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Dissertation
Interim Report
LNG Regasification
ARTICLE INFO
ABSTRACT
Article History:
1st Draft 26 August 2016
Revised 14 October 2016
Final Draft 21 October 2016
Interim Submission 31 October 2016
Keywords:
Liquefied Natural Gas (LNG)
LNG Regasification
Natural Gas Liquids (NGL)
NGL Recovery
Expander-based Technology
Turbo-expander processes
C2+ Recovery
Contents
1
Introduction .................................................................................................................................... 2
1.1
1.2
3.1
3.2
Methodology................................................................................................................................... 5
4.1
4.2
4.3
5.2
Conclusion ..................................................................................................................................... 14
References .................................................................................................................................... 15
1 Introduction
When LNG reaches the receiving terminal, it must be vaporized and pressurized to be distributed in
the pipelines. The heating value could be controlled by dilution with nitrogen. However, when the
import LNG is rich, this method becomes inapplicable as the amount of nitrogen necessary to bring
the HHV down will far exceed the percentage limit of nitrogen allowed.
Component
Abu
Bay,
Bintulu
Arun,
Lumut,
Botang,
Laffan,
wt %
Methane
(C1)
Ethane
(C2)
Propane
(C3)
Butane
(C4)
Pentane
(C5)
Dhabi
87.1
Australia
87.8
Malaysia
91.2
Indonesia
89.2
Brunei
89.4
Indonesia
90.6
Qatar
89.6
11.4
8.3
4.28
8.58
6.3
6.25
1.27
2.98
2.87
1.67
2.8
2.48
2.19
0.141
0.875
1.36
0.511
1.3
0.82
1.07
0.001
0.01
0.02
0.01
0.04
2 Problem Statement
This paper critically examines the work presented by Fahmy et al. [3] and proposed alternative
configuration for the several factors not considered in the paper. The seven conceptual designs
presented in the work were simulated using Aspen HYSYS. Although, the configurations compared
were based on the treatment of the residue gas, the paper did not consider LNG feed compositions
lean and rich. Moreover, the feed conditions and fractionation were at high pressure ranges only.
Moreover, both reflux demethanizer and expander based technologies were excluded.
The aim of this paper is to bridge the gaps and to allow a column design which can allow
Imports of lean and rich LNG
High pressures or low pressure operations
Operations optimized for OPEX
Comparison for best configuration based on economic analysis Net Present Value (NPV)
3 Literature Review
3.1 Reflux-Demethanizer Technologies for NGL recovery from LNG
In this section, the current and prior art to the LNG regasification and C2+ recovery will be discussed
and compared to glean some insights for the design of the configurations to be tested. Most of the
configurations and patented technologies used in the industries by companies such as Foster Wheeler
and Ortloff.
It is to be noted that the configurations by Fahmy, Nabih [3] did not incorporate fractionator reflux.
However, patented fractionator technologies [4] do utilize a partial condenser to reflux residue gas
for several reasons. When LPG extraction or chemical composition modification of crude LNG in
involved, it is desirable for additional cooling of the fractionator and reflux. This process is known to
allow propane and ethane recoveries of at least 99% and 70% respectively [5].
In one such configuration by Mak, Nielsen [4] shown in Figure 3-1, the reflux ratio is varied according
to the desired quality and quantity of the bottom product. This configuration is similar to the NGL
recovery configuration from methane rich gaseous feed, which is done prior to liquefaction of LNG
[6]. There is, however, the concern of performance such a configuration based on energy
consumption. An increase in column reboiler duty is expected when there is reflux although the
recovery of C2+ is higher. A configuration by Yokohata, Yamaguchi [7] suggested splitting part of the
reboiler duty with air-heating but such heater would require large heat transfer area. An economic
analysis would elucidate if such a trade-off is worthwhile.
4 Methodology
The eight new configurations proposed contain both reflux de-methanizer and expander-based
technologies. Simulations will be carried out for each proposed configuration using Aspen HYSYS. The
LNG feed conditions and pipeline specifications for the main report were chosen to resemble the
condition for Singapore. However, the preliminary simulations were done according to the parameters
and condition used in Fahmy, Nabih [3]. The Peng-Robinson-Stryjek (PRSV) fluid package was used and
care was taken not to operate any of the columns above the critical pressure of methane (46 bars).
