E+00
1.91E+00
2.15E+00
1.91E+00
1.87E+00
9.79E-01
1.04E+00
1.05E+00
1.03E+00
1.04E+00
9.46E-01
1.09E+00
9.73E-01
9.41E-01
9.41E-01
1.09E+00
9.46E-01
9.21E-01
1.23E+00
1.24E+00
1.25E+00
1.23E+00
1.17E+00
1.21E+00
1.30E+00
1.16E+00
1.12E+00
1.12E+00
1.30E+00
1.13E+00
1.10E+00
X
X
X
X
X
X
X
X
X
X
X
X
X
1.55E+00
1.56E+00
1.58E+00
1.55E+00
1.56E+00
1.54E+00
1.64E+00
1.47E+00
1.43E+00
1.43E+00
1.64E+00
1.44E+00
1.40E+00
4.86E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.56E-03
5.86E-03
8.97E-02
5.31E-01
1.69E+00
5.31E-01
2.78E+00
1.57E-03
5.63E-02
5.63E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
4.85E+00
2.76E+00
1.68E+00
5.28E-01
8.91E-02
8.91E-02
5.60E-02
5.60E-02
9.36E-03
9.36E-03
9.36E-03
1.56E-03
5.84E-03
X
X
X
X
X
X
X
X
X
X
X
X
X
4.83E+00
2.76E+00
1.67E+00
5.26E-01
2.76E+00
8.88E-02
5.58E-02
5.58E-02
9.33E-03
9.33E-03
9.33E-03
1.55E-03
5.82E-03
1.44E+00
1.18E+00
9.31E-01
4.21E-01
8.55E-02
8.56E-02
5.47E-02
5.46E-02
9.34E-03
9.34E-03
9.35E-03
1.56E-03
5.84E-03
8.52E-01
7.57E-01
6.47E-01
3.51E-01
8.21E-02
8.24E-02
5.36E-02
5.33E-02
9.33E-03
9.33E-03
9.34E-03
1.57E-03
5.84E-03
9.79E-01
8.54E-01
7.15E-01
3.69E-01
8.27E-02
8.30E-02
5.37E-02
5.34E-02
9.28E-03
9.28E-03
9.29E-03
1.56E-03
5.81E-03
X
X
X
X
X
X
X
X
X
X
X
X
X
1.18E+00
9.98E-01
8.11E-01
3.93E-01
8.37E-02
8.39E-02
5.39E-02
5.38E-02
9.27E-03
9.27E-03
9.27E-03
1.55E-03
5.79E-03
1436.0
0.0
0.0
-665.4
-189.8
-111.7
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2422
7388
29.4
174.9
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1077
0.0
258.5
701.9
0.0
1156
0.0
0.0
0.0
0.0
0.0
0.0
0.0
X
X
X
X
X
X
X
X
X
X
X
X
X
2125
0.0
331.1
588.1
-47.1
62.9
0.0
0.0
0.0
0.0
0.0
0.0
0.0
96.6
0.0
0.0
-465.8
-88.7
-53.3
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
162.3
5179.6
13.7
83.5
0.0
0.0
0.0
0.0
0.0
0.0
0.0
72.2
0.0
17.3
491.8
0.0
552.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
X
X
X
X
X
X
X
X
X
X
X
X
X
142.4
0.0
22.2
412.1
-22.0
30.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
154
Table 2: Continued
Sampling
Location
event
September
Feburary
March
April
May 2011
155
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
LA
Compound
Air
ng/m
Water
ng/L
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
0.015
0.013
0.062
0.522
0.891
0.703
BDL
0.070
BDL
BDL
BDL
BDL
BDL
X
X
X
X
X
X
X
X
X
X
X
X
X
0.007
BDL
0.008
0.110
0.883
0.650
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.105
BDL
0.130
1.360
3.453
2.356
0.663
BDL
BDL
BDL
BDL
BDL
BDL
0.005
0.011
0.034
0.278
1.004
0.710
0.054
0.077
BDL
BDL
BDL
BDL
BDL
1.468
0.240
0.292
0.914
0.975
0.934
0.118
1.753
0.134
0.040
0.063
BDL
BDL
X
X
X
X
X
X
X
X
X
X
X
X
X
1.587
0.329
0.278
0.674
0.586
0.545
0.042
0.733
0.064
0.012
BDL
BDL
BDL
0.757
0.261
0.250
0.731
0.545
0.439
0.089
0.480
0.029
BDL
BDL
BDL
BDL
1.009
0.336
0.229
0.477
0.353
0.297
0.029
0.198
0.023
0.005
BDL
BDL
BDL
Water
Air temperature
temperature
K
K
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
300 (306,291) 301 (306,294)
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
296 (302,287) 298 (302,292)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
299 (301,292) 300 (301,298)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
297 (307,290) 298 (305,296)
S14
Wind speed
m/s AVE
(max,min)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
3.7 (9.1.0.1)
X
X
X
X
X
X
X
X
X
X
X
X
X
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
4 (14,0.2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
6 (12,2)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
4 (12,0.1)
Kw
Ka
MTC
Flux
SD
1.53E+00
1.54E+00
1.57E+00
1.53E+00
1.46E+00
1.51E+00
1.61E+00
1.45E+00
1.41E+00
1.41E+00
1.61E+00
1.41E+00
1.38E+00
X
X
X
X
X
X
X
X
X
X
X
X
X
1.64E+00
1.65E+00
1.67E+00
1.64E+00
1.57E+00
1.63E+00
1.73E+00
1.56E+00
1.52E+00
1.52E+00
1.73E+00
1.53E+00
1.49E+00
3.24E+00
3.26E+00
3.28E+00
3.24E+00
3.13E+00
3.22E+00
3.38E+00
3.11E+00
3.04E+00
3.04E+00
3.38E+00
3.05E+00
3.00E+00
1.77E+00
1.78E+00
1.79E+00
1.77E+00
1.69E+00
1.75E+00
1.86E+00
1.68E+00
1.63E+00
1.63E+00
1.86E+00
1.64E+00
1.60E+00
5.04E+00
2.88E+00
1.75E+00
5.49E-01
9.27E-02
9.27E-02
5.82E-02
5.82E-02
9.74E-03
9.74E-03
9.74E-03
1.62E-03
6.07E-03
X
X
X
X
X
X
X
X
X
X
X
X
X
4.92E+00
2.81E+00
1.70E+00
5.36E-01
9.04E-02
9.04E-02
5.68E-02
5.68E-02
9.50E-03
9.50E-03
9.50E-03
1.58E-03
5.92E-03
4.90E+00
2.79E+00
1.70E+00
5.33E-01
9.00E-02
9.00E-02
5.65E-02
5.65E-02
9.45E-03
9.45E-03
9.45E-03
1.58E-03
5.90E-03
4.88E+00
2.78E+00
1.69E+00
5.31E-01
8.97E-02
8.97E-02
5.63E-02
5.63E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
1.17E+00
1.00E+00
8.27E-01
4.04E-01
8.71E-02
8.73E-02
5.62E-02
5.60E-02
9.67E-03
9.67E-03
9.68E-03
1.62E-03
6.05E-03
X
X
X
X
X
X
X
X
X
X
X
X
X
1.23E+00
1.04E+00
8.42E-01
4.04E-01
8.55E-02
8.56E-02
5.50E-02
5.48E-02
9.44E-03
9.44E-03
9.44E-03
1.58E-03
5.90E-03
1.95E+00
1.50E+00
1.12E+00
4.58E-01
8.74E-02
8.75E-02
5.56E-02
5.55E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
1.30E+00
1.08E+00
8.69E-01
4.08E-01
8.51E-02
8.53E-02
5.47E-02
5.45E-02
9.37E-03
9.37E-03
9.37E-03
1.57E-03
5.85E-03
1722
239.8
234.3
268.4
-144.8
-100.1
0.0
79.0
0.0
0.0
0.0
0.0
0.0
X
X
X
X
X
X
X
X
X
X
X
X
X
1954
0.0
233.5
251.3
-170.4
-116.1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1469
0.0
152.8
38.8
-70.1
-7.3
-174.3
0.0
0.0
0.0
0.0
0.0
0.0
1308
364.0
194.6
140.6
-221.8
-153.1
-12.9
-9.7
0.0
0.0
0.0
0.0
0.0
115.5
112.1
15.7
188.1
-47.8
0.0
37.7
0.0
0.0
0.0
0.0
0.0
X
X
X
X
X
X
X
X
X
X
X
X
X
131.0
0.0
15.7
472.4
-79.7
-55.4
0.0
0.0
0.0
0.0
0.0
0.0
0.0
98.4
0.0
10.2
27.2
-32.8
-3.5
-83.2
0.0
0.0
0.0
0.0
0.0
0.0
87.7
170.2
13.0
98.5
-103.7
-73.1
-6.1
-4.6
0.0
0.0
0.0
0.0
0.0
156
Table 2: Continued
Sampling
event
May 2010
June -1
June -2
July
August
157
Location
Compound
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Air
Water
Air
Water
ng/m ng/L temperature K temperature K
0.078
BDL
1.204
5.887
1.377
0.636
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.129
BDL
1.532
3.650
0.857
0.346
BDL
0.368
BDL
BDL
BDL
BDL
BDL
0.004
BDL
0.015
0.210
2.622
0.823
0.075
0.191
BDL
BDL
BDL
0.055
BDL
0.009
BDL
0.072
0.673
3.984
1.210
0.124
0.449
BDL
BDL
BDL
BDL
BDL
0.004
BDL
0.020
0.205
BDL
0.814
0.082
0.346
0.198
BDL
BDL
0.055
BDL
0.977
0.524
0.556
0.888
1.120
0.663
0.078
0.072
0.032
0.022
0.018
BDL
BDL
0.836
BDL
1.546
1.461
0.872
0.466
0.079
0.070
BDL
BDL
BDL
0.008
BDL
7.103
0.573
0.439
0.549
3.080
2.164
0.276
0.487
0.227
0.089
0.087
0.048
BDL
4.915
1.919
1.289
1.788
3.304
2.200
0.269
0.645
0.289
0.089
0.039
0.058
BDL
1.879
0.419
0.230
0.412
2.545
1.948
0.245
0.461
0.256
0.106
0.062
0.054
0.015
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
303 (300,304)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
302 (298,307)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
304 (298,309)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (297,308)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
301 (300,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (307,303)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
304 (306,302)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
302 (300,306)
S15
Wind speed
m/s AVE
(max,min)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
