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Temperature
Refrigerating System
Tc
Refrigerating Efficiency
s
COP
=
COPideal
Effect of Temperature
COPc =
14
COP
12
COP T
16
Example
Te= 273 K and
Tc= (273+40) K
COPc =
10
273
= 6.825
40
If Te +10 K
6
4
2
Te-COP
COPc =
Tc=320K
283
= 9.433
30
0
0
50
100
150
200
Te , Tc250
300
350
If Tc -10 K
COPc =
273
= 9.1
30
hr
= 50 kcal
min
lb = 12000 Btu
= 12600 kJ
hr
= 210 kJ
hr
= 200 Btu
miin
min
= 3.5kW
Rating
hp
12,000 Btu
4.72
=
=
ton
(COP)2545 Btu (hp - hr ) COP
(ton - hr )
or
kW
12,000 Btu
ton
(ton - hr )
3.52
COP
In US,
Performanc e of HVAC System is given in Energy Efficiency Ratio (EES) Btu
1Btu = 3.412W hr, 1 EES =
W - hr
1
COPc = 0.293 COPc
3.412
Compressor
Condenser
Evaporator
Expansion Valve
Control System
Cooling Tower - Sometimes
Distinctions of Refrigerators
Evaporator
cools the air stream directly Direct
Expansion (DX) coil systems
cools water or brine chillers (common in
commercial units)
Types of Compressors
Positive Displacement Compressor
Increases the pressure of refrigerant vapour by
reducing volume Reciprocating, Rotary, Scroll,
etc.,
Compressor
Energy Consuming Component
Reciprocating 1/16 to 150 hp or 50 to 112 kW
Orbital Scroll 1 15 tons or 3.5 to 52.5 kW
Helical Rotary 100 to 1000 tons or 350 to 3500 kW
Centrifugal 100 tons or 350 kW, upper limit
determined by physical size
Reciprocating Compressor
10
Rotating Compressors
Axial Flow
Centrifugal Type
Roots
TypeMcMaster University
Department of Mechanical
Engineering,
11
Reciprocating Compressor
12
Reciprocating Compressor
Pa = Pb and Pc = Pd
3
State d State a
Gas remaining in state d, Vd expands
polytropically to state a
Pressure, P
P4
State a State b
Mixing of clearance volume vapour
and intake vapour
State b State c
Vapour is compressed polytropically
Heat transfer in this exhaust process
P3
Cylinder Volume, V
13
P-V diagram
14
Reciprocating Compressor
Additional Assumptions
Polytropic exponent n is same for
state bstate c and state dstate a
Heat Transfer during exhaust is
negligible state c & d are same
Pressure, P
P4
P3
Cylinder Volume, V
15
Reciprocating Compressor
Assumptions
Polytropic exponent n is same for
state bstate c and state dstate a
Heat Transfer during exhaust is
negligible state c & d are same
Pressure, P
c, d
P4
P3
b, a
specific Volume, v
16
Pressure, P
c, d
P4
Forrelaxationprocess,
Pd v dn = Pa v an
P3
specific Volume, v
and
n = n
v a = v b
At state b,
mass of vapour in cylinder =
massofclearancevapou r =
Vb
vb
Va
v a
Vb Va Vb Va
=
v b v a
vb
17
Volumetric Efficiency, v
v =
the compression
(Vb Va )v3
(Vb Vd )vb
But,Vb Va = (Vb Vd ) (Va Vd )
v =
P
and ,Va = Vd d
Pa
Pressure, P
c, d
P4
P3
P
= Vd c
Pb
LetusdefinieclearanceFactor , C =
specific Volume, v
b, a
Vd
Vb Vd
Pc n v 3
v = 1 + C C
Pb v b
1 + C C
P
and reexpansio n of the clearance volume vapour
v 3
[Effect of pressure drop and heating of intake vapour]
v b
18
Volumetric Efficiency, v
Factors affecting Volumetric
Efficiency
Reexpansion of Clearance
Vapour
Pressure drop in suction and
discharge valves
Heating of vapour on the
intake stroke
1
Pc n v 3
v = 1 + C C
Pb v b
1 + C C
P
and reexpansion of the clearance volume vapour
v 3
[Effect of pressure drop and heating of intake vapour]
v b
19
Volumetric Efficiency, v
Also,
! v3
m
PD
PD Piston Displacement in volume per unit time
v =
c, d
Pressure, P
P4
P3
Specific Volume, v
b, a
Pc n PD
! = 1 + C - C
m
P
v
b b
n isentropic exponent, k
n
P
c
Compressor Work, w =
Pb v b
1
Pb
n -1
!w
! =m
Power Requirement = W
m
20
Pressure, P
P4
P3
Compressor Work, v
a
Cylinder Volume, V
Using PV n = constant
(n 1 )
n
P
c
Compressor Work, W =
Pb (Vb Va )
1
Pb
n -1
n
P
w=
Pb v b c
1
Pb
n -1
21
22
Power Requirements
23 = m
(h 3 h 2 )
Capacity = Q
=
m
v PD
v4
,& ) n 1n /
nP
v
P
45 = W
comp = m
w 45 = m
b b .( c +
Power = W
11
1
n 1 .' Pb *
0
,& ) n 1 n /
Power
nPb v b
.( Pc +
=
11
1
Capacity (n 1)(h 3 h 2 ) .' Pb *
0
comp
W
23
Example Problem 1
Refrigerant 134a vapour enters the suction header
of a single-stage reciprocating compressor at 45
psia and 40 F. The discharge pressure is 200 psia.
