MEG Polyester Grade MSDS UK

Safety Data Sheet
MEGlobal Europe GmbH

Safety Data Sheet according to Reg. (EC) N. 453/2010
Product Name: ETHYLENE GLYCOL POLYESTER GRADE
Revision Date: 2014/09/11

Print Date: 12 Sep 2014
MEGlobal Europe GmbH encourages and expects you to read and understand the entire (M)SDS, as
there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
Section 1. Identification of the substance/preparation and of the

company/undertaking
1.1 Product identifiers
Product Name
ETHYLENE GLYCOL POLYESTER GRADE
Chemical Name: Ethanediol; ethylene glycol
CAS-No. 107-21-1
EC-No. 203-473-3
REACH Registration Number
01-2119456816-28-0009
01-2119456816-28-0012
01-2119456816-28-0013
01-2119456816-28-0014
01-2119456816-28-0015
01-2119456816-28-0016
01-2119456816-28-0017
01-2119456816-28-0018
01-2119456816-28-0074
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Manufacture of substances Industrial use as intermediate. Use as process chemical, industrial.
Distribution of substance, industrial. Formulation & (re)packing of substances and mixtures, industrial.
Polymer production, industrial. Use in paints and coatings, industrial. Use in Cleaning Agents,
industrial. Use in lubricants, industrial. Use in metal-working fluids, industrial. Use in laboratories,
industrial. Water treatment chemicals Production of polymers, filled polymers, foams, coatings,
adhesives and sealants, industrial. Functional Fluids, industrial. Use in paints, coatings, adhesives,
sealants, foams, polymers and filled polymers, professional. Use in Cleaning Agents, professional.
Use in metal-working fluids, professional. Functional Fluids, professional. Use in laboratories,
professional. Use in paints, coatings and surface treatment products, consumer. Use in heat transfer
and hydraulic fluids, consumer. Use in adhesives and sealants, consumer. Production of rigid foam,
consumer.
Uses advised against
Production of tobacco products Generation of artificial smoke Electronic cigarettes (e-cigarettes)
Applications with direct or indirect food or potable water contact Any application where the product is
to be purposely used as a non-reactant component where the potential for sufficient human contact
and/or ingestion exists Freezer gel packs and heating packs Glues and pastes Manufacturing of
munitions Sprinkler systems Deicing of road or sidewalks Deicing of aircraft lavatories Consumer or
hospital usage for deodorizing or air purifying purposes by spraying as an aerosol Fluid for pressure
testing piping Pharmaceutical Use Treatment of wood rot and fungus in marine applications
(TM)*Trademark
Page 1 of 74
1.3 Details of the supplier of the safety data sheet

COMPANY IDENTIFICATION
MEGlobal Europe GmbH
Bachtobelstrasse 3
8810 Horgen
Switzerland
Customer Information Number:
+41 44728 2077

http://www.meglobal.biz/
SDSQuestion@dow.com
1.4 EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact:
Local Emergency Contact:
Section 2.
0041 447 28 2820

00 31 115 69 4982
Hazards Identification
2.1 Classification of the substance or mixture

Classification - REGULATION (EC) No 1272/2008
Acute toxicity (Oral)
Specific target organ
toxicity - repeated
exposure (Oral)
Category 4
Category 2
H302
H373
Harmful if swallowed.
May cause damage to organs through
prolonged or repeated exposure if
swallowed.
Classification according to EU Directives 67/548/EEC or 1999/45/EC

Xn
R48/22
Harmful: danger of serious damage to

health by prolonged exposure if
swallowed.
2.2 Label elements

Labelling - REGULATION (EC) No 1272/2008
Hazard pictograms
Signal Word: Warning

Hazard statements:
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements:
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P314 Get medical advice/ attention if you feel unwell.
P501 Dispose of contents and container to licensed, permitted incinerator, or other thermal
destruction device.
2.3 Other Hazards

No information available.
Page 2 of 74
Section 3.
Composition/information on ingredients
3.1 Substance
This product is a substance.
CAS-No. / EC-No. /
Index
REACH No.
Amount
Component
Classification:
REGULATION (EC)
No 1272/2008
CAS-No.
107-21-1
EC-No.
203-473-3
Index
603-027-00-1
01211945681628
> 99.0 %
Ethanediol;
ethylene glycol
Acute Tox., 4, H302

STOT RE, 2, H373
CAS-No. / EC-No. /
Index
Amount
Component
Classification:
67/548/EEC
CAS-No.
107-21-1
EC-No.
203-473-3
Index
603-027-00-1
> 99.0 %
Ethanediol; ethylene
glycol
Xn: R48/22
For the full text of the H-Statements mentioned in this Section, see Section 16.
See Section 16 for full text of R-phrases.
Section 4.
First-aid measures
4.1 Description of first aid measures

General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Skin Contact: Immediately flush skin with water while removing contaminated clothing and shoes. Get
medical attention if symptoms occur. Wash clothing before reuse. Destroy contaminated leather items
such as shoes, belts, and watchbands. Suitable emergency safety shower facility should be
immediately available.
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Ingestion: Do not induce vomiting. Seek medical attention immediately. If person is fully conscious
give 1 cup or 8 ounces (240 ml) of water. If medical advice is delayed and if an adult has swallowed
several ounces of chemical, then give 3-4 ounces (1/3-1/2 Cup) (90-120 ml) of hard liquor such as 80
proof whiskey. For children, give proportionally less liquor at a dose of 0.3 ounce (1 tsp.) (8 ml)
liquor for each 10 pounds of body weight, or 2 ml per kg body weight [e.g., 1.2 ounce (2 1/3 tbsp.) for a
40 pound child or 36 ml for an 18 kg child].
4.2 Most important symptoms and effects, both acute and delayed
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
4.3 Indication of immediate medical attention and special treatment needed

If several ounces (60 - 100 ml) of ethylene glycol have been ingested, early administration of ethanol
may counter the toxic effects (metabolic acidosis, renal damage). Consider hemodialysis or peritoneal
Page 3 of 74
dialysis & thiamine 100 mg plus pyridoxine 50 mg intravenously every 6 hours. If ethanol is used, a
therapeutically effective blood concentration in the range of 100 - 150 mg/dl may be achieved by a
rapid loading dose followed by a continuous intravenous infusion. Consult standard literature for
details of treatment. 4-Methyl pyrazole (Antizol) is an effective blocker of alcohol dehydrogenase
and should be used in the treatment of ethylene glycol (EG), di- or triethylene glycol (DEG, TEG),
ethylene glycol butyl ether (EGBE), or methanol intoxication if available. Fomepizole protocol (Brent,
J. et al., New England Journal of Medicine, Feb. 8, 2001, 344:6, p. 424-9): loading dose 15 mg/kg
intravenously, follow by bolus dose of 10 mg/kg every 12 hours; after 48 hours, increase bolus dose to
15 mg/kg every 12 hours. Continue fomepizole until serum methanol, EG, DEG, TEG or EGBE are
undetectable. The signs and symptoms of poisoning include anion gap metabolic acidosis, CNS
depression, renal tubular injury, and possible late stage cranial nerve involvement. Respiratory
symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure
should be observed 24-48 hours for signs of respiratory distress. In severe poisoning, respiratory
support with mechanical ventilation and positive end expiratory pressure may be required. Maintain
adequate ventilation and oxygenation of the patient. If lavage is performed, suggest endotracheal
and/or esophageal control. Danger from lung aspiration must be weighed against toxicity when
considering emptying the stomach. If burn is present, treat as any thermal burn, after
decontamination. Treatment of exposure should be directed at the control of symptoms and the
clinical condition of the patient.
Section 5.
Fire Fighting Measures
5.1 Extinguishing Media

Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam.
Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF)
or protein foams may function, but will be less effective.
Extinguishing Media to Avoid: Do not use direct water stream. May spread fire.
5.2 Special hazards arising from the substance or mixture

Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Nitrogen oxides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
5.3 Advice for firefighters

Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Burning liquids may be extinguished by
dilution with water. Do not use direct water stream. May spread fire. Move container from fire area if
this is possible without hazard. Burning liquids may be moved by flushing with water to protect
personnel and minimize property damage.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
Section 6.
Accidental Release Measures
6.1
Personal precautions, protective equipment and emergency procedures: Isolate area.
Keep unnecessary and unprotected personnel from entering the area. Refer to Section 7, Handling,
for additional precautionary measures. Use appropriate safety equipment. For additional information,
refer to Section 8, Exposure Controls and Personal Protection.
6.2 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Page 4 of 74
6.3 Methods and materials for containment and cleaning up: Contain spilled material if possible.
Collect in suitable and properly labeled containers. Small spills: Absorb with materials such as: Cat
litter. Sand. Sawdust. Zorb-all. Hazorb. Large spills: Dike area to contain spill. Pump into
suitable and properly labeled containers. See Section 13, Disposal Considerations, for additional
information.
Section 7.
Handling and Storage
7.1 Precautions for safe handling
Handling
General Handling: Do not swallow. Avoid contact with eyes. Wash thoroughly after handling. Spills
of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion. See Section 8, EXPOSURE CONTROLS
AND PERSONAL PROTECTION.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Do not store near food, foodstuffs, drugs or potable water supplies. Additional storage and handling
information on this product may be obtained by calling your sales or customer service contact. Ask for
a product brochure.
7.3 Specific end uses

See the technical data sheet on this product for further information.
Section 8.
Exposure Controls / Personal Protection
8.1 Control parameters
Exposure Limits
Component
List
Type
Value
ACGIH
Ceiling
Aerosol.
TWA
STEL
TWA
Particulate.
TWA Vapor.
STEL Vapor.
TWA Vapor.
100 mg/m3
Ethanediol; ethylene glycol
EU IOELV
EU IOELV
UK WEL
UK WEL
UK WEL
Ireland OELV
Ireland OELV
Ireland OELV
TWA
Particulate.
STEL Vapor.
52 mg/m3 20 ppm SKIN

10 mg/m3 SKIN
Indicative OELV
10 mg/m3 SKIN
Indicative OELV
Indicative OELV
A skin notation following the inhalation exposure guideline refers to the potential for dermal
absorption of the material including mucous membranes and the eyes either by contact with vapors or
by direct skin contact.
It is intended to alert the reader that inhalation may not be the only route of exposure and that
measures to minimize dermal exposures should be considered.
Derived No Effect Level (DNEL)

Workers
Potential Health Effects
Possible route(s) of
exposure:
Value
Page 5 of 74
Acute - systemic effects

Acute - local effects
Long-term - systemic effects
Long-term - local effects
Consumers
Potential Health Effects
Skin contact
Inhalation
Skin contact
Inhalation
Skin contact
Inhalation
Skin contact
Inhalation
Not available
Not available
Not available
Not available
106 mg/kg bw/day
Not available
Not available
35 mg/m3
Possible route(s) of
exposure:
Value
Skin contact
Inhalation
Skin contact
Inhalation
Skin contact
Inhalation
Skin contact
Inhalation
Not available
Not available
Not available
Not available
53 mg/kg bw/day
Not available
Not available
7 mg/m3
Predicted No Effect Concentration (PNEC)

Compartment
Value
Fresh water
Marine water
Intermittent releases
Fresh water sediment
Soil
STP
Remarks
10 mg/l
1 mg/l
10 mg/l
20.9 mg/kg
1.53 mg/kg d.w.
199.5 mg/l
8.2 Exposure controls
Personal Protection
Eye/Face Protection: Use safety glasses (with side shields). Safety glasses (with side shields)
should be consistent with EN 166 or equivalent. If there is a potential for exposure to particles which
could cause eye discomfort, wear chemical goggles. Chemical goggles should be consistent with EN
166 or equivalent. If exposure causes eye discomfort, use a full-face respirator.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task. When handling hot
material, protect skin from thermal burns as well as from skin absorption.
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Use chemical resistant gloves classified under
Standard EN374: Protective gloves against chemicals and micro-organisms. If hands are cut
or scratched, use gloves chemically resistant to this material even for brief exposures. Use
gloves with insulation for thermal protection (EN 407), when needed. Examples of preferred
glove barrier materials include: Natural rubber (latex). Neoprene. Nitrile/butadiene rubber
(nitrile or NBR). Polyethylene. Ethyl vinyl alcohol laminate (EVAL). Polyvinyl alcohol
(PVA). Polyvinyl chloride (PVC or vinyl). When prolonged or frequently repeated contact
may occur, a glove with a protection class of 6 (breakthrough time greater than 480 minutes
according to EN 374) is recommended. When only brief contact is expected, a glove with a
protection class of 2 or higher (breakthrough time greater than 30 minutes according to EN
374) is recommended. NOTICE: The selection of a specific glove for a particular application
and duration of use in a workplace should also take into account all relevant workplace factors
such as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to glove
materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. For most
conditions, no respiratory protection should be needed; however, if material is heated or sprayed, use
Page 6 of 74
an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic
vapor cartridge with a particulate pre-filter, type AP2.
Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in
the work area; wash hands and face before smoking or eating.
Engineering Controls
Ventilation: Use local exhaust ventilation, or other engineering controls to maintain airborne levels
below exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust
ventilation may be necessary for some operations.
Section 9.
Physical and Chemical Properties
9.1 Information on basic physical and chemical properties

Appearance
Physical State
Liquid.
Color
Colorless
Odor
Sweet
Odor Threshold
No test data available
pH
9 Literature
Melting Point
Not applicable to liquids
Freezing Point
-11.2 C Literature
Boiling Point (760 mmHg)
197.4 C Literature .
Flash Point - Closed Cup
111 C Literature
Evaporation Rate (Butyl
0.01 Literature
Acetate = 1)
Flammability (solid, gas)
No
Flammable Limits In Air
Lower: 3.2 %(V) Literature
Upper: 15.3 %(V) Literature
Vapor Pressure
0.067 hPa @ 20 C Literature
Vapor Density (air = 1)
2.1 Literature
Specific Gravity (H2O = 1)
1.115 20 C/20 C Literature
Solubility in water (by
100 % Literature
weight)
Partition coefficient, n-1.36 Measured
octanol/water (log Pow)
Autoignition Temperature
398 C Literature
Decomposition
No test data available
Temperature
Dynamic Viscosity
19.83 mPa.s @ 20 C Literature
Explosive properties
no data available
Oxidizing properties
no data available
9.2 Other information
Solubility in Solvents
Molecular Weight
Molecular Formula
Henrys Law Constant (H)
not applicable
62 g/mol Literature
HOC2H4OH
8.05E-09 atm*m3/mole; 25 C Estimated.
Section 10. Stability and Reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability

Thermally stable at recommended temperatures and pressures.
10.3 Possibility of hazardous reactions