Table 4-1: Feed Conditions
Plant Capacity
Inlet Temperature
Inlet Pressure
Heating Value
MMscfd
C
bar
kJ/m3
500
-160
Varied accordingly
40,314.20
kJ/m3
bar
C
38,000
40
15
The target is to get a specific HHV, instead of a range as used in Fahmy, Nabih [3], for a fairer
comparison of the configurations. The configurations of Fahmy, Nabih [3] will be re-simulated for the
newly specified feed conditions and targets together with the 8 new configurations proposed in this
paper. The best configuration will be selected based on economic analysis.
Figure 4-1: Gas Conditioning Process for Rich LNG Feed [9]
Integrating NGL recovery to existing regasification plant would meaning retrofitting an LNG
regasification unit with a NGL recovery unit, which should include the option of being bypassed for
direct regasification or put online for NGL recovery.
The process synthesis of the preliminary configurations was done to encompass both reflux and
expander technologies. The currently patented regasification technologies were thoroughly studied
and to generate the current 8 configurations. As mentioned previously, most the configurations
include reflux, either as cold reflux of a portion of the LNG feed or a portion of the condense residue
refluxed back into the de-methanizer.
Configurations A and D consist of residue treatment, compression and condensation respectively.
Both configurations comprise of a refluxed de-methanizer. Configuration H, without reflux, is studied
as a comparison. H is a simple process suggested for floating regasification with multiple flash and a
demethanizer, where the residue condensed and mixed with the top product of preceding flash units.
Configuration G and F consist of all three processes condensing, compressing and reflux of the
residue. The former use feed as reflux while the latter uses condensed residue reflux.
The turbo expander technology is studied in configurations B and C. Configuration B is adapted from
the Ortloff process [10], consisting of a single turbo-expander. Configuration C adapted from Fluor
Tech Corp. [1], is another configuration suggested for floating regasification. C comprises of LNG feed
pumped to supercritical pressure of 83 bars and subsequently expanded twice. Heat exchange is done
with the residue to fully condense it for pumping and heating to pipeline specifications.
Finally, configuration E explores the option of side reboiler and cold reflux. Configurations are
presented in the next section.
kJ/m3
bar
C
35,768 39,121
100
5
Performance
Units
A cmr
G -ccr
B-Turbo
D-cdr
H-MF
kJ/h*10^(-6)
279.2
279.8
281.0
283.6
284.9
Sim
Total Power
kJ/h*10^(-6)
13.04
12.66
13.80
12.72
11.93
Sim
NG flow rate
370.95
368.93
370.73
383.66
379.06
Sim
C2+ recovery
kg/h * 10^(3)
%
88.38
79.48
75.04
51.55
84.89
Sim
HHV
kJ/Nm3
37792
37911
37994
38532
38197
HHV Reduction
6.06
5.76
5.55
4.22
5.05
Parameters
Description
Units
Sim/Paper
T2
Feed Temp
-92
-86.66
-65
-65
-79.55
Sim/Paper
Column P
bar
30
40
40
43
34
Sim/Paper
Trays
trays
14
14
14
10
Sim/Paper
S6
B C1 mol%
Sim/Paper
P7
Com Discharge P
bar
40
42.5
-65
Sim/Paper
S4
Split Fraction,
Cf5
1:0
no
reflux
29:71
32:68
43
Description
Feed Temp
Column P
Trays
B C1 mol%
Compressor discharge P
Split Fraction, Cf5
kJ/h*10^(-6)
kJ/h*10^(-6)
kg/h * 10^(-3)
%
kJ/Nm3
%
Units
C
bar
trays
%
bar
-
279.22
13.04
370.95
88.38
37792
6.06
-92
30
14
1
40
1:0
Description
Feed Temp
Column P
Trays
B C1 mol%
Compressor discharge P
Split Fraction, Cf5
kJ/h*10^(-6)
kJ/h*10^(-6)
kg/h * 10^(-3)
%
kJ/Nm3
%
Units
C
bar
trays
%
bar
-
280.96
13.80
370.73
75.04
37994
5.55
-65
40
14
1
-
Description
Feed Temp
Column P
Trays
B C1 mol%
Compressor discharge P
Split Fraction, Cf5
kJ/h*10^(-6)
kJ/h*10^(-6)
kg/h * 10^(-3)
%
kJ/Nm3
%
Units
C
bar
trays
%
bar
-
283.56
12.72
383.66
51.55
38532
4.22
-65
43
10
1
283.56
12.72
Description
Feed Temp
Column P
Trays
B C1 mol%
Compressor discharge P
Split Fraction, Cf5
kJ/h*10^(-6)
kJ/h*10^(-6)
kg/h * 10^(-3)
%
kJ/Nm3
%
Units
C
bar
trays
%
bar
-
279.76
12.66
368.93
79.48
37911
5.76
-86.66
40
14
1
42.5
29:71
Description
Feed Temp
Column P
Trays
B C1 mol%
Compressor discharge P
Split Fraction, Cf5
kJ/h*10^(-6)
kJ/h*10^(-6)
kg/h * 10^(-3)
%
kJ/Nm3
%
Units
C
bar
trays
%
bar
-
284.9
11.93
379.06
84.89
38197
5.05
-79.55
34
7
1
-
An alternative solution currently being simulated is the splitting the LNG feed and directly mixing one
of the parts with the residue. However, the flow rate of LNG required to completely absorb all the
residue should be calculated. Moreover, splitting the feed affects the residue being produced in the
first place. Since one is dependent on the other, it is not simple to optimize the split ratio which could
achieve the complete condensation objective. The process of optimization is still ongoing.
