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ABSTRACT
The paper concerns the case study of a group of oil power transformers in which, on the basis of
the measurements of concentration of gases dissolved in oil, excessive generation of hydrogen was
noticed. Analysis performed using the ratio method proposed by IEC 60599 standard, and the
Duval triangle method, identified partial discharge (PD) generation in the transformer units
considered. Deepened analysis indicated however that such a diagnosis may by false and
excessive hydrogen generation is a result of stray gassing. Additional studies such as the
measurements of partial discharge intensity using acoustic emission method as well as internal
inspection and factory tests (including PD measurements using electrical method) of selected
units seem to confirm this hypothesis. However, taking into account the recommendations
described in CIGRE brochure 296, lack of compatibility of constructional materials with the oil
used in the analyzed group of transformers is also probable. Finally, this may be concluded that
assessment of the results of the DGA needs to be carried out carefully when an increase in the
concentration of hydrogen in the transformers in service is observed. An unambiguous
determination of the cause of the fault cannot be indicated only on the basis of basic analysis.
Some other, more specific analyses and tests should be used.
1 INTRODUCTION
DISSOLVED gas analysis (DGA) is a commonly used
method allowing for detection of defects of a thermal and
electrical origin in transformers with oil-paper insulation. Each
type of the defects (breakdowns, partial discharges or thermal
faults) generates, as a result of decomposition of oil and paper
insulation, characteristic pattern of gases. Electrical discharges in
oil lead to the generation of large amounts of hydrogen (H2) and
acetylene (C2H2). If the defect comprises the cellulose insulation,
carbon monoxide (CO) and carbon dioxide (CO2) are also
generated. In the case of partial discharges in oil, large quantities
of hydrogen and methane (CH4) are formed. If the partial
discharges occur in the oil-impregnated cellulose insulation,
small amounts of carbon monoxide and carbon dioxide may be
measured. The type and amount of gases generated as a result of
thermal degradation of oil depend on the temperature of the fault.
As temperature increases, hydrocarbons are generated in
Manuscript received on 8 April 2015, in final form 3 June 2015, accepted
29 June 2015.
DOI: 10.1109/TDEI.2015.005347
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 22, No. 6; December 2015
lacquers which are initially the sources of the gases which then
react catalytically with the oil,
- the existence of hydrogen in stainless steel as a result of the
absorption of hydrogen during the production process or
treatment (hydrogen may be released and infiltrate to the oil
during exploitation phase).
CIGRE brochure 296 [7] has brought the attention of
transformer industry to the concept of stray gassing reported
since late '90. According to this concept stray gassing may appear
in the transformer oil when some types of mineral oils are heated
to the temperature of 90 C - 200 C. At the temperature of 120
C the primary stray gas is H2 and in a smaller amount CH4.
However, at the temperature of 200 C the main gases are CH4,
C2H6 and in a smaller amount H2 and C2H2. The mechanism of
formation of stray gases has not been satisfactorily explained. As
the possible cause of the generation of these gases are listed the
oil oxidation, the weaker chemical structures of oil after the
refining process or the usage of oil hydro-refining. This latter
process is used in the case of uninhibited oils in order to limit
their oxidation and thus their aging. Generally, it has been
recognized that the specific properties of the oil are the main
causes of stray gassing [4, 6, 7].
This article presents the analysis of the case study concerning
a group of oil power transformers in service. For this group, the
dissolved gas analysis was performed using the ratio method
proposed by the IEC 60599 standard and the Duval triangle
method. This analysis indicated that partial discharges may be a
potential cause of excessive hydrogen generation. For this reason
the obtained results of gas concentrations were analyzed further
using the auxiliary Duval triangles. This analysis indicated other
possible cause of excessive hydrogen generation than internal
faults - stray gassing. Additionally performed studies carried out
for the analyzed group of transformers such as the measurement
of partial discharge intensity using acoustic emission method,
internal inspection of selected units as well as the factory tests
performed in accordance with the current standards (withstand
voltage tests, induced voltage tests with partial discharge
measurement, lightning impulse voltage tests, no-load and load
losses), confirmed lack of partial discharges in the insulating
systems of the transformers considered. Additional analysis of
the results obtained, taking into account the set of
recommendations included in the CIGRE brochure 296,
indicated incompatibilities of the materials used as an alternative
to stray gassing source of excessive hydrogen generation.
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Generated gases
CH4/H2
0.15 1
> 0.4
0.02 0.14
< 0.02
%H 2
100 H 2
H 2 CH 4 C2 H 6
%CH 4
100 CH 4
H 2 CH 4 C2 H 6
%C2 H 6
(1)
100 C2 H 6
H 2 CH 4 C2 H 6
3602
Table 2. Boundaries of the zones in the Duval triangle 4 considering H2, CH4
and C2H6 [10].