Page 7 of 74
Polymerization will not occur.
10.4 Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Generation of gas during decomposition can cause pressure in closed systems.
10.5 Incompatible Materials: Avoid contact with: Strong acids. Strong bases. Strong oxidizers.
10.6 Hazardous decomposition products
Decomposition products depend upon temperature, air supply and the presence of other materials.
Decomposition products can include and are not limited to: Aldehydes. Alcohols. Ethers.
Section 11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity
Ingestion
Oral toxicity is expected to be moderate in humans due to ethylene glycol even though tests with
animals show a lower degree of toxicity. Ingestion of quantities (approximately 65 mL (2 oz.) for
diethylene glycol or 100 mL (3 oz.) for ethylene glycol) has caused death in humans. May cause
nausea and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure.
For Ethylene glycol: Lethal Dose, Human, adult 100 ml
LD50, rat, male and female 7,712 mg/kg
Aspiration hazard
Based on physical properties, not likely to be an aspiration hazard.
Dermal
Prolonged skin contact is unlikely to result in absorption of harmful amounts. Repeated skin exposure
to large quantities may result in absorption of harmful amounts. Massive contact with damaged skin or
of material sufficiently hot to burn skin may result in absorption of potentially lethal amounts.
LD50, rabbit > 10,600 mg/kg
LD50, mouse, male and female > 3,500 mg/kg
Inhalation
At room temperature, exposure to vapor is minimal due to low volatility. With good ventilation, single
exposure is not expected to cause adverse effects. If material is heated or areas are poorly ventilated,
vapor/mist may accumulate and cause respiratory irritation and symptoms such as headache and
nausea.
LC50, 6 h, Aerosol, rat, male and female > 2.5 mg/l
Eye damage/eye irritation

May cause slight eye irritation. Corneal injury is unlikely. Vapor or mist may cause eye irritation.
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin. Prolonged contact may cause slight skin irritation with
local redness. Repeated contact may cause skin irritation with local redness.
Sensitization
Skin
Did not cause allergic skin reactions when tested in guinea pigs.
Respiratory
No relevant data found.
Repeated Dose Toxicity

Observations in humans include: Nystagmus (involuntary eye movement). In animals, effects have
been reported on the following organs: Kidney. Liver.
Chronic Toxicity and Carcinogenicity

Ethylene glycol did not cause cancer in long-term animal studies.
Developmental Toxicity
Based on animal studies, ingestion of very large amounts of ethylene glycol appears to be the major
and possibly only route of exposure to produce birth defects. Exposures by inhalation or skin contact,
the primary routes of occupational exposure, had minimal effect on the fetus, in animal studies.
Reproductive Toxicity
Ingestion of large amounts of ethylene glycol has been shown to interfere with reproduction in animals.
Genetic Toxicology
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Page 8 of 74
Section 12. Ecological Information

12.1 Toxicity
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, Pimephales promelas (fathead minnow), static test, 96 h: 72,860 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, Daphnia magna (Water flea), static test, 48 h, immobilization: > 100 mg/l
Aquatic Plant Toxicity
ErC50, Pseudokirchneriella subcapitata (green algae), Growth rate inhibition, 96 h: 6,500 - 13,000 mg/l
Toxicity to Micro-organisms
EC50, activated sludge test (OECD 209), Respiration inhibition, 30 min: 225 mg/l
12.2 Persistence and Degradability

Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is
ultimately biodegradable (reaches > 70% biodegradation in OECD test(s) for inherent
biodegradability).
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
10 Day Window
90 - 100 %
10 d
OECD 301A Test
pass
90 %
1d
OECD 302B Test
Not applicable
12.3 Bioaccumulative potential

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient, n-octanol/water (log Pow): -1.36 Measured
12.4 Mobility in soil

Mobility in soil: Given its very low Henrys constant, volatilization from natural bodies of water or
moist soil is not expected to be an important fate process., Potential for mobility in soil is very high
(Koc between 0 and 50).
Partition coefficient, soil organic carbon/water (Koc): 1 Estimated.
Henrys Law Constant (H): 8.05E-09 atm*m3/mole; 25 C Estimated.
12.5 Results of PBT and vPvB assessment

This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is
not considered to be very persistent and very bioaccumulating (vPvB).
12.6 Other adverse effects

This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the
ozone layer.
Section 13. Disposal Considerations

13.1 Waste treatment methods
This product, when being disposed of in its unused and uncontaminated state should be treated as a
hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in
compliance with all national and provincial laws and any municipal or local by-laws governing
hazardous waste. For used, contaminated and residual materials additional evaluations may be
required. Do not dump into any sewers, on the ground, or into any body of water.
Page 9 of 74
Section 14. Transport Information

ADR/RID
14.1 UN number
Not applicable
14.2 UN proper shipping name
Proper Shipping Name: NOT REGULATED
14.3 Transport hazard class(es)
Not applicable
14.4 Packing Group
Not applicable
14.5 Environmental hazards
Not considered environmentally hazardous based on available data
14.6 Special precautions for user
Special Provisions: no data available
Hazard identification No:no data available
ADNR / ADN
14.1 UN number
Not applicable
Not applicable
14.4 Packing Group
Not applicable
no data available
IMDG
14.1 UN number
Not applicable
Not applicable
14.4 Packing Group
Not applicable
EMS Number: Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Product Name: ETHYLENE GLYCOL
Ship Type: 3
Pollution Category: Y
ICAO/IATA
14.1 UN number
Not applicable
Not applicable
14.4 Packing Group
Not applicable
Page 10 of 74

no data available
Section 15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
European Inventory of Existing Commercial Chemical Substances (EINECS)
This product is on the EINECS inventory.
15.2 Chemical Safety Assessment

A Chemical Safety Assessment has been carried out for this substance.
Section 16. Other Information

Hazard statement in the composition section
H302
H373
Harmful if swallowed.
May cause damage to organs through prolonged or repeated exposure if
swallowed.
Risk-phrases in the Composition section

R48/22
Harmful: danger of serious damage to health by prolonged exposure if

swallowed.
Restrictions in Usage:
Production of tobacco products Generation of artificial smoke Electronic cigarettes (e-cigarettes)
Applications with direct or indirect food or potable water contact Any application where the product is
to be purposely used as a non-reactant component where the potential for sufficient human contact
and/or ingestion exists Freezer gel packs and heating packs Glues and pastes Manufacturing of
munitions Sprinkler systems Deicing of road or sidewalks Deicing of aircraft lavatories Consumer or
hospital usage for deodorizing or air purifying purposes by spraying as an aerosol Fluid for pressure
testing piping Pharmaceutical Use Treatment of wood rot and fungus in marine applications
Revision
Identification Number: 23826 / 3945 / Issue Date 2014/09/11 / Version: 12.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
MEGlobal Europe GmbH urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyers/users responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyers/users duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
Page 11 of 74
Section 1
Title
Exposure Scenario: worker

Manufacturing of substance
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 8a, 8b and 15
Product Category
n/a
Article Category
n/a
Environmental Release Category
ERC 1
Specific Environmental Release Category

