Beruflich Dokumente
Kultur Dokumente
Calorimetry
1. Define the term heat.
Ans. It is the sum total of kinetic and potential energy of all the molecules of a
given substance.
2. Name the SI unit of heat.
Ans. Joule (J) is the SI unit of heat.
3. Define temperature :
Ans. The average kinetic energy of all the molecules of a given substance is
called temperature.
4. State the SI unit of temperature.
Ans. Kelvin (K) is the SI unit of temperature.
5. The temperature of a substance rises by 25C. How much is the rise on
kelvin scale and why?
Ans. The rise on kelvin scale is 25 K. It is because, rise in temperature in
C = rise in temperature in kelvin.
6. What is a calorimeter? Why is it made of copper? Give two reasons.
Ans. A copper vessel along with copper stirrer used in the measurement of heat
energy is called calorimeter. Calorimeter is made from copper because,
(i) it takes the temperature of the contents within it very quickly.
(ii) it has a very low specific heat capacity and hence takes very little amount
of heat energy from the contents within it.
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11. The thermal capacity of a vessel is 428 J K1. What do you understand by
the statement?
Ans. From the above statement, it implies that, if the temperature of the given vessel
is raised through 1 K, then heat energy required to do so is 428 K.
12. The heat capacity of a vessel is 42 J C1. How much heat energy is required
to raise its temperature from 10C to 20C?
Ans. Rise in temperature = (20 10)C = 10C
Heat energy required to raise its temperature through 10C =
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m1c1T1 + m2 c2T2
m2c2 + m1c1
16. Why are hot water bottles very efficient for fomentation?
Ans.Water has the highest sp. heat capacity of 4.2 Jg1 C1. Furthermore, its
temperature does not rise beyond 100 C, under normal conditions. Thus, it
can store large amount of heat energy at quite a bearable temperature and
hence it is ideal for fomentation purposes.
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17. What are land and sea breezes? Explain how are they caused in the coastal
regions.
Ans. Local winds which blow from the sea to the land during the day-time and from
the land to the sea during night-time are called sea and land breezes.
Formation of sea breeze : Specific latent heat capacity of land is about five time
less, as compared to water. Thus, when the sun shines equally on the sea, as well
as on the land, the land gets comparatively hot as compared to the sea. The air
above the land gets hot and hence, rises, thereby causing a drop in pressure. To
make up for the drop in pressure, the cold air from the sea, blows towards the
land, thereby giving rise to sea breeze.
Formation of land breeze : At night the sea water, as well as the land radiate
heat energy. However, the land radiates heat energy, at much faster rate as
compared to the sea, owing to its five times less specific heat capacity, as
compared to the sea water. Thus, on the whole, the sea is comparatively warmer
as compared to the land. The air above the sea gets warm and rises up.
This causes a fall in pressure. To make up for this fall in pressure, the cold air
from the land blows towards the sea, thereby giving rise to land breeze.
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18. Discuss the role of high specific heat capacity of water, with reference to the
climate in coastal regions.
Ans. The climate in coastal regions remains moderate due to the blowing in of the cold
air from sea during day-time (sea breeze) and blowing out of the cold air from
land to sea (land breeze), during night-time. The land and sea breeze are formed
as under :
Write here formation of land and sea breeze as in Q 17.
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22. Why do sandy soils get heated up quickly as compared to wet soils?
Ans. The specific heat capacity of the sand is about five times less than that of the
water. Thus, when sun shines equally on sandy soil and the wet soil, the sandy
soil gets heated up rapidly as compared to the wet soil. It is because, water
absorbs large amount of heat energy, but its temperature does not rise
sufficiently.
23. Why is water considered the best liquid for quenching thirst?
Ans. Water has the highest specific heat capacity of 4.2 Jg1 C1 and hence it
can absorb large amount of heat energy, without rising in temperature
sufficiently. Thirst is the natural signal, when body produces more heat energy
than required. Thus, water is ideal for quenching thirst, because it can absorb
large amount of heat energy.
24. Why is it advisable to pour cold water over burns, caused on the human body,
by hot solids?
Ans. Water has the highest specific heat capacity of 4.2 Jg1 C1. Thus, it can
extract large amount of heat energy rapidly from the site of burn and hence
gives a lot of relief.
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25. Why does a wise farmer waters his fields, if the forecast says it is going to be
frost?
Ans. The frost can seriously damage the leaves and fruits of the plants.
When a farmer waters his fields, during night, this water gives large amount
of heat energy, because 1 g of water will liberate 4.2 J of energy for every
1 C fall in temperature. Thus, the air around the field is saturated with heat
energy and its temperature does not fall below 0 C. Thus, no frost is formed.
26. Why are big tubs of water kept in underground cellars for storing fresh fruit
and vegetables in cold countries?
