Beruflich Dokumente
Kultur Dokumente
G= H-T*. S
Enthalpy term
Entropy term
H: Measure of the actual energy that is liberated when the reaction occurs
S: Measure of the change in the possibilities for disorder in the products
compared to the reactants
Ellingham Found that, the standard enthalpy and entropy of formation of a compound
dont change significantly with temperature as long as there is no change of state
Y= mx+C
Intercept
Slope
1Ellingham H. J. T., Reducibility of Oxides and sulfides in Metallurgical Processes , J Soc Chem Ind (London) 63 125 (1944)
Oxide stable
Metal stable
Y=-mX
2 F.D. Richardson
and J.H.E. Jeffes, "The Thermodynamics of Substances of Interest in Iron and Steel Making from 0C to 2400C: I-Oxides," J. Iron
and Steel Inst. (1948), 160 261.
Limitation
Limitation
References
1. D.R. Gaskell, "Introduction to the Thermodynamics of Materials
2. http://www.doitpoms.ac.uk/tlplib/ellingham_diagrams/
Thank you
Questions?