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You are on page 1of 25

BMAT1/CPM/P(II)/Qns

05.12.2010

FOR OUR STUDENTS

TOWARDS

PAPER II

CHEMISTRY PHYSICS MATHEMATICS

QUESTION PAPER CODE

Time: 3 Hours

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

A. General

1. This booklet is your Question Paper containing 57 questions. The booklet has 25 pages.

2. This question paper CODE is printed on the right hand top corner of this sheet and on the back page

(page no. 25) of this booklet.

4. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers, and electronic

gadgets in any form are not allowed to be carried inside the examination hall.

5. Fill in the boxes provided below on this page and also write your Name and Enrollment No. in the

space provided on the back page (page no. 25) of this booklet.

6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided separately, in which

appropriate bubble for each question must be darkened with HB pencil.

SEAL

3. This question paper contains 2 blank pages for your rough work. No additional sheets will be provided for

rough work.

8. Do not break the seals of the question paper booklet before being instructed to do so by the invigilators.

B. Question paper format: Read the instructions printed on the back page (page no. 25) of this booklet.

C. Marking scheme: Read the instructions on the back page (page no. 25) of this booklet.

Name: .

Enrollment No.:

shall abide by them.

filled in by the Candidate.

IIT/B.MAT1/CPM/P(II) - 1

SEAL

DO NOT BREAK THE SEALS ON THIS BOOKLET, AWAIT INSTRUCTIONS FROM THE INVIGILATOR

INSTRUCTIONS:

CHEMISTRY

TEST-II

PART-I

Atomic number: Co = 27, Pt = 78 ; RH = 109677 cm1 ; Velocity of light, C = 3 108 m sec1

SECTIONI

Single Correct Choice Type

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) for its answer, out of which ONLY ONE is correct.

CH3O

1.

(b)

AlBr3(3 equiv.)

AlBr3(1 equiv.)

CH2Cl2

CH3O

Cl

CH3O

(A)

CH3O

O

CH3O

(B)

CH3O

O

CH3O

(C)

CH3O

O

CH3O

(D)

CH3O

O

2.

(a)

CH2Cl2

O

CH3O

,

CH3O

CH3O

CH3O

CH3O

,

CH3O

CH3O

,

CH3O

(A) Group I A hydroxides are hygroscopic.

(B) Dissolution of group I A hydroxide is endothermic.

(C) Iodine is considerably more soluble in ethanol than in water.

(D) SO2 bleaches by reduction while Cl2 by oxidation.

IIT/B.MAT1/CPM/P(II) - 2

3.

The E.M.F. of a Daniel cell, Zn(s) | Zn2+(aq) || Cu2+ (aq) | Cu(s) can be increased by

(A) Increasing the area of the electrodes.

(B) Increasing the concentration of the copper sulphate solution.

(C) Increasing the concentration of the zinc sulphate solution.

(D) It remains constant.

4.

(I) The colour of hydrophobic sol depends on the wavelength of light scattered by the

dispersed particle.

(II) The smaller the gold number value of a hydrophilic colloid, the greater is its protective

power.

(III) Equivalent conductance increases with dilution for an electrolyte solution while its

specific conductance decreases.

(IV) Aluminium is obtained from Al2O3 by reduction with carbon monoxide.

The correct statements are

(A) (I) and (II)

(B) (I), (II) and (III)

(C) (II), (III) and (IV)

(D) (I), (III) and (IV)

5.

A solution containing As3+, Cd2+, Ni2+ and Zn2+ is made alkaline with dilute NH4OH and

treated with H2S. The precipitate obtained will consist of

(A) As2S3 and CdS

(B) CdS, NiS, and ZnS

6.

OH / H O

2

(I) (2R, 3S) 3-Bromo-butan-2-ol

OH / H O

2

(II) (2R, 3R) 3-Bromo-butan-2-ol

(A) Reaction (I) will proceed at a faster rate.

