BMAT2/CPM/P(II)/Qns
19.12.2010
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. General
1. This booklet is your Question Paper containing 57 questions. The booklet has 25 pages.
2. This question paper CODE is printed on the right hand top corner of this sheet and on the back page
(page no. 25) of this booklet.
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6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided separately, in which
appropriate bubble for each question must be darkened with HB pencil.
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rough work.
Name: .
Enrollment No.:
IIT/B.MAT2/CPM/P(II) - 1
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INSTRUCTIONS:
TEST-II
CHEMISTRY
PART-I
SECTIONI
Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B) ,
(C) and (D) for its answer, out of which ONLY ONE is correct.
1.
2.
A 250 ml flask containing NO(g) at 046 atm is connected to a 100 ml flask containing oxygen
gas at 086 atm by means of a stop cock at 350 K. The gases are mixed by opening the stop
cock where the following equilibrium is established.
2NO(g) + O2(g) 2NO2(g)
N2O4(g)
The first reaction is complete while the second is at equilibrium. If the total pressure is
037 atm, Kp is
(A) 10 atm1
(B) 0645 atm 1
Calculate the ratio of pH of a solution containing 1 mole of CH 3COONa + 1 mole of HCl per
litre to that of a solution containing 1 mole of CH 3COONa + 1 mole of CH 3COOH per litre.
1
2
(A)
(B)
2
1
3
2
(C)
(D)
2
3
IIT/B.MAT2/CPM/P(II) - 2
4.
A compound has the following percent composition and its molar mass is 148 g mol1.
Be = 61% , N = 378%, Cl = 48%, H = 81% . What is the structural formula for the compound,
if in water, 1.48 g of the compound reacts with excess of AgNO3 to give 2.87 g of AgCl.
(Given : Atomic mass of Be = 9)
(A) [Be(NH 3 )2 Cl 2 ]
(B) [Be(NH3)4]Cl2
(C) [Be(NH 3 )4 Cl 2 ]
5.
(D) [Be(NH3)3Cl]Cl
(III)
C
C
OH
OH
6.
(B) IV only
(D) I and II
IIT/B.MAT2/CPM/P(II) - 3
SECTIONII
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.
7.
8.
If the equilibrium constant for the reaction of weak acid HA with strong base NaOH is 1010,
then the pH of 0.01 M NaA is _______.
Asbestos [CaMg3O(Si 4O11 )] is an example of "amphiboles", which is a special type of chain
silicates in which two strands are cross-linked. The magnitude of charge on silicate anion
is________.
9.
A mixture having one mole each of 1-butene and 2-butene is treated with excess of Br2 in
CCl4 to form C4H8Br2. The number of isomeric structures including stereoisomers of product
C4H8Br2 is _________ .
10.
The 30.87 eV / atom energy released during the following change: A + 2e A2. If the
energy released is used to dissociate 44.8 L of H2 (at STP), equally into H+ and H*
(it is the excited state, where the electrons travels in orbit whose circumference equal to four
times its de-Broglie's wavelength). Find the minimum moles of 'A' that would be required.
H2
H + + H *
(Given : bond energy of H2 = 4.526 eV / molecule, I.E. of H = 13.6 eV/atom)
11. In CsCl structure, the number of Cs+ ions that occupy second nearest neighbour locations of a
Cs+ ion is ________ .
IIT/B.MAT2/CPM/P(II) - 4
SECTIONIII
Paragraph Type
This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice
questions have to be answered. Each of these question has four choices (A), (B) , (C) and (D)
out of which ONLY ONE is correct.
12.
OEt
(i) K2CO3
(ii) Br
X, X is
Br
O O
(A)
13.
OEt
(B)
O OH
O O
(C)
(D)
14.
A, A is
O
COOH
(A)
(B)
(C)
IIT/B.MAT2/CPM/P(II) - 5
15.
The total number of moles of protons, helium nuclei and electrons combined per cm3 at the
core of the sun are
(A) 57
(B) 107
(C) 189
(D) 289
16.
Find the percentage of space occupied by particles in hydrogen gas at 300K and 1 atm. The
radius of nuclear particle can be estimated from r = (1.4 1013 cm) (mass number)1/3.
Assume that the volume of a hydrogen molecule is twice that of a hydrogen atom, and the
hydrogen atom is a sphere with the Bohr radius (0.53 108 cm).
(A) 0.003%
(B) 0.006%
(C) 2%
(D) 0.06%
17.
If the density of the liquid hydrogen is 0.09 gm/cm3 then find the percentage of space
occupied by particles in liquid hydrogen. Other required data can be taken from the above
problem.