7.1 (3.7,9.2)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.9 (2.5,6.6)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.1 (0.1,12.3)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.4 (0.0,10.4)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
4.9 (0.0,12.1)
Kw
Ka
MTC
Flux
SD
4.16E+00
4.18E+00
4.20E+00
4.16E+00
4.02E+00
4.13E+00
3.92E+00
4.01E+00
3.92E+00
3.92E+00
4.32E+00
3.94E+00
3.87E+00
2.32E+00
2.33E+00
2.35E+00
2.32E+00
2.23E+00
2.17E+00
2.43E+00
2.12E+00
2.16E+00
2.16E+00
2.43E+00
2.17E+00
2.12E+00
1.81E+00
1.82E+00
1.83E+00
1.81E+00
1.73E+00
1.79E+00
2.43E+00
1.72E+00
1.67E+00
1.67E+00
1.90E+00
1.68E+00
1.64E+00
2.01E+00
2.02E+00
2.04E+00
2.01E+00
1.92E+00
1.99E+00
2.11E+00
1.91E+00
1.86E+00
1.86E+00
2.11E+00
1.87E+00
1.83E+00
2.36E+00
2.38E+00
2.39E+00
2.36E+00
2.27E+00
2.34E+00
2.48E+00
2.25E+00
2.20E+00
2.20E+00
2.48E+00
2.21E+00
2.16E+00
4.86E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
9.39E-03
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
4.88E+00
2.78E+00
1.69E+00
5.31E-01
8.97E-02
1.57E-03
5.63E-02
5.88E-03
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
4.88E+00
2.78E+00
1.69E+00
5.31E-01
8.97E-02
8.97E-02
5.64E-02
5.64E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
4.80E+00
2.74E+00
1.66E+00
5.22E-01
8.82E-02
8.82E-02
5.54E-02
5.54E-02
9.26E-03
9.26E-03
9.26E-03
1.54E-03
5.78E-03
4.83E+00
2.76E+00
1.67E+00
5.26E-01
8.88E-02
8.88E-02
5.58E-02
5.58E-02
9.33E-03
9.33E-03
9.33E-03
1.55E-03
5.82E-03
2.24E+00
1.67E+00
1.20E+00
4.70E-01
8.74E-02
8.75E-02
9.37E-03
5.54E-02
9.37E-03
9.37E-03
9.37E-03
1.56E-03
5.85E-03
1.57E+00
1.27E+00
9.82E-01
4.32E-01
8.62E-02
1.57E-03
5.51E-02
5.86E-03
9.38E-03
9.38E-03
9.38E-03
1.57E-03
5.86E-03
1.32E+00
1.10E+00
8.79E-01
4.11E-01
8.53E-02
8.54E-02
5.51E-02
5.46E-02
9.37E-03
9.37E-03
9.38E-03
1.57E-03
5.86E-03
1.42E+00
1.16E+00
9.15E-01
4.15E-01
8.43E-02
8.44E-02
5.40E-02
5.39E-02
9.22E-03
9.22E-03
9.22E-03
1.54E-03
5.76E-03
1.59E+00
1.28E+00
9.84E-01
4.30E-01
8.54E-02
8.55E-02
5.46E-02
5.44E-02
9.29E-03
9.29E-03
9.29E-03
1.55E-03
5.80E-03
2182
0.0
455.7
-905.5
-258.0
-106.5
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1305
0.0
1298.8
-120.6
-142.4
-47.8
0.0
-94.8
0.0
0.0
0.0
0.0
0.0
9371
0.0
383.7
184.5
-395.9
-22.1
-4.9
-24.4
0.0
0.0
0.0
-16.1
0.0
6964
0.0
1169.5
606.2
-727.8
-120.3
-18.7
-85.2
0.0
0.0
0.0
0.0
0.0
2982
0.0
223.5
134.9
0.0
-40.7
-8.7
-67.8
-53.7
0.0
0.0
-15.9
0.0
146.3
0.0
30.5
-634.5
-120.6
-50.9
0.0
0.0
0.0
0.0
0.0
0.0
0.0
87.5
0.0
87.1
-84.5
-66.5
-22.8
0.0
-45.3
0.0
0.0
0.0
0.0
0.0
628.2
0.0
25.7
129.3
-185.1
-10.5
-2.4
-11.6
0.0
0.0
0.0
-7.7
0.0
466.8
0.0
78.4
424.8
-340.2
-57.4
-8.9
-40.7
0.0
0.0
0.0
0.0
0.0
199.9
0.0
15.0
94.5
0.0
-19.4
-4.1
-32.4
-36.6
0.0
0.0
-7.6
0.0
158
Table 2: Continued
Sampling
event
September
Feburary
March
April
May 2011
159
Location
Compound
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Air
Water
Air
Water
ng/m ng/L temperature K temperature K
0.010
0.021
0.075
0.960
3.009
2.364
0.077
0.393
0.241
BDL
BDL
0.080
BDL
0.009
0.013
0.037
0.342
1.040
0.648
BDL
0.175
0.122
BDL
BDL
0.072
BDL
0.009
0.013
0.037
0.342
1.040
0.648
BDL
0.175
0.122
BDL
BDL
0.072
BDL
0.011
0.009
0.023
0.107
0.926
0.719
BDL
BDL
0.133
BDL
BDL
0.049
BDL
0.179
0.126
0.342
1.740
3.282
2.301
BDL
BDL
BDL
DBL
BDL
BDL
BDL
0.342
0.478
0.281
0.522
3.169
2.392
0.265
0.388
0.286
0.098
0.097
0.055
BDL
2.066
1.022
0.311
0.584
1.832
0.954
0.131
0.116
0.053
0.017
0.009
BDL
BDL
2.066
1.022
0.311
0.584
1.832
0.954
0.131
0.116
0.053
0.017
0.009
BDL
BDL
1.308
0.619
0.264
0.501
1.782
1.323
0.107
0.167
0.104
0.041
0.024
0.021
BDL
0.568
0.792
0.388
0.845
2.910
2.024
0.150
0.190
0.055
0.020
0.013
BDL
BDL
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
299 (285,307)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
289 (273,297)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
295 (283,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
300 (297,301)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
298 (286,312)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
301 (293,307)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
290 (278,295)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
297 (290,301)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
298 (289,300)
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
301 (289,310
S16
Wind speed
m/s AVE
(max,min)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
4.5 (0.8,10.8)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.0 (0.1,14.2)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
5.7 (0.3,14.5)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
9.0 (2.2,14.2)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
5.3 (0.1,14.5)
Kw
Ka
MTC
Flux
SD
2.06E+00
2.08E+00
1.98E+00
2.06E+00
1.98E+00
2.05E+00
2.17E+00
1.97E+00
1.92E+00
1.92E+00
2.17E+00
1.92E+00
1.88E+00
2.25E+00
2.27E+00
2.28E+00
2.25E+00
2.17E+00
2.23E+00
2.35E+00
2.16E+00
2.11E+00
2.11E+00
2.35E+00
2.12E+00
2.08E+00
2.91E+00
2.92E+00
2.94E+00
2.91E+00
2.80E+00
2.88E+00
3.03E+00
2.79E+00
2.73E+00
2.73E+00
3.03E+00
2.74E+00
2.69E+00
6.10E+00
6.13E+00
6.16E+00
6.10E+00
6.13E+00
6.07E+00
6.31E+00
5.91E+00
5.80E+00
5.80E+00
6.31E+00
5.82E+00
5.74E+00
2.66E+00
2.67E+00
2.69E+00
2.66E+00
2.56E+00
2.63E+00
2.78E+00
2.54E+00
2.48E+00
2.48E+00
2.78E+00
2.49E+00
2.44E+00
4.88E+00
2.78E+00
8.96E-02
5.31E-01
8.96E-02
8.96E-02
5.63E-02
5.63E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.87E-03
5.05E+00
5.50E-01
1.75E+00
5.50E-01
9.28E-02
9.28E-02
5.83E-02
5.83E-02
9.75E-03
9.75E-03
9.75E-03
1.62E-03
6.08E-03
4.94E+00
2.82E+00
1.71E+00
5.37E-01
9.07E-02
9.07E-02
5.70E-02
5.70E-02
9.53E-03
9.53E-03
9.53E-03
1.59E-03
5.94E-03
4.89E+00
2.79E+00
1.69E+00
5.32E-01
2.79E+00
8.98E-02
5.65E-02
5.65E-02
9.44E-03
9.44E-03
9.44E-03
1.57E-03
5.89E-03
4.88E+00
2.78E+00
1.69E+00
5.31E-01
8.97E-02
8.97E-02
5.64E-02
5.64E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
1.45E+00
1.19E+00
8.57E-02
4.22E-01
8.57E-02
8.59E-02
5.49E-02
5.48E-02
9.37E-03
9.37E-03
9.37E-03
1.57E-03
5.85E-03
1.56E+00
4.42E-01
9.89E-01
4.42E-01
8.90E-02
8.91E-02
5.69E-02
5.68E-02
9.70E-03
9.70E-03
9.71E-03
1.62E-03
6.06E-03
1.83E+00
1.43E+00
1.08E+00
4.54E-01
8.79E-02
8.79E-02
5.59E-02
5.59E-02
9.49E-03
9.49E-03
9.50E-03
1.59E-03
5.93E-03
2.71E+00
1.92E+00
1.33E+00
4.90E-01
1.92E+00
8.85E-02
5.60E-02
5.59E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
1.72E+00
1.36E+00
1.04E+00
4.43E-01
8.67E-02
8.67E-02
5.52E-02
5.51E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
495.4
566.5
252.0
27.0
-488.6
-392.8
-6.1
-84.0
-65.7
0.0
0.0
-23.2
0.0
3215
1293
302.3
188.4
-100.3
-79.4
0.0
-40.2
-34.0
0.0
0.0
0.0
0.0
2393
887.1
281.5
204.3
-80.3
-67.7
0.0
0.0
-36.7
0.0
0.0
-14.4
0.0
1521
1496
447.8
3.4
-606.9
-426.9
0.0
0.0
0.0
0.0
0.0
0.0
0.0
6390.5
0.0
127.2
-37.7
-250.7
-168.7
-11.7
-49.2
-46.2
0.0
0.0
0.0
0.0
33.2
264.8
16.9
18.9
-228.4
-187.5
-2.9
-40.1
-44.8
0.0
0.0
-11.1
0.0
215.5
604.6
20.3
132.0
-46.9
-37.9
0.0
-19.2
-23.2
0.0
0.0
0.0
0.0
160.4
414.7
18.9
143.2
-37.6
-32.3
0.0
0.0
-25.1
0.0
0.0
-6.9
0.0
101.9
699.5
30.0
2.4
-283.7
-203.8
0.0
0.0
0.0
0.0
0.0
0.0
0.0
428.4
0.0
8.5
-26.4
-117.2
-80.5
-5.6
-23.5
-31.5
0.0
0.0
0.0
0.0
160
Table 2: Continued
Sampling
event
May 2010
June -1
June -2
July
August
161
Location
Compound
Air
ng/m
Water Air temperature