Processes, tasks, activities covered
ESVOC1
PROC 1- Use of the substance in high integrity contained system
where little potential exists for exposures, e.g. any sampling
via closed loop systems
PROC 2- Continuous process but where the design philosophy is not
specifically aimed at minimizing emissions. Occasional
exposure will arise e.g. through maintenance, sampling and
equipment breakages
PROC 3 and 4- Batch manufacture of a chemical or formulation where the
predominant handling is in a contained manner, e.g. through
enclosed transfers, but where some opportunity for contact
with chemicals occurs, e.g. through sampling
Use in batch manufacture of a chemical where significant
opportunity for exposure arises, e.g. during charging,
sampling or discharge of material, and when the nature of
the design is likely to result in exposure.
PROC 8a- Sampling, loading, filling, transfer, dumping, bagging in
non- dedicated facilities. Exposure related to dust, vapour,
aerosols or spillage, and cleaning of equipment to be
expected.
PROC 8b- Sampling, loading, filling, transfer, dumping, bagging in
dedicated facilities. Exposure related to dust, vapour,
expected.
PROC15- Use of substances at small scale laboratory (< 1 l or 1 kg
present at workplace). Larger laboratories and R+D
installations should be treated as industrial processes.
Section 2
Product/article characteristics
Operational conditions and risk management measures
Physical form of product/article
Liquid
Volatility
1067 hPa or 106.7 kPa (Vapour pressure corresponds to temperatures of ca. 200
C) for PROC 1, 2
0.123 hPa for PROC 3, 4, 8a, 8b and 15
Dustiness
n/a
Concentration in a preparation/product (w/w%)
100%
Other product/article characteristics
n/a
Section 2.1
Operational conditions
Control of worker exposure
Amounts used
Not relevant
Frequency and duration of use
Duration >4hrs/day, Frequency 240 days/year
Human factors not influenced by risk management
PROC 1, 3 and 15- Exposed skin surface- Palm of one hand (240 cm)
PROC 2, 4, 8a, 8b- Exposed skin surface- Palm of both hands (480 cm 2)
Other Operational Conditions affecting exposure
Location-indoor, Domain- industrial
Page 12 of 74
Risk Management Measures

Contributing Scenarios
Use in closed process, no likelihood of exposure
Local exhaust ventilation required- No, Respiratory protection required- No
Use in closed, continuous process with occasional

controlled exposure
Local exhaust ventilation required- Yes (Effectiveness 90%), Respiratory

protection required- No
Use in closed batch process (synthesis or

formulation).
Use in batch and other process (synthesis) where
opportunity for exposure arises.
Transfer of substance or preparation

(charging/discharging) from/to ves-sels/large
containers at non-dedicated facilities
Local exhaust ventilation required- Yes (Effectiveness 90%), In case no LEV is

present, a suitable respiratory protection with adequate effectiveness is
required.Respiratory protection required- No

(charging/discharging) from/to vessels/large
containers at dedicated facilities
Use of substances at small scale laboratory (< 1 l or

1 kg present at workplace). Larger laboratories and
R+D in-stallations should be treated as industrial
processes
Section 2.2
Control of environmental exposure
Amounts used
Maximum daily site tonnage (kg/day): 86773
Frequency and Duration of use/exposure
Emission days (days/year): 300
Environmental factors not influenced by risk

management
Local freshwater dilution factor 10

Local marine water dilution factor 100
Other Operational Conditions of use affecting

environmental exposure
Release fraction to air from process 0.0001

Release fraction to wastewater from process 0.01
Release fraction to soil from process (regional only) 0.0001

Technical conditions and measures at process level
(source) to prevent release
None
Technical onsite conditions and measures to reduce

or limit discharges, air emissions and releases to
soil
Treat wastewater (prior to discharge to receiving water) to provide the required

removal efficiency of (%) 87%
Organisation measures to prevent/limit release from

site
Not relevant
Conditions and measures related to municipal

sewage treatment plant
n/a
Conditions and measures related to external

treatment of waste for disposal
n/a

recovery of waste
n/a
Other environmental control measures additional to

above
n/a
Page 13 of 74
Section 3
3.1. Health
Exposure Estimation
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
3.2. Environment
The environmental assessment was performed using the SpERC scenario.
When the recommended risk management measures and operational conditions are observed, exposures are not expected to exceed the
predicted PNECs and the resulting risk characterisation ratios are expected to be less than 1.
Section 4
Guidance to check compliance with the Exposure Scenario
4.1. Health
Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted.
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at
least equivalent levels.
4.2. Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define
appropriate site-specific risk management measures.
Further details on scaling and control technologies are provided in spERC factsheet (http://cefic.org/en/reeach-for-industrieslibraries.html).
Page 14 of 74
Section 1
Title

Use as Intermediate
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 8a, 8b, 9 and 15;
Product Category
n/a
Article Category
n/a
ERC 6a

Processes, tasks, activities covered (1 of 2)
ESVOC 2
PROC 1- Use of the substance in high integrity contained system where little
potential exists for exposures, e.g. any sampling via closed loop systems
PROC 2- Continuous process but where the design philosophy is not specifically
aimed at minimizing emissions. Occasional exposure will arise e.g. through
maintenance, sampling and equipment breakages
predominant handling is in a contained manner, e.g. through enclosed transfers,
but where some opportunity for contact with chemicals occurs, e.g. through
sampling
Use in batch manufacture of a chemical where significant opportunity for exposure
arises, e.g. during charging, sampling or discharge of material, and when the
nature of the design is likely to result in exposure
Processes, tasks, activities covered (continued, 2 of

2)
PROC 5- Manufacture or formulation of chemical products or articles using

technologies related to mixing and blending of solid or liquid materials, and where
the process is in stages and provides the opportunity for significant contact at any
stage
PROC 8a- Sampling, loading, filling, transfer, dumping, bagging in non- dedicated
facilities. Exposure related to dust, vapour, aerosols or spillage, and cleaning of
equipment to be expected
PROC 8b and 9- Sampling, loading, filling, transfer, dumping, bagging in
dedicated facilities. Exposure related to dust, vapour, aerosols or spillage, and
cleaning of equipment to be expected. Filling lines specifically designed to both
capture vapour and aerosol emissions and minimise spillage
PROC 15- Use of substances at small scale laboratory (< 1 l or 1 kg present at
workplace). Larger laboratories and R+D installations should be treated as
industrial processes
Section 2
Liquid
Volatility
0.123 hPa for PROC 1, 2, 5
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
PROC 2, 4, 5, 8a, 8b and 9- Exposed skin surface- Palm of both hands (480 cm2)

controlled exposure

Page 15 of 74

formulation).Use in batch and other process
(synthesis) where opportunity for exposure arises.
Mixing or blending in batch processes for

formulation of preparations and articles (multistage
and/or significant contact).
Local exhaust ventilation required- No, Respiratory protection required- No, Use
of suitable gloves with specific activity training- Yes (Effectiveness-90%)

containers at non-dedicated facilities.


containers at dedicated facilities. Transfer of
substance or preparation into small containers
(dedicated filling line, including weighing)
Use as laboratory reagent
Section 2.2
Amounts used

management




n/a

soil
Treat wastewater (prior to discharge to receiving water) to

provide the required removal efficiency of (%) ETotal,RMM
= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Page 16 of 74
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 17 of 74
Section 1
Title

Use as Process chemical
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 13, 14, and 15
Product Category
n/a
Article Category
n/a
ERC 4

ESVOC 44
PROC2- Continuous process but where the design philosophy is not
specifically aimed at minimizing emissions. Occasional exposure will arise e.g.
through maintenance, sampling and
equipment breakages
PROC 5- Manufacture or formulation of chemical products or articles
using technologies related to mixing and blending of solid or
liquid materials, and where the process is in stages and
provides the opportunity for significant contact at any stage
PROC8a- Sampling, loading, filling, transfer, dumping, bagging in
expected.
expected.
Filling lines specifically designed to both capture vapour and
aerosol emissions and minimise spillage

