Volume of NaOH

0
0.6
1
1.5
2.1
2.4
3.1
3.6
4
4.5
5
5.6
6.1
6.6
7.1
7.6
8
8.5
9
9.6
9.95
10.5
11
11.45
11.95
12.55
12.95
13.5
13.9
14.5
15
15.4
16
16.3
16.65
16.9
17.05
17.2

pH Meter Volume of NaOH

1.92
0
1.93
0.6
1.94
1
1.94
1.5
1.95
2.1
1.95
2.4
1.96
3.1
1.97
3.6
1.97
4
1.98
4.5
1.99
5
2
5.6
2.01
6.1
2.02
6.6
2.03
7.1
2.05
7.6
2.06
8
2.07
8.5
2.09
9
2.11
9.6
2.12
9.95
2.14
10.5
2.16
11
2.18
11.45
2.2
11.95
2.23
12.55
2.25
12.95
2.29
13.5
2.32
13.9
2.36
14.5
2.4
15
2.45
15.4
2.51
16
2.54
16.3
2.59
16.65
2.64
16.9
2.66
17.05
2.7
17.2

Adjusted pH
1.916292
1.926668
1.937044
1.937044
1.94742
1.94742
1.957796
1.968172
1.968172
1.978548
1.988924
1.9993
2.009676
2.020052
2.030428
2.05118
2.061556
2.071932
2.092684
2.113436
2.123812
2.144564
2.165316
2.186068
2.20682
2.237948
2.2587
2.300204
2.331332
2.372836
2.41434
2.46622
2.528476
2.559604
2.611484
2.663364
2.684116
2.72562

17.35
17.6
17.8
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
19.95
20.1
20.3
20.5
20.7
20.9
21.15
21.3
21.5
21.7
21.9
22.1
22.6
23
23.6
24
24.5
25.1
25.65
26.1
26.55
27
27.5
28
28.6
29.1
29.6
30

2.73
2.78
2.83
2.88
2.96
3.04
3.13
3.24
3.38
3.53
3.78
3.99
4.17
4.33
4.43
4.51
4.58
4.67
4.74
4.81
4.86
4.91
4.96
5
5.04
5.11
5.19
5.25
5.33
5.39
5.45
5.5
5.55
5.6
5.64
5.69
5.74
5.79
5.83
5.88
5.92

17.35
17.6
17.8
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
19.95
20.1
20.3
20.5
20.7
20.9
21.15
21.3
21.5
21.7
21.9
22.1
22.6
23
23.6
24
24.5
25.1
25.65
26.1
26.55
27
27.5
28
28.6
29.1
29.6
30

2.756748
2.808628
2.860508
2.912388
2.995396
3.078404
3.171788
3.285924
3.431188
3.586828
3.846228
4.064124
4.250892
4.416908
4.520668
4.603676
4.676308
4.769692
4.842324
4.914956
4.966836
5.018716
5.070596
5.1121
5.153604
5.226236
5.309244
5.3715
5.454508
5.516764
5.57902
5.6309
5.68278
5.73466
5.776164
5.828044
5.879924
5.931804
5.973308
6.025188
6.066692

30.5
31
31.5
32
32.5
33.05
33.55
34
34.5
35
35.6
36.05
36.35
36.5
36.9
37.1
37.3
37.5
37.8
38.05
38.25
38.5
38.8
39
39.25
39.45
39.75
40
40.2
40.4
40.6
40.8
41
41.3
41.5
41.7
41.9
42.1
42.5
43
43.5

5.96
6
6.06
6.11
6.17
6.22
6.27
6.34
6.4
6.46
6.53
6.62
6.67
6.7
6.78
6.84
6.88
6.93
7.06
7.14
7.25
7.44
7.75
8.13
9.04
9.62
10.1
10.4
10.62
10.78
10.87
10.96
11.04
11.11
11.16
11.21
11.24
11.27
11.33
11.39
11.45

30.5
31
31.5
32
32.5
33.05
33.55
34
34.5
35
35.6
36.05
36.35
36.5
36.9
37.1
37.3
37.5
37.8
38.05
38.25
38.5
38.8
39
39.25
39.45
39.75
40
40.2
40.4
40.6
40.8
41
41.3
41.5
41.7
41.9
42.1
42.5
43
43.5

6.108196
6.1497
6.211956
6.263836
6.326092
6.377972
6.429852
6.502484
6.56474
6.626996
6.699628
6.793012
6.844892
6.87602
6.959028
7.021284
7.062788
7.114668
7.249556
7.332564
7.4467
7.643844
7.9655
8.359788
9.304004
9.905812
10.40386
10.71514
10.943412
11.109428
11.202812
11.296196
11.379204
11.451836
11.503716
11.555596
11.586724
11.617852
11.680108
11.742364
11.80462