(A) 0.003%
(B) 0.03%
(C) 0.0003%
(D) 3%
IIT/B.MAT2/CPM/P(II) - 6
SECTIONIV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D) given in
Column I and five statements (p, q, r, s and t) in Column II. Any given statement in
Column I can have correct matching with one or more statement(s) given in Column II. For
example, if for a given question, statement B matches with the statements given in q and r,
then for that particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
18.
Column I
Column II
(p)
(q)
(r)
(s)
(t)
19.
Column I
Column II
(p)
(q)
100 mL of H2O
(r)
22 g of CO2
(s)
(t)
IIT/B.MAT2/CPM/P(II) - 7
PHYSICS
PART-II
SECTION I
Single Correct Choice Type
This Section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
20.
21.
Electric motor
m
(D) 30 m/s2
v0
m
5R
1
8GM
(A) sin 1
1+ 2
5v0 R
2
1
8GM
(B) sin 1 1 + 2
5v0 R
5
1
2GM
(C) sin 1 1 + 2
5v0 R
5
1
8GM
(D) sin 1 1 + 2
3v0 R
5
IIT/B.MAT2/CPM/P(II) - 8
22.
All the wires on the front and the back hexagonal face (of
the Skelton hexagonal prism) have resistance R. All the
wires along the lines joining the vertices of two hexagons
have resistance 2R. The equivalent resistance between P and
Q as shown in the figure is
Q
(A)
23.
23R
20
15R
20
(C)
13R
20
(D)
(A) 17.8 cm
24.
(B)
(B) 18.7 cm
(C) 23 cm
3R
20
20cm
K
(0, 0)
(D)
Figure (A)
(1m, 0)
20.3 cm
Figure (B)
IIT/B.MAT2/CPM/P(II) - 9
10
25.
A thin walled sphere made up of glass is kept at rest on a horizontal surface. The radius of
the sphere is 1 m and it is filled with a transparent liquid of refractive index . S is the
luminous source moving directly toward a plane vertical mirror M. A fish in the liquid is
moving toward S. The eye of the fish and S are collinear and perpendicular to mirror M. At
the moment S is 3 m away from the center of the sphere, the fish observes that image of S
due to reflection is moving with a speed of 13 ms1. If speed of the fish relative to the sphere
is 10 ms1 and = 1.5, then the speed of the source at that instant will be (The system is
placed in air)
M
Fish
A
2m
S
(A) 10 m/s
(B) 9 m/s
(C) 8 m/s
(D) 6 m/s
SECTION II
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be
bubbled.
26.
The diameter of a wire of length 50 cm is measured with the help of a screw gauge. The main
scale reading is 1mm and circular scale reading is 25. Pitch of the screw gauge is 1 mm and
the total number of divisions on the circular scale is 100. This wire is used in an experiment
of determination for the Youngs modulus of material of a wire by Searles method. The
following data are available: elongation in the wire l = 0.125 cm under the tension of 50 N,
least count for measuring normal length of wire is 0.01 cm and for elongation in the wire is
0.001 cm. The maximum percentage error in calculating value of Youngs modulus (Y) is n
0.484. Find n. (assuming that the force is measured very accurately, Y = Fl/Al, where
symbols have their usual meaning)
IIT/B.MAT2/CPM/P(II) - 10
11
27.
28.
kl n
nkl 3
Q
l
IIT/B.MAT2/CPM/P(II) - 11
12
29.
30.
An adiabatic cylinder of length 1 m and area of cross section 102 m2 is closed at both ends.
A freely moving non conducting thin piston divides the cylinder into two equal parts. Each
part contains 28 gm of N2. The natural length of the spring connected to the piston and the
N
1
right wall of the cylinder is l = 50 cm and k = 2 10 3 . Initially rd molecules of the
m
3
nitrogen in the right part are dissociated into atoms. Initial pressure in each part is
P0 = 2 10 5 N/m2. The gas on left side is heated slowly by the heater so as to compress the
3l
spring by
. The work done by the gas in right part is 707 nJ. Find the value of n.
4
k
IIT/B.MAT2/CPM/P(II) - 12
13
SECTION III
Paragraph Type
This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions
have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
D
l
v
A
B
C
31.
32.
(A) 0.7 v
(C) 0.3 v
33.
v
2
v
(D)
4
(B)
IIT/B.MAT2/CPM/P(II) - 13
14
h1
h0
R
34.
35.
36.