2)
PROC 13- Immersion operations. Treatment of articles by dipping,

pouring, immersing, soaking, washing out or washing in
substances; including cold formation or resin type matrix.
Includes handling of treated objects (e.g. after dying,
plating). Substance is applied to a surface by low energy
techniques such as dipping the article into a bath or pouring
a preparation onto a surface.
PROC 14- Processing of preparations and/or substances (liquid and
solid) into preparations or articles. Substances in the
chemical matrix may be exposed to elevated mechanical
and/or thermal energy conditions. Exposure is predominantly
related to volatiles and/or generated fumes, dust may be
formed as well.
PROC 15- Use of substances at small scale laboratory (< 1 l or 1 kg
Page 18 of 74
Section 2
Liquid
Volatility
0.123 hPa for PROC 13 and 14
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
PROC 2, 4, 5, 8a, 8b, 9, 13 and 14- Exposed skin surface- Palm of both hands
(480 cm2)


controlled exposure

formulation).




containers at dedicated facilities. Transfer of
substance or preparation into small containers
Treatment of articles by dipping and pouring.
Production of preparations or articles by tabletting,

compression, extrusion, pelletisation.
Section 2.2
Amounts used

management



Release fraction to wastewater from process 0

n/a
Page 19 of 74

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 20 of 74
Section 1
Title

Distribution of substance
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 8a, 8b, 9, and 15
Product Category
n/a
Article Category
n/a
ERC 1

ESVOC 3
equipment breakages
expected.
expected.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
n/a
PROC 2, 4, 8a, 8b and 9 - Exposed skin surface- Palm of both hands (480 cm2)
n/a
Page 21 of 74


controlled exposure

formulation).



containers at dedicated facilities.
Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
Page 22 of 74
4.2. Environment
Page 23 of 74
Section 1
Title

Formulation & (re)packing of substance and mixtures
Sector of Use
Process Category
SU3
PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 14, and 15
Product Category
n/a
Article Category
n/a
ERC 2
ESVOC 4

equipment breakages
provides the opportunity for significant contact at any stage.
expected.
expected.

chemical matrix may be exposed to elevated mechanical and/or thermal energy
conditions. Exposure is predominantly
formed as well.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Page 24 of 74
Amounts used
n/a
n/a
PROC 2, 4, 5, 8a, 8b, 9 and 14- Exposed skin surface- Palm of both hands (480
cm2)
n/a


controlled exposure
Use in closed batch process (synthesis or formulation). Local exhaust ventilation required- No, Respiratory protection required- No
Mixing or blending in batch processes for formulation
of preparations and articles (multistage and/or
significant contact).
Local exhaust ventilation required- No, Respiratory protection required- No, Use of
suitable gloves with specific activity training- Yes (Effectiveness-90%)

(charging/discharging) from/to vessels/large containers present, a suitable respiratory protection with adequate effectiveness is
at non-dedicated facilities.
(charging/discharging) from/to vessels/large containers
at dedicated facilities.
Section 2.2
Amounts used

management




n/a
Technical onsite conditions and measures to reduce or Treat wastewater (prior to discharge to receiving water) to
limit discharges, air emissions and releases to soil
= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%
n/a
site
Conditions and measures related to municipal sewage n/a
treatment plant
Conditions and measures related to external treatment n/a
of waste for disposal
Conditions and measures related to external recovery n/a
of waste
above
n/a
Page 25 of 74
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least
equivalent levels.
4.2. Environment
Further details on scaling and control technologies are provided in spERC factsheet (http://cefic.org/en/reeach-for-industries-libraries.html).
Page 26 of 74
Section 1
Title

Production of polymers
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 6, 8a, 8b, 9, and 15
Product Category
n/a
Article Category
n/a
ERC 6c

ESVOC 43
equipment breakages
PROC 6- Processing of product matrix Calendering at elevated
temperature an large exposed surface.
expected.

2)

expected.
Section 2
Liquid
Volatility
0.123 hPa- PROC 6
Dustiness
n/a
100%
Fugacity - low
Section 2.1
Amounts used
Not relevant
PROC 2, 4, 5, 6, 8a, 8b and 9- Exposed skin surface- Palm of both hands (480
cm2)

Page 27 of 74

controlled exposure


Calendering operations



Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Page 28 of 74
Section 4
4.1. Health
4.2. Environment
Page 29 of 74
Section 1
Title

Use in Paints/Coatings (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 7, 8a, 8b, 10, 13, and 15
Product Category
n/a
Article Category
n/a
ERC 4

CEPE 16a
equipment breakages
PROC 7- Air dispersive techniques
Spraying for surface coating, adhesives, polishes/cleaners,
air care products, sandblasting
Substances can be inhaled as aerosols. The energy of the
aerosol particles may require advanced exposure controls; in
case of coating, overspray may lead to waste water and
waste.

2)

expected.
expected.
PROC 10- Low energy spreading of e.g. coatings
Including cleaning of surfaces. Substance can be inhaled as
vapours, skin contact can occur through droplets, splashes,
working with wipes and handling of treated surfaces.
Page 30 of 74
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
PROC 2, 4, 5, 6, 8a, 8b and 13- Exposed skin surface- Palm of both hands (480
cm2)
PROC 7- Exposed skin- whole body


controlled exposure

formulation).

Industrial spraying
Local exhaust ventilation (Direction of airflow away from the worker)- Yes
(effectiveness ca. 50%), Respiratory protection required-No, Use of suitable
gloves with basic training-Yes (Effectiveness 90%), Wearing of appropriate
working clothes (e.g. an overall)- Yes (Effectiveness 80%)



Roller application or brushing
Page 31 of 74
Section 2.2
Amounts used

management



Release fraction to soil from process (regional only) 0

n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
CEPE 16a - Wet scrubber or filtration

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 32 of 74
Section 1
Title

Use in Paints/Coatings/ Adhesives/ Sealants/ Foams/
Polymers/
filled Polymers (professional)
Sector of Use
SU22
Process Category
PROC 1, 2, 3, 4, 5, 8a, 8b, 9, 10, 11, 13, 14, 15, and 19
Product Category
n/a
Article Category
n/a
ERC 8d

n/a
equipment breakages

2)

expected.
expected.
PROC 10- Low energy spreading of e.g. coatings. Including cleaning of
surfaces. Substance can be inhaled as vapours, skin contact
can occur through droplets, splashes, working with wipes
and handling of treated surfaces.
PROC 11-Air dispersive techniques
aerosol particles may require advanced exposure controls.
PROC 13 and 14- Immersion operations. Treatment of articles by dipping,
plating,). Substance is applied to a surface by low energy
Use of the substances in high integrity contained system
via closed loop systems.
PROC 19- Addresses occupations where intimate and intentional
contact with substances occurs without any specific exposure
controls other than PPE.
Section 2
Liquid
Volatility
0.123 hPa
Page 33 of 74
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
Exposed skin surface- Palm of one hand (240 cm)- PROC 1 and 3, 15
Palm of two hands (480 cm2)- PROC 2, 4, 5, 8b, 9, 13 and 14
Both hands (960 cm2)- PROC 8a, 10
Both hands and main part of arms (1980 cm2)- PROC 19
Location-indoor, Domain- professional

Use in closed process, no likelihood of
exposure.Use in closed, continuous process with
occasional controlled exposure.Use in closed batch
process (synthesis or formulation).
Local exhaust ventilation required- No, Respiratory protection required- NoLocal

exhaust ventilation required- Yes (Effectiveness 90%), Respiratory protection
required- NoLocal exhaust ventilation required- No, Respiratory protection
required- No

and/or significant con-tact)



containers (dedicated filling line, including weighing).

