Beruflich Dokumente
Kultur Dokumente
[111
4,265,639
Scholtz
[45]
May 5 9 1981
[54]
COMBUSTION CATALYSTS
3,711,525
3,758,534
l/ 1973
9/1973
3,833,590
9/1974
[76]
Inventon
4,145,190
3/1979
Webb . . . . . .
LSA 2L2
. . . . . .. 44/57
[57]
[52]
U S Cl
[58]
......................................... ..
44/57
44
260/429 j
[56]
'
References Cted
5/1950
3,282,858
11/1966
ABSTRACT
.
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1
COMBUSTION CATALYSTS
tages:
(i) improvement in the fuel economy;
(ii) reduction of hydrocarbon and carbon monoxide
emissions;
(iii) reduction of carbon formations; and
(iv) for an oil ?red plant, a reduction in excess air
methyl
cyclopentadienyl
manganese
tricarbonyl
4,265,639
mula
tally removed therefrom. Therefore, for the purposes of 20 where R1, R2 and R3 are hydrocarbyl groups having 1
to 12 carbon atoms, and more particularly 2 to 8 carbon
the present speci?cation and the claims which follow
atoms, or hydrogen, provided that the amine contains at
the expression picric acid shall connote free picric
plexes.
4,265,639
thereof.
Stock solutions containing from about 1.01 to about
0.20 g of iron in the +2 valence state per liter of stock
EXAMPLE 1
Preparative Method 1
EDTA (8 g) and cyclohexylamine (100 g) was dis
Preparative Method 2
EDTA/ cyclohexylamine/ methanol and picric acid/
methanol solutions are prepared in accordance with the
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7
EXAMPLE 5
-continued
VEHICLES TESTED:
# Make
Model
3
4
1979 Ford
1979 Ford
Thunderbird 2 dr.
Thunderbird 2 dr.
Engine Milage
V-8
V-8
22,636
22,690
4,200 lbs.
4,200 lbs.
Weight
5
6
1980 Toyota
1980 Toyota
Corolla 4 dr.
Corolla 4 dr.
l-4
l-4
2,721
2,384
2,400 lbs.
2,400 lbs.
city cycle.
COMPARATIVE EXAMPLE B
Gasoline is prepared in an identical manner as Exam
ple 5 except that the picric acid is the only additive. The
EXAMPLE 6
Performance Tests
N-R3
R2
VEHICLES TESTED:
# Make
Model
1
2
Bonneville 4 dr.
Bonneville 4 dr.
l979 Pontiac
l979 Pontiac
Engine Milage
V-B
V-8
17,606
l7,84()
Weight
3,900 lbs.
3,975 lbs.
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10
nol solution;
'
'
RI
N-R3
R7
30
nol solution;
solution;
55
dissolving;
(iii) adding a source of +2 iron to the solution of step
(ii) and stirring to suspend and dissolve to give a
red orange solution; and
11
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12
N-R3
R2
'
20
25
35
45
50
55
60
65
1|
it