Product Name: Infineum D3426

Revision Date: 04May2005

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MATERIAL SAFETY DATA SHEET

SECTION 1

PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name:
Infineum D3426
Product Description:
Petroleum Product Additive
Product Code:
34717100
Intended Use:
Lubricating oil additive
COMPANY IDENTIFICATION
Supplier:

INFINEUM AUSTRALIA PTY. LTD

Level 2
6 Riverside Quay
Southbank, Vic
MELBOURNE3006 Australia

24 Hour Environmental / Health Emergency

Telephone
Supplier General Contact

SECTION 2

1800 023 005 (within Australia) / 0800 222 002 (within NZ) /
65-6867-1939 (regional)
1-800-815-297

COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)

Name

Concentration*

Symbols/Risk Phrases

ZINC ALKYL DITHIOPHOSPHATE

5-9.9%

Xi;R38, Xi;R41

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Other
ingredients determined not to be hazardous up to 100%.
SECTION 3

HAZARDS IDENTIFICATION

This material is dangerous according to regulatory guidelines (see (M)SDS Section 15).
CLASSIFICATION: |

Xi; R36 |

PHYSICAL / CHEMICAL HAZARDS

Thermal burn hazard - contact with hot material may cause thermal burns.
HEALTH HAZARDS
Irritating to eyes. Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. May
be irritating to the eyes, nose, throat, and lungs.
ENVIRONMENTAL HAZARDS
Harmful to aquatic organisms, may cause long -term adverse effects in the aquatic environment.

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Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice.
Health studies have shown that chemical exposure may cause potential human health risks which may vary from person
to person.

SECTION 4

FIRST AID MEASURES

INHALATION
Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance,
avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if
available. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth
resuscitation.
Skin Contact
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before
reuse. For hot product: Immediately immerse in or flush affected area with large amounts of cold water to
dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance.
Ingestion
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5

FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams,
sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces,
self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect
personnel.
Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in
Section 8.
Hazardous Combustion Products: Smoke, Fume, Carbon Monoxide, Sulphur Oxides, Nitrogen Oxides,
Carbon Dioxide
FLAMMABILITY PROPERTIES
Flash Point [Method]: >110C (230F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: N/D

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Autoignition Temperature: N/A

SECTION 6

ACCIDENTAL RELEASE MEASURES

Notification Procedures
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required,
due to toxicity or flammability of the material. See Section 3 for Significant Hazards. See Section 5 for fire fighting
information. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment.
SPILL MANAGEMENT
Land Spill:
Water Spill: Confine the spill immediately with booms. Stop leak if you can do so without risk. Warn other
shipping. Seek the advice of a specialist before using dispersants. Report spills as required to appropriate
authorities. Remove from the surface by skimming or with suitable absorbents.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however,
geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed
may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note:
Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7

HANDLING AND STORAGE

HANDLING
Product should be stored at recommended temperatures to avoid degradation of product quality and
decomposition. Caution must be exercised when heating this product. If heated, product temperature should be
constantly monitored and product should be agitated to avoid localised high temperatures. If product cannot be
agitated, use electrical or steam heating systems with self limiting maximum temperature not exceeding 120 C
(e.g.: low pressure steam at 2 bar(g) / 30 psig) for blend containing ZDDP, or tempered water at maximum 60 C
for pure or concentrated ZDDP. Extreme caution must be used in tank gauging or similar operations as
overheating could lead to accumulation of lethal concentrations of hydrogen sulfide in the head-space of
containers. Avoid contact with eyes. Avoid contact with skin. Warning: If this material is overheated, especially in
the presence of water, hydrogen sulphide may be released; this can cause rapid respiratory collapse, coma and
death without necessarily any warning odour being sensed. Prevent small spills and leakage to avoid slip hazard.
Loading/Unloading Temperature: 60C (140F) - 70C (158F)
Transport Temperature: < 70C (158F)
Transport Pressure: [Ambient]
Static Accumulator: This material is not a static accumulator.

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STORAGE
Do not store in open or unlabelled containers.
Storage Temperature: < 60C (140F)
Suitable Containers/Packing: Tankers; Tank Trucks; Drums; Bulk Containers
Suitable Materials and Coatings: Carbon steel; Stainless steel; Inorganic Zinc Coatings; Epoxies
Unsuitable Containers/Packing: Natural rubber
Unsuitable Materials and Coatings: Natural rubber; Butadiene rubber; Polyethylene; Styrene Rubber; Butyl
rubber
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

Exposure limits/standards
Substance Name
Hydrogen Sulphide
Hydrogen Sulphide

Form
N/A
N/A

Limit/Standard
STEL
15 ppm
TWA
10 ppm

Note

Source
ACGIH
ACGIH

Exposure limits/standards for materials that can be formed when handling this product:
can occur, the following are recommended: 5 mg/m - ACGIH TLV, 10 mg/m - ACGIH STEL.

Year
2003
2003

When mists / aerosols

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level
which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use,
and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be
considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
Particulate,Type B filter material.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour
warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:

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If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet-style gloves. Thermally protective, chemical resistant gloves are
recommended. If contact with forearms is likely, wear gauntlet-style gloves. Nitrile,Polyvinyl Chloride
(PVC)
Eye Protection: If contact with material may occur, safety glasses and face shield are recommended. Chemical
goggles are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Thermally
protective, chemical resistant apron and long sleeves are recommended when volume of hot material is
significant.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.
GENERAL INFORMATION
Physical State: Liquid
Colour: brown
Odour: mild petroleum/solvent
Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15.6 C):
Density (at 15 C): 947 kg/m (7.9 lbs/gal, 1.06 kg/dm)
Flash Point [Method]: >110C (230F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: N/D
Autoignition Temperature: N/A
Boiling Point / Range: N/A
Vapour Density (Air = 1): N/D
Vapour Pressure: N/D
Evaporation Rate (N-Butyl Acetate = 1): N/A
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/D
Solubility in Water: Slight
Viscosity: 4112 cSt (4112 mm/sec) at 40C [Typical] | 191 cSt (191 mm/sec) at 100C
Oxidising properties: See Sections 3, 15, 16.

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OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/D
Coefficient of Thermal Expansion: 0.0007 V/V/DEG C
SECTION 10

STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. Elevated temperatures.
MATERIALS TO AVOID: Strong oxidisers, Water
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Sulphide
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11

TOXICOLOGICAL INFORMATION

Acute Toxicity
Route of Exposure
INHALATION
Toxicity: LC50 > 5 mg/l
Irritation: No end point data.

Conclusion / Remarks
Minimally Toxic.
Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs.

Ingestion
Toxicity: LD50 > 2000 mg/kg

Minimally Toxic.

Skin
Toxicity: LD50 > 2000 mg/kg
Irritation: No end point data.

Minimally Toxic.
Mildly irritating to skin with prolonged exposure.

Eye
Irritation: No end point data.

Irritating and will injure eye tissue.

Warning: If this material is overheated, especially in the presence of water, hydrogen sulphide may be released; this can
cause rapid respiratory collapse, coma and death without necessarily any warning odour being sensed.

Additional information is available by request.

IARC Classification:
The Following Ingredients are Cited on the Lists Below: None.

1 = IARC 1

--REGULATORY LISTS SEARCHED-2 = IARC 2A

3 = IARC 2B

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Revision Date: 04May2005
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SECTION 12

ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
MOBILITY
Base oil component -- Expected to partition to sediment and wastewater solids. Low solubility and floats and is
expected to migrate from water to the land.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
A component -- Expected to be inherently biodegradable

SECTION 13

DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws
and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
Empty Container Warning (where applicable): Empty containers may retain residue and can be dangerous. DO NOT
PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY
OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be
completely drained, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of
in an environmentally safe manner and in accordance with governmental regulations.
SECTION 14

TRANSPORT INFORMATION

LAND : Not Regulated for Land Transport

SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport

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SECTION 15

REGULATORY INFORMATION

***AP_DANGEROUS - Material is dangerous as defined by the EU Dangerous Substances/Preparations Directives.***

CLASSIFICATION: Irritant.
EU LABELING
Symbol: Xi

Irritant.
Nature of Special Risk:

R36; Irritating to eyes.

Safety Advice: S25; Avoid contact with eyes. S26; In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice. S61; Avoid release to the environment. Refer to special instructions/safety data sheets.
Contains: ZINC ALKYL DITHIOPHOSPHATE
NATIONAL CHEMICAL INVENTORY LISTING: AICS, IECSC, DSL, EINECS, ELINCS, ENCS, KECI, PICCS,
TSCA
SECTION 16

OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
R36; Irritating to eyes.
R38; Irritating to skin.
R41; Risk of serious damage to eyes.
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
No revision information is available.
----------------------------------------------------------------------------------------------------------------------------------------------------The information contained in this document is based upon data believed to be reliable at the time of going to press and
relates only to the matters specifically mentioned in this document. Although Infineum has used reasonable skill and care
in the preparation of this information, in the absence of any overriding obligations arising under a specific contract, no
representation, warranty (express or implied), or guarantee is made as to the suitability, accuracy, reliability or
completeness of the information; nothing in this document shall reduce the user's responsibility to satisfy itself as to the
suitability, accuracy, reliability, and completeness of such information for its particular use; there is no warranty against
intellectual property infringement; and Infineum shall not be liable for any loss, damage or injury that may occur from the
use of this information other than death or personal injury caused by its negligence. No statement shall be construed as an
endorsement of any product or process. For greater certainty, before use of information contained in this document,
particularly if the product is used for a purpose or under conditions which are abnormal or not reasonably foreseeable, this
information must be reviewed with the supplier of such information.
----------------------------------------------------------------------------------------------------------------------------------------------------DGN: 6028911 (1008861) (AP Core)

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Revision Date: 04May2005
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