ng/L
K
Water
temperature K
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
0.156
BDL
BDL
0.987
0.372
0.143
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.033
0.086
0.224
0.675
0.575
0.181
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.033
0.086
0.224
0.675
0.575
0.181
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.004
BDL
0.026
0.208
0.990
0.244
0.030
BDL
BDL
BDL
BDL
BDL
BDL
0.004
0.004
0.012
0.138
0.794
0.199
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.278
1.687
1.212
0.471
0.087
0.088
0.055
0.055
0.009
0.009
0.009
0.002
0.006
0.708
1.636
0.614
0.518
1.166
0.694
0.144
0.169
0.088
BDL
BDL
0.026
BDL
3.400
2.046
0.625
0.494
2.130
1.491
0.227
0.485
0.287
0.075
0.106
0.046
BDL
2.009
5.146
1.288
0.963
3.214
1.976
0.291
0.745
0.506
0.146
0.107
0.079
BDL
2.395
2.463
0.681
0.551
2.402
1.752
0.256
0.598
0.408
0.126
0.054
0.063
0.016
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
299 (298,300)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (303,305)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (302,307)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (303,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
304 (299,309)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
298 (297,300)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (301,305)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
303 (298,307)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
305 (299,317)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
303 (297,316)
S17
Wind speed
m/s AVE
(max,min)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
7.2 (3.3,10.6)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.8 (2.9,7.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.4 (0.1,12.2)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.2 (0.3,11.4)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
4.9 (0.2,15.1)
Kw
Ka
MTC
4.28E+00
4.31E+00
4.33E+00
4.28E+00
4.15E+00
4.25E+00
4.45E+00
4.13E+00
4.04E+00
4.04E+00
4.45E+00
4.06E+00
3.99E+00
2.26E+00
2.27E+00
2.29E+00
2.26E+00
2.17E+00
2.24E+00
2.37E+00
2.16E+00
2.10E+00
2.10E+00
2.37E+00
2.11E+00
2.07E+00
2.02E+00
2.03E+00
2.05E+00
2.02E+00
1.94E+00
2.00E+00
2.12E+00
1.93E+00
1.87E+00
1.87E+00
2.12E+00
1.88E+00
1.84E+00
1.93E+00
1.94E+00
1.95E+00
1.93E+00
1.84E+00
1.91E+00
2.03E+00
1.83E+00
1.78E+00
1.78E+00
2.03E+00
1.79E+00
1.75E+00
2.44E+00
2.46E+00
2.47E+00
2.44E+00
2.35E+00
2.42E+00
2.56E+00
2.33E+00
2.27E+00
2.27E+00
2.56E+00
2.28E+00
2.26E+00
4.86E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
4.88E+00
2.78E+00
1.69E+00
5.31E-01
8.97E-02
8.97E-02
5.63E-02
5.63E-02
9.42E-03
9.42E-03
9.42E-03
1.57E-03
5.88E-03
4.87E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
4.80E+00
2.74E+00
1.66E+00
5.23E-01
8.82E-02
8.82E-02
5.54E-02
5.54E-02
9.27E-03
9.27E-03
9.27E-03
1.54E-03
5.78E-03
4.83E+00
2.76E+00
1.67E+00
5.26E-01
8.88E-02
8.88E-02
5.58E-02
5.58E-02
9.33E-03
9.33E-03
9.33E-03
1.55E-03
5.82E-03
2.28E+00
1.69E+00
1.21E+00
4.71E-01
8.75E-02
8.75E-02
5.55E-02
5.54E-02
9.37E-03
9.37E-03
9.37E-03
1.56E-03
5.85E-03
1.54E+00
1.25E+00
9.72E-01
4.30E-01
8.61E-02
8.62E-02
5.50E-02
5.49E-02
9.38E-03
9.38E-03
9.38E-03
1.57E-03
5.86E-03
1.43E+00
1.17E+00
9.24E-01
4.20E-01
8.54E-02
8.56E-02
5.47E-02
5.46E-02
9.34E-03
9.34E-03
9.35E-03
1.56E-03
5.84E-03
1.37E+00
1.14E+00
8.98E-01
4.11E-01
8.42E-02
8.43E-02
5.40E-02
5.38E-02
9.22E-03
9.22E-03
9.22E-03
1.54E-03
5.76E-03
1.62E+00
1.30E+00
9.98E-01
4.33E-01
8.55E-02
8.56E-02
5.46E-02
5.45E-02
9.29E-03
9.29E-03
9.29E-03
1.55E-03
5.80E-03
Flux
SD
2986 200.2
0
0.0
0
0.0
195.78 137.2
-0.529
-0.2
12.881
6.1
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
1091.3
73.1
2037.3 952.4
564.79
37.9
84.606
59.3
-45.46
-21.3
13.849
6.6
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
4851.3 325.2
2391.8 1118.1
547.59
36.7
71.757
50.3
36.87
17.2
81.857
39.1
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
-16.13
-7.7
0
0.0
2760.3 185.0
0
0.0
1153.1
77.3
354.27 248.2
20.91
9.8
105.04
50.1
7.6094
3.6
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
3886.4 260.5
3200.4 1496.1
677.76
45.4
209.74 147.0
3.4644
1.6
99.264
47.4
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
-15.9
-7.6
0
0.0
162
Table 2: Continued
Sampling
event
September
Feburary
March
April
May 2011
163
Location
Compound
Air
ng/m
Water Air temperature