Ans. During sub-zero temperatures, the water within the cells of fruits and vegetables
freezes and hence damages them. To avoid such a damage the huge water tubs
are kept. The water gives off 4200 J of heat energy for every one kg for 1 C fall
in temperature. Thus, it does not allow the temperature of cellar to fall below
0 C, and hence, their is no damage to fresh fruits or vegetables.
27. Define the following terms :
(i)Fusion (ii) Melting point
Ans. Fusion : The process of changing of a solid in liquid state, at some fixed
temperature, by the absorption of heat from some external source is called
fusion.
Melting point : It is the temperature at which a solid changes into liquid state.
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29. Bottled drinks are cooled more effectively, when surrounded by lumps of ice
than iced water.
Or
Why do bottled soft drinks get cooled more quickly by ice cubes than by iced
water.
Ans. Every 1 kg of ice at 0 C absorbs 336,000 J of heat energy to form water at
0 C. As ice can extract 336,000 J of heat energy, more than water at 0 C,
therefore, it cools the bottled drinks more effectively.
30 . Why does atmospheric temperature fall after a hailstorm?
Ans. Ice has the highest sp. latent heat of fusion of 336,000 Jkg1. Thus, when the
hail melts, it absorb large amount of heat energy from the surroundings.
Thus, the atmospheric temperature drops.
31. Why does weather become pleasant when it starts freezing in cold countries?
Ans. Ice has the highest sp. latent heat of fusion of 336,000 Jkg1. Thus, every 1 kg
of water at 0 C, on freezing releases 336,000 J of heat energy. As enormous
amount of heat energy is released in atmosphere, therefore weather becomes
pleasant.
32. Why does it gets warm during a snow storm?
Ans. Same as Q.31.
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33. Why does it become bitterly cold when ice melts in cold countries?
Ans. Same as Q.30.
34. Specific latent heat of fusion of lead is 27 103 Jkg 1. What do you
understand by the statement?
Ans. It means one kg of lead at its melting point, on solidification at the same
temperature will release 27 103 J of heat energy.
35. Given figure shows variation in temperature with time when some wax cools
from liquid phase to solid phase.
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Ans.
37. The melting point of naphthalene, a crystalline solid, is 80C and room
temperature is 30C. Liquid naphthalene at 100C is cooled down to room
temperature. Draw a temperature-time graph to represent cooling curve.
Ans.
38. Ice-cream appears colder to mouth than water at 0C. Give a reason.
Ans. Ice has the highest sp. latent heat of fusion, i.e., 336 Jg1. Thus, every one
gram of ice on melting in mouth extracts out 336 J of extra heat energy, as
compared to water at 0C. Thus, ice-cream appears colder than water at 0C.
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Ans. (i) Boiling : The process of rapid change of a liquid into gaseous state, without any
change in temperature, and by the absorption of heat energy from an external
source is called boiling.
(ii) Boiling point : The constant temperature at which a liquid rapidly changes
to its gaseous state is called boiling point.
40. Graph shows change of phases of a substance on temperature-time graph.
(a)What do parts AB, BC, and CD represent?
(b)What is the melting point of substance?
(c) What is the boiling point of substance?
Ans.(a) (i) AB represents the solid being heated still it attains a temp T1.
(ii) BC represents changes in the state of solid to liquid at constant temperature.
(iii) CD represents the liquid being heated till it attains a temperature of T3.
(b) The melting point of the substance is T1.
(c) The boiling point of the substance is T2.
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Numerical Problems
1. Calculate the amount of heat energy required to raise the temperature of 100 g
of copper from 20C to 70C (sp. heat capacity of copper = 390 J kg1 K1)
Ans. Mass of copper (m) = 100 g = 0.1 kg
Rise in temperature ( R ) = (70 20) = 50C
Sp. heat capacity of copper (c) = 390 J kg1 K1
= 390 J kg1 C1
Heat required = mc R
= 0.1 kg 390 J kg1C 50C
= 1950 J
2. 1300 J of heat energy is supplied to raise the temperature of 0.5 kg of lead from
20C to 40C. Calculate the specific heat capacity of lead.
Ans.
c=
H
m R
1300 J
0.5 kg 20C
= 130 J kg1 C1
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= mc R = 50 kg 960 J kg1 K1 20 K
= 960000 J
Energy supplied by the heater = Heat energy absorbed by the material
500 J s1 t = 960000 J
t=
=
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96000 J
500 Js 1
= 1920 s
1920
min = 32 min
60
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= 60000 J
Rise in temperature ( R )
= (15.0 10.0)C
= 5C = 5 K
60000 J
= 12000 JK1
5K
Heat capacity
Mass
12000 JK 1
4.0 kg
= 3000 Jkg 1 K 1
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5. A piece of iron of mass 2.0 kg has thermal capacity 966 J C1. Find : (i) the
heat energy needed to raise it to 15C and (ii) its sp. heat capacity in SI unit.
