CHE 161 // FOS ) EXAL CHE 161 - EXAM I COVER SHEET INSTRUCTOR: Dr. Colleen Craig October 3, 2008 1:00 pm ~ 2:20 pm SAM 400 YOUR NAME: _ 1a € YOUR FAVORITE BAND: wt VCE There are in this exam, including this cover sheet. MAKE SURE TO TURN IN 41.) 246 NO GRAPHING/TEXT-ENTRY CALCULATORS ALLOWED. ONLY CALCULATORS MAY BE USED AS CALCULATORS (NO CELL PHONES!) NO HEADPHONES ALLOWED (KARPLUGS ARE OK). NO HATS WITH BRIMS ALLOWED. THIS EXAM IS WORTH 100 PO! YOU HAV eVENTY-FIVE MINUTES. Good luck!! ® CF. Craig Page 1CHE 161 // FOS / EXAM 1 Version 1 MULTIPLE CHOICE - 22 @ 3 POINTS EACH --> 66 POINTS TOTAL CHOOSE ONE ANSWER ONLY. L. The beakers shown below have different precisions as shown. aaa 26.6 Ks | 24 Suppose you pour the water from these three beakers into one container. What would be the volume in the container reported to the correct number of significant figures? 78.82 mL. 9 mb. ) 90. mL, D) 78.817 mL. E) 78.8 mL, 2. An example of a pure substance is, A) compounds. B) carbon dioxide, ©) elements. D) pure water. © Morthese 3. The average mass of a carbon atom is 12.011. Assuming you were able to pick up only the chances that you would randomly get one with a mass of 12.011 is greater than 50%, D) 0.011%. 12.01%, CE. Craig Page 2CHE 161 // FO8 EXAM 1 Version 1 4. Consider the following reaction: CH,(g)+4Ch(g) > CCL(g) + 4HCI(g) What mass of CCI; is formed by the reaction of 8.96 g of methane (CH,) with an excess of chlorine? 85.9 g ) 1.383 g © 215g D) 0.938 E) none of these 5. What is the total number of fons in one formula unit of Cax(PO,)2? A) 2 3B) 5 D) 8 BE) 13 6. An unknown substance dissolves readily in water but not in benzene (a nonpolar solvent). Molecules of what type are present in the substance’ A) either polar or nonpolar B) nonpolar g polar neither polar nor nonpolar E) none of these ‘The boiling of water is a Datos change because the gaseous water is chemically the same as the liquid, chemical change because a gas (steam) is given off. ©) physical change because the water merely’ disappears. D) chemical and physical damage. E) chemical change because heat is needed for the process to occur. CR. Craig Page 3CHE 161 // FOS // EXAMI Version | 8. ‘The following reactions 2K(S) + Bro(l) > 2KBr(s) AgNOx(aq) + NaCl(aq) > AgCl(s) + NaNOs(aq) HCl(aq) + KOH(aq) > H20(1) + KCl(aq) are examples of A)_ precipitation (two) and acid-base reactions, respectively B)_ precipitation reactions. redox reactions, ® redox, precipitation, and acid-base, respectively. ) none of these 9. A 12.4-g sample of HF is dissolved in water to give 0.200 L of solution. The concentration of the solution is 3.1M ) 0.06 M ©) 62M D) 0.12M E) 0.62M 10, How many significant figures are there in the number 0,04560700? Ayo B) 8 os D) 4 ©? 11. A sample of ammonia has a mass of 72.8 g. How many molecules are in this sample? 