ng/L
K
Water
temperature K
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
AL
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
0.009
0.010
0.026
0.191
0.577
0.440
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.011
BDL
0.027
0.208
0.491
0.308
BDL
BDL
0.060
BDL
BDL
0.045
BDL
0.008
0.003
0.006
0.042
0.273
0.207
0.014
BDL
BDL
BDL
BDL
BDL
BDL
0.119
0.050
0.103
0.315
0.459
0.308
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.004
BDL
0.013
0.165
0.710
0.500
0.064
BDL
BDL
BDL
BDL
BDL
BDL
1.128
5.151
1.608
1.367
4.296
2.712
0.306
0.634
0.464
0.131
0.150
0.066
0.019
0.986
2.634
0.830
0.958
1.741
0.947
0.087
0.086
0.037
0.011
0.012
BDL
BDL
2.124
1.595
0.379
0.536
2.759
1.823
0.305
0.636
0.359
0.120
0.084
0.060
0.015
2.124
1.595
0.379
0.536
2.759
1.823
0.305
0.636
0.359
0.120
0.084
0.060
0.015
0.758
3.279
0.660
0.847
2.876
1.637
0.377
0.871
0.567
0.189
0.119
0.083
0.023
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
300 (289,308)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
290 (278,296)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
297 (291,302)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
299 (298,301)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
302 (294,307)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
300 (287,317)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
290 (273,307)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
297 (285,312)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
298 (291,301)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
300 (287,308)
S18
Wind speed
m/s AVE
(max,min)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.1(0.1,13.8)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.5 (0.1,16)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
5.4 (0.2,17)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
8.2 (0.6,12.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
4.5 (0.3,16.7)
Kw
Ka
MTC
2.52E+00
2.53E+00
2.55E+00
2.52E+00
2.42E+00
2.50E+00
2.63E+00
2.41E+00
2.35E+00
2.35E+00
2.63E+00
2.36E+00
2.31E+00
2.63E+00
2.61E+00
2.63E+00
2.63E+00
2.51E+00
2.58E+00
2.71E+00
2.50E+00
2.44E+00
2.44E+00
2.71E+00
2.45E+00
2.41E+00
2.71E+00
2.72E+00
2.74E+00
2.71E+00
2.61E+00
2.69E+00
2.83E+00
2.60E+00
2.53E+00
2.53E+00
2.83E+00
2.54E+00
2.50E+00
2.50E+00
3.74E+00
3.76E+00
3.78E+00
3.74E+00
3.61E+00
3.71E+00
3.89E+00
3.59E+00
3.52E+00
3.52E+00
3.89E+00
3.53E+00
3.47E+00
2.07E+00
2.10E+00
2.07E+00
1.98E+00
2.05E+00
2.17E+00
1.97E+00
1.92E+00
1.92E+00
2.17E+00
1.93E+00
1.89E+00
4.87E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
5.03E+00
2.87E+00
1.74E+00
5.48E-01
9.24E-02
9.24E-02
5.81E-02
5.81E-02
9.71E-03
9.71E-03
9.71E-03
1.62E-03
6.06E-03
4.92E+00
2.81E+00
1.70E+00
5.36E-01
9.04E-02
9.04E-02
5.68E-02
5.68E-02
9.50E-03
9.50E-03
9.50E-03
1.58E-03
5.93E-03
5.93E-03
4.87E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
4.87E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
1.66E+00
1.32E+00
1.01E+00
4.38E-01
8.62E-02
8.63E-02
5.50E-02
5.49E-02
9.35E-03
9.35E-03
9.36E-03
1.56E-03
5.84E-03
1.73E+00
1.37E+00
1.05E+00
4.53E-01
8.91E-02
8.92E-02
5.69E-02
5.68E-02
9.67E-03
9.67E-03
9.67E-03
1.62E-03
6.04E-03
1.75E+00
1.38E+00
1.05E+00
4.47E-01
8.74E-02
8.75E-02
5.57E-02
5.56E-02
9.46E-03
9.46E-03
9.47E-03
1.58E-03
5.91E-03
5.91E-03
2.11E+00
1.60E+00
1.17E+00
4.64E-01
8.72E-02
8.73E-02
5.54E-02
5.53E-02
9.37E-03
9.37E-03
9.37E-03
1.56E-03
5.85E-03
1.45E+00
9.34E-01
4.22E-01
8.55E-02
8.57E-02
5.48E-02
5.46E-02
9.35E-03
9.35E-03
9.35E-03
1.56E-03
5.84E-03
Flux
SD
1872 125.5
6819.8 3188.1
1627.1 109.1
558.17 391.1
223.2 104.3
121.92
58.2
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
-23.2
-11.1
0
0.0
1700.9 114.0
0
0.0
865.56
58.0
390.75 273.8
30.189
14.1
5.8829
2.8
0
0.0
0
0.0
-16.78
-11.4
0
0.0
0
0.0
0
0.0
0
0.0
3709.9 248.7
2204.1 1030.4
397.02
26.6
230.73 161.7
171.54
80.2
106.63
50.9
13.216
6.3
0
0.0
0
0.0
0
0.0
0
0.0
-14.39
-6.9
0
0.0
1416.3
94.9
6025.7 2816.9
1018
68.2
391.48 274.3
11.089
5.2
-5.973
-2.9
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
1101
73.8
0
0.0
614.45
41.2
324.11 227.1
66.56
31.1
13.617
6.5
3.5791
1.7
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
0
0.0
164
Table 2: Continued
Sampling
event
May 2010
June -1
June -2
July
August
165
Location
Compound
Air
ng/m
Water ng/L
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
0.0922
BDL
0.3007
0.8534
0.2296
0.0933
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.0163
BDL
0.0593
0.56
0.3373
0.1684
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.016
BDL
0.0182
0.1311
0.5228
0.1848
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.019
BDL
0.0111
0.094
0.6128
0.1982
BDL
0.2334
BDL
BDL
BDL
BDL
BDL
0.0232
0.0155
0.0227
0.1159
0.5491
0.1737
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.692
0.236
0.216
0.280
0.144
0.059
0.056
0.000
0.000
0.000
0.000
0.000
0.000
1.999
BDL
0.207
0.174
0.317
0.162
BDL
0.062
BDL
BDL
BDL
0.013
BDL
BDL
BDL
0.187
0.193
0.670
0.444
0.083
0.458
0.091
0.032
BDL
0.021
BDL
BDL
BDL
0.222
0.160
1.040
0.588
0.088
0.562
0.161
0.054
BDL
0.038
BDL
0.570
0.614
0.584
0.935
4.347
2.457
0.379
1.367
0.520
0.168
0.253
0.133
BDL
Wind
Air
Water temperature speed m/s
temperature K
AVE
K
(min,max)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
301 (297,304)
299 (298,302)
2.1 (0.4,6.7)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (302,305)
303 (299,307)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
303 (299,307)
303 (302,305)
2.9 (0.4,5.9)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
302 (298,309)
304 (302,307)
2.3 (0.1,9.2)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
304 (300,309)
305 (302,307)
2.7 (0.1,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
302 (297,310)
303 (300,306)
2.6 (0.2,8.5)
S19
Kw
Ka
7.33E-01
7.39E-01
7.46E-01
7.33E-01
6.92E-01
7.24E-01
6.61E-01
6.87E-01
6.61E-01
6.61E-01
7.82E-01
6.65E-01
6.46E-01
1.15E+00
1.16E+00
1.17E+00
1.15E+00
1.09E+00
1.14E+00
1.22E+00
1.08E+00
1.05E+00
1.05E+00
1.22E+00
1.05E+00
1.03E+00
7.85E-01
7.92E-01
7.99E-01
7.85E-01
7.43E-01
7.76E-01
8.36E-01
7.37E-01
7.11E-01
7.11E-01
8.36E-01
7.15E-01
6.95E-01
1.06E+00
8.22E-01
8.29E-01
1.06E+00
1.00E+00
8.05E-01
8.69E-01
7.65E-01
7.37E-01
7.37E-01
8.69E-01
7.41E-01
7.20E-01
9.89E-01
9.97E-01
1.01E+00
9.89E-01
9.37E-01
9.78E-01
1.05E+00
9.31E-01
8.99E-01
8.99E-01
1.05E+00
9.04E-01
8.80E-01
4.83E+00
2.76E+00
1.67E+00
5.26E-01
8.88E-02
8.88E-02
9.33E-03
5.58E-02
9.33E-03
9.33E-03
9.33E-03
1.55E-03
5.82E-03
4.81E+00
2.74E+00
1.66E+00
5.23E-01
8.83E-02
8.83E-02
5.55E-02
5.55E-02
9.28E-03
9.28E-03
9.28E-03
1.55E-03
5.79E-03
4.89E+00
2.79E+00
1.69E+00
5.32E-01
8.98E-02
8.98E-02
5.64E-02
5.64E-02
9.43E-03
9.43E-03
9.43E-03
1.57E-03
5.88E-03
4.80E+00
2.74E+00
1.66E+00
5.23E-01
8.82E-02
8.82E-02
5.54E-02
5.54E-02
9.26E-03
9.26E-03
9.26E-03
1.54E-03
5.78E-03
5.31E+00
2.75E+00
1.67E+00
5.24E-01
6.66E-01
8.85E-02
5.56E-02
5.56E-02
9.29E-03
9.29E-03
9.29E-03
1.55E-03
5.80E-03
MTC
Flux
6.36E-01 1074.1
5.83E-01
0.0
5.16E-01 88.3
3.06E-01 -40.0
7.87E-02 -42.5
7.91E-02 -17.3
9.20E-03
0.0
5.16E-02
0.0
9.20E-03
0.0
9.20E-03
0.0
9.22E-03
0.0
1.55E-03
0.0
5.77E-03
0.0
9.27E-01 1853.1
8.14E-01
0.0
6.86E-01 135.7
3.59E-01 -35.0
8.17E-02 -56.5
8.19E-02 -28.0
5.31E-02
0.0
5.28E-02
0.0
9.20E-03
0.0
9.20E-03
0.0
9.21E-03
0.0
1.54E-03
0.0
5.75E-03
0.0
6.76E-01
0.0
6.17E-01
0.0
5.42E-01 100.1
3.17E-01 41.5
8.01E-02 -69.6
8.04E-02 -8.0
5.28E-02
0.0
5.24E-02
0.0
9.31E-03
0.0
9.31E-03
0.0
9.32E-03
0.0
1.57E-03
0.0
5.83E-03
0.0
8.66E-01
0.0
6.32E-01
0.0
5.53E-01 122.1
3.50E-01 40.0
8.10E-02 -64.5
7.95E-02 -0.4
5.21E-02
0.0
5.17E-02 -30.8
9.15E-03
0.0
