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A layer of material of known thickness and area can be heated from one
side by an electric resistance heater of known output. If the outer surfaces of
the heater are well insulated, all the heat generated by the resistance heater
will be transferred through the material whose conductivity is to be
determined.
Then measuring the two surface temperatures of the material when
steady heat transfer is reached and substituting them into Eq. 121 together
with other known quantities give the thermal conductivity
(Fig. 128)
that pure crystals and metals have
the highest thermal conductivities, and gases and insulating materials the
lowest.
Temperature is a measure of the kinetic energies of the particles such as
the molecules or atoms of a substance. In a liquid or gas, the kinetic energy
of the molecules is due to their random translational motion as well as their
vibrational and rotational motions. When two molecules possessing different
kinetic energies collide, part of the kinetic energy of the more energetic
(highertemperature)
molecule is transferred to the less energetic (lower-temperature)
molecule, much the same as when two elastic balls of the same mass at
different
velocities collide, part of the kinetic energy of the faster ball is transferred to
the
slower one. The higher the temperature, the faster the molecules move and
the
.higher the number of such collisions, and the better the heat transfer
The kinetic theory of gases predicts and the experiments confirm that the
thermal conductivity of gases is proportional to the square root of the
thermodynamic
temperature T, and inversely proportional to the square root of
the molar mass M. Therefore, for a particular gas (fixed M), the thermal
conductivity increases with increasing temperature and at a fixed temperature
the thermal conductivity decreases with increasing M. For example, at
a fixed temperature of 1000 K, the thermal conductivity of helium (M = 4)
is 0.343 W/mK and that of air (M =29) is 0.0667 W/mK, which is much
.lower than that of helium
This relation is based on the requirement that the rate of heat transfer
through
a medium with constant average thermal conductivity kavg equals the rate of
heat transfer through the same medium with variable conductivity k(T). Note
that in the case of constant thermal conductivity k(T) 5 k, Eq. 275 reduces
to kavg5 k, as expected.
Then the rate of steady heat transfer through a plane wall, cylindrical layer, or
spherical layer for the case of variable thermal conductivity can be
determined
where b is called the temperature coefficient of thermal conductivity.
The
average value of thermal conductivity in the temperature range T1 to T2 in this
case can be determined from
fig The variation of temperature in a plane
wall during steady one-dimensional
heat conduction for the cases
of constant and variable
.thermal conductivity