Pressure drop in the suction valve is 2 psi, and the
pressure loss in the discharge valve is 4 psi. The
vapour is superheated by 12 F during the intake
stroke. The clearance volume is 5 % of piston
displacement. Determine:
(a) Volumetric efficiency
(b) Compressor pumping capacity if the piston
displacement is 10 in3 and the crankshaft rotates
at 1725 rpm, and
(c) Shaft horsepower required for a mechanical
efficiency of 70 %
Department of Mechanical Engineering, McMaster University
24
Solution to 1
c, d
Pressure, P
P4
P3
b, a
Specific Volume, v
P4 = 200 psia;
Pc = Pd = P4 + 4 = 204 psia
P3 = 45 psia and Pb = P3 2 = 43 psia
Tb = 52 F
25
Solution to 1
Given,
C = 0.05
n = k = 1.26
1
Pc n v 3
v = 1 + C C
Pb v b
204
1.26 1.09
(a) v = 1 + 0.05 0.05
= 0.83
43
1.16
v (PD )
0.83
10 in3 1725 rpm
! =
(b)m
=
= 7.6 lbm
3
3
min
v3
1728 in 3
1.09 ft
lbm
ft
(n 1 )
n
!
!
m
w
m
n
P
!
(c)W
=
1
Pb v b c
shaft =
Pb
m m n 1
!
W
shaft
!
W
shaft
(1.26 1 )
1.26
7.6 1.26
204
=
1
(43 )(144)(1.16 )
0.7 1.26 1
43
= 143,000 ft lbf
= 4.3 hp
min
26
Solution to 1
v3 = 1.09 ft3/lbm
3
b v = 1.16 ft3/lbm
b
27
Solution to 1
Given,
C = 0.05
n = k = 1.26
1
Pc n v 3
v = 1 + C C
Pb v b
204
1.26 1.09
(a) v = 1 + 0.05 0.05
= 0.83
43
1.16
v (PD )
0.83
10 in3 1725 rpm
! =
(b)m
=
= 7.6 lbm
3
3
min
v3
1728 in 3
1.09 ft
lbm
ft
(n 1 )
n
!
!
m
w
m
n
P
!
(c)W
=
1
Pb v b c
shaft =
Pb
m m n 1
!
W
shaft
!
W
shaft
(1.26 1 )
1.26
7.6 1.26
204
=
1
(43 )(144)(1.16 )
0.7 1.26 1
43
= 143,000 ft lbf
= 4.3 hp
min
28
Types of Compressors
Rotary Compressors
Two Types
Rolling Piston Type
Rotary Vane Type
30
Vs =
W
4
(A
B2 )
Pc n v 3
v = 1 + C C
Pb v b
31
Pc n PD
! = 1 + C - C
m
P
v
b b
(PD) = Vs (comp )
Also, comp =
(PD ) =
W
4
shaft
A A
B 1 B
(A
B2 )
shaft
A A
B 1 B
32
33
Scroll Compressors
34
Screw Compressors
35
36
Example Problem 2
An air cooled direct-expansion single-stage mechanical
vapour-compression refrigeration system uses
Refrigerant-22 and operated under steady conditions. A
schematic drawing of this system is shown in Fig. 4.21.