9.15E-03
0.0
9.17E-03
0.0
1.54E-03
0.0
5.73E-03
0.0
8.34E-01 474.3
7.32E-01 448.2
6.27E-01 364.3
3.43E-01 301.1
3.89E-01 1054.3
8.11E-02 157.3
5.28E-02
0.0
5.25E-02
0.0
9.20E-03
0.0
9.20E-03
0.0
9.21E-03
0.0
1.55E-03
0.0
5.76E-03
0.0
SD
72.0
0.0
5.9
-28.0
-19.8
-8.2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
124.2
0.0
9.1
-24.5
-26.4
-13.4
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
6.7
29.1
-32.5
-3.8
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
8.2
28.1
-30.2
-0.2
0.0
-14.7
0.0
0.0
0.0
0.0
0.0
31.8
209.5
24.4
211.0
492.9
75.1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
166
Table 2: Continued
Sampling
event
September
Feburary
March
April
May 2011
167
168
169
170
Location
Compound
Air
ng/m
Water ng/L
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
FL
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
Naphthalene
Acenaphthene
Fluorene
Phenanthrene
Fluoranthene
Pyrene
Benz(a)anthracene
Chrysene
Benzo(a)pyrene
0.0109
0
0.0269
0.1463
0.7953
0.588
0.0298
0.0559
0.0987
BDL
0
0.051
0
0.0076
0
0.0192
0.1453
0.5089
0.3351
0
0
bdl
0
0
0.0556
0
0.0097
BDL
0.0054
0.0221
0.2595
0.2089
0.0276
0.1041
BDL
BDL
BDL
0.0383
0
0.1341
0.0211
0.0955
0.304
0.4231
0.2813
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.0033
BDL
0.013
0.1648
0.71
0.5
0.0637
BDL
BDL
BDL
BDL
BDL
BDL
1.001
0.564
0.630
1.270
3.377
1.785
0.230
0.638
0.328
0.105
BDL
0.067
BDL
0.920
0.299
0.206
0.415
0.448
0.211
0.076
0.052
0.020
BDL
BDL
BDL
BDL
0.466
BDL
0.115
0.274
0.646
0.348
0.041
0.097
0.056
0.019
0.010
0.015
BDL
0.620
0.098
0.091
0.194
0.179
0.065
BDL
0.029
0.015
BDL
BDL
BDL
BDL
0.385
BDL
0.179
0.243
0.759
0.346
0.061
0.150
0.090
0.036
0.013
0.024
BDL
Wind
Air
Water temperature speed m/s
Kw
temperature K
K
AVE
(min,max)
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.69E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.77E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.84E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.69E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.23E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.59E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 9.24E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 8.18E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 7.89E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 7.89E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 9.24E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 7.94E-01
300 (287,306)
302 (292,306)
2.4 (0.1,6.7) 7.72E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.65E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.71E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.77E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.65E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.26E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.56E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 8.12E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.21E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 6.96E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 6.96E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 8.12E-01
290 (281,295)
289 (273,298)
2.4 (0.03,7.2) 7.00E-01
2.4 (0.03,7.2) 6.82E-01
290 (281,295)
289 (273,298)
3.2 (0.1,11.4) 1.20E+00
295 (284,301)
296 (291,300)
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.21E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.22E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.20E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.14E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.19E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.27E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.14E+00
3.2 (0.1,11.4) 1.10E+00
295 (284,301)
296 (291,300)
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.10E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.27E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.11E+00
295 (284,301)
296 (291,300)
3.2 (0.1,11.4) 1.08E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.86E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.88E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.89E+00
5.6 (0.6,10.4) 2.86E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.75E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.84E+00
299 (292,302)
300 (298,301)
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.99E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.74E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.67E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.67E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.99E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.68E+00
299 (292,302)
300 (298,301)
5.6 (0.6,10.4) 2.63E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.38E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.39E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.40E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.38E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.31E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.36E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.45E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.30E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.26E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.26E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.45E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.27E+00
299 (286,307)
300 (289,306)
3.4 (0.1,11.1) 1.24E+00
Ka
4.87E+00
2.78E+00
1.69E+00
5.30E-01
8.95E-02
8.95E-02
5.62E-02
5.62E-02
9.40E-03
9.40E-03
9.40E-03
1.57E-03
5.87E-03
5.05E+00
2.88E+00
1.75E+00
5.49E-01
9.27E-02
9.27E-02
5.83E-02
5.83E-02
9.74E-03
9.74E-03
9.74E-03
1.62E-03
6.08E-03
4.94E+00
2.82E+00
1.71E+00
5.38E-01
9.08E-02
9.08E-02
5.71E-02
5.71E-02
9.54E-03
9.54E-03
9.54E-03
1.59E-03
5.95E-03
4.87E+00
2.77E+00
1.68E+00
5.30E-01
8.94E-02
8.94E-02
5.62E-02
5.62E-02
9.39E-03
9.39E-03
9.39E-03
1.57E-03
5.86E-03
4.89E+00
2.79E+00
1.69E+00
5.32E-01
8.98E-02
8.98E-02
5.64E-02
5.64E-02
9.43E-03
9.43E-03
9.43E-03
1.57E-03
5.88E-03
MTC
Flux
7.38E-01 737.8
6.66E-01 375.5
5.80E-01 362.9
3.29E-01 395.5
8.07E-02 83.1
8.11E-02
4.0
5.30E-02
4.5
5.26E-02 19.2
9.29E-03 -24.7
9.29E-03
0.0
9.31E-03
0.0
1.56E-03 -14.8
5.82E-03
0.0
6.64E-01 611.1
6.08E-01 181.6
5.38E-01 109.3
3.20E-01 111.1
8.22E-02 -82.4
8.26E-02 -61.4
5.44E-02
4.1
5.39E-02
2.8
9.60E-03
0.0
9.60E-03
0.0
9.62E-03
0.0
1.62E-03
0.0
6.02E-03
0.0
9.65E-01 449.0
8.46E-01
0.0
7.11E-01 81.0
3.72E-01 97.8
8.41E-02
-9.2
8.44E-02 -21.9
5.46E-02
-5.0
5.44E-02 -22.0
9.46E-03
0.0
9.46E-03
0.0
9.47E-03
0.0
1.59E-03 -11.2
5.92E-03
0.0
1.80E+00 1104.9
1.41E+00 135.6
1.06E+00 81.8
4.47E-01 21.1
8.66E-02 -93.9
8.67E-02 -67.2
5.51E-02
0.0
5.51E-02
0.0
9.36E-03
0.0
9.36E-03
0.0
9.36E-03
0.0
1.56E-03
0.0
5.85E-03
0.0
1.07E+00 413.0
9.26E-01
0.0
7.65E-01 135.6
3.84E-01 63.0
8.40E-02 -111.8
8.42E-02 -94.8
5.43E-02 -13.6
5.41E-02
0.0
9.36E-03
0.0
9.36E-03
0.0
9.37E-03
0.0
1.57E-03
0.0
5.85E-03
0.0
SD
49.5
175.6
24.3
277.1
38.9
1.9
2.1
9.2
-16.8
0.0
0.0
-7.1
0.0
41.0
84.9
7.3
77.9
-38.5
-29.3
2.0
1.3
0.0
0.0
0.0
0.0
0.0
30.1
0.0
5.4
68.6
-4.3
-10.5
-2.4
-10.5
0.0
0.0
0.0
-5.3
0.0
74.1
63.4
5.5
14.8
-43.9
-32.1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
27.7
0.0
9.1
44.2
-52.3
-45.2
-6.5
0.0
0.0
0.0
0.0
0.0
0.0
Table 2: Sampling date, sampling location, air ng/m3, water ng/L, temperature Kelvin
average(min,max), wind speed meters/second average(min,max) water side mass transfer
coefficient, air side mass transfer coefficient, total mass transfer coefficient, flux, flux variance.
S20
171
172
173
Table 3: Instrumental detection limits

