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CHEM F111 : General Chemistry
1
(12 Lectures)
Quantum theory
Conformation
Atomic structure and spectra Stereochemistry
Spectroscopy:
Types of reactions:
Rotational & Raman
Vibrational
NMR
Elimination
Addition
Substitution
Pericyclic
Chemical thermodynamics
Aromatic compounds
Chemical Kinetics
Coordination compounds (6 Lectures)
Octahedral, Tetrahedral , Square planar geometries
2
Books
Text Books
T1: P.W. Atkins and Julio de Paula, Elements of Physical Chemistry: 6th
Edition, Oxford University Press, Oxford, reprinted in 2015.
T2: T. W. Graham Solomons and Craig B. Fryhle, Organic Chemistry,
10th Edition, John Wiley & Sons, Inc. New York, 2011
Reference Books:
R1: Physical Chemistry, David Ball
R2: J. D. Lee, Concise Inorganic Chemistry, 5th Edition, Blackwell
Science, Oxford, 1999.
R3: Inorganic Chemistry: Principles of Structure and Reactivity, 4th
Edition, Huheey, Keiter
R4: R. T. Morrison and R. Boyd, Organic Chemistry, 6th Edition, PHI,
New Delhi, 1992.
BITS Pilani, Pilani Campus
15 min.
(each)
30
[90 M]
Compre.
Exam.
3 hours
40
[120 M]
Continuous
Remarks
Closed book
(i) Assignment
(Open book)
(ii) Quiz
(Closed book)
Password: BITSPILANI
CLASSROOM RULES
Black body
Study of Interaction of light with matter was in progress.
(How light was emitted or absorbed ??)
Any object radiates energy, when heated. The amount of
energy emitted, and its frequency distribution depends on
the temperature and on the material.
Nearly-perfect
black body
Intensity (I) or
Power density
?
Wavelength
BITS Pilani, Pilani Campus
13
Area under the curve at T = Total Power per unit surface area (M)
M is proportional to 4th power of absolute temperature
M = T4
(W/m2)
[Stefan-Boltzmann Law]
Rayleigh-Jeans Law
Energy density (d) is the energy per unit volume associated
with radiation of wavelength from to +d :
dE = d = (8kT/4) d
k =Boltzmann constant
Rayleigh-Jeans Law:
unsuccessful attempt to explain the black body radiation
spectrum.
Rayleigh-Jeans Equation predicts that
Oscillators of short wavelength (UV) are excited even
Real
at room temperature.: This cannot be true
Picture
This paradox:
ULTRAVIOLET CATASTROPHE!
faster than 5
Energy density 0 as 0
20
UV Catastrophe
avoided
= 2 5k4/15h3c2)T4 = T4
Stefan Boltzman Law
M = ( (, T) d
Dropping
Rayleigh-Jeans formula
21