Non industrial spraying
Respiratory protection required-No, Use of suitable gloves with basic training-Yes

(Effectiveness- 80%), Wearing of appropriate working clothes (e.g. an overall)Yes (Effectiveness-80%)

of suitable gloves with specific activity training- Yes (Effectiveness-90%) Proc 13
and No for PROC 14
Use as laboratory reagent.
Hand-mixing with intimate contact and only PPE

available
Section 2.2
Amounts used

management

Page 34 of 74



n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
CEPE 16b-Wet Scrubber or Filtration

n/a

n/a

recovery of waste
n/a

above
n/a
Page 35 of 74
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
The environmental assessment was performed using ERC (8d).
Section 4
4.1. Health
4.2. Environment
Page 36 of 74
Section 1
Title

Use in Cleaning agents (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 7, 8a, 8b, 10, and 13
Product Category
n/a
Article Category
n/a
ERC 4

AISE 13
equipment breakages
waste.
expected.
expected.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Page 37 of 74
Section 2.1
Amounts used
n/a
n/a
PROC 1, 3 Exposed skin surface- Palm of one hand (240 cm)

PROC 2, 4, 8a, 8b, 10 and 13- Exposed skin surface- Palm of both hands (480
cm2)
n/a


controlled exposure

formulation).
Industrial spraying
gloves with basic
training-Yes (Effectiveness 90%), Wearing of appropriate working clothes (e.g. an
overall)- Yes (Effectiveness 80%)



Section 2.2
Amounts used

management


Release fraction to air from process 0

Page 38 of 74

None

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 39 of 74
Section 1
Title

Use in Cleaning agents (professional)
Sector of Use
SU22
Process Category
PROC 1, 2, 3, 4, 8a, 8b, 10, 11, and 13
Product Category
n/a
Article Category
n/a
ERC 8a

AISE 16
equipment breakages
expected.
expected.
PROC 10- Low energy spreading of e.g. coatings. Including cleaning of
surfaces. Substance can be inhaled as vapours, skin contact
can occur through droplets, splashes, working with wipes
and handling of treated surfaces.
plating,). Substance is applied to a surface by low energy
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Page 40 of 74
Section 2.1
Amounts used
n/a
n/a
PROC 1, 3 - Exposed skin surface- Palm of one hand (240 cm)

PROC 2, 4, 8a, 8b, 10 and 13- Exposed skin surface- Palm of both hands (480
cm2)
PROC 11- Whole body
n/a


controlledexposure

formulation).
opportunity
for exposure arises.

(charging/discharging)
from/to vessels/large containers at non-dedicated
facilities.


from/to vessels/large containers at dedicated
facilities.

Section 2.2
Amounts used

management


Release fraction to air from process 0

Page 41 of 74

n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
EUSES version 2.1. has been used to estimate environmental emissions unless otherwise indicated.
Section 4
4.1. Health
4.2. Environment
Page 42 of 74
Section 1
Title

Use in lubricants (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 7, 8a, 8b, 9, 10, 13, 17 and 18
Product Category
n/a
Article Category
n/a
ERC 4

ESVOC 13
equipment breakages
waste.
expected.
expected.
PROC 9- Filling lines specifically designed to both capture vapour and
aerosol emissions and minimise spillage.
PROC 17 and 18- Lubrication at high energy conditions (temperature, friction)
between moving parts and substance; significant part of
process is open to workers. The metal working fluid may
form aerosols or fumes due to rapidly moving metal parts.
Use as lubricant where significant energy or temperature is
applied between the substance and the moving parts.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
Page 43 of 74
100%
n/a
Section 2.1
Amounts used
Not relevant
Duration > 4 hours/day, Frequency 240 days/year

PROC 2, 4, 5, 8a, 8b, 9, 10, 13, 17 and 18- Exposed skin surface- Palm of both
hands (480 cm2)
Location- Indoor, Domain- Industrial


controlled
exposure

(synthesis) where opportunityfor exposure arises.

formulation of
preparations and articles (multistage and/or
significant
con-tact)
Industrial spraying

from/to vessels/large containers at non-dedicated
facilities.


from/to vessels/large containers at dedicated
facilities.
containers
Lubrication at high energy conditions and in partly

open
process.
Greasing at high energy conditions.
Local exhaust ventilation required- Yes (Effectiveness 90%), In case no local

exhaust ventilation is present a suitable respiratory protection of adequate
effectiveness is required. Respiratory protection required- No, Use of suitable
gloves with basic training- Yes (Effectiveness 90%)
Section 2.2
Amounts used

management



Page 44 of 74

n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
n/a
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 45 of 74
Section 1
Title

Use in metal-working fluids (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 7, 8a, 8b, 9, 10, 13, and 17
Product Category
n/a
Article Category
n/a
ERC 4

ESVOC 18
equipment breakages
waste.
expected.
expected.
PROC 17- Lubrication at high energy conditions (temperature, friction)
process is open to workers. The metal working fluid may
form aerosols or fumes due to rapidly moving metal parts.
Page 46 of 74
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
n/a

PROC 2, 4, 5, 8a, 8b, 9, 10, 13 and 17 Exposed skin surface- Palm of both hands
(480 cm2)
n/a


controlled exposure


and/or significant contact)
Industrial spraying





open process.

Section 2.2
Amounts used
Page 47 of 74

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 48 of 74
Section 1
Title

Use in metal-working fluids (professional)
Sector of Use
SU22
Process Category
PROC 1, 2, 3, 5, 8a, 8b, 9, 10, 11, 13, and 17
Product Category
n/a
Article Category
n/a
ERC 8a

n/a
equipment breakages
PROC 3- Batch manufacture of a chemical or formulation where the
expected.
expected.
aerosol emissions and minimise spillage.
PROC 17- Lubrication at high energy conditions (temperature, friction)
process is open to workers.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
Duration of exposure- >4 hours/day, Frequency of exposure 240 days/yr
Page 49 of 74

PROC 2, 5, 8a, 8b, 9, 10, 13 and 17- Exposed skin surface- Palm of both hands
(480 cm2)
PROC 11- Whole body
Location- Indoor, Domain-Professional


controlled
exposure

formulation).

and/or significant contact)






open process.

Section 2.2
Amounts used

management




soil
n/a

site
n/a

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%
Page 50 of 74

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 51 of 74
Section 1
Title

Use in / as functional fluids (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 8a, 8b, and 9
Product Category
n/a
Article Category
n/a
ERC 7

ESVOC 31
equipment breakages
expected.
expected.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
n/a

PROC 2, 4, 8a, 8b and 9- Exposed skin surface- Palm of both hands (480 cm2)
n/a


controlled exposure

formulation).


