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p&=4f4r-
ABSTRACT
N(#Wi&L&Ol+E:
I
R15F#INNGCO.
,.
6iwn
t ~
of e~~
.
SOCIETY
,OF ?ETBOLSUM
ENQIFJESRS
#O~R~AL
-.
.,. .,
OF
MICROSCOPIC DISPERSION
Kl
1
-Cm;+
D
1
Kt
.
D =;+
H
()
L
alln
&
FOR
,.
4.
XAllCtt,
196S
..
.
,.
OF
BASIC
SCAJJNG
CRITERIA
.&xgAp H
3. Groups describing boundary and initial conditions.
i.e., the
2 4. Groups relating fluid propertie~
dimensionless
viscositv
ratio of the solvent-oil
mixture to the solven; pm/p~, a dimensionless
density (pm - pJ/(p ~ - p~), artd the dimensionless
diffusion coefficient (Dm - DJ/(DQ - D J must be
congruent functions of concentration in model and
prototype.
5. Groups which scale the effects of mixing or
microscopic dispersion,
K!
9
UL
KtL
KtL
,
UH2 UW2
etc.
= 9.6X 104
For a typical model experiment, (D. )
aq f@, (f!&~d = 20 cp, fbrnad = 8?$I and Apmod
= 25 lb/eta ft. Relation between particle size and
permeability
for unconsolidated
sands used in
models CM be approximated by the relation ap =
0.002641/& where ap is in centimeters and k is in
darcies. For a typical reservoir, vres = 0.1 ft/D,
(po)re~ = 05 CP*&rern = 25 lbtcu ft~ + res = 0925
and kres = 0.5 dzrcies. Under these conditions,
.
.
SOCIETY
.
,.
..
-,,
OF ETROLEUM
ENGINEERS
JO-IIRNAI,
,-
%es (I&es
(Qes
~mod(~o)mod (%)mad
. ,.MARCH,
...
196S
-.
...
kxgApH
2. The viscous-gravity
ratio must be identical
in model and prototype when
k%gApH
- L
The viscous-gr~vity
when
ratio
need
not be
scaled
V/AoL
CL
<
< cu.
krgApH
The limits CL and Cu mum be determined experimentally.
3. Boundary and initial conditions must be the
same in model and prototype.
4. Dirrmnsionleas fluid properties must be congruent functions of concentration
in model and
prototype.
S. The transverse mixing group (KtL/Uff2) must
be identical in model and prototype.
The relaxed scaling criteria do not forma comple$e
set and, therefore, lack rigor. The experimental
program described in the following sections of this
paper was initiated to determine the limits CL and
CU and to confirm the criteria when transverse
mixiag is important.
EXPERIMENTAL VERIFICATION OF
RELAXED SCALING CRITERIA
To verify the relaxed scaling criteria, a number
of experiments were performed to determine dependmodel geometry,
ence of recovery on dispersion,
viacosit y ratio and viscous-gravity
ratio. Reaidts
of some of these experiments defined the viscous-. .,.
.,--
undo!
Numlwr
. .,
L/H
6X 3/S X 19.S
6x I x70
2
%,
3
4
s
6
7
8
9
10
11
12
13
---14
6X
3/8
x71
X23.8
x147
x72
X 19.S
X70
x147
x70.S
X30
2x 2
6x
2
2x
2
3/8 X 6
1X 6
2x
6
3/8 X 6
1*O5x 1/2
1/2 x 1.0s X30
1/2 X 3/$ x52,7
3/8 X 1/2 x72*3
0.012 xO.U44 x213
--x-
gravity
DETERMINATION OF LIMITS
To determine
()
=0,45,
sx
b%gApH
.. x
,.~
t+
(0)
L
3*25
11.7
114
14.4
X.6
36
52
70
73.s
186
28.6
60
105
193
262
The lower limit, CL, waa determined by compsring the performance of models in which the transverse mixing group and viscosity ratio were scaled,
and geometry and the viscous-gravity
ratio were
left unscaled. Data from experiments of this type
are shown in Fig. 3 for a viscosity ratio of 16.3.
In this figure, the dimensionless solvent penetration
x~/L is plotted against the dimensionless time Ut/L,
which is equivalent to hydrocarbon pore volumes
iajected. The simila performance of Models 12 and
13 for viscous-gravity ratios of 4.5 and 321, respectively, may be contrasted with the performance of
ratio of 0.15. A value
Model 10 for viscous-gravity
of 4.0 was selected as a conservative
estimate
of the link CL for a viscosiry ratio of 16.3. A
simiktr procedure was used to determine values of
eppr~ximarely 27 and 20 for CL at viscosity ratios
of 1.85 and 69, respectively.
