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Nytro Libra
SAFETY DATA SHEET
Nytro Libra
Insulating oil
Liquid.
Reason
None known.
Signal word
Hazard statements
Precautionary statements
Prevention
Response
Danger
May be fatal if swallowed and enters airways.
Not applicable.
IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT
induce vomiting.
2013-10-28.
1/15
Not applicable.
Dispose of waste product or used containers according to local regulations.
No.
No.
Mixture
Classification
Product/ingredient
name
Distillates (petroleum),
hydrotreated light
naphthenic
Distillates (petroleum),
hydrotreated light
paraffinic
Distillates (petroleum),
hydrotreated heavy
paraffinic
Lubricating oils
(petroleum), C15-30,
hydrotreated neutral
oil-based
Distillates (petroleum),
solvent-refined light
naphthenic
Distillates (petroleum),
solvent-refined heavy
naphthenic
Identifiers
REACH #:
01-2119480375-34
EC: 265-156-6
CAS: 64742-53-6
Index: 649-466-00-2
REACH #:
01-2119487077-29
EC: 265-158-7
CAS: 64742-55-8
Index: 649-468-00-3
REACH #:
01-2119484627-25
EC: 265-157-1
CAS: 64742-54-7
Index: 649-467-00-8
REACH #:
01-2119474878-16
EC: 276-737-9
CAS: 72623-86-0
Index: 649-482-00-X
REACH #:
01-2119480374-36
EC: 265-098-1
CAS: 64741-97-5
Index: 649-458-00-9
REACH #:
01-2119483621-38
EC: 265-097-6
CAS: 64741-96-4
Index: 649-457-00-3
67/548/EEC
Type
50 - 70
Not classified.
[1] [2]
0 - 50
Not classified.
[1] [2]
0 - 50
Not classified.
Not classified.
[2]
0 - 50
Not classified.
[1] [2]
0-5
Not classified.
[1] [2]
0-5
Not classified.
[1] [2]
2013-10-28.
2/15
Ingestion
Protection of first-aiders
Accidental high pressure injection through the skin requires immediate medical
attention. Do not wait for symptoms to develop.
Always assume that aspiration has occurred. Do not induce vomiting as there is
high risk of aspiration. Never give anything by mouth to an unconscious person.
Seek professional medical attention or send the casualty to a hospital. Do not wait
for symptoms to develop.
No action shall be taken involving any personal risk or without suitable training.
Before attempting to rescue casualties, isolate area from all potential sources of
ignition including disconnecting electrical supply. Ensure adequate ventilation and
check that a safe, breathable atmosphere is present before entry into confined
spaces.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact
Eye contact may cause redness and transient pain.
Inhalation
Inhalation of oil mist or vapours at elevated temperatures may cause respiratory
irritation.
Skin contact
No known significant effects or critical hazards.
Ingestion
Nausea or vomiting. Aspiration hazard if swallowed. Can enter lungs and cause
damage. Ingestion (swallowing) of this material may result in an altered state of
consciousness and loss of coordination.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
Due to low viscosity there is a risk of aspiration if the product enters the lungs.
Ingestion (swallowing) of this material may result in an altered state of
consciousness and loss of coordination. Treat symptomatically.
Specific treatments
Always assume that aspiration has occurred.
2013-10-28.
3/15
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Note : recommended measures are based on the most likely spillage scenarios for
this material; however, local conditions (wind, air temperature, wave/current
direction and speed) may significantly influence the choice of appropriate actions.
For this reason, local experts should be consulted when necessary. Local
regulations may also prescribe or limit actions to be taken.
Small spillages: normal antistatic working clothes are usually adequate.
Large spillages: full body suit of chemically resistant and thermal resistant material
should be used. Work gloves providing adequate chemical resistance, specifically to
aromatic hydrocarbons. Note : gloves made of PVA are not water-resistant, and are
not suitable for emergency use. Safety helmet, antistatic non-skid safety shoes or
boots. Goggles and /or face shield, if splashes or contact with eyes is possible or
anticipated.
Respiratory protection : A half or full-face respirator with filter(s) for organic vapours
(and when applicable for H2S) a Self Contained Breathing Apparatus (SCBA) can
be used according to the extent of spill and predictable amount of exposure. If the
situation cannot be completely assessed, or if an oxygen deficiency is possible, only
SCBAs should be used.