(B) Reaction (II) will proceed at a faster rate.

(C) Both the reactions follow different mechanism.

(D) Both the reactions will proceed at the same rate.

IIT/B.MAT1/CPM/P(II) - 3

SECTIONII

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

7.

Among the following the total number of compounds which can act both as an acid and a base

is _______ .

CH3CCH3, PhCPh, CH3COOH, CH3CN, NH3, H2O, SO3, BF3.

O

8.

An electron absorbs a photon of light of frequency 7.312 1014 s 1 in the first excited state of

hydrogen and jumps from there to nth excited state. The value of n is ________ .

9.

depression of 0.93 K in freezing point. The same solution boiled at 100.26C. When 7.9 g

of Bn was dissolved in 100 g water, the solution boiled at 100.44C. Given K f for water =

1.86 K mol1 kg and Atomic mass of B = 31. The value of n is _________ .

10.

Total number of monochlorination products that can be obtained on treating 1-butene with Cl2

in presence of light is _________ .

11. One g of a compound (C 6 H 10 O 5 ) n on combustion gave only CO2(g) and H2O(l) alongwith

17.49 kJ/g of energy. Given: Hf of H2O(l) = 285.85 kJ mol1, Hf of CO2(g) =

293.7 kJ mol1, Hf(C6H10O5)n = 2148.42 kJ mol1. The value of n is _________ .

IIT/B.MAT1/CPM/P(II) - 4

SECTIONIII

Paragraph Type

This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice

questions have to be answered. Each of these question has four choices (A), (B), (C) and (D) out of

which ONLY ONE is correct.

Stereoisomerism occurs when the bond connectivity is the same but the spatial arrangement of

more than one type is possible. Stereoisomerism finds vast use in organic chemistry, mainly

biochemistry as all the biomolecules, are generally stereospecific in their actions. Stereoisomerism

is limited not only to organic compounds but also to inorganic compounds, mainly in

co-ordination complexes.

12.

13.

(B) trans form exists as a pair of enantiomers.

(C) trans form is the meso form.

(D) both (A) and (C).

14.

(B) chelate complex of glycine and platinum shows stereoisomerism.

(C) square planar complex of platinum with four different groups always exists as

enantiomers.

(D) all of these.

IIT/B.MAT1/CPM/P(II) - 5

Compound (A), C 6 H 12 O 2 , optically active was oxidized by Ag( NH 3 ) +2 to an optically active

compound (B), C 6 H 12 O 3 . (A) on oxidation with CrO3 in pyridine gives optically inactive

compound (C) which on treating with Zn-Hg / HCl gave 3-methylpentane. (A) on oxidation with

H 2 CrO 4 gave optically inactive compound (D).

15.

O

(A)

(B)

(C) CH3CH=CCH2CHO

CH3

16.

OH

(A)

OCH3

(B)

O

OCH3

17.

OH

(C)

OCH3

(D)

OH

O

(A)

O

O

(B)

O

O

(C)

O

O

(D)

O

O

IIT/B.MAT1/CPM/P(II) - 6

SECTIONIV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given in

Column I and five statements (p, q, r, s and t) in Column II. Any given statement in

Column I can have correct matching with one or more statement(s) given in Column II. For

example, if for a given question, statement B matches with the statements given in q and r, then for

that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

18.

Column I

(A)

(B)

Column II

H O+ / H O

2

C 2 H 5 O CH = CH 2 3

CH3

CH3

HOCCCCOH

CH3

(q)

Enol

(r)

Cyclic ring

(s)

(t)

Aldehyde

CH3

CH3CCH2CH2CH2Cl

KOH

H2O

OH

(D)

Ketone

Hg2+, H3O+

(C)

(p)

PhCCH3

Br

A+B

IIT/B.MAT1/CPM/P(II) - 7

19.