TRANSVERSE MIXING BY
MOLECULAR DIFFUSION
Groups
of experiments
were conducted
in each
I
II
Ill
Description
20.30 M.sh
~{cm)
$6
.
k,(darcios)
000357
0e33
200
0.0075
0.36
15
0,37
oit13W0
SIJnd
%3
Fluid
System
Numbsr
&
Dil
Hexom
B
c
Hoxans
Honono
Hoxwm
Bayel-D
Psrchlorasthylms
1.(:)=
[*]
G
viscosity (Cp)
Dsnslty (gr/cc)
solvent
(Dyed Rad)
Haxons
&e&
0s5s
60. Parchlorasthybre
40. l%xano
,
WS-4212 Isoparoffinlc SoIvont
50. NF 65 ,Whits011
SO. Porchlorasthylons
78.4. NF 65 Whit. Oii
16.3- iiXXO,W
S.3 - Pwchlwocthylwm
S5.S - USP 33S White Oil
14.2- Porchlorosthylonc
93.9- NF 65 Whita Oil
6.1- Psrahiarrnthyims
NF 65 Whits Oii
i.w
1.00
1.89
794
1*OO
-
0.717
1,224
0,045 0.630
0.860
0.168 S.46
16.3
0.644
0,980
0.192
30.5
16.2
0.5s9
14.9
16.3
0.496
23*O
69
0,s00
0.S52
0,893
0.042
-0.730
0.170
%47
..
I+:)
,
.
SOCIETY
/;/-..
~
,-
-.
OF ETROLEUM
EN fJIPIEERS 10 URNAL
.
..
. .
. .
. .
.
,
of which geometrically
distorted models were
scaled to the same prototype in initial experiments
where transverse mixing was dothiaated by molecular
diffusion,
A criterion for molecular
diffusion,
obtained
from published correlations for equal=
viacosit y systems (Fig. 1), requites Ithst apU/Ds
be less than 2.0 in the model.
Measurement of diffusion coefficients of some of
diathe fluid systems in Table 2(B) by the POrOUa
phragm method, 16 together with published data,17
led to the approximate relationship
DH E 10-5
sq cm-cp/sec
for a temperature of 70F. In this
to
paper, the diffusion ~oefficient corresponding
the viscosity of solvent is used in the scaling
groups; thus, for fluid system E(Ps = 1.S8 CP), the
characteristic diffusion coefficient Dst is 0.53 x
10-S Sq cm/See, ~xperiment~
measurement
of
diffusion coefficients fog reservoir flui& at reservoir
temperature and pressure is usually necessary,
although typical diffusion coefficients
have been
published 18-20 for some systems.
Transverse
dispersion coefficients
in the molecular diffusion
region were calculated from the relittion Kt = Ds /r.
For unconsolidated
sands or glass beads, r was
as sunwd to be 1,5. For consolidated media, r can
be obtsined moat conveniently from electrical meaaurementa.
Model performance before solvent breakthrough
was monitored by recording the maximum penetration
distance x ~ of the red-dytd solvent as a function of
a dimensionless
time UtiL, wtitch is equivalent
to hydrocarbon #ore volumes injected. Performance
after breakthrough was monitored by recording the
oil concentration
in the effluent, determined by
refractive
index measuretrients,
as. a function of
dimensionless
time.
Tests were conducted to c?~ermine if movement
of the red dye contained in the solvent was a
useful indicator of solvent penetration.
These
tests
consisted
of comparison of breakthrough
recoveries obtained by dye observation with breskchtougb recoveries obtained by refractive index
analysis of the effluent. In all cases, breakthrough
recoveries
determined by two methods were in
agreemeot.
Viscous.gravity
ratio was not scaled in experiments hi geometrical y distorted models at several
viscosity ratios. Models 10 to 13, where L/ff varied
from 28.6 to 193, were used. These models were
scaled to a common protot ypc by requiring that the
transverse mixing group, (K:LWH 2, have the same
numerical value in all models. Since modet geometry
was predetermined and Kt was fixed by the fluid
system, this equality had to be satisfied by choosing appropriate injection rates,
Results of these experiments are shown in Figs.
4 to 7 for viscosity ratios of 1,85, 7.4, 16.3 and
69. Good agreement of dimensionless
solvent
penetration
and effluent composition shows that
equivalent
model performance was obtained even
though L/H and vp&jkxgApH
were left unscaled.
