Beruflich Dokumente
Kultur Dokumente
Title of Project:
General Purpose:
Main Purpose: to study the geochemical interaction between water and the matrix of the
target aquifer in order to identify the causes of high concentrations of molybdenum in drinking
water. For this purpose a geochemical modeling is necessary to identify the different species
of molybdenum existing in the aquifer
B- Secondary Objectives
1- Effect of molybdenum on the human health, and plant growth.
2- Effect of molybdenum on the water quality.
3- Find relation between the molybdenum and other elements in the ground
water.
4- Determined the concentration of molybdenum in the ground water that
found in area contain rich amount of agricultural waste.
4- Indicators that will show that the research was achieved, and the
results obtained.
*-Many of published scientific study talked about this subject as.
A-. Factors affecting molybdenum adsorption by soils and minerals.( Goldberg S
et al.,1998)
B-adsorption of molybdate ion by natrolite and clinoptilolite-rich tuffs (Faghihian
et al.,2002).
C- molybdenum and tungsten in volcanic rocks and in surface and <100 c ground
water in Iceland (Stefan et al.,2006).
D- geochemistry of molybdenum in the chao phraya river estuary, Thailand : role
of suboxic diagenesis and porewater transport (Tarun K et al.,2005).
E-. molybdenum adsorption by soils using soil chemical parameters in the
Constant Capacitance Model (Goldberg, S et al .,2002)
*- published world health organization (WHO) a integrated report about the
molybdenum in drinking water in (1996)
As a main principle in all scientific research it must take into account
(no result its a result)
Molybdenum is important in plant growth and is added to some fertilisers in trace amounts to
enhance crop production. It also has a role in nitrogen fixation (Bostick et al., 2003). However,
excessive molybdenum concentrations have been linked to abnormal plant growth
(Das et al., 2007). Molybdenum availability to plants from soils is known to be pH-dependent,
being greatest in alkaline soils (National Research Council, 1980).
B-Organoleptic properties
Ammonium molybdate imparts a slightly astringent taste to water at concentrations
above
About 10 mg of molybdenum per liter.
C-Major uses
Molybdenum is used in the manufacture of special steels, in electrical contacts, spark
plugs, X-ray tubes, filaments, screens, and grids for radio valves, and in the production
of tungsten, Glass-to-metal seals, nonferrous alloys, and pigments. Molybdenum
disulfide has unique Properties as a lubricant additive. Molybdenum compounds are
used in agriculture either for the direct treatment of seeds or in the formulation of
fertilizers to prevent molybdenum Deficiency
D-Environmental facte:
Molybdenum disulfide is sparingly soluble in water but is readily oxidized to give more
Soluble molybdates, which are stable in water in the absence of a reducing agent .
E-ANALYTICAL METHODS
Molybdenum can be determined by graphite furnace atomic absorption
spectroscopy with a Detection limit of 0.25 g/litre. Inductively coupled plasma
atomic emission spectroscopy has a detection limit of 2 g/litre .
F-ENVIRONMENTAL LEVELS AND HUMAN EXPOSURE
Air
Molybdenum was present in 32.7% of surface water samples from 15 major river basins
in the USA at concentrations ranging from 2 to 1500 g/litre (mean 60 g/litre) (7,8).
Levels in groundwater ranged from undetectable to 270 g/litre in another survey in the
USA (9). In a survey of finished water supplies in the USA, concentrations ranged from
undetectable to 68 g/litre (median 1.4 g/litre) (10). In another survey of 380 finished
6
water samples from across the USA, 29.9% contained measurable concentrations of
molybdenum, with a mean of 85.9 g/litre and a range of 31024 g/litre.
Levels of molybdenum in drinking-water do not usually exceed 10 g/litre . However,
in areas near molybdenum mining operations, the molybdenum concentration in
finished water can be as high as 200 g/litre. Tap water concentrations as high as 580
g/litre have been reported in Colora.
Phase 2:
A-Collecting the sample of water.
*- Duration of this phase = 1 month.
Phase 3:
A-Chemical analysis for the water sample.
*- duration of this phase = 2 months.
Phase 4:
A Collection the result and make scientific analysis.
*- duration of this phase = 1month.
Phase 5:
A- Writing the final report for the research.
*-duration of this phase = 2 months .
Role
Man days or
Man months
Malik name abu alrous Sampel collection and 6 month
chemical analyses for
water.
Remuneration
500 JD
Collection and
preparation of data
4 month
500 JD
2-Instruments
Name of Instrument
atomic absorption
spectrophotometer
digital integrator
graphite furnace
X-ray diffraction
(XRD)
Scanning electron
microscope (SEM)
Purpose
To detect the concentration
of molybdenum
to quantitate peak areas
reaching a temperature
sufficient to atomize
molybdenum
characterize the atomic-scale
structure of an already
identified mineral
used to generate highresolution images of shapes
of objects
Estimated Cost
50 JD / Sampel
20JD / Sampel
50 JD / Sampel
50 JD / Sampel
80 JD / Sampel
Purpose
Keeping the sample
For preparation
chemical solution
10
Estimated Cost
3 JD / unit
5 JD / unit
Graduated cylinder
Beakers
Test Tubes
For preparation
5 JD / unit
chemical solution and
the sampel
For preparation
5 JD / unit
chemical solution
hold a fraction of
5 JD / unit
material or liquid
11
Purpose
Temperature test
Total dissolved solid
test
PH test
Turbidity test
Estimated Cost
30 JD / Unit
100 JD
Purpose
Detect the study area
Estimated Cost
350 JD
Supply geographic
information
Research
500 JD
100 JD
200 JD
5- Informatics.
Description
Digital Geographic
maps
GIS Program
Internet
30 JD / month
6- Other Costs
Description
Molybdenum standard solution
acidified water to make all dilutions
Buffer for calibration
Estimated Cost
150 JD
100 JD
50 JD
12
Budget
Item No.
1
2
3
4
5
6
7
8
9
10
Category
Main Researches
Research assistants
Instruments
Consumables
Equipment
Informatics
Other
Total Cost
Amount of outside grant if available
Total requested from University
Signatures of Researchers.
Date :
Total
1000
1500
3000
230
430
380
300
7840
0
6840
/ 2012
Department Remarks :
References:
14
Deans Remarks :
15