Column I

Column II

(p)

Ssystem = 0

(q)

Ssurrounding = 0

(r)

Ssys = + ve

(s)

(t)

IIT/B.MAT1/CPM/P(II) - 8

PHYSICS

PART-II

SECTIONI

Single Correct Choice Type

This Section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONLY ONE is correct.

20.

21.

and edge BC is attached with a string such that the loop is

horizontal. A magnetic field is present along +ve x-axis. A

current flows along D A B C D such that the tension

in the string becomes zero. If the direction of current is reversed

by keeping magnitude same, the tension in the string will

become

(A) Mg

(B) 2 Mg

(C) 3 Mg

(D)

Y

B

L

D

Z

3Mg

2

a frictionless surface. When it is at extreme position, a bullet of

mass m moving with a velocity v0 collides and gets embedded

into it at time t = 0. The displacement x at any time t will be

(mv02 = 2kA2 )

k

(A) x = 2 A sin

t + / 4

2m

(B) x = 2 A sin

(C) x = 2 A sin

t +

3

2m

(D) x = A sin

extreme

position

mean

t = 0 position

m

v0 m

x=0

A

k

t

2m

k

t

m

IIT/B.MAT1/CPM/P(II) - 9

10

22.

One mole of oxygen is contained in a rigid container with walls of inner surface area A,

thickness d and thermal conductivity K. The gas is at initial temperature T 0 and the

surrounding temperature of air is 2T 0 . The temperature of the gas at time t is (R is gas

constant)

(A) T = T0 (2 e

(C) T = T0 e

23.

2 KA

t

5 dR

(B) T = T0 (1 e

2 KA

t

5 dR

KA

2 KA

t

5 dR

t

2

(D) T = T0 e dR

5

fixed lightly at P and Q. The youngs modulus of the

material of the wire is Y and a << L. If it is pulled into the

form PRQ, the tension generated in the wire is

2L

P

O

a

T

T

R

(A)

24.

Ya 2

2L2

Ya 2 r 2

L2

(B)

(C)

Ya 2 r 2

2L2

(D)

r 2Ya 2

L2

In the circuit shown, the equivalent resistance between the points A and B is

R

A

(B)

R/4

R

2

to

4R

2R

R

R/2

(A) R

R/4

R/2

to

R/8

(C)

to

4R

3

(D)

2R

3

IIT/B.MAT1/CPM/P(II) - 10

11

25.

fixed vertical circular track of radius 1m. A bullet of mass m

strikes the block horizontally with initial speed

v0 = 990 m/s and remains embedded in the block. Assume

no friction between block and circular track. The ratio of

tangential and centripetal acceleration for = 60 is

(g = 10 m/s2)

(A) 5 3 : 1

(B) 10 : 3

(C)

m v0

2m

(D) 1 : 2 3

3 : 20

SECTIONII

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

26.

electric field of a parallel-plate capacitor whose plates extend over a length l = 6 cm in the

direction of initial velocity. The electric field is normal to the direction of initial velocity and

its strength varies with time as E = a t where a = 3200 Vm1s1. Then the electron enters a

region of uniform magnetic field of induction B = 109 T. Direction of magnetic field is

same as that of the electric field. Calculate the pitch (in mm) of helical path traced by the

electron in the magnetic field. (Mass of electron, m = 9 1031 kg, e = 1.6 1019C). [Neglect

the effect of induced magnetic field].

27.

resistance. On closing switch 2 with other two

switches open, the balance length AJ is L1. On

closing all the switches, the balance length AJ1

is L2. The internal resistance of the battery V is

L

nR. Find n. 1 = 3

L2

V1

J

J1

1

R

3

r

IIT/B.MAT1/CPM/P(II) - 11

12

28.

An adiabatic piston of mass m equally divides a diathermic container of volume V0 and length

l. A light spring connects the piston to the right wall. In equilibrium pressure on each side of

the piston is P0. The container starts moving with acceleration a towards right. The stretch x

of the spring when the acceleration of the piston equals the acceleration of the container is

n

given as

m . Find n (Assume that x << l, the gas in the container has the adiabatic

nP0 A

k+

l

exponent (ratio of CP and CV) = , m = 2kg, a = 2m/s2)

l

k

a

are ideal and surface is frictionless. The rod is

massless. The time period of horizontal

nm

oscillations of the block is 2

s. The

k

strings are inextensible. Find n.

k/4

l

l

k

m

30. A solid sphere of mass m rolling without slipping on a horizontal surface strikes a vertical

wall elastically. The coefficient of friction between the sphere and the surface is . After the

collision, the centre of mass of the sphere follows a parabolic trajectory and the sphere strikes

the horizontal surface at a distance R from the wall. The value of such that R is maximum is

1

. Find n.

n

IIT/B.MAT1/CPM/P(II) - 12

13

SECTIONIII

Paragraph Type

This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions have

to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY

ONE is correct.

The ability of a capacitor to store potential energy is the basis of defibrillator devices, which

are used in emergency by medical team to stop the fibrillation of heart attack victims. In a

portable defibrillator device, a battery charges a capacitor to a high potential difference,

storing a large amount of energy in less than a minute. The battery maintains only a modest

potential difference, an electronic circuit repeatedly uses that potential difference for greatly

increasing the potential difference of the capacitor. When a control switch is closed, the

capacitor lends a portion of its stored energy from paddle to paddle through the victim. The

figure shows an arrangement, to understand the working of a defibrillator.

R 1 = 12R

k 1 R 3 = 6R

k3

k2

V

31.

C

k4

R 2 = 6R

is given by

t

V 10 RC

e

15 R

t

V

(C)

1 + 5 e 20 RC

90 R

V 20 RC

e

10 R

t

V

(D)

5 2e 20 RC

90 R

(A)

32.

(B)

Long time after closing k 1 , k 2 and k 3 the energy stored in each capacitor is

(A)

CV 2

2

(B)

CV 2

18

(C)

CV 2

72

(D)

CV 2

144

IIT/B.MAT1/CPM/P(II) - 13

14

33.

Long time after closing k 1, k 2 and k 3 , if k 1, k 3 are opened and k 4 is closed, then heat

produced in R 2 will be

1

1

1

1

(A)

(B) CV 2

(C) CV 2

(D) CV 2

CV 2

36

9

4

6

A particle of mass 10 kg is projected from a

horizontal surface with a velocity of 20 m/s at an

angle of 60 with the horizontal. When it hits the

horizontal surface, its velocity makes an angle of 30

with the horizontal. Apart from gravity, a horizontal

force acts on the particle during the motion

(g = 10 m/s2)

34.

35.

36.

20m/s

60

30

(A) 20 m/s

(B) 20 3 m/s

(C) 10 m/s

(D) 10 3 m/s.

The work done by the horizontal force during the complete motion is

(A) 2000 J

(B) 6000 J

(C) 5000 J

(D) 4000 J.

The average power delivered by the horizontal force during the time of flight will be

(A)

1000

W

3

(B) 1000 W

(C)

2000

W

3

(D) 2000 W.

IIT/B.MAT1/CPM/P(II) - 14

15

SECTIONIV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given in

Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I

can have correct matching with one or more statement(s) given in Column II.

For example, if for a given question, statement B matches with the statements given in q and r, then

for that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

37.

(A)

All the lenses used in column I are thin, each of refractive index = 1.5 and one of their

surfaces is silvered. An object is shown moving in front of their silvered surface. Match with

column II suitably.

Column-I

Column-II

R=20cm

2cm/s

O

(p)

given instant.

(q)

(r)

magnitude of power 10 D

(s)

(t)

to the direction of objects velocity

40/3cm

2cm/s

(B)

6cm

R1=20cm R2=10cm

R=40cm

(C)

0.5cm/s

O

80cm

O

(D)

5cm

4cm/s

R1=R2=10cm

IIT/B.MAT1/CPM/P(II) - 15

16

38.