Pressure drops occur in all piping, and heat gains or loses
occur as indicated. Power input includes compressor
power and the power required to operate fans. The
following performance data are obtained:
Ambient Temperature, T0
90 F
20 F
Refrigeration Load, Q! E
2 tons
3 hp
Evaporator-Fan Input
0.15 hp
0.2 hp
37
Example Problem 2
Refrigerant Pressures and Temperatures are measured in seven
locations shown in the schematic. The table lists the measured and
computed properties of R-22, neglecting dissolved oil. A P-h diagram
of this cycle is shown comparing this cycle with a theoretical single
stage cycle between the air temperatures TR and To. Compute the
energy transfers to the refrigerant in each component of the system
and determine the second law irreversibility in each component.
Show that the total exergy destruction is equal to the difference
between the actual power input and the power required by a Carnot
cycle operating between TR and To with the same refrigerating load.
State
Measured
Computed
P, psia
T, F
h, Btu/lbm
s, Btu/lbm.R
v, ft3/lbm
45
15
106
0.2291
1.21
44
25
108
0.233
1.28
210
180
129
0.2374
0.33
208
160
125
0.2314
0.32
205
94
37.4
0.0761
0.01
204
92
36.8
0.075
0.01
46.5
36.8
0.08
0.31
38
Example Problem 2
39
Example Problem 2
40
Solution to 2
41
Solution to Problem 2
Evaporator
! =m
! = 2tons 12,000 Btu
! (h1 h7 ) = Q
EB :
Q
71
E
! =
m
2nd Law :
24,000 Btu
hr
Btu
(106.4 36.8)
Sgen
71
hr
= 24,000 Btu
= 345 lbm
hr
lbm
!
Q
24,000
! (s1 s7 ) 71 = 345(0.2291 0.08 )
=m
= 1.405 Btu
hr R
TR
479.67
Suction Line
! =m
! (h 2 h1 ) = 345(108.1 106.4 ) = 586 Btu
EB :
Q
12
2nd Law :
Sgen
12
hr
hr
!
Q
! (s 2 s1 ) 12 = 0.279 Btu
=m
hr R
To
Compressor
! =m
! = 345(128.8 108.1) 3 2545 = 494 Btu
! (h 3 h 2 ) + W
EB :
Q
23
23
2nd Law :
Sgen
23
! (s 3 s 2 )
=m
!
Q
23
= 2.417 Btu
hr R
To
Discharge Line
! =m
! (h4 h 3 ) = 345(108.1 106.4 ) = 1380 Btu
EB :
Q
34
2nd Law :
Sgen
34
! (s4 s 3 )
=m
hr
!
Q
34
= 0.441 Btu
hr R
To
Condenser
! =m
! (h5 h4 ) = 345(108.1 106.4 ) = 30,153 Btu
EB :
Q
45
2nd Law :
Sgen
45
! (s5 s4 )
=m
hr
!
Q
45
= 1.278 Btu
hr R
To
hr
42
Solution to Problem 2
Liquid Line
! =m
! (h6 h5 ) = 207 Btu
EB :
Q
56
2nd Law :
Sgen
56
! (s6 s5 )
=m
hr
!
Q
56
0 Btu
hr R
To
Expansion Device
! =m
! (h7 h6 ) = 0 Btu
EB :
Q
67
2nd Law :
Sgen
67
hr
!
Q
! (s7 s6 ) 67 = 1.725 Btu
=m
hr R
To
TR
= 6.852
To TR
!
Q
E
=
= 3502 Btu
hr
(COP )carnot
(COP )carnot =
!
W
carnot
!
W
comp
actual
Btu
!
=W
carnot + ToS gen = 3502 + 7.545 549.67 = 7649
hr
43
Solution to Problem 2
Component
Q
Btu/hr
W
Btu/hr
Sgen
Btu/lbm.R
Sgen/Stotal
%
Evaporator
24,000
1.405
19
Suction Line
586
0.279
Compressor
-494
7,653
2.417
32
Discharge Line
-1,380
0.441
Condenser
-30,153
1.278
17
Liquid Line
-207
Expansion
Device
1.725
23
Total
-7,648
7,653
7.545
W!comp
actual
hr
44
Absorption Refrigeration
Distinctions of Refrigeration
Evaporation
cools the air stream directly Direct Expansion (DX)
coil systems
cools water or brine chillers (common in commercial
units)
Compression
Mechanical Vapour Compression
Absorption Principle
Criteria
Changing
Economics and
Fuel Availability
46
Types of Compressors
Positive Displacement Compressor
Increases the pressure of refrigerant vapour by
reducing volume Reciprocating, Rotary, Scroll,
etc.,
47
Compressor
Energy Consuming Component
Reciprocating 1/16 to 150 hp or 50 to 112 kW
Orbital Scroll 1 15 tons or 3.5 to 52.5 kW
Helical Rotary 100 to 1000 tons or 350 to 3500 kW
Centrifugal 100 tons or 350 kW, upper limit
determined by physical size
48
49
50
51
TG
Pump
QG
WP
Absorption
Fluids
System
TR
QE
Refrigerated
Space
Qo=QA+QC
To
Environment
52
2nd Law S = S G + S R + S o 0
ForGenerator
or
S G =
QG
TG
S =
QG Q E Qo
0
TG TR To
(2)
TG To
To TR
WP
QG
QE
TR
TG
Assuming WP is negligible,
For Environment
Q
S o = o
To
COP =
QE TR (TG To )
QG TG (To TR )
($T!o #
TR )
T
!