Compound Name
LOD
LOQ
Naphthalene
0.066
0.328
2-Methylnaphthalene
0.078
0.391
1-Methylnaphthalene
0.093
0.465
1,6-Dimethylnaphthalene
0.177
0.883
Acenaphthylene
0.260
1.302
Acenaphthene
0.104
0.519
Fluorene
0.160
0.799
Dibenzothiophene
0.064
0.322
Phenanthrene
0.126
0.632
Anthracene
0.137
0.685
2-Methylphenanthrene
0.188
0.942
2-Methylanthracene
0.226
1.131
1-Methylphenanthrene
0.153
0.765
9-Methylanthracene
0.126
0.628
3,6-Dimethylphenanthrene
0.071
0.355
2,3-Dimethylanthracene
0.200
0.998
Fluoranthene
0.159
0.795
9,10-Dimethylanthracene
0.135
0.674
Pyrene
0.112
0.562
Retene
0.639
3.195
1-Methylpyrene
0.100
0.502
Benz(a)anthracene
0.275
1.377
Chrysene
0.281
1.407
6-Methylchrysene
0.334
1.669
0.136
0.678
0.284
1.419
Benzo(e)pyrene
0.130
0.649
Benzo(a)pyrene
0.299
1.496
0.339
1.697
0.332
1.658
Benzo(ghi)perylene
0.211
1.056
Dibenzo(a,l)pyrene
0.632
3.162
1,4 Naphthoquinone-D6
0.32
1.6
2-Methyl-1,4-naphthoquinone-d8
0.42
2.1
9-Fluorenone-D8
0.18
0.91
9,10-Anthraquinone-d8
0.65
3.2
1,4 Benzoquinone
0.49
2.4
Chromone
0.89
4.4
1,4 Naphthoquinone
0.45
2.3
1,2-Naphthoquinone
36
179
9-Fluorenone
0.20
1.0
Xanthone
0.38
1.9
Acenapthenequinone
11
57
Perinaphthenone
0.89
4.4
Phenanthrene-1,4-dione
0.86
4.3
9,10-Anthraquinone
1.5
7.7
1,4-Anthraquinone
5.6
28
4H-cyclopenta[def]phenanthren-40.21
1.0
9,10-phenthrenequinone
6.90
34.5
2-Ethylanthraquinone
0.35
1.8
Benzofluorenone
0.45
2.3
Benzanthrone
0.78
3.9
Aceanthracenequinone
27
133
Pyrene 4,5 dione
11
57
7,12-benz[a]anthracenquinone
0.85
4.2
Benzo[c]phenanthrene-[1,4]quinon
1.7
8.5
5,12-Napthacenequinone
1.3
6.3
Benzo(cd)pyrenone
1.1
5.7
Table 3: Instrumental limits of detection and quantitation for PAH and OPAH using GC/MS
S21
174
Table 4: Concentrations of OPAH in crude oil