2.57e24 molecules 1.41e23 molecules C) 17.0e24 molecules D) 4.38e25 molecules E) 4.27 molecules 12. Convert 0.8140 m to mm. A) 0.08140 mm BD s14.0 mm ©) 8.140e-3 mm D) 8.140e—4 mm E) none of these CF.Craig PageCHE 161 //FO8 // EXAMI Version 1 13. A chemical reaction has the equation: 2A + B-sC. In which case is B the limiting reactant? @o 6 o eal oo ® ,e2@ e® 8 A) Ill 1 Cc) IV D) I E) None of these 14, Which one of the following statements about atomic structure is false? The protons and neutrons in the nucleus are very tightly packed. @ The number of protons and neutrons is alway’ the same in the neutral atom. Almost all of the mass of the atom is concentrated in the nucleus. D) The electrons occupy a very large volume compared to the nucleus. E) All of the above statements (a-d) are true. 15. Which of the following has 61 neutrons, 47 protons, and 46 electrons? A ) 108 4. 47 B) 108 ) Par 16. Express 0.00560 in exponential notation, A) 5.60 B) 5.60 10° ©) 5.6*« 10° @ 5.60 x 10° ) none of these CF. Craig Page 5CHE 161 //FO8 // EXAMI. Version | 17. A piece of indium with a mass of 16.56 g is submerged in 46.3 cm’ of water ina graduated cylinder. The water level increases to 48.6 cm’. The correct value for the density of indium from these data is: A) more than 0.1 g/cm’ away from any of these values. B) 0.139 g/cm? C) 7.200 gem D) 0.14 gem? © 7.2 gicm*® 18, What is the coefficient for oxygen when the following equation is balanced? NEa(g) + O2(2) > NOx) + H20(g) A) 12 B) 3 Qu 2% Use the following to answer questions 19-22: a ecesrats » 9 re oO «0 | eos eee Ce) ates oO ° ie oO onmaec Tanane oomdes 2525 © @m@oomo@eo] [no ooo © 19, Which best represents a gaseous compound? 20. Which best represents a solid element? “F, 21, Which best represents a heterogeneous mixture of two elements? “| ) Which best represents a homogeneous mixture of an element and a compound? E CE. Craig Page 6cue ratrorvexan vesint $ Uersuoy 2. NOMENCLATURE - 6 @ 2 POINTS EACH -> 12 POINTS ‘Name the following compounds: 23. CCl, par bore he va @lilon oe 24, MnSOs Whew vr £ $2, Ghugs L le 25. HNOs niMic G4 A Write the formula for: 26. dinitrogen trioxide N 2 Dz 27. iron (III) oxide See Oe 28. hydrosulfuuric acid Ut ¢ eee CE.Craig_ Page 7‘CHE 161 // FOS !/ EXAM | vesion Version. 2. LONG ANSWER - 22 POINTS TOTAL, YOU MUST SHOW ALL YOUR WORK TO EARN PARTIAL CREDIT!! 29. (12 pts) Suppose the rset Ca PO €GULSO, > 3CaSO, + 2HsPO, is carried out starting with 103 g of Cas(PO3);-and 67.0 g of HSO,. How much phosphoric acid will be produced? 4, greens, MM(Cax(PO4)2) = 310.18 g/mol; MM(H2SO,) = 98.09 g/mol MM(CaSO,) = 136.15 g/mol; MM(HsPOy) = 97.99 g/mol 2 nul bs (Foy), = (09a, #04), or 26. 3320 7 nak SIONS Park HySoy = Grog re ewe - 6. bF50F nol. ‘a O1g. - eae pole US me Howe wean y be c Oe st needled breach wa & Luk Hy S0y= 0.320% Ble a Sal 80 Te 320 ae 04. ‘Gretiadap = 22 Hae - Need ie nok u,5¢ 6.6 305 nk 69962uwL => H, S05 6 H428 by Hee ip isles sdubeomts femenia a5 42) z roy i 244.6214 ish CP. Craig Page 8CHE 161/FOB,/EXAMA Version “$f VES OVE 2. 30. (10 pts) It is estimated that uranium is relatively common in the earth's crust, occurring in amounts of 4 g / metric ton of crust. A metric ton is 1000 kg. At this concentration, \what mass in ng (nanograms) of uranium is present in 1.9 mg of the earths crust? (10% g=lng) a ws 2nq= | tengo (Lge Leg Cs Oy | mebictin” \ - Tebag neh 1006 4 Gase cae a | uw Heth yng x 6 a We 10 'g-th ) > Bnqu in 14a oe a arth’ Ense Ce CH. Craig Page 9