The maximum value of angular velocity of the cylindrical vessel so that the liquid will not
start spilling over the brim is
(A) 2 5 rad/s
(B) 2 10 rad/s
(C) 2 15 rad/s
(D) 3 10 rad/s
If the liquid is not spilling over the brim, the bottom most point of the liquid meniscus will
be at a height of h from the base of the cylindrical vessel. The value of h is
(A) 2 m
(B) 1 m
(C) 1.5 m
(D) 1.2 m
The angular velocity of the cylindrical vessel so that half of the initial volume will spill out is
(A) 2 10 rad/s
(B) 2 15 rad/s
(C) 3 10 rad/s
IIT/B.MAT2/CPM/P(II) - 14
15
SECTION IV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D) given
in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in
Column I can have correct matching with one or more statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in q and
r, then for that particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
37.
Column II
Q
a = 30
(q)
P
V S
R
C
Q
a = 30
IIT/B.MAT2/CPM/P(II) - 15
16
P
V S
a
a = 30
P
V S
a
C
Q
a = 30
(t)
IIT/B.MAT2/CPM/P(II) - 16
17
38.
In the given arrangement, all the strings are ideal. The tension in
each string and acceleration of the blocks are indicated. If
A
T3
pulleys are massless and frictionless, they are termed as ideal
T1 T2
and if pulleys have mass and friction is sufficient to prevent
slipping of thread over the pulley, the pulleys are said to be real.
a1 5kg
B
Column I represents different situation for pulley A and B and
T4
Column II represents the relation between tensions and
20kg
a2
accelerations. Match Column I with Column II.
Column I
Column II
(A)
(p)
T1 = T2
(B)
(q)
T2 = T3
(C)
(r)
T4 = T2 + T3
(D)
(s)
(t)
T4 T2 + T3
a2 < a1
IIT/B.MAT2/CPM/P(II) - 17
18
MATHEMATICS
PART-III
SECTION - I
Single Correct Choice Type
This Section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
39.
40.
41.
(A)
5 +3
4
(B)
3+ 5
4
(C)
3 5
4
(D)
3 5 +1
4
42.
Let w, w is complex cube root of unity and P(z) is point on a circle |z| = 4 such that |z 1| is
maximum and centroid of triangle formed by z, w, w is then Re() is
2
(A) 2
(B) 2
(C) 1
(D)
3
43.
44.
IIT/B.MAT2/CPM/P(II) - 18
19
SECTION II
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be
bubbled.
45.
46.
If four points be taken on a rectangular hyperbola such that the chord joining any two points
is perpendicular to the chord joining the other two points and if , , , be the
inclinations to either asymptote of the straight line joining these points to the centre, then
find the value of tan tan tan tan .
5x
If function f ( x) = cos(nx) sin satisfies f ( x + 3 ) = f ( x), then find the number of
n
integral values of n.
47.
Three circles touch one another externally. The tangents at their points of contact meet at a
point whose distance from point of contact is 4. Find the ratio of the product of the radii to
the double of the sum of the radii of the circles.
48.
49.
Find the number of integral values of 'a ' for which the inequality 3 | x a |> x 2 is satisfied
by at least one negative x.
IIT/B.MAT2/CPM/P(II) - 19
20
SECTION - III
Paragraph Type
This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions
have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
Paragraph for Question Nos. 50 to 52
Consider two parabolas C1 : y = (x 1)2 + f(k) and C2 : x2 2x + 4y 7 = 0 where
1
f(k) = |k2 3 k + 2| + , kR
4
50.
51.
52.
(A) = , k = 1
(C) = , k =
3
2
,k=2
8
(D) = , k = 2
4
(B) =
IIT/B.MAT2/CPM/P(II) - 20
21
53.
54.
(D) a circle
(A) 8
(C)
2
5
2 2
5
(B)
(D)
4 2 1
4 2 +1
5
IIT/B.MAT2/CPM/P(II) - 21
22
SECTION - IV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D)
given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement
in Column I can have correct matching with one or more statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in q
and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.
56.
3
If x , y, z are unit vectors such that x + y + z = a , x ( y z ) = b , ( x y ) z = c , a x = ,
2
7
a y = , a = 2a , then match the following columnI with columnII
4
ColumnI
ColumnII
(A)
x=
p.
4c
(B)
y=
q.
4
(c b )
3
(C)
z=
r.
1
(3a + 4b + 8c )
3
s.
(3a + 4c )
t.
2
c b
3
(D)
3x + 2 y + 3z =
IIT/B.MAT2/CPM/P(II) - 22
23
57.
Column-I
Column-II
(A)
(B)
If f ( ) = 0 , then can be
q.
14
(C)
r.
25
s.
(D)
t.
10
IIT/B.MAT2/CPM/P(II) - 23
24
IIT/B.MAT2/CPM/P(II) - 24
25
Name: .
Enrollment No.:
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
IIT/B.MAT2/CPM/P(II) - 25
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