Beruflich Dokumente
Kultur Dokumente
Which would undergo SN2 reaction faster in the following pair and why ?
1.
CH3
|
CH3 CH2 Br and CH3 C CH3
|
Br
Out of BaCl2 and KCl, which one is more effective in causing coagulation of a
5.
6.
(i)
(ii)
7.
?
C6H5 CH2 CH3 C6H5 COOK+
What is meant by positive deviations from Raoults law ? Give an example. What is
the sign of mixH for positive deviation ?
OR
What are the transition elements ? Write two characteristics of the transition elements.
Write the names and structures of the monomers of the following polymers :
(i) Nylon-6, 6
(ii) PHBV
(iii) Neoprene
10
(a)
E = +0.80 V
1
H+(aq) + e H2(g)
2
E = 0.00 V
On the basis of their standard reduction electrode potential (E) values, which
reaction is feasible at the cathode and why ?
(b)
11.
(ii)
11.
(i)
(ii)
On the basis of crystal field theory, write the electronic configuration for d4 ion
if o < P.
(iii) Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].
(At.no. of Ni = 28)
13.
14.
(i)
(ii)
NaOH / CaO
(iii) CH3 COONa ?
16.
Phenol to anisole
(ii)
Propan-2-ol to 2-methylpropan-2-ol
OR\
(a)
(b)
17.
(i)
(ii)
(iii) Write the name of vitamin whose deficiency causes bone deformities in children.
18.
Give reasons :
(a)
(b)
(c)
19. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point
of 1.62 K. Calculate the vant Hoff factor and predict the nature of solute (associated
or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol1, Kf for benzene = 4.9 K kg mol1)
20.
(i)
Indicate the principle behind the method used for the refining of zinc.
(ii)
(iii) Which form of the iron is the purest form of commercial iron ?
21.
22.
An element with molar mass 27 g mol1 forms a cubic unit cell with edge length
4.05 108 cm. If its density is 2.7 g cm3, what is the nature of the cubic unit cell ?
(a) How would you account for the following :
(a)
(b)
(i)
(ii)
Mr. Roy, the principal of one reputed school organized a seminar in which he invited
parents and principals to discuss the serious issue of diabetes and depression in
students. They all resolved this issue by strictly banning the junk food in schools and
to introduce healthy snacks and drinks like soup, lassi, milk etc. in school canteens.
They also decided to make compulsory half an hour physical activities for the students
in the morning assembly daily. After six months, Mr. Roy conducted the health survey
in most of the schools and discovered a tremendous improvement in the health of
students.
After reading the above passage, answer the following :
(i) What are the values (at least two) displayed by Mr. Roy ?
(ii) As a student, how can you spread awareness about this issue ?
(iii) What are tranquilizers ? Give an example.
(iv) Why is use of aspartame limited to cold foods and drinks ?
24.
OR
(a)
Write the structures of main products when aniline reacts with the following
reagents :
(i)
Br2 water
(ii)
HCl
(c)
25.
For the hydrolysis of methyl acetate in aqueous solution, the following results were
obtained :
t/s
[CH3COOCH3]/mol L1
(i)
30
60
0.60
0.30
0.15
Show that it follows pseudo first order reaction, as the concentration of water
remains constant.
(ii)
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(Given log 2 = 0.3010, log 4 = 0.6021)
OR
(a)
(b)
(i)
(ii)
A first order reaction takes 30 minutes for 50% completion. Calculate the time
required for 90% completion of this reaction.
(log 2 = 0.3010)
26.
(a)
(ii)
There is large difference between the melting and boiling points of oxygen
and sulphur.
Cl F3
(ii)
XeF4
OR
(i)
(ii)
How the supersonic jet aeroplanes are responsible for the depletion of ozone
layers ?