Thermal capacity
Mass of iron
966 JK 1
2.0 kg
483 Jkg 1 K 1
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52500
30 Js
= 1750 s
1750 s
= 29.167 min
60
7. 200 g mass of a certain metal at 83C is immersed in 300 g water at 30C. The
final temperature is 33C. Calculate the specific heat capacity of the metal.
(Assume that specific heat capacity of water is 4.2 Jg1K1).
Ans.
DATA
Mass
Sp. heat capacity
Initial temp.
Final temp. = 33C
Substances
Metal
Water
200 g
300 g
?
4.2 Jg1K1
83C
30C
f = (83 33)
R = (33 30)
= 50C = 50 K
= 3C = 3 K
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200 g c 50 K = 3780 J
c=
3780 J
200 50 gk
= 0.378 Jg1K1
8. You are required to make a water bath of 40 kg, at 40 C, by mixing hot water
at 100 C and cold water at 15 C. Calculate the ratio of hot and cold water,
which should be mixed.
Substance
Mass
Cold water
Hot water
x
40 kg x
S.H.C
Initial
temp.
4200 Jkg 1 C 1 15 C
4200 Jkg 1 C 1 100 C
Final temp. = 40 C
R = (40 15) = 25 C
F = (100 40) = 60 C
(40 x) 12 = 5x.
480 = 17x
x=
480
= 28.235 kg.
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Ans.
Substance
Mass
S.H.C
4.2 Jg 1 C 1
R = 15C
Hot water
4.2 Jg 1 C 1
50 C
F = (50C x )
300 g
x = 20 C (Final temp.)
10. 200 g of hot water at 80C is added to 400 g of cold water, when the temperature
of cold water rises by 18 C. Calculate the initial temperature of cold water.
Ans. Proceed as in Q 9.
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[Ans. 26 C]
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11. Some amount of heat is given out to 120 g of water and its temperature rises by
10 K. When same amount of heat is given to 60 g of oil, its temperature rises by
40 K. The specific heat capacity of water is 4200 Jkg1 K1. Calculate :
(i) amount of heat in joules given to water.
(ii) specific heat capacity of oil.
120
4200 10
1000
= 5040 J.
(ii) Heat absorbed by water = Heat absorbed by oil
5040 J = 60 g c 40.
c=
5040 1000
60 40
= 2100 Jkg1K1.
12. A metal drill of power 500 W, drills a hole in a metal cube of mass 0.25 kg in
6.5s. The specific heat capacity of lead is 130 J kg1 C1.
(i) How much heat is generated by metal drill in one second?
(ii) Calculate the heat generated in 6.5 s.
(iii) If t C, is the rise in temperature of metal cube, state the amount of heat
energy absorbed by it in terms of t.
(iv) Write down an equation and calculate the value of t.
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t=
3250
= 100 C.
32.5
13. An electric heater is of power 1000 W. It heats 0.4 kg of water for 2 minutes.
The specific heat capacity of water is 4200 J kg1K1.
(i) How much heat is liberated by heater in 1 s?
(ii) How much heat is liberated by heater in 2 minutes?
(iii) If C, is the rise in temperature of water, state the amount of heat energy
absorbed by it, in terms of .
(iv) Write down an equation and calculate the value of .
Ans. Proceed as in Q. 12. [Ans. (i) 1000 J; (ii) 120,000 J; (iii) 1680 ; (iv) 71.428 C]
14. A copper calorimeter, weighing 57.5 g, contains 60 g of water at 12 C. 55 g of
iron nails at 100 C, are dropped into the calorimeter and stirred rapidly. The
final temperature attained by the calorimeter and its contents is 20 C. Calculate
the specific heat capacity of iron. (Sp. heat capacity of copper is 0.4 Jg1 C1
and that of water is 4.2 Jg1 C1.
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Ans.
Substance
Mass
S.H.C
60 g
Iron
55 g
4.2 Jg 1 C 1 12C
100C
?
R = (20 12) = 8C
F = (100 20) = 80C
c=
2200
= 0.5 Jg1 C1.
4400
15. A molten metal weighing 150 g, is kept at its melting point, at 800C. When
allowed to solidify at the same temperature, it gives off 7500 J of heat energy.
What is the specific latent heat of fusion of metal?
If its specific heat capacity is 200 Jkg1 K1, how much additional heat will it
give out in cooling to 50 C?
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7500
= 50 Jgl
150
150
200 [800 ( 50)] J = 25,500 J.
1000
16. A solid weighing 200 g, is kept at its melting point at 0C. When allowed to
melt at the same temperature, it absorbs 67200 J of heat energy.
Calculate the specific latent heat of fusion of solid. If its specific heat
capacity is 4200 Jkg1K1, how much additional heat will it absorb in
attaining a temperature of 80 C?
Ans Proceed as in
17. One kg of molten lead at its melting point 327 C, is dropped in 1 kg of water at
20 C. Assuming no heat is lost to surroundings, calculate final temperature of
water. [Sp. heat capacity of lead and water is 130 Jkg1 K1 and 4200 Jkg1 K1
respectively. Sp. latent heat of fusion of lead = 27000 J kg1]
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Ans.
Substance Mass S.H.C/S.L.H
Lead
Water
R = (x 20C)
1 kg
1 kg
Initial
temp.
130 Jkg 1 C 1 /27000 Jkg 1 327C
20C
4200 Jkg 1 C 1
F = (327C x)
4330x = 153510
x = 35.45 C.
18. 0.6 kg of molten metal at its melting point 420 C, is dropped into 2 kg of water
at 25 C. Assuming no heat is lost to surroundings, calculate the final
temperature of water.[sp. heat capacity of metal and water are 250 Jkg1 K1
and 4200 Jkg1 K1 respectively. Sp. latent heat of fusion of metal = 29000
Jkg1]
Ans. Proceed as Q : 17
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[Ans. 30.98C]
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Ans.(i) Heat required to bring the lead to its melting point = mcR
= 1 130 (327 27) = 39000 J
(ii) Heat required to melt lead = mL = 1 26,000 = 26,000 J.
20. A block of a metal of mass 0.8 kg at 20 C is heated in a furnace, till it
completely melts. Find the quantity of heat required : (i) to bring the metal to its
melting point, (ii) to completely melt the metal at its melting point [m.p of metal
= 420 C; sp. heat capacity of metal 250 Jkg1 K1 and sp. latent heat of fusion
of metal = 29000 Jkg1]
Ans. Proceed as Q : 19
100
kg 4200 20 C = 8400 J
1000
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100
kg 336,000
1000
Jkg1 = 33600 J
Heat lost by ice to attain temp. of 10 C
J
100
kg 2100
10 C = 2100 J
1000
kg. C
Total heat lost= (8400 + 33600 + 2100) J = 44,100 J
44,100 J
22. A cooling machine freezes 1.2 kg of water at 20C, into ice at 40C in
12 minutes. Calculate the average rate of extraction of heat energy in watts.
[S.H.C of ice = 2100 Jkg1 K1, S.H. C of water = 4200 Jkg1 K1, S.L.H of ice
= 336000 Jkg1]
Ans. Proceed as in Q. 21
[Ans. 336 W]
23. An ice cube of mass 30 g, is dropped in 200 g of water at 30 C, such that all the
ice melts. Calculate final temperature of water. [Latent heat of ice = 80 cal g1;
Specific heat capacity of water = 1 cal g1 C1]
Ans.
Substance Mass
S.H.C/S.L.H
Ice
30 g
80 cal g 1
0C
R = ( x 0) = x
Water
200 g
1 cal g 1 C 1
30 C
F = (30 x )
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x = 15.65 C.
24. 50 g of ice cubes are placed in 500 g of water at 40 C, such that all the ice melts.
Calculate final temperature of water. [Latent heat of ice = 80 cal g1; specific heat
capacity of water = 1 cal g1 C1]
Ans. Proceed as in Q. 23
[Ans. 29.09C]
25. 10 g of ice at 0C absorbs 5460 J of heat energy to melt and change to water
at 50C. Calculate the specific latent heat of fusion of ice. Specific heat
capacity of water is 4200 J kg1 K1.
Ans.Mass of ice = 10 g.
Heat absorbed by ice to form water at 0C = m Lice = 10 g Lice
Rise in temperature ( R ) = (50 0) = 50C.
Heat absorbed by water at 0C to attain temp. of 50C
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Lice =
3360 J
= 336 Jg1.
10 g
26. How much heat is released when 5.0 g of water at 20C changes to ice at 0C?
[Take sp. heat capacity of water = 4.2 J g1C1, specific latent heat of
fusion of ice = 336 Jg1]
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5712 J
= 336 Jg1.
17 g
28. Find the result of mixing 10 g of ice at 10C with 10 g of water at 10C.
[sp. heat capacity of ice = 2.1 Jg1K1; sp. latent heat of ice = 336 Jg1
and specific heat capacity of water = 4.2 J g1 K1]
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29. What will be the result of mixing 400 g of copper chips at 500C with 500 g of
crushed ice at 0C.
[sp. heat capacity of copper = 0.42 Jg1K1 and sp.
latent heat of fusion of ice = 340 Jg1].
x=
84000
= 247.05 g
340
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