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INTRODUCTION TO
CHEMICAL ENGINEERING
Look it up.
Perrys Chemical Engineers Handbook, 8th ed. RH Perry
& DW Green, Eds., McGraw-Hill, New York, ___.
CRC Handbook of Chemistry and Physics, 79th ed. D
Lide, Ed., Chemical Rubber Company, Boca Raton, FL.
1998.
Estimate it.
Use empirical correlations (Reid, Prausnitz & Poling. The
Properties of Gases and Liquids. 4th ed. McGraw-Hill,
New York, 1986.)
Measure it.
Determine properties experimentally using published
methods or techniques.
Incompressible substances
Sources of Densities
REFERENCE
DETAILS
Different substances at
a single temp.
Perrys ChE
Handbook, 7th ed.
Different substances
Liquid mixtures or
solutions of a solid in a
liquid
Densities of Mixtures
i 1
xi
xi i
i 1
Sample Problem
1.29 g / cm3
EQUATION OF STATE
PV nRT
Where:
P = absolute pressure of a gas
V or V = volume or volumetric
flow rate of the gas
n or n = number of moles or
molar flow rate of the gas
R = the gas constant
T = absolute temperature of the
gas
PV nRT
IDEAL GAS EQUATION - derived
from the kinetic theory of gases with
the assumptions that gas molecules:
have negligible volume
exert no forces on each other
collide elastically with the walls of
their container.
Does not require a knowledge of the gas species: 1 mol of an ideal gas at
0 oC and 1 atm occupies 22.415 Liters
Gas constant R units:
(pressure x volume)/(mole x temperature)
(energy)/(mole x temperature)
Videal RT / P
(diatomic gases)
(other gases)
Sample Problem
Sample Problems
An ideal gas mixture at 10 bar absolute and 200oC in a 100m3 tank contains 50 mole% H2 and 50 mole% N2. What is the
partial pressure of H2? What is the pure-component volume of
H2? What would happen to PH2 and VH2 if the temperature
were raised?
An ideal gas mixture at 10 atm absolute contains 50 wt% H2
and 50 wt% N2. Is the partial pressure of H2 less than, equal
tp, or greater than 5 atm?
CLASS DISMISSED
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