Zone identifier
PD
S
C
O
3 CASE STUDY
After few years in service of the group of identical oil
power transformers (63 MVA, 110 kV) produced at the same
time and filled with the same type of mineral uninhibited
naphthenic oil (Nytro Taurus), sudden increase of hydrogen
concentration was observed. The results of subsequent
measurements for four selected transformers from the group
are presented in the form of chart in Figure 3.
Figure 1. Location of the zones in the Duval triangle 4 considering H2, CH4
and C2H6.
Table 3. Boundaries of the zones in the Duval triangle 5 considering CH4,
C2H4, C2H6 [10].
Zone identifier
PD
S
C
O
T3
Figure 2. Location of the zones in the Duval triangle 5 considering CH4, C2H4
and C2H6 [10].
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 22, No. 6; December 2015
H2
C2H2
C2H4
C2H6
CH4
CO
CO2
0
1208.2
1074.3
746.8
1529.4
1322.8
1549.5
1568.8
1543.9
0
0
0
0
0
0
0
3.7
3
0
3
2.8
1.9
2.4
2.2
2.6
4.6
6.1
0
66.9
125.9
122.8
146.8
151.7
148.8
148.1
141.2
0
1.6
4.7
4
4.9
4.2
4.6
4.6
5.6
1.4
39.7
44.4
45.1
50.5
48.4
48.4
52.6
51.6
56.6
965.6
1408.2
1407.6
1524.1
1509.4
1344.6
1468.8
1413.2
3603
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Partial discharges
Thermal fault T < 300C
H2
C2H2
C2H4
C2H6
CH4
CO
CO2
0.0
6388.6
6387.6
7501.6
7467.4
7647.8
7471.5
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3.3
2.6
3.1
3.1
12.3
13.2
0.0
327.8
333.3
392.1
399.3
410.2
409.7
0.0
507.7
498.6
601.2
603.5
617.1
634.8
3.0
59.8
56.8
64.6
65.1
61.2
64.0
76.9
2380.9
2430.5
2579.7
2587.6
2303.0
2322.9
Figure 4. Location of fault on the basis of basic version of Duval triangle for
the latest measurement in transformer "c" (49th month).
* Result obtained on the basis of simplified version of ratio method. Full version did not allow for
identification the nature of fault
Figure 5. Location of fault on the basis of basic version of Duval triangle for
the latest measurement in transformer "d" (34th month).
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interpreted with caution. The reason for this is a fact that when
the diagnostic methods indicate the possibility of occurrence
in transformer the partial discharges or low-temperature
overheating, it is desirable to consider whether the cause of
gas generation is not a result of catalytic reactions or existing
of stray gases among them the dominant gas is hydrogen [69].
Such a consideration was conducted for the analyzed group
of transformers using two methods. First method based on the
relationships between CH4 and H2 [7] while second on the
auxiliary Duval triangles [10]. The results of the analysis of
relationship between methane and hydrogen for both
transformers analyzed and for the distinctive measurements
are shown in Tables 8 and 9. In all the cases a PD diagnosis
was indicated because CH4 to H2 ratio was in each case in the
range between 0.02 and 0.14.
Table 8. Interpretation of observed ratios of methane to hydrogen on the basis
of IEC 60559 standard.
Time in months
Values of CH4/H2
Interpretation
15
0.090
PD
39
0.109
PD
44
0.139
PD
45
0.088
PD
46
0.104
PD
47
0.088
PD
48
0.091
PD
49
0.090
PD
Values of CH4/H2
Interpretation
25
0.079
PD
30
0.078
PD
31
0.080
PD
32
0.081
PD
33
0.081
PD
34
0.085
PD
25
Stray gassing
Stray gassing
30
Stray gassing
Stray gassing
31
Stray gassing
Stray gassing
32
Stray gassing
Stray gassing
33
Stray gassing
Stray gassing
34
Stray gassing
Stray gassing
15
Stray gassing
Stray gassing
39
Stray gassing
Stray gassing
44
Stray gassing
45
Stray gassing
Stray gassing
46
Stray gassing
Stray gassing
47
Stray gassing
Stray gassing
48
Stray gassing
Stray gassing
49
Stray gassing
Stray gassing
IEEE Transactions on Dielectrics and Electrical Insulation Vol. 22, No. 6; December 2015
3605
Figure 10. Localization of the sensors on the housing of the transformer tank
intended to the PD measurement using acoustic method.
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IEEE Transactions on Dielectrics and Electrical Insulation Vol. 22, No. 6; December 2015
REFERENCES
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