Chemical Bondg

Level 1
Q No: 1
Which of the following diagram / statement is correct for the hybrid orbitals.
(1) s + py z'
(2) s + py + pz sp2 orbitals lie in the xy plane
(3) ns + np3 + nd2 results octahedral geometry of sp3d2 hybrid orbitals
(4) none of these
Correct Answer: 4 Status: unattempted
All options are not correct for the hybridization.
NA
NA
Q No: 2
In a molecule of phosphorus (V)oxide, there are
(1) 4P P, 10P O and 4P = O bonds
(2) 12P O and 4P = O bonds
(3) 2P O and 4P = P bonds
(4) 6P P, 12P O and 4P = P bonds
[X]
Phosphrus (V) oxide is P4O10
Count the bonds (12) P O, (4) P = O

Q No: 3
Among the following, van der Waals forces are maximum in
(1) HBr
(2) LiBr
(3) LiCl
(4) AgBr
[X]
AgBr has maximum vander-waals force

AgBr has maximum molar mass and maximum surface valume
NA
Q No: 4
Molecular shapes of SF4, CF4 and XeF4 are :

(1) the same, with 2, 0 and 1 lone pair of electrons respectively
(2) the same, with 1, 1 and 1 lone pair of electrons respectively
(3) different with 0, 1 and 2 lone pair of electrons respectively
(4) different with 1, 0 and 2 lone pair of electrons respectively
hybridization in SF4 (sp3d), CF4(sp3), XeF4 (sp3d2)
Draw the structure
NA
Q No: 5
Identify isostructural pairs from NF3(I), NO3(II), BF3(III), H3O+(IV), HN3(V)
(1) I & II, III & IV
(2) I & V, II & III
(3) I & IV, II & III
(4) I & IV, III & V
Find the hybridization in all molecule.
NA
Q No: 6
Which of the following compounds would have significant intermolecular hydrogen
bonding ?
HF, CH3OH, N2O4, CH4
(1) HF, N2O4
(2) HF, CH4, CH3OH
(3) HF, CH3OH
(4) CH3OH, CH4
HF and CH3OH have intermolecular hydrogen bond
NA
NA
Q No: 7
Which of the following have a three dimentional network structure ?
(1) SiO2
(2) (BN)x
(3) P4(white)
(4) CCl4
Correct Answer: 1,2 Status: unattempted
[X]
SiO2 and (BN)x have three dimensional network structure.
P4 and CCl4 are discrete molecules.
(BN)x has graphite like structure.

NA
Q No: 8
Which of the following factors are responsible for origination of van der Waals forces ?
(1) Instantaneous dipole-induced dipole interaction
(2) Dipole-induced dipole interaction and ion-induced dipole interaction
(3) Dipole-dipole interaction and ion-induced dipole interaction
(4) Small size of molecule
Correct Answer: 1,2,3 Status: unattempted
[X]
Vander Waals forces are the intermolecular force of attraction, of the type
London force or instantaneous dipole induced dipole interaction
Dipole induced dipole interaction

Ioninduced dipole interaction
Iondipole interaction etc.
NA
NA
Q No: 9
The noble gases have closed-shell electronic configuration and are monoatomic gases
under normal conditions. The direct reaction of xenon with fluorine leads to a series of
compounds with oxidation number 2+, 4+ and 6+. XeF4 reacts violently with water to
give Xe and XeO3. The compounds of xenon exhibit rich stereochemistry and their
geometries can be deduced considering the total number of electron pairs in the valence
shell.
The geometry of XeO3 is
(1) Linear
(2) Planar
(3) Pyramidal
(4) T-shaped
In XeO3 hybridization of Xe is sp3 and it contains one p. so its geometry is pyramidal like
that of NH3.
NA
NA
Q No: 10
shell.
Hybridization of XeF4 is
(1) sp3
(2) dsp2
(3) sp3d2
(4) sp3d
In XeF4, central atom has 4 -bonds and two p. so its steric number is 6. Hence,
hybridization of Xe in XeF4 is sp3d2.
NA
NA
Q No: 11
shell.
The shape of XeF6 is
(1) Octahedral
(2) Trigonal bipyramidal
(3) Distorted octahedral
(4) Pentagonal bipyramidal
In XeF6, the p on Xe is stereochemically active hence, its geometry is distorted octahedral
NA
NA
Q No: 12
Statement-1 : HNO3 is a stronger acid than HNO2.
Statement-2 : In HNO3, there are two NO bonds whereas in HNO2 there is only one.
(1) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.
(2) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct
explanation for statement-1.
(3) Statement-1 is true, statement-2 is false.
(4) Statement-1 is false, statement-2 is true.
Higher the oxidation state of the central atom of an oxy-acid, stronger will be the oxy-acid.
NA
NA
Q No: 13
Statement-1 : b and * orbitals obtained from 2p orbital are lying in the same plane.
Statement-2 : Bonding M.O's are formed by constructive interference while antibonding
M.O's are formed by destructive interference.
statement-1.