In the experiments conducted at a viscosity ratio
of 16.3 (Fig. 6), values of L/H ranged from 28.6
to 193, and values of vpoL/kxgApH ranged from
4.5 to 32L In the experiments conducted at a
viscosity ratio of 69 (Fig. 7), the values, of L/H
were 105 and 193, end the corresponding
values
of vKJJk=gApH
were 20 and 1,470. Occurrence
of l;teral -fin~ering at the high rates used in
Model 13 was responsible
for the greater solvent
penetration at a given pore volume injected.
Longitudinal
dispersion
was unscaled
in all
experiments. In Fig, 6, for example, the Iongit udinal
dispersion group Kt[UL varies from about 3 x 10~
in Model 13 to 24 x 104 in Model 10. There is no
noticeable influence of longitudinal dispersion on
model performance.
Viscous-gravity
ratio was scaled in two sets of
experiments
in geometrically
dissimilar
models
where gravitational
forces dominated the shape of
gravity tongue. Models 3 and 4 were scaled to a
common prototype and flooded at viscous-gravity
ratios of about 1.1; Models I and 2a were scaled
to another prototype and flooded at viacousxravity ratios of about 0.33. Fi&s. 8 and 9 show
~hat ~quivalent performance wa; obtained.
1.0
/
/
0.8!
It
06
,Cl
I
10
103
I
I
102 Id
1. .
@
cu.
~H[ii
2.02
1.73
MO
0.2
o~
o
~2
{#
Sm. 2 TNE UPPER LIhliT ICv ON V12COUS(MtAVITY RAT~ IS A FUNCTION OF (L/H)% 3ECONDARYFINGERS NAVE NO EFFECT ON PERFORMANCE WHENVISCOUS-GRAVITYRATIO IS LESS THAN
.
D
0.13 0.1S
121
o
1,16 4,5
D
0.60 321
!3
II
FIG. 3
0,2
EXPERIMENTAL
DETERNWATION
OF
THE
Lo
008
0.6
~
- 60
0,4
ModBl
.
1
0.2
80
kdia
IB
13
II
1,9
10
12
13
Ill
Ill
0.04
O*54
0.34
41
27
57
Ill
0.82
260
0.53
40
+ 20
0.52
,>q
o
1
0,8
0,6
0.4
0,2
Tim., WI-
Dimonsienl.ss
?,2
FIG. 4 -
Model
4/
13
12
JzJ_L~
i5
i
0.4
0.2
G..
Media
Fluid
.
II
~.
c
c
Ill
0,5
0.08
%6
43
55
2.00
2,19
1,2
Lo
0.8
<.
0.8
80
1!
~ 0,6
$
3 4
*
,g
f
iso
o
0.4
0.2
008
0,6
Dimnsiocdoss Tim., Ut/1.
1.0
1,2.
FIG. 6 GEOMETRICALLY
1
.
. .
.-.:....
:,
~M
la F
Msdcl kdia
f3
lt
0.4
0.2
Fluid g&
.
G
906
121
ix)
f470
L1
20
40
-Gi-
1,78:
20
0.2
0.4
0.6
0.8
Dim.nsionl.ss Tim.,
1,0
1.2
WA
Vertical
sweep efficiency
correlations
were
developed by assembling recovery data from all
experiments.
These correlations
not only aid in
interpreting
the experimental results, but they also
provide a convenient method for prcdicting,recovery
performance. Correlations for the region in which
viscous-gravity ratio can be left unscaied are slaowg
in Figs. 10 through 12. In these figures, recoveries
(i.e., vertical sweep efficiency) aker breakthrough
are plotted as a function of the transverse miaing
group with dimensionless
time (i.e., hydrocarbon
pore volumes injected) as a parameter. CorrcJations
O.n
Fafi! 10.2
0.4
setJ
weL
0,4
KL
~ [-)
UHH
..
31
E1.6t0
0=
#I
E1.2102
0.022
O.l
[/
.
o
.
0.15
0,10
0.05
0,?9
tm
cat
L1,0
0,44
E,w
WI
d
m.
0,0Z9
B,m
a
:
0,1
01
0.3
D&m,imbm
0.4
0.5
0
a4
0.01
I
0.1
I
1,0
10
Tim, uvl
MIXING
AND
VISCOUS-GRA~
RATIO
VBCOUS-GRA~Y
RATIO IS LESS THAN
XARC5t. 196S
DISSINtLARMOlk8 SHOW
FIG.9 - GEOMETRICALLY
WHEN T-vERSE
-fi=
pERFOUCE
..
o.?
i
@%
SCALED,
CL, AND
.
as
,.
,
MIXING BY
DISPERSION
To verify the relaxed scaling criteria for convective dispersion, additional experiments were
conducted, These experiments were performed in
the intermediate range of viscous=geavity ratios
where scaling of this ratio i a not required.