"
$!#G!
"
ideal
(COP )refr
ig between TR &To
ideal
engine
between TG &To
(COP
) of Mechanical
with Engineering,
TG McMaster
& University
TR
Department
53
54
55
56
57
! 1h1 + m
! 2h 2 = m
! 3h 3
m
!1 +m
!2 =m
!3
m
! 1x 1 + m
! 2x 2 = m
! 3x 3
m
mass of material two
x=
mass of mixture
! 1 h2 h3 x 2 x 3
m
=
=
! 2 h 3 h1 x 3 x 1
m
Department of Mechanical Engineering, McMaster University
58
Example 3
A stream of liquid aqua-ammonia
! = 10 lbm
m
min
, x = 0.7
lbmNH3
lbmmix.
min
59
Solution to 3
60
61
Solution to Problem 3
(a) Let the state of stream for the flow of 10 lbm/min be
state 1. We find that the state 1 is subcooled condition
and we locate the point at T=60 F and x=0.7. State 2,
being saturated I located at T=200 F and p=100 psia.
!2
m
5
(x 2 x1 ) = 0.70 + (0.26 0.70) = 0.533 lbm NH 3 lbm mix
x 3 = x1 +
!3
m
15
62
Solution to Problem 3
(d) Since state 3 is a mixture of liquid and vapour, the
usual mixing equations apply. Thus,
! g x 3 x f
m
=
! 3 x g x f
m
f 3
=
= 0.033
fg
63
!
! 1 h1 + m
! 2h 2 = m
! 3h 3 + Q
m
!1 +m
!2 =m
!3
m
! 1x 1 + m
! 2x 2 = m
! 3x 3
m
! 1 x2 x3
m
=
! 2 x 3 x1
m
and,
!
!2
m
Q
(h 2 h1 )
h 3 = h1 +
!3
!3
m
m
Department of Mechanical Engineering, McMaster University
64
Example #4
1 Kg/min of saturated ammonia vapour with
concentration equal to 1 at 30 kPa is mixed
with 10 kg/min of saturated liquid aquaammonia at 30 kPa and 40 C. The final
desired mixture is to be saturated liquid at
30 kPa. Determine:
(a)The concentration, T and h of the mixture
state.
(b) The rate of heat removal during the
process in kJ/min
Department of Mechanical Engineering, McMaster University
65
=
=
! 2 x 4 x 3 h4 h 3
m
! 4 x 2 x 3 h2 h3
m
=
=
! 2 x 4 x 3 h4 h 3
m
and,
!
!2
m
Q
(h 2 h1 )
h 3 = h1 +
!3
! 66
m
m
Department of Mechanical Engineering, McMaster University
3
Throttling
67
Example 4
68
Solution to Problem 4
We draw straight line (12)
and locate state 3. We then
proceed vertically
downward to the saturated
liquid line for 30 psia and
locate state 3. We read T3 =
80 F, h3 = -24.0 Btu/lbm mix.
!2
m
(x 2 x1 ) = 0.345 + 1 (1.0 0.345 ) = 0.405 lbm NH 3 lbm mix
(a) x 3 = x1 +
!3
m
11
(b)From figure (b)
!
Q
= h3 h 3 = 54 ( 24) = 78 Btu
lbmmix
!3
m
! = 11 lbm
Q
min
78 Btu
lbmmix
= 858 Btu
min
69
Example Problem 5
Exam 2 in 2007
The
schema-c
shows
a
part
of
an
aqua-ammonia
absorp-on
refrigera-on
system.
0.5
kg/min
of
saturated
vapour
of
100
%
ammonia
coming
from
the
evaporator
at
50
kPa,
is
mixed
in
an
adiaba-c
absorber
with
a
weak
solu-on
containing
10
%
by
weight
of
ammonia
at
50
kPa
and
10
C,
and
owing
at
10
kg/min.