[X]
NA
NA
Q No: 14
CH bond distance is the longest in :
(1) C2H2
(2) C2H4
(3) C2H6
(4) C2H2Br2
[X]
C C bond order in C2H6 compound is (minimum) = 1 so its bond length is maximum in

C2H6
Q No: 15
Two ice cubes are pressed over each other and unite to form one cube. Which force is
responsible for holding them together :
(1) van der Waal's forces
(2) Covalent attraction
(3) Hydrogen bond formation
(4) Dipole-dipole attraction
Hydrogen bonding
NA
NA
Q No: 16
Which of the following has the least dipole moment
(1) NF3
(2) CO2
(3) SO2
(4) NH3
[X]
NA
NA
Q No: 17
Number of anti bonding electrons in N2 is :
(1) 4
(2) 10
(3) 12
(4) 14
[X]
NA
NA
Number of antibonding electrons in N2 is
Q No: 18
Which have fractional bond order?
(1) O2+
(2) O2
(3) NO
(4) H2+
Correct Answer: 1,2,3,4 Status: unattempted
MOT
B.O.
O2+ 2.5
O2 1.5
NO 2.5
H2+ 0.5
All have fractional bond order.

Q No: 19
Which of the following have planar structure?
(1) I3
(2) H2O
(3) PCl5
(4) XeF4
All the bond pair are present in a same plane.

I3 linear H2O Bent
PCl5 Trigonal bipyramidal
XeF4 Square planer
I3, H2O and XeF4 are planar metals.
Q No: 20
Statement-1 : NH3 and CH3 both have pyramidal shape.
Statement-2 : N in NH3 and C in CH3 both have sp3-hybridisation with one lone pair of
electron on each.
statement-1.
[X]
Isoelectronic.
sp3 hybridised.
Q No: 21
Statement-1 : The bond angle in H2O is greater than H2S.
Statement-2 : H-bonding does not occur in H2S due to low electronegativity of S.

statement-1.
[X]
E.N. of central atom increases bond angle increases.

Bond angle of H2O > H2S.
Q No: 22
Statement-1 : The melting point of noble gases increases as its atomic mass increases.
Statement-2 : Instantaneous dipole induced dipole attraction increases with increase in
atomic mass.
statement-1.
NA
NA
Vanderwaal force of attraction molecular mass.
Q No: 23
Among the following, the element which show inert-pair effect are :
(1) Bi
(2) Sn
(3) Pb
(4) C
Pb belong to 6 period.
In 6 period lanthanoid contraction effect is observe.
NA
Q No: 24
The maximum covalency is equal to
(1) the number of unpaired p-electrons
(2) the number of paired d-electrons
(3) the number of unpaired s and p-electrons
(4) total number of unpaired electron in ground state or in excited state
The, maximum covalancy is equal to total number of unpaired electron in ground state or in
excited state.
NA
NA
Q No: 25
Statement-1 : PCl bond in PCl3 and PCl5 had different bond energy.
Statement-2 : P in PCl3 and PCl5 is sp3-hybridised.
statement-1.
Hybridisation of P in PCl3 and PCl5 is sp3 and sp3d respectively.

PCl bond in PCl3 and PCl5 is formed by the overlapping of different orbitals, so different
bond energy.
NA
NA
Level 2
Q No: 1
Borax is actually made of two tetrahedra and two triangular units joined together and
should
be
written
as:
Na2[B4O5(OH)4]8H2O
Consider
the
following
statements
about
borax:
1.
Each
boron
atom
has
four
BO
bonds
2.
Each
boron
atom
has
three
BO
bonds
3. Two boron atoms have four BO bonds while other two have three BO bonds
4.
Each
boron
atom
has
one
OH
groups
Select correct statement(s) :
(1) 1, 2
(2) 2, 3
(3) 3, 4
(4) 1, 3
[X]
Draw the structure.
(1) In this structure two boron atoms have four BO bonds while other three BO bonds
(2) Each boron has one OH group.
NA
Q No: 2
Which of the following has been arranged in order of decreasing bond length ?
(1) P O > Cl O > S O
(2) P O > S O > Cl O
(3) S O > Cl O > P O
(4) Cl O > S O > P O
P O > S O > Cl O = Bond length order due to size of P > S > O
Size bond length
NA
Q No: 3
Which has higher bond energy :
(1) F2
(2) Cl2
(3) Br2
(4) I2
Correct Answer: 2
Status: unattempted
[X]
Cl2 has higher bond energy than F2.