Sampling
site
DWH
LA
MS
AL
FL
175
176
177
178
179
OPAH
9,10-Anthraquinone
Benzofluorenone
9,10-Anthraquinone
Benzofluorenone
9,10-Anthraquinone
Benzofluorenone
9,10-Anthraquinone
Benzofluorenone
9,10-Anthraquinone
Benzofluorenone
Crude oil ng/mL

May 21, 2010
138.1
155.3
67.9
138.1
155.3
67.9
138.1
155.3
67.9
138.1
155.3
67.9
138.1
155.3
67.9
Deep Water Horizon OPAHs

Water ng/L
Air ng/m
Water ng/L
May 2010
May 2010
June-1
X
X
X
X
X
X
X
X
X
12.2
BDL
BDL
0.8
BDL
49.7
BDL
BDL
3.2
22.2
BDL
BDL
1.3
BDL
BDL
BDL
38.3
0.1
BDL
BDL
11.7
1.1
BDL
0.8
BDL
BDL
0.1
BDL
BDL
0.0
0.98
BDL
1.4
0.02
BDL
0.1
Air ng/m
June-1
X
X
X
BDL
BDL
BDL
BDL
BDL
35.4
BDL
BDL
BDL
BDL
BDL
BDL
Water ng/L
June-2
X
X
X
529.9
75.1
2.0
BDL
BDL
0.2
BDL
1.1
0.1
40.4
2.4
0.1
Air ng/m
June-2
X
X
X
BDL
BDL
123.0
BDL
BDL
76.5
BDL
BDL
BDL
BDL
BDL
64.4
Table 4: OPAH concentrations in; crude oil sample QA10OIL01, dissolved OPAH
concentrations in water, OPAH vapor phase concentrations in air. Crude oil sample collected
May 21, 2010 at the site of the Deepwater Horizon (DWH) oil rig.7 Sample analyzed in house by
instrumental method defined in OConnell et al 2013.8
180
181
182
183
184
185
186
References:
187
188
189
190
191
192
193
194
195
1.
Huckins, J. N.; Petty, J. D.; Booij, K., Monitors of organic chemicals in the environment:
semipermeable membrane devices. Springer New York: 2006.
2.
Bartkow, M. E.; Jones, K. C.; Kennedy, K. E.; Holling, N.; Hawker, D. W.; Mller, J. F., Evaluation of
performance reference compounds in polyethylene-based passive air samplers. Environmental Pollution
2006, 144 (2), 365-370.
3.
Huckins, J. N.; Petty, J. D.; Lebo, J. A.; Almeida, F. V.; Booij, K.; Alvarez, D. A.; Cranor, W. L.; Clark,
R. C.; Mogensen, B. B., Development of the permeability/performance reference compound approach
for in situ calibration of semipermeable membrane devices. Environmental Science & Technology 2002,
36 (1), 85-91.
S22
196
197
198
199
200
201
202
203
204
205
206
207
208
209
4.
Sderstrm, H. S.; Bergqvist, P.-A., Passive air sampling using semipermeable membrane devices
at different wind-speeds in situ calibrated by performance reference compounds. Environmental Science
& Technology 2004, 38 (18), 4828-4834.
5.
Wang, Z.; Stout, S., Oil spill environmental forensics: fingerprinting and source identification.
Academic Press: 2010.
6.
Ns, K.; Oug, E., Multivariate approach to distribution patterns and fate of polycyclic aromatic
hydrocarbons in sediments from smelter-affected Norwegian fjords and coastal waters. Environmental
Science & Technology 1997, 31 (5), 1253-1258.
7.
Kucklick, J. R.; Schantz, M. M., Interlaboratory Analytical Comparisons Study to Support
Deepwater Horizon Natural Resource Damage Assessment: Description and Results for Crude Oil
QA10OIL01, NISTIR 7793, Gaithersburg, MD. 2011.
8.
OConnell, S. G.; Haigh, T.; Wilson, G.; Anderson, K. A., An analytical investigation of 24
oxygenated-PAHs (OPAHs) using liquid and gas chromatographymass spectrometry. Analytical and
bioanalytical chemistry 2013, 405 (27), 8885-8896.
210
211
S23