44.1
44.5
45
45.6
46.1
46.6
47
47.6
48
48.5
49
49.6
50

11.5
11.53
11.56
11.6
11.63
11.65
11.67
11.69
11.7
11.73
11.74
11.76
11.77

44.1
44.5
45
45.6
46.1
46.6
47
47.6
48
48.5
49
49.6
50

11.8565
11.887628
11.918756
11.96026
11.991388
12.01214
12.032892
12.053644
12.06402
12.095148
12.105524
12.126276
12.136652


Volume of NaOH
0
0.6
1
1.5
2.1
2.4
3.1
3.6
4
4.5
5
5.6
6.1
6.6
7.1
7.6
8
8.5
9
9.6
9.95
10.5
11
11.45
11.95
12.55
12.95
13.5
13.9
14.5
15
15.4
16
16.3
16.65
16.9
17.05
17.2

pH/volume
Volume of NaOH
0.0172933333
0
0.02594
0.6
0
1
0.0172933333
1.5
0
2.1
0.0148228571
2.4
0.020752
3.1
0
3.6
0.020752
4
0.020752
4.5
0.0172933333
5
0.020752
5.6
0.020752
6.1
0.020752
6.6
0.041504
7.1
0.02594
7.6
0.020752
8
0.041504
8.5
0.0345866667
9
0.0296457143
9.6
0.0377309091
9.95
0.041504
10.5
0.0461155556
11
0.041504
11.45
0.05188
11.95
0.05188
12.55
0.0754618182
12.95
0.07782
13.5
0.0691733333
13.9
0.083008
14.5
0.1297
15
0.10376
15.4
0.10376
16
0.1482285714
16.3
0.20752
16.65
0.1383466667
16.9
0.2766933333
17.05
0.20752
17.2

17.35
17.6
17.8
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
19.95
20.1
20.3
20.5
20.7
20.9
21.15
21.3
21.5
21.7
21.9
22.1
22.6
23
23.6
24
24.5
25.1
25.65
26.1
26.55
27
27.5
28
28.6
29.1
29.6
30

0.20752
0.2594
0.2594
0.41504
0.41504
0.46692
0.57068
0.72632
0.7782
1.297
1.08948
0.93384
1.1067733333
0.6917333333
0.41504
0.36316
0.46692
0.36316
0.290528
0.3458666667
0.2594
0.2594
0.20752
0.20752
0.145264
0.20752
0.10376
0.20752
0.124512
0.10376
0.0943272727
0.1152888889
0.1152888889
0.0922311111
0.10376
0.10376
0.0864666667
0.083008
0.10376
0.10376
0.083008

17.35
17.6
17.8
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
19.95
20.1
20.3
20.5
20.7
20.9
21.15
21.3
21.5
21.7
21.9
22.1
22.6
23
23.6
24
24.5
25.1
25.65
26.1
26.55
27
27.5
28
28.6
29.1
29.6
30

30.5
31
31.5
32
32.5
33.05
33.55
34
34.5
35
35.6
36.05
36.35
36.5
36.9
37.1
37.3
37.5
37.8
38.05
38.25
38.5
38.8
39
39.25
39.45
39.75
40
40.2
40.4
40.6
40.8
41
41.3
41.5
41.7
41.9
42.1
42.5
43
43.5

0.083008
0.124512
0.10376
0.124512
0.0943272727
0.10376
0.1614044444
0.124512
0.124512
0.1210533333
0.20752
0.1729333333
0.20752
0.20752
0.31128
0.20752
0.2594
0.4496266667
0.332032
0.57068
0.788576
1.0721866667
1.97144
3.776864
3.00904
1.66016
1.24512
1.14136
0.83008
0.46692
0.46692
0.41504
0.2421066667
0.2594
0.2594
0.15564
0.15564
0.15564
0.124512
0.124512
0.0864666667

30.5
31
31.5
32
32.5
33.05
33.55
34
34.5
35
35.6
36.05
36.35
36.5
36.9
37.1
37.3
37.5
37.8
38.05
38.25
38.5
38.8
39
39.25
39.45
39.75
40
40.2
40.4
40.6
40.8
41
41.3
41.5
41.7
41.9
42.1
42.5
43
43.5

44.1
44.5
45
45.6
46.1
46.6
47
47.6
48
48.5
49
49.6
50

0.07782
0.062256
0.0691733333
0.062256
0.041504
0.05188
0.0345866667
0.02594
0.062256
0.020752
0.0345866667
0.02594
0.24273304