Mdh
M9dol
Fluid
Ill
13
Ill
260
10
Ill
82
10
Ill
II
Ill
{. 10
a.oo
0.01
I
Lo
0.I
13
01
324
13
ill
S60
13
12
11
10
II
I
II
Ill
D
D
D
D
321
4s
26
15
Ill
61
Ill
1s2
114
co
[
0.4
h-
o
0.01
i!4//I
0.1
Lo
-.. ..
FI& 12 VERTICAL
SWEEP
EFFICIENCY
(N )
CORRRLAISON
FOR A VISCOSITY
RATIO
OF %9
WNEN TRANSVERSE
BIIXING X3 RY NCXJ342ULAR
DIFFUSION.
..
.
.
.
. . . .. . . . .. .
86
10
10
10
II
V{S6QS@ Ratio 69
z.
.. .
57
27
10
KL
t (-]
UH H
41
A
A
B
13
12
13
II
290
12
20
13
II
1470
10
II
62
10
13
II
e
e
.G
270
a
970
E 0.517,
OF WETUOLEUH
..EF3GIIUEERS 30 URNAL
Typicaf reiovery
illustrated in Fig. 14
Recov@riea at nolvent
bretaktimmagh end at 1 PV injected ate shown as a
function of viscous=gravity do. Recoveries shown
in Fig. 14 initially decrease but approach a constant
value as rate incrsases; (At rates high eaough to
generate
and propagate significant
secondsty
fingers.
rscvvexies
a#n
increase,)
A s@iiar
characteristic reitiion between recovery end rate
has been observed in other investigations,$ and
was obtsined in ail csperiments which were performed
in the convective dispersion ~egion. The difference
in breakthrough
recovery for ModeIs 13 and 9
resulted fkom the occurrence of lateral fingers in
the 6-in.-wide model (No. 9). To iaimiz#k6ccffcct@
of iatetal fingers, subsequerm experiments were
performed in modeis of 1 in. or less in width.
t?/fectivs
dispersion coefficients
have been
defined to facilitate interpretation of the data and
permit the development of a correlation usefui in
designing
laboratory models. Those coefficients
are so defined as to permit urm of the vertical
sweep efficiency correlations developed for the
molecular diffusion region iv predicting model
performance in the convective dispersion region.
The effective transverse dispexsiort coefficients
can be evaluated by comparing recovery vsdimension=
less time data obtained in the conveaive dispersion
region with recovery vs dimensionless
time data
obtained in the molecular diffusion region (presented
in Figs. 10 through, 12), At each dimensionless
time, the value of the mixing group, (~ L/ (JH2),
which gives the recovery experimentally observed
in the convective ditipersion region, is read from
the vertic~
sweep efficiency
correlation.
The
ratio of K*C/Ds is then calculated from the mixing
group, using the known values of L, H, U and De.
Site
it ia known that the ratio f$ /D for equslfor a wide
data -
range of rates,
viscodt y, equxi-density
systems correlates
with
a dimensionless velocity a#iAls one might expect
the effective dispersion coefficients to correlate
with s similw qusntity. it was found empirically
thata @u&able group is a#l/D= Np.
Extensive data obtained in Models 11, ~2, 13
and 14 for a viscosity ratio of 16.3 and mote limited
data chained in Modeis 11 sad 12 for a viscosity
ratio of 69 sre presented in Fig. 15. The effective
transverse dispersion coefficients
were obtained
by rastching recoveries, using the described pro- ~
pore volumes
cedure, from 0,6 to 1.2 hydrocsrkn
injected. A viscous-gravity rsrige of 16.7 to 17,000
is covered by these data,
Correlatiori
of the effective transverse
coefficients for 20=30 mesh Ottawa sand for unequal=
draeity, unequal-viscosity
fluids essentially dupli=
cates the correlation presented in Fig 1 for this
for equai.densit y, equsi-visco sity
same
sand
fluids. The data obtained for the 80-120 mesh
giass beads fail above the 20=30 mesh data; howevert the curve correlating
these results
fails
sii@ciy below that obtained for 40-200 mesh silica
sand shown in Fig. L
Close similarity between the correlations
presented in Figs, 1 and 15 suggests that transverse
dispersion coefficients
for equ.f.i density,
equslwiscosity fluid sytnerns may be adapted for use in
unequal-density,
unequal-yiscosit y fluid systems.