Supplementary Information PDF

Hochgeladen von

Dokumentinformationen

Originaltitel

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Supplementary Information PDF

Hochgeladen von

Copyright:

Verfügbare Formate

1

Supplementary Information: PAH and OPAH Air and Water Exchange

during the Deepwater Horizon Incident

Air concentration calculationpg.S3

Figure S1: Individual PAH in air....pg.S4-S6

Figure S2: Alkylation profiles of selected PAH......pg.S7

Figure S3: Individual OPAH in air and water.pg.S8-12

Table 2: Individual PAH flux,.pg.S13-20

Table 3: PAH and OPAH LOD and LOQ ......pg.S21

Table 4: Concentrations OPAH in crude oilpg.S22

Table 1: Sampling events and durations

May 10-13, 2010

List 1: 33 PAH analyte method compounds

Deuterated performance reference compounds (PRC): fluorene-D10, p,p-DDE-D8, and

The deuterated surrogate recovery standards: naphthalene-D8, acenaphthylene-D8,

List 2: 22 OPAH analyte method compounds

benz[a]anthracene-7,12-dione, xanthone, 1,2-napthoquinone, 1,4-naphthoquinone,

Deuterated surrogate recovery standards: 9,10-anthraquinone-D8 and 9-fluorenone-D8. The

Air concentration calculation.

Environmental vapor phase air concentrations were determined using an empirical

Figure S1: Individual PAH concentrations

PAHs ng/m in air

PAHs ng/m in air

Figure S1 continued: Individual PAH concentrations

PAHs ng/m in air

PAHs ng/m in air

Figure S1 continued: Individual PAH concentrations

Figure S2: Selected PAH alkylation profiles

Figure S3: Individual OPAH concentrations

OPAH ng/L water

OPAHs ng/m^3 air

Figure S3: Individual OPAH concentrations

OPAH ng/L water

OPAHs ng/m^3 air

Figure S3 continued: Individual OPAH concentrations

OPAH ng/L water

OPAHs ng/m^3 air

Figure S3 continued: Individual OPAH concentrations

OPAH ng/L water

OPAHs ng/m^3 air

Figure S3 continued: Individual OPAH concentrations

Table 2: Individual PAH flux

301 (303,300) 4.5 (6.8,2.8)

Water Air temperature

Water Air temperature

Table 3: Instrumental detection limits

Table 4: Concentrations of OPAH in crude oil

Crude oil ng/mL

Deep Water Horizon OPAHs

Das könnte Ihnen auch gefallen