44.1
44.5
45
45.6
46.1
46.6
47
47.6
48
48.5
49
49.6
50

Titration of Na
14

pH of solution

12
10
8
6
4
2
0

10

20

Volume of

pH as a Function of
4
3.5
3

pH/volume

(pH/volume)/volume
0.0144111111
-0.06485
0.0345866667
-0.0288222222
0.0494095238
0.0084702041
-0.041504
0.05188
0
-0.0069173333
0.0057644444
-8.88178419700125E-016
0
0.041504
-0.031128
-0.01297
0.041504
-0.0138346667
-0.0082349206
0.0231005566
0.0068601653
0.0092231111
-0.0102479012
0.020752
5.20417042793041E-016
0.0589545455
0.0042876033
-0.0216166667
0.0230577778
0.093384
-0.06485
1.96601993944038E-015
0.1482285714
0.1694040816
-0.2766933333
0.9223111111
-0.4611555556
1.96139401017108E-014

Unknown D-24
Balance #8
pH meter #4

2.5
2
1.5
1
0.5
0

10

20

pH/vol

1.5
1
0.5
0

10

20

Volume of

Change in pH/Volume as a Functi

10

(pH/volume)/volume

0.20752
0
0.7782
0
0.2594
0.5188
0.7782
0.2594
2.594
-1.0376
-0.7782
0.8646666667
-2.7669333333
-1.8446222222
-0.2594
0.5188
-0.5188
-0.36316
0.2213546667
-0.5764444444
0
-0.2594
-4.06619182768965E-014
-0.31128
0.124512
-0.2594
0.1729333333
-0.20752
-0.041504
-0.0157212121
0.0381120294
2.03540887847944E-015
-0.0512395062
0.0256197531
-3.5527136788005E-015
-0.0345866667
-0.0057644444
0.041504
-2.80331313717852E-015
-0.05188
0

8
6
4
2
0

Half Equivalence
Point #1
0

10

20

-2
-4
-6
-8

Volume of N

0.083008
-0.041504
0.041504
-0.0603694545
0.0171504132
0.1152888889
-0.0819832099
-3.5527136788005E-015
-0.0069173333
0.1441111111
-0.0768592593
0.1152888889
6.661338147751E-015
0.2594
-0.5188
0.2594
0.9511333333
-0.3919822222
0.954592
1.08948
1.1344426667
2.9975111111
9.02712
-3.071296
-6.7444
-1.3834666667
-0.41504
-1.5564
-1.8158
8.29891710907293E-014
-0.2594
-0.8646666667
0.0576444444
0
-0.5188
-2.77555756156295E-014
5.82867087928199E-014
-0.07782
0
-0.0760906667
-0.0144111111

-0.03891
0.0138346667
-0.0115288889
-0.041504
0.020752
-0.0432333333
-0.0144111111
0.09079
-0.083008
0.0276693333
-0.0144111111
0.5419826
0.0048546608

[NaOH] = 0.09656 M
KHP mass = .7076 grams
NaOH Volume = 36.00 mL

adjusted pH = 1.0376(pH meter reading) - 0.0759

Titration of NaOH with Maleic Acid

14
12
10
Equivalence Point #2

8
6

Half Equivalence Point

#2

4
Equivalence Point #1
2
0

Half Equivalence Point

#1
0

10

20

30

40

50

Volume of NaOH Titrant Added (mL)

pH as a Function of Volume of NaOH Titrant

4
Equivalence Point #2
3.5
3
2.5
2
1.5

Equivalence Point #1

1
0.5
0

10

20

30

40

50

2
1.5
1
0.5
0

Half Equivalence Point

#2

Half Equivalence
Point #1
0

10

20

30

40

50

Volume of NaOH Titrant Added (mL)

nge in pH/Volume as a Function of Volume in Volume of NaOH Titr

10
8
6
4
2
0
-2

Half Equivalence Point

#2

Half Equivalence
Point #1
0

10

Equivalence
Point #1

20

30

Equivalence Point #2
40

-4
-6
-8

Volume of NaOH Titrant Added (mL)

50

eading) - 0.0759

Titration of NaOH with Male

14

pH of solution

12
10
8
6
4
2
0

10

20

30

Volume of NaOH Titrant Adde

50

60

ant

50

60

pH Meter

50

60

me of NaOH Titrant

50

60

of NaOH with Maleic Acid

20

30

40

Volume of NaOH Titrant Added (mL)

pH Meter

50

60

2
4
7
10

Calibration Curve for Actu

Actual pH of bufer solution

observed pH
actual pH
1.83
4.09
6.99
9.55

12
10

f(x) = 1.0375675572x
R = 0.9967706832

8
6
4
2
0

pH M

bration Curve for Actual pH and pH Meter Reading

f(x) = 1.0375675572x - 0.0759418339

R = 0.9967706832

pH Meter Reading

10