Prevent product from entering sewers, rivers or other bodies of water. If necessary
dike the product with dry earth, sand or similar non-combustible materials. In case
of soil contamination, remove contaminated soil and treat in accordance with local
regulations. In case of small spillages in closed waters (i.e. ports), contain product
with floating barriers or other equipment. Collect spilled product by absorbing with
specific floating absorbents.
If possible, large spillages in open waters should be contained with floating barriers
or other mechanical means. If this is not possible, control the spreading of the
spillage, and collect the product by skimming or other suitable mechanical means.
The use of dispersants should be advised by an expert, and, if required, approved
by local authorities.
2013-10-28.
4/15
Obtain special instructions before use. Keep away from heat/sparks/open flames/
hot surfaces. - No smoking. Use and store only outdoors or in a well-ventilated area.
Avoid release to the environment.
Advice on general
occupational hygiene
Note: see section 8 for personal protective equipment and section 13 for waste
disposal.
Ensure that proper housekeeping measures are in place. Contaminated materials
should not be allowed to accumulate in the workplaces and should never be kept
inside the pockets. Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed. Wash hands thoroughly after
handling. Change contaminated clothes at the end of working shift.
Storage area layout, tank design, equipment and operating procedures must comply
with the relevant European, national or local legislation. Storage installations should
be designed with adequate bunds in case of leaks or spills. Cleaning, inspection
and maintenance of internal structure of storage tanks must be done only by
properly equipped and qualified personnel as defined by national, local or company
regulations.
2013-10-28.
5/15
Type
Exposure
DNEL
Long term
Inhalation
Long term
Inhalation
Long term
Inhalation
Long term
Inhalation
Long term
Inhalation
DNEL
DNEL
DNEL
DNEL
Value
Population
Effects
5,4 mg/m
Workers
Local
5,4 mg/m
Workers
Local
5,4 mg/m
Workers
Local
5,4 mg/m
Workers
Local
5,4 mg/m
Workers
Local
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
Environmental exposure
controls
Mechanical ventilation and local exhaust will reduce exposure via the air. Use oil
resistant material in construction of handling equipment. Store under recommended
conditions and if heated, temperature control equipment should be used to avoid
overheating.
Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Ensure that eyewash stations and safety showers are close to the workstation
location. Wash contaminated clothing before reuse.
If potential exists for splashing, use goggles.
Wear oil-resistant protective gloves (e.g. nitril rubber). PVC gloves. Neoprene
gloves.
Wear protective clothing if there is a risk of skin contact. Change contaminated
clothes at the end of working shift.
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. Use a
properly fitted, particulate filter respirator complying with an approved standard if a
risk assessment indicates this is necessary.
Emissions from ventilation or work process equipment should be checked to
ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
2013-10-28.
6/15
Not applicable.
-51C
>250C
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or
explosive limits
Not available.
Not available.
Not available.
Vapour pressure
Vapour density
Density
Solubility(ies)
Partition coefficient: n-octanol/
water
160 Pa @ 100 C
Not available.
0,88 g/cm [15C]
Insoluble in water.
Not available.
Auto-ignition temperature
Decomposition temperature
Viscosity
Explosive properties
Oxidising properties
DMSO extractable compounds
for base oil substance(s)
according to IP346
>270C
>280C
Kinematic (40C): 0,096 cm2/s (9,6 cSt)
Not available.
Not available.
< 3%
No specific test data related to reactivity available for this product or its ingredients.
Under normal conditions of storage and use, hazardous reactions will not occur.
Oxidising agent.
10.6 Hazardous
decomposition products
Result
Species
Dose
Exposure
Rat
>5,53 mg/l
4 hours
Rabbit
LD50 Oral
Rat
Rat
>5000 mg/
kg
>5000 mg/
kg
>5,53 mg/l
LD50 Oral
Rat
>5000 mg/
kg
>5000 mg/
kg
2013-10-28.
Rabbit
4 hours
7/15
Irritation/Corrosion
Skin
Eyes
Respiratory
Sensitiser
Skin
Carcinogenicity
Conclusion/Summary
Reproductive toxicity
Conclusion/Summary
Aspiration hazard
LD50 Dermal
Rabbit
LD50 Oral
Rat
Rat
LD50 Oral
Rat
Rat
LD50 Oral
Rat
Rat
LD50 Oral
Rat
Rabbit
Rabbit
Rabbit
>5000 mg/
kg
>5000 mg/
kg
>5,53 mg/l
>5000 mg/
kg
>5000 mg/
kg
>5,53 mg/l
>5000 mg/
kg
>5000 mg/
kg
>5,53 mg/l
>5000 mg/
kg
>5000 mg/
kg
4 hours
4 hours
Skin contact
Eye contact
Potential chronic health effects
Chronic effects
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Other information
Result
Ingestion
4 hours
Product/ingredient name
8/15
Result
Species
Exposure
Algae
48 hours
Fish
Algae
96 hours
48 hours
Fish
Fish
96 hours
96 hours
Fish
96 hours
Algae
Fish
48 hours
96 hours
Algae
48 hours
Fish
96 hours
Aquatic toxicity data on base oils indicate LC50 values of > 100 mg/l, which is
considered as low toxicity.