F2 have high inter electron repultion.
NA
Q No: 4
The enolic form of acetone contains :
(1) 9 sigma, 1 pi bond and 2 lone pairs
[X]
Cl2 has higher bond energy than F2.
F2 have high inter electron repultion.
NA
Q No: 5
Arrange
the
following
in
order
of
(1)
(2)
(3)
n-Butyl
(4) Isobutane
(1) 4 > 3 > 2 > 1
(2) 4 > 2 > 3 > 1
(3) 1 > 2 > 3 > 4
(4) 2 > 3 > 1 > 4
decreasing
boiling
point
:
n-Butane
n-Butanol
chloride
Boiling point order :

n-Butyle alcohol > n-Butyle chloride > n-butane > Isobutan
Due to Vander-Waal force and hydrogen bond.
NA
Q No: 6
A, B, C are three substances. A does not conduct electricity in the solid, molten state and
aqueous solution. B conducts electricity both in the fused and aqueous states, while C
conducts electricity only in the aqueous state. In solid state neither B nor C conducts
electricity. Which of the following statements is/are true regarding A, B and C ?
(1) A has polar covalent linkage

(2) A has nonpolar covalent linkage
(3) B is ionic in nature
(4) Cation formed by C is highy polarizing
[X]
non-polar covalent bond doesn't ionize, ionic compounds dissociate into ions in molten state
as
well
as
in
aqueous
state.
Polar covalent compounds such as HCl ionise in aqueous state.
NA
NA
Q No: 7
Which of the following species are linear ?
(1) ICl2
(2) I3
(3) N3
(4) ClO2
[X]
ICI2, I3 and N3 are linear.
In ICl2 and I3, central atom is sp3d hybridized and contains two lone pair electrons.
NA
Q No: 8
Statement-1
:
POF3
exist
but
NOF3
does
not
exist.
Statement-2 : 'P' can form five bond by expanding its octet while 'N' can not expand its
octet to form five bonds.
statement-1.
Both
POF3
and
NOF3
[X]
exist.
P has vacant d-orbital in its outermost orbit, so its octet can be expanded but N doesnot have
vacant d-orbital in its outermost orbit, so its octet cannot be expanded.
NA
NA
Q No: 9
Statement-1 : Although PF5, PCl5 and PBr5 are known, the penta halide of nitrogen have
not
been
observed.
Statement-2 : Phosphorus has lower electronegativity than nitrogen.
statement-1.
N doesnot have vacant d-orbital in its outermost orbit so its octet cannot be expanded. It has
only 3 unpaired electrons in its outermost orbit ; so it can form only three covalent bonds.
NA
NA
Q No: 10
Statement-1 : PCl3 on hydrolysis gives

Statement-2 : H3PO3 exists in two tautomeric forms :
statement-1.
[X]
NA
NA
Q No: 11
The bond angle and hybridization in ether (CH3OCH3) is :
(1) 10651', sp3
(2) 10431', sp3
(3) 110, sp3
(4) None of these
[X]
Due to the steric repulsition of bulky group (CH3) bond order in CH3OCH3
Bond angle is compound is maximum 110 and sp3 hybridisation.
Q No: 12
A : Tetracyanomethane
B : Carbondioxide
C : Benzene
D : 1, 3butadiene
Ratio of and bonds is in order :
(1) A = B < C < D
(2) A = B < D < C
(3) A = B = C = D
(4) C < D < A < B
[X]
A=B<C<D
Q No: 13
Among KO2, AlO2, BaO2 and NO2+ unpaired electron is present in :
(1) KO2 only
(2) NO2+ and BaO2
(3) KO2 and AlO2
(4) BaO2 only
[X]
+
+2
K / O2 AlO2 , Ba / O2 NO2
Unpaired electrons is present in O2.
NA
Q No: 14
Identify isostructural pairs from NF3(I), NO3(II), BF3(III), H3O+(IV), HN3(V)
(1) I & II, III & IV
(2) I & V, II & III
(3) I & IV, II & III
(4) I & IV, III & V
[X]
(I) NF3 Pyramidal
(II) NO3 Trigonal planar
(III) BF3 Trigonal planar
(IV) H3O+ Pyramidal
(V) N3H Bent
I & IV isostructural pair
II & III isostrucural pair
NA
Q No: 15
Which of the following is true ?
(1)
Bond order
bond energy
(2)
Bond order bond length
(3)
Bond order
(4) Bond order bond length bond energy
[X]
If the B.O. increase altraction between two atoms increases.
NA
No: 16
In the structure of H2CSF4, which of the following statement is/are correct?
(1) Two CH bonds are in the same plane of axial SF bonds.
(2) Two CH bonds are in the same plane of equitorial SF bonds.
(3) Total six atoms are in the same plane.
(4) Equitorial SF plane is perpendicular to nodal plane of bond.
[X]
Minimum repulstion is present when H atoms are present in the same plane with and S F
bonds.
NA
Q No: 17
Which of the following statements are not correct?
(1) All CO bonds in CO32 are equal but not in H2CO3.
(2) All CO bonds in HCO2 are equal but not in HCO2H.
(3) CO bond length in HCO2 is longer than CO bond length in CO32.
(4) CO bond length in HCO2 and CO bond length in CO32 are equal.
[X]
Q No: 18
Which of the following have identical bond order?
(1) O22+
(2) NO+
(3) CN
(4) CN+
[X]
M.O.T.
O2+2 NO+ CN are isoelectronic species.
Bond order
O2+2, NO+, CN is 3 and CN+ is 2.
Q No: 19
Which of the following statement is/are correct ?
(1) The peroxide ion has a bond order of 1 while the oxygen molecule has a bond order
of 2
(2) The peroxide ion has a weaker bond than the dioxygen molecule
(3) The peroxide ion as well as the dioxygen molecules are paramagnetic
(4) The bond length of the peroxide ion is greater than that of the dioxygen molecule
[X]
Paramagnetic species unpaired electron should be present.

O22 is diamagnetic. O2 is paramagnetic
Q No: 20
The structure of XeF6 is :
(1) pentagonal bipyramidal
(2) distorted octahedral
(3) capped octahedral
(4) square pyramidal
[X]
NA
Lone pair is stereochemically active therefore it is observed capped octahedral.
Level 3
Q No: 1
Among the following, the correct statement is :
(1) Between NH3 and PH3, NH3 is a better electron donor because
electrons occupies spherical 's' orbital and is less directional
(2) Between NH3 and PH3, PH3 is a better electron donor because
electrons occupies sp3 orbital and is more directional
(3) Between NH3 and PH3, NH3 is a better electron donor because
electrons occupies sp3 orbital and is more directional
(4) Between NH3 and PH3, PH3 is a better electron donor because
electrons occupies spherical 's' orbital and is less directional
the lone pair of

the lone pair of
the lone pair of
the lone pair of
[X]
H3 > PH3 = Electron donating nature
H3 is sp3 hybridized which is more directional but PH3 not show hybridization so lone pair
will be nondirectional
NA
Q No: 2
Comment on the CNC and HNN in CH3NCS and HN3 respectively.

(1) less than 120 and less than 120
(2) Greater than 120 and less than 120
(3) less than 120 and greater than 120
(4) Greater than 120 and greater than 120
In CH3NCS bond angle CNC will be greater than 120 due to steric repultion of CH 3 and in
N3H bond angle HNN will be less than 120
CH3NCS has steric repultion and N3H has only lone pair and bond pair repultion
NA
Q No: 3
Which of the following do not exists ?
(1) SH6
(2) HFO4
(3) FeI3
(4) HClO3
SH6,
HFO4
and
FeI3
donot
exist.
H is less electronegative so cannot excite electron in sulphur upto 2nd excitation state.
F is most electronegative and doesnot have vacant orbital in its outermost orbit so F
doesnot
form
stable
oxy-acids.
Fe3+ is powerful oxidising agent and I is powerful reducing agent, so donot co-exist
hence, FeI3 does not exist.
NA
NA
Q No: 4
Given the species : N2, CO, CN and NO+. Which of the following statements are true for
these
(1) All species are paramagnetic
(2) The species are isoelectronic
(3) All the species have dipole moment
(4) All the species are linear
NA
NA
(2) and (4) options are correct.
Q No: 5
Oxidation state of 'S' in peroxodisulphuric acid and sodium tetrathionate
(1) +6, +5, 0
(2) +6, +6, +6
(3) +6, +4, +2
(4) +6, +2, +0
formula of peroxodisulphuric acid = H2S2O8

sodium tetrthionate = Na2S4O8
Count the oxidation state of S

+6, + 5 and O
Q No: 6
In which of following cases CC bond length will be highest.
(1) CH3 CF3
(2) FCH2 CH2F
(3) F2CH CHF2
(4) CF3 CF3
[X]
Apply bent rule
F CH2 CH2F
FC bond has low s% character so CC bond has high s% character So CC bond length will
be lowest.
NA
No: 7
Statement-1 : The direction of dipole moment in CO is from 'O' to 'C'.
Statement-2 : The contribution of co-ordinated bond is more compared to
electronegativity factor in the overall polarity of the molecule.
statement-1.
[X]
The direction of covalent bond moment is from carbon to oxygen and the direction of dative
bond moment is from O to C.
NA
NA
Q No: 8
The bond energy order of He2+ and HeH+ is
(1) He2+ > HeH+
(2) HeH+ = He2+
(3) HeH+ > He2+
(4) Can't be predicted
[X]
Bond energy Bond order
Bond order of HeH+ = 0
He2+ = 0.5
Bond energy of He2+ > HeH+
Q No: 9
Which of the following are paramagnetic ?
(1) B2
(2) O2
(3) N2
(4) He2
[X]
In B2 and O2 there ore two unpaired electrons, so they are paramagnetic.
Only MOT explains that B2 and O2 are paramagnetic
Q No: 10
The correct order of decreasing X O X bond angle is (X = H, F or Cl) :
(1) H2O > Cl2O > F2O
(2) Cl2O > H2O > F2O
(3) F2O > Cl2O > H2O
(4) F2O > H2O > Cl2O
[X]
Cl2O > H2O > F2O = bond angle
According to electronegativity of side atoms
NA
Q No: 11
In the context of carbon, which of the following is arranged in the correct order of
electronegativity :
(1) sp > sp2 > sp3
(2) sp3 > sp2 > sp
(3) sp2 > sp > sp3
(4) sp3 > sp > sp2
[X]
Draw the all structur's
NA
Q No: 12
Arrange the following in order of decreasing N O bond length : NO+2, NO2, NO3
(1) NO3 > NO+2 > NO2
(2) NO3 > NO2 > NO+2
(3) NO+2 > NO3 > NO2
(4) NO2 > NO3 > NO+2
[X]
NO3 > NO2 > NO+2 draw the digram
1.33, 1.5 and 2
Q No: 13
Which of the following species contain coordinate bond :
(1) AlCl3
(2) CO
(3) [Fe(CN)6]4
(4) N3
Correct Answer: 2,3,4
Status: unattempted
[X]
[Fe(CN)6]4 is coordination compound.
NA
Q No: 14
Statement-1 : C3O2 has linear structure.
Statement-2 : Each C atom in C3O2 is sp-hybridised.
statement-1.
[X]
NA
C atom is sp hybridised.
Linear
Q No: 15
Statement-1 : The species [I(CN)2] is overall linear.
Statement-2 : I-atom and C-atoms are 'sp' hybridised.
statement-1.
[X]
All the atoms are present in smae planes.

Hybridization is sp3d.

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Level 1

Count the bonds (12) P O, (4) P = O

AgBr has maximum vander-waals force

Molecular shapes of SF4, CF4 and XeF4 are :

(BN)x has graphite like structure.

Dipole induced dipole interaction

(4) Statement-1 is false, statement-2 is true.

C C bond order in C2H6 compound is (minimum) = 1 so its bond length is maximum in

All have fractional bond order.

All the bond pair are present in a same plane.

Statement-2 : H-bonding does not occur in H2S due to low electronegativity of S.

E.N. of central atom increases bond angle increases.

Hybridisation of P in PCl3 and PCl5 is sp3 and sp3d respectively.

Cl2 has higher bond energy than F2.

Boiling point order :

(1) A has polar covalent linkage

Statement-1 : PCl3 on hydrolysis gives

Paramagnetic species unpaired electron should be present.

the lone pair of

Comment on the CNC and HNN in CH3NCS and HN3 respectively.

formula of peroxodisulphuric acid = H2S2O8

Count the oxidation state of S

All the atoms are present in smae planes.

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