The
resultant
mixture
at
50
kPa
is
pumped
to
a
pressure
of
100
kPa.
The
solu-on
is
then
passed
through
a
generator
and
separator
to
be
heated
to
80
C
at
100
kPa.
The
resultant
vapour
is
cooled
to
obtain
a
saturated
vapour
containing
94
%
ammonia
by
weight.
What
is
the
net
energy
required
in
kW,
hp
and
tons
for
this
opera-on.
Assume
density
of
liquid
water
to
be
1000
kg/m3.
Department of Mechanical Engineering, McMaster University
70
Example Problem 5
71
Solution
Problem 5
72
Solution
Problem 5
73
Solution
Problem 5
74
75
76
Problem 6
Design the (generator + rectifier) unit followed by a (cooling +
rectifier) unit for the aqua-ammonia system shown in Figure
P3. The properties of a few state points are shown below. The
refrigeration required is 10 Tons. The residual heat from the
mixture of weak water solutions coming out of the two
rectifiers is used to heat the strong mixture in a heat
exchanger (HX) before getting further heated in the
generator. Carry out an energy audit for the system. 1 Ton =
12000 Btu/h. Neglect pump work.
77
Problem 6
78
NOT EFFICIENT
79
80
Rectification
@ Steady State Steady Flow
Ascending Vaopour Strengthens
Descending Liquid Weakens
At any two locations in the column, AA and
BB as in the figure. Mass flowing up is +ve &
vice-versa.
mVA+mLB = mVB+mLA
Or, mVA - mLA = mVB - mLB
Thus, at any cross-section,
mV mL = Constant = m3
Mass balance mVcV mLcL = m3c3
Energy Balance
mVhV mLhL = m3h3 + qD
Department of Mechanical Engineering, McMaster University
81
Rectification
@ Steady State Steady Flow
Mass balance mVcV mLcL = m3c3
Energy Balance
mVhV mLhL = m3h3 + qD
Thus,
82
Rectification
@ SSSF
83
Cool
Heat
84
Cool
Heat
KNOWN c3 = ca = c
m and c are mass flow and concentration
of vapour to the Condenser.
85
Cool
Heat
86
87
Cool
Heat
88
Cool
Heat
KNOWN m2
KNOWN c2 = cb
m and c are mass flow and concentration
of weak solution leaving generator.
89
Cool
Heat
90
91
Rectification process
92
Rectification process
Combining
Vapour leaving
generator travels up
and gets purified to 3.
This vapour continues
and gets purified to
state 3 in
dephlegmator.
Strong solution enters at
state 1 and mixed with
liquid leaving the
middle column.
93
Rectification process
Combined Process
Total Mass balance:
m1 = m2 + m3
Mass balance of B:
m1c1 = m2c2 + m3c3
Energy balance:
Ein = Eout (@SSSF)
Ein = m1h1 + qG
Ein = m2h2 + m3h3 + qD
Combining all
Equations, we get:
94
Rectification process
95
Problem #7
The following data are known for an absorption refrigeration system.
Condensing pressure 200 psia
Evaporator pressure 30 psia
Generator temperature 240 F
Temperature of vapour leaving dephlegmator 130 F
Ambient temperature 79 F
Temperature of Strong solution entering column 200 F.
The temperature of liquid leaving the condenser is reduced 10 F in the heat exchanger.
Assume equilibrium (saturated) conditions for the states 7, 9, 10, 1, 2 and 6. Neglect
pressure drop in components and lines. Assume that the system produces 100 tons of
refrigeration. Determine
a. Thermodynamic properties p, T, x and h for all the state points of the system.
b. The mass flow rates in lbm/min for all parts of the system.
c. Horsepower required for the pump if the mechanical efficiency is 75 %.
d. System COP
e. System refrigeration efficiency
f. Compare COP of the cycle with that of the theoretical sycle.
g. Energy balance for the entire system in Btu/min.
Department of Mechanical Engineering, McMaster University
96
Problem #7 Figure
97
Problem 8
Design the combined generator + rectifier + dephlegmator
unit for the aqua-ammonia system shown in Figure P8. The
properties of a few state points are shown below. The
refrigeration required is 10 Tons. The residual heat from the
mixture of weak water solutions coming out of the two
rectifiers is used to heat the strong mixture in a heat
exchanger (HX) before getting further heated in the
generator. Carry out an energy audit for the system. 1 Ton =
12000 Btu/h. Neglect pump work.
98
Problem 8
99