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1. (a) Iodine monochloride , ICl dissociates at 25 oC to I2 and Cl2.

The equilibrium constant , Kp


for the dissociation is 2.2 x 10-3.
ICl (g)

I2 (g) + Cl2 (g)

Calculate Kp and Kc for the following reaction at temperature 25oC :


I2 (g) + Cl2 (g)

2ICl (g)
[7 marks]

(b) At a temperature of 400 oC and pressure of 3.0 x 107 Pa, the hydrogen gas and nitrogen
gas are mixed in the mole ratio of 3: 1. Under these conditions, 61% of nitrogen is
converted to ammnonia.
N2(g) + 3H2 (g)

2NH3 (g)

Calculate the percentage of ammonia produced in an equilibrium mixture and calculate


the equilibrium constant, Kp for the reaction above.
[13 marks]

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