Kt having been defined as described ebove, the
vertical
sweep efficiency correlations
developed
for molecular diffusion may be used to predict
performance
for convective
dispersion
when the
relation between Kt*/P= and, a#J/D= NP is known
for a specific porous media. 131s relatlon provides
a reliable criterion for predicting whether transverse
mixing is dominated by molecular diffusion or by
convective
dispersion.
were obtained for a wide
The above correlations
range of L/H in a region in which the viscousgravity ratio was not srded. The correlation demonstrates that the relaxed scaling criteria are also
valid in the convective
dispersion region when the
viscous-gravity
ratio
OF DENSITY DIFFERENCE
ON CONGESTIVE DISPERSION
EFFECT
Measurements
1---:
%!01
----- 1
-
coeffi-
Lo
dispersion
O.t
*)
MARCH,
of transverse
Siiuk
10
10%
IM
IO,OKI Ioa,om
&
k, \,4i
,,,.
in model
length,
APPLICATION
SCALING
OF RELAXED
CRITERIA
la
4(
Ei
b?-
.f
%%+
FIO,16~ TNR EFFRCT OF A NIGH D13NS~Y IXFFERENCE ON fCt*/D* FOR 20-30 NESH SAND DECi?lEA~S
WITH INCREASINtl
MODELLENGTEL
.-, -,
. .. . . . .
.-...-,-. .. .. . . . .. .. .
~~fA:>cO?5ymmD%t&FdLkD#RvAa&i~2fi:
SOCIETY
.,---
100
10
..
OF PETROLEUM
WVQ1?WERS
IOURNAL
..-..
........ >---- ,------...........
. .
: -..
: .,.
,-,.
a pore volume
1 = time (t) .
U = V/( LSwc)#,
CONCLUSIONS
...:.,.
-, =,.
. ..
.
. ---..:
~..
,.
~. ----. .
.,
,..
. .. . . .
------- .4:
....
. . .-
....- .=,.
.
. . ..
.,
.,
,.
.. ,---
velocity (L/t)
darcy
FO - PS (MIL3)
tortuosity
of this investigatio~
the fol~ow=
.. .
. . .. .
.
frond
velocicy (Lit)
W = width (L)
z~ = rnaxhnlun aolvcnt
psnctration
in
direction of flow (L+)
angle of dip
empirical
constant
in viscosity.
concentration equation
empirical
constants
in dispcmion
relations
viscosity (MZIJ)
density (MIL?)
v =
.,.
.e,
.r
.,.$.
..
.,
# = Porosity, frsaionel
veid space
SUBSCRIPTS
m .
~,
Josr, FMd Me&. (1959) VOL
DW
P. t3.: ~in~~mlon
t L Saffina~
mi~me
c4E4)ii
# . ~[vegt
~ff.~
27S.
2.Cross, G, A,, Gaartms, & and 8wmtrAN.: ihaory
9f Dlnwnsionally Sealed Model* of Petrc4eum ffeserWO&S , lkwm,
ml%
(1956) Vol. 207, 1la
% Offerings, J. sad van dor Poe& C.: DtaplssureerIt
by
kMacible
~@&tS*O,
of Oil from k%SOUB kbdk
Tnmsi, AIME (1954) ~Oi, 243L 310.
4* ~~ der Poei, Cl: #tE@~ of ~terml h~fus~v~& on
Vol. 210,
%~o&5#
19s9).
Studies Or ~_4WOPiC
a Bfackvnll, R J.: hbwStOrY
~&;~:al
Phenomena, Sec. Pet. R*. Jore. {Mare%
~~,
fif~us
low.
JCW
tm
Tensor Form of Dbwondm ~
t$adia~,Jws. Geophys Res. (1961) VOL 66,
J,:
.
ff~ob~abt~V. N.:f9c~Vo~~Ve DiffiMkl h orws
ktsdk, ~w.
$$92 @r@sb
@#.
translation].
Weio@mr~r, A (E41tor] Tacbdgae o~ OrgmdcGbam6SW, VOL X,Pert [, %cond S36., Physical Methods
6, 4S L
Rear@m, il.SS and Sage, B. R: IXffusion CoPhaae of the Etbenseffiokrmt of Etharw in the Liquid
White Oil Syatemt, Joar. Chsm. Eng. Data (1961)
VOL 6, 180.
!?emner, EL K esidSage, B. H.: DiffusionCceff~ients
& $fydroearbon Syatemai Methane in the Liqutd
Pbnae of the MaWme-t%nto Fe Springs Crude Oil
System,
,,
321,
~ol~dw
v& 7, 144.
L cra~
6,
to
REFERENCES
(1957)
metltm,on ~iqf
by Fluid ~OW in Pmokw ktis,
lb. P*L slag,@re. Qfar&i, t%l) L
10. Ssffman, P. G.: 8fA Thawy of Dixparaion in Porous