Aquatic half-life
Photolysis
Biodegradability
Distillate (petroleum),
hydrotreated light naphthenic
Distillate (petroleum),
Hydrotreated Light Paraffinic
Lubricating oils (petroleum),
C15-30, hydrotreated
neutral oil-based
Distillates (petroleum),
hydrotreated heavy paraffinic
Distillates (petroleum),
solvent-refined heavy
naphthenic
Distillates (petroleum),
solvent-refined light
naphthenic
Inherent
Inherent
Inherent
Inherent
Inherent
Inherent
Conclusion/Summary
Inherently biodegradable.
Insoluble in water. Spills may form a film on water surfaces causing physical
damage to organisms. Oxygen transfer could also be impaired.
2013-10-28.
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Hazardous waste
Packaging
Methods of disposal
Mineral oil.
2013-10-28.
10/15
Justification
Calculation method
2013-10-28.
11/15
Nytro Libra
Annex to the extended Safety Data Sheet (eSDS)
Industrial
Manufacture of
substance -Industrial
Distribution of
substance- Industrial
Formulation and (re)
packing of
substances and
mixtures -Industrial
Uses in Coatings Industrial
Uses in Coatings Professional
Use as functional
fluids e.g. cable oils,
transfer oils, coolants,
insulators,
refrigerants, hydraulic
fluids in industrial
equipment including
maintenance and
related material
transfers. -Industrial
Use as functional
fluids e.g. cable oils,
transfer oils, coolants,
insulators,
refrigerants, hydraulic
fluids in industrial
equipment including
maintenance and
related material
transfers. Professional
Mixture
Nytro Libra
Sector of
uses [SU]:
Process
categories
[PROC]:
Product Article
3, 8, 9
1, 2, 3, 4, 8a, 8b, 15
Not
Not
1, 4
applicable. applicable.
3, 10
1, 2, 3, 4, 5, 8a, 8b, 9,
14, 15
Not
Not
2
applicable. applicable.
1, 2, 3, 4, 5, 7, 8a, 8b,
10, 13, 15
Not
Not
4
applicable. applicable.
22
1, 2, 3, 4, 8a, 8b, 9
Not
Not
7
applicable. applicable.
22
1, 2, 3, 8a, 9, 20
Not
Not
9a, 9b
applicable. applicable.
categories categories
[PC]:
[AC]:
Environmental
release
categories
[ERC]:
SpERC
Section 1: - Title
Short title of the exposure
scenario
List of use descriptors
12/15
Nytro Libra
Section 1: - Title
Environmental contributing
scenarios
Health Contributing Scenarios
Number of the ES
Industry Association
Generic exposure scenario
Processes and activities
covered by the exposure
scenario
Concawe
01, 01a, 02, 13a, 13b
01- Manufacture of the substance or use as a process chemical or extraction agent
within closed or contained systems. Includes incidental exposures during recycling/
recovery, material transfers, storage, sampling, associated laboratory activities,
maintenance and loading (including marine vessel/barge, road/rail car and bulk
container).
01a- Bulk loading (including marine vessel/barge, rail/road car and IBC loading) of
substance within closed or contained systems, including incidental exposures during
its sampling, storage, unloading, maintenance and associated laboratory activities.
02- Formulation, packing and re-packing of the substance and its mixtures in batch
or continuous operations, including storage, materials transfers, mixing, tabletting,
compression, pelletisation, extrusion, large and small scale packing, sampling,
maintenance and associated laboratory activities.
13a- Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators,
refrigerants, hydraulic fluids in industrial equipment including maintenance and
related material transfers.
13b- Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators,
refrigerants, hydraulic fluids in professional equipment including maintenance and
related material transfers.
Additional information
Organisational measures to
prevent/limit release from site
Conditions and measures
related to external treatment
of waste for disposal
Conditions and measures
related to external recovery
of waste
13/15
Nytro Libra
Not applicable.
14/15
Nytro Libra
Health