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CHEMISTRY TEST PAPER

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DURATION: 24 Hrs.

Marks:_______

Instructions for the examinee:

1. Each question carries one mark. There is no negative marking.
2. You need to provide a detailed solution for all the questions.
3. You will need to receive a minimum score of 16/20 in order to pass so, please
answer the questions carefully and check your work.
4. Please feel free to ask any query regarding the questions.
5. Use of calculator and books are allowed during the examination.
6. Any kind of plagiarism, if found, may lead to cancellation of your candidature.

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Instructions for the examinee:
1. All questions are compulsory
2. Numerical should be solved step by step.
3. Provide reactions wherever necessary.
Q1.

Give reason and justify with appropriate chemical reaction.

Bleaching powder looses its bleaching property when kept in an open bottle for long time.

Q2.

Give relevant chemical equation for the preparation of iodine from kelp.

Q3.

Name the elements which are estimated with the below mention method with reactions
a. Liebig method
b. Duma's method

Q4.

Find the longest wavelength of light that will be needed to remove an electron from the third
orbit of the He+ ion.

Q5.

The formation of F(g) from F(g) is exothermic whereas that of O2(g) from O(g) is
endothermic. Explain.

Q6.

Calculate the temperature at which oxygen molecules will have the same r.m.s velocity as
CO2 molecule at 300K.

Q7.

KCl has NaCl type of structure. Calculate the ratio of side of unit cell for KCl to that for
NaCl if r Na+ / r K+ is 0.7 and r Na+ / r Cl is 0.5.

Q8.

Balance the following oxidation reduction equation by the ion-electron method.

Zn + NaNO3 + NaOH (Na)2 ZnO2 2 + NH3 + H2O

Q9.

The solubility of Mg(OH)2 in pure water is 9.57 103 gm/lt. Calculate its solubility in 0.02
M of Mg(NO3)2 solution.

Q10. Calculate the amount of work required for adiabatic reversible expansion of 1 mole of a
polyatomic gas at 50 C and 10 atm pressure to 1 atm. (given Cp / Cv = 1.33)
Q11. (i) A black colored compound (B) is formed on passing hydrogen sulphide through the
solution of compound (A) in NH4OH.
(ii) (B) on treatment with HCl and potassium chlorate gives (A).
(iii) (A) on treatment with HCl and potassium cyanide gives a buff colored ppt. Which
dissolves in excess of this reagent forming a compound (C).
(iv) The compound (C) is changed into a compound (D) when its aqueous solution is boiled.
(v) The solution of (A) was treated with bromine water. On cooling and shaking for
sometime, a green colored compound (E) is formed. No change is observed on heating.
Identify (A) to (E) and give chemical equation for steps (i) to (v).
Q12. The base imidazole has Kb of 9.8 108 at 298 K.
(a) In what amount should 0.02 M imidazole be mixed to make 100 ml of a buffer at pH = 7.
(b) If the resulting buffer is diluted to 1 litre. Find the pH of the diluted buffer.

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Q13. What products will be obtained by the reaction of 1-phenylpropyne with (a) H2O/ Hg2+,
H2SO4 and (b) HCl (one mole)?
Q14. Write the S-cis conformation of cis, cis-hexa-2, 4-diene and trans, trans-hexa-2, 4-diene.
Which one of these two geometrical isomers will undergo Diels- alder reaction easily?
Q15. Draw most stable chair conformation of trans-1-isoprpyl-3-methlcyclohexane.
Q16. How many staggered conformation are possible for 1, 2-dichloroethane? Why does dipole
moment of this compound increase with temperature?
Q17

What products will be formed from 2, 3-Diphenylbutane-2, 3-diol on heating them in acidic
medium? Explain with mechanism.

Q18. How the cis cyclopentane-1, 2- dicarboxylic acid and trans cyclopentane-1, 2-dicarboxylic
acid can be distinguish and draw their structures also.
Q19. Conversion
(a) m-Xylene to 3, 5-dimethylchlorobenzene.
(b) Nitrobenzene to o-nitroaniline.
(c) Furfural Furan-2-acrylic acid.
Q20. How can the mixture of pentanal and pentan-3-one be seprated in pure form.
Q21. A hexapeptide on edman degradation yielded thiohydantoin derivative of valine. Hydrolysis
with trypsin gave two fragments, one containing Lys, Val, Leu, and other containing Phe,
Ala and Gly. Hydrolysis with chymotrypsin gave glycine and pentapeptide containing Lys,
Leu, Val, Phe and Ala. Hexapeptide on hydrolysis with carboxy-peptidase gave glycine.
Identify the sequence of amino acid in peptide chain.
Q22. Two separate experiments were carried out involving adiabetic reversible expansion, taking
mono-atomic gas in one case and a diamtomic gas in the second case. In each case, the
initial temperature was Ti and expansion was freom volume V1 to V2. The final
temperatures attained were Tm for monoatomic gas and Td for diatomic gas. Then arrange
the temperatures (Ti, Tm and Td) in increasing order.

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