Page 52 of 74

Section 2.2
Amounts used

management


soil
n/a

site
n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%
n/a
n/a
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 53 of 74
Section 1
Title

Use in/as functional fluids (professional)
Sector of Use
SU22
Process Category
PROC 1, 2, 3, 4, 8a, 9, and 20
Product Category
n/a
Article Category
n/a
ERC 9b

n/a
equipment breakages
expected.
PROC 20- Motor and engine oils, brake fluids.
Also in these applications, the lubricant may be exposed to
high energy conditions and chemical reactions may take
place during use. Exhausted fluids need to be disposed of as
waste. Repair and maintenance may lead to skin contact.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100%
n/a
Section 2.1
Amounts used
Not relevant
Duration of exposure- >4 hours/day, Frequency of exposure 240 days/yr

PROC 2, 4, 8a, 8b, 9 and 20 - Exposed skin surface- Palm of both hands (480
cm2)
Location-Indoor, domain-Professional
Page 54 of 74


controlled exposure

formulation).



Heat and pressure transfer fluids in dispersive,

professional use but closed systems.
of suitable gloves- No
Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
Page 55 of 74
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 56 of 74
Section 1
Title

Use in laboratories (industrial and professional)
Sector of Use
SU3 and SU22
Process Category
PROC 15
Product Category
n/a
Article Category
n/a
ERC 8a

ESVOC 39
PROC 15- Use of substances at small scale laboratory (< 1 L or 1 kg present at
workplace). Larger laboratories and R+D installations should be treated as
industrial processes.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
Duration of exposure: >4 hours/day, Frequency of exposure: 240 days/year
Palm one both hand (240 cm)
Location- Indoor, Domain- Industrial

Use of substances at small scale laboratory (< 1 l or
1 kg present at workplace). Larger laboratories and
R+D in-stallations should be treated as industrial
processes- PROC 15
Local exhaust ventilation required- No, Respiratory protection required- No,

Additional good practice advice (for environment) beyond the REACH CSA- Use
of tightly fitting safety goggles
Section 2.2
Amounts used

Continuous, Emission days (days/year): 365

management




soil
n/a

site
n/a

n/a

recovery of waste
n/a

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%
n/a
Page 57 of 74

above
n/a
Section 3
Exposure Estimation
3.1. Health
3.2. Environment
The environmental assessment was performed using the SpERC scenario.When the recommended risk management measures and
operational conditions are observed, exposures are not expected to exceed the predicted PNECs and the resulting risk characterisation
ratios are expected to be less than 1.
Section 4
4.1. Health
4.2. Environment
Page 58 of 74
Section 1
Title

Use in water-treatment chemicals (industrial)
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 8a, 8b, and 13
Product Category
n/a
Article Category
n/a
ERC 3

ESVOC 46
equipment breakages
expected.
expected.
Section 2
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
n/a
n/a
n/a
Page 59 of 74


controlled exposure

formulation).



Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Page 60 of 74
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 61 of 74
Section 1
Title

Production of Polymers, filled polymers, foams, coatings,
adhesives, sealants
Sector of Use
SU3
Process Category
PROC 1, 2, 3, 4, 5, 7, 8a, 8b, 9, 10, 13, 14, and 15
Product Category
n/a
Article Category
n/a
ERC 6c

ESVOC 43
equipment breakages
waste.
expected.
expected.
chemical matrix may be exposed to elevated mechanical
and/or thermal energy conditions. Exposure is predominantly
formed as well.
Section 2
Page 62 of 74
Liquid
Volatility
0.123 hPa
Dustiness
n/a
100
n/a
Section 2.1
Amounts used
n/a
n/a
PROC 1, 3 and 15- Exposed skin surface- Palm of one hand (240 cm)PROC 2,
4, 5, 8a, 8b, 9, 10, 13 and 14- Exposed skin surface- Palm of both hands (480
cm2)PROC 7- Exposed skin- whole body
n/a


controlled exposure

formulation).

Industrial spraying
gloves with basic
training-Yes (Effectiveness 90%), Wearing of appropriate working clothes (e.g. an
overall)- Yes (Effectiveness 80%)





Section 2.2
Amounts used

management

Page 63 of 74



n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Page 64 of 74
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
Estimated workplace exposures are not expected to exceed DNELs when the identified risk management measures are adopted.Where
other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least
equivalent levels.
4.2. Environment
Section 1
Title
Exposure Scenario: consumer

Use in Paints/Coatings /Surface treatment products
(Consumer use)
Sector of Use
SU21
Process Category
n/a
Product Category
PC 9a, 15, 18, 23, 31 and 34
Article Category
n/a
ERC 8d

n/a
PC9a and PC15:
Regarding PC 9a and PC 15 two Sub-scenarios have been evaluated.
Sub-Scenario 1: Use in Paints/Coatings non-spraying products (Water borne
wall paint)
Sub-Scenario 2: Use in Paints/Coatings spraying products
These Sub-Scenarios are intended to represent reasonable worst-case
scenarios for PC9a and 15.
PC18:
To reflect a reasonable worst case scenario, the following assumptions have
been made:
- An ink cartridge contains 50g of printing ink
- 50g printink ink are sufficient to print 300 pages
Generally, two steps have been assessed. Refilling of cartridges (Part A) and
the printing process itself (Part B).
For the step Refilling of toners the ConsExpo default database for Cleaning
and washing/All-purpose cleaner/Liquid/Mixing and Loading was regarded to be
suitable as a basis for the inhalative and dermal exposure estimation (in case
the ConsExpo default values have been used, this is stated below). Exposure
via the oral route is anticipated to be not relevant.
The step Printing process was calculated using the evaporation model
postulating instantaneous release as a worst case regarding inhalative
exposure. With regard to the printing process dermal and oral exposure is
considered to be negligible.
PC23 and 34:
It is assumed that the use of impregnation products for leather or textiles is
covered
within the scenarios described for PC 9a and 15. As DEG is a solvent which
usually
evaporated during or immediately after the application, a possible exposure to
DEG
by wearing/using impregnated products is considered to be neglible.
Page 65 of 74
PC31:
For PC 31 the use of a floor/furniture polish reflects a representative worst case
scenario.
Section 2
Liquid
Volitility
0.123 hPa
Dustiness
n/a
5%, 25% (PC 31)
n/a
Section 2.1
Control of consumer exposure
Amounts used
Sub-scenario 1- 1250 g/day (PC 9a, 15)

Sub-scenario 2- mass generation rate 0.33 g/s (PC9a and 15)
Sub-scenario 3- 50 g (PC 18- refilling step), 16 g/day (PC 18- printing process)
Sub-scenario 4- 550 g/day (PC 31)
Sub-scenario 1- PC 9a, 15- Frequency 1 day/year, Duration of exposure- 132

min, Duration of application- 120 min
Sub-scenario 2- PC 9a and PC 15- Duration of spraying- 15 min, Duration of
exposure- 15 min, Frequency of exposure- 2 days/year
Sub-scenario 3- PC 18 (Refilling step)- Duration of exposure- 0.75 min,
Duration of application- 0.3 min, Frequency of exposure 104 days/year
PC 18 (Printing process)- Duration of exposure- 600 mins, Frequency of
exposure 365 days/year
Sub-scenario 4- Duration of exposure- 240 mins, Duration of application- 900
min, Frequency of exposure 1 day/year
Page 66 of 74
Sub-scenario 1- PC 9a, 15,

Exposed skin surface- Hands and forearms (1900 cm)
Contact rate- 30 mg/min
Release duration- 7200 s
Type of activity (inhalation rate)- Light activity
Sub-scenario 2- PC9a and PC15
Inhalation cut-off diameter- 15 um
Non-respirable uptake fraction 1
Exposed skin surface- Hands and forearms (1900 cm)
Sub-scenario 3- PC 18
(Refilling step)
Exposed skin surface- Palm of one hand (215 cm)
(Printing process)
Sub-scenario 4- PC31
Exposed skin surface- One hand or palm of both hands (430 cm)
Other Operational Conditions affecting exposure (1

of 2)