In column I, certain thermodynamic process are given and in column II, the value of physical

quantities are given. Match the column I with the column II suitably.

Q = amount of heat exchange,

U = change in internal energy,

W = amount of pressure-volume work,

T = temperature of the gas,

P = pressure of the gas,

= density of the gas.

(A) 1 mole of N2

Column I

V

V T

T0

P

(B)

1 mole of He

Column II

2T0

2T0

P

T0

1

T

2T0

degree of freedom f = 4

(q)

| U |

(r)

| W | RT0

(s)

line.

(t)

parabola

3

RT0

2

V

T0

| Q | 2 RT0

P T

T0

1 mole of a gaseous V

mixture having

(C) adiabatic index

= 1.5

(p)

1

T

2T0

IIT/B.MAT1/CPM/P(II) - 16

17

MATHEMATICS

PART-III

SECTIONI

Single Correct Choice Type

This Section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)

and (D) out of which ONLY ONE is correct.

39.

1

2

4

7

3

5

6

9

10

(A) 58

(B) 61

(C) 63

40.

(A) k <

41.

(D) 65

1

2

(B) k > 4

(C)

1

k4

2

(D)

1

k 5.

2

2

Let two non-collinear vectors a and b inclined at an angle

be such that a = 3 and

3

b = 2. If a point P moves so that at any time t its position vector OP (where O is the

1 1

origin) is given as OP = t + a + t b , then least distance of P from the origin is

t

t

(A)

42.

2 133 10

(B)

2 133 + 10

(C) 5 + 133

least value of n for which a 2 + a3 is negative, is

(A) 2

(B) 6

(C) 4

(D) 1

IIT/B.MAT1/CPM/P(II) - 17

18

43.

44.

1

p ( x)

has the form k n n +1 where

x 1

( x 1)

pn ( x) is a polynomial of degree n with p 0 (1) = 1 . Then the value of pn (1) is

(A) (n 1) ! (k )n

(B) n ! (k )n 1

(C) (n 1) ! (k )n 1

(D) n ! (k ) n .

If f ( x) = x + sin x, then

( x)dx is equal to

(A)

3 2

2

2

(C) 3 2

(B)

3 2

+2

2

SECTIONII

Integer Type

This section contains FIVE questions. The answer to each question is a single-digit integer,

ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

45.

Number of triangles with each side having integral length and the longest side is of 11 unit is

equal to k 2 . Then the value of k is equal to

46.

47.

1

having slope unity is

, then k is equal to

k

48.

1

If x 0, and cos x = then the value of

3

2

n =0

cos nx

is equal to .

3n

IIT/B.MAT1/CPM/P(II) - 18

19

49.

Let

S1

and

denote

S2

the

circles

x 2 + y 2 + 10 x 24 y 87 = 0

and

which the line y = ax contains the centre of a circle which touches S2 externally and S1

p

internally). Given that m 2 = , where p and q are relatively prime integers, if ( p + q ) is

q

k

equal to 13 , then the value of k is equal to .

2

SECTIONIII

Paragraph Type

This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions have

to be answered. Each of these uestions has four choices (A), (B), (C) and (D) out of which ONLY

ONE is correct.

Paragraph for Question Nos. 50 to 52

A parabola touches the bisectors of the angle obtained by the lines x + 2 y + 3 = 0 and

2 x + y + 3 = 0 at the points (1, 1) and (0, 2) .

50.

(A) (2, 3)

2 7

(C) ,

5 5

51.

(A) 3 x + y + 4 = 0

(C) 8 x y + 7 = 0

52.

(B) ( 2, 3)

1 7

(D) ,

5 5

(B) x 3 y 2 = 0

(D) none of these

16

(A) 3 / 2

5

16 5

(C)

( 2 )3 / 2

16 2

5

16 2

(D)

(5)3 / 2

(B)

IIT/B.MAT1/CPM/P(II) - 19

20

Let f ( x) = x 4 6 x 3 + 26 x 2 46 x + 65 . All the roots of f ( x) = 0 are of the form ak + ibk for

k = 1, 2, 3, 4,

where

i = 1.

Further

a k and bk

are

all

integers.

Also

ai ' s and bi ' s, then

The value of + is equal to

(A) 16

(C) 10

(B) 4

(D) 6.

54.

(A) 1 2 i, 2 3 i

(C) 2 2 i, 1 3 i

(B) 2 2 i, 1 3 i

(D) 1 2 i, 2 3 i .

55.

53.

(A) 84

(C) 85

(B) 88

(D) 86 .

IIT/B.MAT1/CPM/P(II) - 20

21

SECTIONIV

Matrix Type

This section contains 2 questions. Each question has four statements (A, B, C and D) given in

Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I

can have correct matching with one or more statement(s) given in Column II.

For example, if for a given question, statement B matches with the statements given in q and r, then

for that particular question, against statement B, darken the bubbles corresponding to

q and r in the ORS.

56.

Column I

(A)

(B)

f ( x) =

Column II

(p)

x

, is

x

part of x) is

Discontinuous function

Even function

x2 + x + 2

, is

f ( x) = sgn 2

x + x +1

(r)

Odd function

(C)

(D)

f ( x) = [ x] + [1 x], is

(s)

Periodic function

(t)

Continuous function

IIT/B.MAT1/CPM/P(II) - 21

22

57.

Column I

Column II

(A)

different boxes if each box can have at most one ball is greater than

or equal to

(p)

361

(B)

in the plane x 2 y z + 1 = 0 is equal to

(q)

392

(C)

a 8 8 chess board, so that all the squares are in same diagonal line

is equal to

(r)

(D)

Number of ways in which the letters of the word ' ABBCABBC ' can

be arranged such that the word ABBC does not appear in any word

is less than or equal to

(s)

35

(t)

12

IIT/B.MAT1/CPM/P(II) - 22

23

IIT/B.MAT1/CPM/P(II) - 23

24

IIT/B.MAT1/CPM/P(II) - 24

25

Name: .

Enrollment No.:

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

9. The question paper consists of 3 parts (Part I: Chemistry, Part II: Physics and Part III: Mathematics). Each

part has 4 sections.

10. Section I contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its

answer, out of which only one is correct.

11. Section II contains 5 questions. The answer to each of the questions is a single-digit integer, ranging

from 0 to 9. The answer will have to be appropriately bubbled in the ORS as per the instructions given at the

beginning of the section.

12. Section III of each part contains 2 sets of Comprehension type questions. Each set consists of a paragraph

followed by 3 questions. Each question has 4 choices (A), (B), (C) and (D) out of which only one Choice is

correct.

13. Section IV contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and

five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching

with one or more statement(s) given in Column II. For example, if for a given question, statement B

matches with the statements given in q and r, then for that particular question, against statement B, darken

the bubbles corresponding to q and r in the ORS.

D. Marking scheme:

14. For each question in Section I, you will be awarded 5 marks if you darken the bubble corresponding to

the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus

two ( 2 ) mark will be awarded.

15. For each question in Section II, you will be awarded 3 marks if you darken the bubble corresponding to

the correct choice for the answer, and zero mark if no bubble is darkened. No negative marks will be

awarded for incorrect answers in this section.

16. For each question in Section III you will be awarded 3 marks if you darken only the bubble corresponding

to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (1) mark will

be awarded.

17. For each question in Section IV, you will be awarded 2 marks for each row in which you have darkened

the bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of

8 marks. There is no negative marking for incorrect answer(s) for this section.

IIT/B.MAT1/CPM/P(II) - 25

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