The final challenge was to decide on a fair basis of comparison. Fahmy, Nabih [3] had chosen the
acceptance/rejection criteria to be the net gain from economic analysis. However, the optimization
seems to be biased towards the configuration which achieves maximum gains from sale of C2+
recovery. This is the case because the price of the NGL recovered is higher than the sales price of NG
[11]. Hence, optimization would naturally result in the configuration with higher NGL recovery.
However, the prices used may not be applicable to countries where NG would fetch a higher gain. In
that case, the decision for the best configuration might be entirely different.
Further refinement to the methodology was recently done. Since the optimization and
acceptance/rejection criteria was heavily influenced by the fluctuating spot market prices of LNG, C2+
and NG, incorporating them would result in a bias selection of the best configuration. Hence, the
problem was circumvented by first calculating the additional cost of recovering C2+ for HHV control
of rich LNG (minus any savings from a better deal of LNG imported). Next, refer to figure 11, the sales
price of C2+ stream ($x/kg) necessary to break even for the additional cost of recovery should be
determined. This price can now be easily compared with the fluctuating spot price of C2+ at a certain
point in time. If the spot prices of C2+ is higher than the breakeven price, it would make business sense
to put the C2+ recovery unit online and purchase rich LNG sold at better deals from various sources.
The amount addition rich LNG needed to maintain the same production of NG at a specific HHV would
depend on the composition of the LNG purchased. Hence, the analysis and discussion would be
considering various feed compositions and its impact on performance of the separating unit.
6 Conclusion
Cost estimates, CAPEX and OPEX might sway selection of the best configuration and is dependent on
the relative prices of NG and NGL. Based on the recent refinement to the methodology, the
configurations to be simulated are being reconsidered as percentage recovery of C2+ is no longer the
target. The new target would be to minimize the additional cost of C2+ production per kg.
7 References
1.
Mak, J., Configurations and methods for offshore LNG regasification and heating value
conditioning. 2014, Google Patents.
2.
Yang, C.C., A. Kaplan, and Z. Huang, Method and apparatus for reducing C2 and C3 at LNG
receiving terminals. 2007, Google Patents.
3.
Fahmy, M.F.M., H.I. Nabih, and T.A. El-Rasoul, Optimization and comparative analysis of LNG
regasification processes. Energy, 2015. 91: p. 371-385.
4.
Mak, J., R.B. Nielsen, and C. Graham, Liquid natural gas fractionation and regasification plant.
2013, Google Patents.
5.
Mak, J., et al., Lng regasification configurations and methods. 2006, Google Patents.
6.
Lee, R.J., et al., Enhanced NGL recovery utilizing refrigeration and reflux from LNG plants. 2002,
Google Patents.
7.
Yokohata, H., S. Yamaguchi, and A. Tamakoshi, Process and apparatus for separation of
hydrocarbons from liquefied natural gas. 2014, Google Patents.
8.
9.
Shah, K., Gas conditioning process for the recovery of LPG/NGL (C2+) from LNG. 2016, Google
Patents.
10.
Cuellar, K.T., H. Hudson, and J. Wilkinson. Economical options for recovering NGL/LPG at LNG
receiving terminals. in 86th Annual Convention of the Gas Processors Association, San Antonio. 2007.
11.
U.S. Energy Information Administration. Natural Gas Prices. 2015; Available from:
https://www.eia.gov/dnav/ng/NG_PRI_FUT_S1_A.htm.
30 Oct, 2016
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15/8/16
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26/8/16
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