(continued, 2 of 2)
Sub-scenario 1- PC 9a, 15Location- InsideRoom Volume- 20m3Ventilation rate0.6 per hourRelease area- 10m2Application temperature- 25CSub-scenario 2PC9a and PC15Location- InsideRoom Volume- 34m3Room height- 2.25
mVentilation rate- 1.5 per hourApplication temperature- 25CSub-scenario 3PC 18(Refilling step)Location- InsideRoom Volume- a personal volume of 1 m3
is assumedVentilation rate- 0.5 per hourRelease area- 20 cm2Application
temperature- 25C
(Printing process)
Location- Inside
Room Volume- 25 m3
Ventilation rate- 0.6 per hour
Application temperature- 25C
Sub-scenario 4-PC 31
Location- Inside
Room Volume- 58 m3
Ventilation rate- 0.5 per hour
Release area- 22 cm2

Product (sub) Categories
Sub-scenario 1- Use in Paints/Coatings - nonspraying products
n/a
Sub-scenario 2- Use in Paints/Coatingsspraying

products
n/a
Sub-scenario 3- Use in Printing inks
n/a
Sub-scenario 4- Use in surface treatment products

non-spraying products
n/a
Section 2.2
Amounts used
n/a
n/a

management
n/a

n/a
Page 67 of 74

n/a

soil
n/a

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
The ConsExpo tool has been used to estimate consumer exposures unless otherwise indicated.
When the recommended risk management measures and operational conditions are observed, exposures are not expected to exceed
the predicted DNELs and the resulting risk characterisation ratios are expected to be less than 1.
3.2. Environment
The environmental assessment was performed using ERC (8d).
the predicted PNECs and the resulting risk characterisation ratios are expected to be less than 1.
Section 4
4.1. Health
Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions outlined in
section 2 are implemented.
4.2. Environment
Page 68 of 74
Section 1
Title

Use in Heat transfer and Hydraulic fluids (Consumer use)
Sector of Use
SU21
Process Category
PROC8a
Product Category
PC 16, PC17
Article Category
n/a
ERC 9b

n/a
Generally, heat transfer and hydraulic fluids are products being in closed
systems. Thus, exposure towards the substance is considered to be negligible
within that stage of use. Relevant exposure may occur during charging and/or
discharging.
Several scenarios (default databases) in ConsExpo 4.1 address a Mixing and
Loading step. However, usually these scenarios are based on the assumption
that relatively small amounts of prooduct (<100g) are charged.
Regarding the charging/discharging of heat transfer and hydraulic fluids
presumably greater amounts of product are handled. Thus, the exposure
resulting from charging/discharging of heat transfer and hydraulic fluids is
assessed by means of a calculation of PROC 8a for the professional domain
which is considered to represent the charging/discharging process performed
by consumers in a appropriate way.
To calculate PROC 8a the ECETOC TRA worker tool (v2.0) was used.
Deviating from the ECETOC TRA calculation algorithms a direct multiplication
of the basic estimate by the fraction of the substance in the preparation used
was done. This approach is considered to be applicable due to the low volatility
of the substance.
Oral exposure is regarded to be no relevant route of exposure for the ES.
Section 2
Liquid
Volitility
0.123 hPa
Dustiness
n/a
30%
n/a
Section 2.1
Amounts used
Not applicable
Duration of exposure <15 min
Exposed skin surface-Both hands (960 cm2)

Location-Inside

Use in Heat transfer and Hydraulic fluids
n/a
Section 2.2
Amounts used

management




n/a
Page 69 of 74

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 70 of 74
Section 1
Title

Use in Adhesives and Sealants (Consumer use)
Sector of Use
SU21
Process Category
PC1
Product Category
n/a
Article Category
n/a
ERC 8c

n/a
In order to assess products included in PC1, the use of a carpet glue has been
chosen as representative worst case
Section 2
scenario
Liquid
Volitility
0.123hPa
Dustiness
n/a
0.075%
n/a
Section 2.1
Amounts used
9000 g/day
Duration of exposure 75 min

Duration of application 75 min
Frequency of exposure 0.25 days/yr
Exposed skin surface- 50% of one hand palm (110 cm)

Location-Inside
Room volume- 58 m3
Ventilation rate- 0.5 per hr
Release area- 4 m2
Release duration 4500 s

Use in Adhesives and Sealants
n/a
Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a
Page 71 of 74

n/a

n/a

recovery of waste
n/a

above
n/a
Section 3
3.1. Health
Exposure Estimation
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 72 of 74
Section 1
Title

Production of rigid foam (Consumer use)
Sector of Use
SU21
Process Category
n/a
Product Category
PC 32
Article Category
n/a
n/a
ERC 8f
PC32
Section 2
Liquid
Volitility
0.123 hPa
Dustiness
n/a
5%
n/a
Section 2.1
Amounts used
825 g
Duration of exposure- 30 min, Exposure frequency- 0.2 l/yr

Exposed skin surface- 1900 cm2
Location- Inside
Inhalation rate- 1.5 l/hr
Room volume- 57.5 m3

Production of rigid foam (Consumer use)
n/a
Section 2.2
Amounts used

management




n/a

soil

= 1 ((1 ERMM, 1) x (1 ERMM,2)) 87%

site
n/a

n/a

n/a

recovery of waste
n/a
Page 73 of 74

above
n/a
Section 3
3.1. Health
Exposure Estimation
The ConsExpo tool has been used to estimate consumer exposures unless otherwise indicated.When the recommended risk
management measures and operational conditions are observed, exposures are not expected to exceed the predicted DNELs and the
resulting risk characterisation ratios are expected to be less than 1.
3.2. Environment
Section 4
4.1. Health
4.2. Environment
Page 74 of 74

MEG Polyester Grade MSDS UK

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Safety Data Sheet

MEGlobal Europe GmbH

Revision Date: 2014/09/11

Section 1. Identification of the substance/preparation and of the

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

1.3 Details of the supplier of the safety data sheet

+41 44728 2077

1.4 EMERGENCY TELEPHONE NUMBER

0041 447 28 2820

2.1 Classification of the substance or mixture

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Harmful: danger of serious damage to

2.2 Label elements

Signal Word: Warning

2.3 Other Hazards

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Acute Tox., 4, H302

4.1 Description of first aid measures

4.3 Indication of immediate medical attention and special treatment needed

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Fire Fighting Measures

5.1 Extinguishing Media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Accidental Release Measures

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Handling and Storage

7.1 Precautions for safe handling

7.3 Specific end uses

Exposure Controls / Personal Protection

8.1 Control parameters

Ethanediol; ethylene glycol

52 mg/m3 20 ppm SKIN

Derived No Effect Level (DNEL)

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Acute - systemic effects

Predicted No Effect Concentration (PNEC)

Revision Date: 2014/09/11

8.2 Exposure controls

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Section 10. Stability and Reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Polymerization will not occur.

Section 11. Toxicological Information

Eye damage/eye irritation

Repeated Dose Toxicity

Chronic Toxicity and Carcinogenicity

Product Name: ETHYLENE GLYCOL POLYESTER GRADE

Revision Date: 2014/09/11

Section 12. Ecological Information

12.2 Persistence and Degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment