Beruflich Dokumente
Kultur Dokumente
Department of Chemical Engineering, Tarbiat Modares University, Jalal Ale Ahmad Highway, P.O. Box 14115-111, Tehran, Iran
Catalysis and Nanotechnology Research Division, Research Institute of Petroleum Industry (RIPI), P.O. Box 14665-1998, Tehran, Iran
c
Department of Chemistry, University of Zanjan, P.O. Box 45195-313, Zanjan, Iran
b
A R T I C L E I N F O
Article history:
Received 4 June 2013
Accepted 19 August 2013
Available online 30 August 2013
Keywords:
Pickering emulsion
Nanohybrid
Enhanced oil recovery
Silica
Carbon nanotube
A B S T R A C T
1. Introduction
Gradual reductions in oil extraction from old reservoirs on the
one hand and the increasing demand for oil on the other hand have
encouraged scientists to apply emerging novel technologies for
enhanced oil recovery (EOR) [14]. In this respect, nanotechnology,
as a leading edge and promising technology, has recently attracted
the attention of many scientists. Various strategies have so far been
proposed for implementation of this technology in EOR processes,
among which are the use of polymeric nanocomposites [5,6],
synthesis and application of emulsions and micro-emulsions in
EOR process [79], the use of nanocatalysts in water and oil
interface within oil reservoirs [1012], employing nano-surfactants [13,14], and the injection of metallic nanomaterials into the
oil reservoirs [15]. The diversity in these listed efforts to integrate
nanotechnology in EOR processes can be attributed to the
following factors: (A) intense diversity in the type of oil and its
1226-086X/$ see front matter 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.jiec.2013.08.022
A.H. Bornaee et al. / Journal of Industrial and Engineering Chemistry 20 (2014) 17201726
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2.1. Materials
2.5. Analysis methods
MWCNT was supplied by Nanotechnology Research Center of
Research Institute of Petroleum Industry (RIPI) [24]. Functionalized nanotubes were prepared through reuxing by a 12 molar
nitric acid solution (70 mL acid/g MWCNT). Sodium silicate (SiO2/
Na2O = 2.1) was used as the precursor to form the silica structure.
CaCl22H2O, MgCl26H2O, and NaCl (Merck) were the ionic salts
used in this study. The oily phase used in this research was
kerosene supplied by Tehran Oil Renery. Formation water
samples and their analyses were taken from Water and Environment Research Centre of Research Institute of Petroleum Industry
(RIPI).
2.2. Production of nanostructured nanohybrid
Functionalized MWCNTs were added to silica formation
reaction in order to produce these types of nanohybrids by sol
gel method. The functionalized MWCNT was kept in 50 mL of 2.5%
hydrochloric acid at 80 8C with a stirring rate of 300 rpm until the
functionalized MWCNT was fully distributed. Afterwards, the
Table 1
Concentration of ions in water in various synthesized samples.
Sample
Ca2+ (mg/L)
Mg2+ (mg/L)
Na+ (mg/L)
a
b
c
d
e
0
0
3000
6000
6000
0
0
750
1500
1500
0
40 000
0
0
10 000
A.H. Bornaee et al. / Journal of Industrial and Engineering Chemistry 20 (2014) 17201726
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Table 2
Concentration of cations in formation water taken from southwestern oil elds in Iran.
Sample
Ca2+ (mg/L)
Mg2+ (mg/L)
Na+ (mg/L)
K+ (mg/L)
Sr2+ (mg/L)
Oil (mg/L)
f
g
9400
11 650
2420
3061
29 900
31 100
270
4
1715
15
113
42
similar in size, it seems that the type of ionic charge is the most
important parameter in changing the structural behavior. Studies
also reveal that the ions bring about irreversible changes in the
nanohybrid. The effect of ion interactions on the nanohybrid
behavior was also studied in multi-ionic systems. It appeared that
sodium ions did not disturb the magnesium and calcium ions. The
images, taken by the optic microscope, show that the drop size in
all systems is approximately equal.
Nanohybrid behavior was studied in formation water (f and g
samples). Stable emulsion was formed as an intervening phase.
Fig. 1. Left: Sedimentation of nanohybrid in the beginning of immersion. Right: Spontaneous emulsication of O/W that tends to be placed in the interface by stirring.
A.H. Bornaee et al. / Journal of Industrial and Engineering Chemistry 20 (2014) 17201726
1723
Fig. 3. Optic microscopic images from water and oil interface and the emulsion stabilized by functionalized MWCNT-silica nanohybrid with a concentration of 0.1%. No
emulsion has been formed in Sample b, which contained only sodium ions.
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A.H. Bornaee et al. / Journal of Industrial and Engineering Chemistry 20 (2014) 17201726
Fig. 4. Zeta potential for equal concentrations of the nanohybrid. (A) Nanohybrid in an ion-free environment and (B) nanohybrid after the effect of ions.
FT-IR analysis was carried out on the structure before and after
being immersed in water in order to study the bonds of the
structure affected by ions dissolved in water. Fig. 6 displays the
results of the analysis. Taking into consideration the nanohybrid
combination, small movements in the peaks seem to be normal.
Sample b was dried at a temperature of 80 8C for 72 h after being
immersed in salt-containing water. However, a great peak
intensity increase is seen for this sample in the range of
3400 cm 1. The reason is the presence of crystal water in the
Fig. 5. XRD analysis and peak list of the structure before and after the effect of ions. (A) Nanohybrid before the effect of ions on its structure: silica structure is seen in form of
amorphous. (B) Nanohybrid after the effect of ions on its structure: nanohybrid has an alpha quartz structure.
A.H. Bornaee et al. / Journal of Industrial and Engineering Chemistry 20 (2014) 17201726
1725
0.0016
0.0014
0.0012
0.0010
0.0008
0.0006
0.0004
Fig. 6. FT-IR analysis of the nanohybrid: (A) before the effect of ions on nanohybrid
structure and (B) after the effect of ions on nanohybrid structure.
0.0002
0.0000
1e+02
1e+03
Fig. 7. Average size of pore diameters on the structure is in the two ranges of about
23 nm and 30 nm, which increases the possibility of the presence of water in the
pores.
Fig. 8. (A) SEM image of nanohybrid structure with clarity of 500 nm. (B) TEM image of nanohybrid structure. Carbon nanotube structure and silica particles can clearly be
distinguished.
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