Beruflich Dokumente
Kultur Dokumente
Division of Materials Science and Engineering, Engineering Research Center, Gyeongsang National University,
900 Gazwa-dong, Chinju 660-701, Republic of Korea
Department of Metallurgical Engineering, Changwon National University, Changwon 641-773, Republic of Korea
Received 12 October 2004; received in revised form 18 January 2005; accepted 18 January 2005
Abstract
Despite the significant use in the industry, the effect of Mn on the tensile and corrosion behavior of cast duplex stainless steels has not
been well established. In the present study, the tensile and corrosion behavior of CD4MCU cast duplex stainless steels with different Mn
contents of 0, 0.8 and 2%, respectively, was therefore examined. The polarization and the in situ slow strain rate tests were conducted in
3.5% NaCl + 5% H2 SO4 aqueous solution to quantify the resistances to pitting corrosion and stress corrosion cracking with different Mn
contents. The addition of Mn, which stabilized ferrite in the present study, affected the microstructure of the present alloy, and eventually the
tensile and corrosion behaviors in a complex manner. Tensile properties of CD4MCU cast duplex stainless steel, for example, was found to be
determined by the volume fraction of hard ferritic phase and the shape of austenitic phase. The addition of 0.8% Mn was detrimental to both
pitting corrosion and stress corrosion cracking properties of CD4MCU cast duplex stainless steel due to the significant increase in contact
area between the less-noble ferritic and the noble austenitic phases. With the addition of 2% Mn, the resistance to pitting corrosion and stress
corrosion cracking in 3.5% NaCl + 5% H2 SO4 aqueous solution is recovered. The resistance to stress corrosion cracking of the specimen with
2% Mn was still greatly inferior to that of the 0% Mn counterpart. The relationship between the microstructural evolution and the tensile
and corrosion behavior of CD4MCU cast duplex stainless steels with different Mn contents was discussed based on the micrographic and
fractographic observations.
2005 Elsevier B.V. All rights reserved.
Keywords: Mn; Tensile behavior; Corrosion behavior; CD4MCU cast duplex stainless steels
1. Introduction
The industrial use of duplex stainless steel is rapidly increasing due to the combined advantages of better mechanical and corrosion properties [15]. Since the development
of first-generation duplex stainless steels in 1930s, considerable research efforts have been conducted to improve both
mechanical and corrosion properties, particularly by controlling alloying elements, such as N, Cr, W and Mo [3,616].
Charles, for example, reported that the addition of Cr and/or
Mo improved the resistance to pitting corrosion and stress
corrosion cracking of duplex stainless steels [4]. He fur
Corresponding author. Tel.: +82 55 751 5309; fax: +82 55 759 1745.
E-mail address: sang@gsnu.ac.kr (S.S. Kim).
0921-5093/$ see front matter 2005 Elsevier B.V. All rights reserved.
doi:10.1016/j.msea.2005.01.046
Y.H. Jang et al. / Materials Science and Engineering A 396 (2005) 302310
2. Experimental procedures
In the present study, CD4MCU cast duplex stainless steels
with different Mn contents of 0, 0.8 and 2%, respectively,
were used. Table 1 represents the measured chemical
compositions of the alloys used in the present study. The
alloys were designated as CD4MCUMn0, CD4MCUMn1
303
Table 1
Chemical compositions of CD4MCU cast duplex stainless steels in wt.%
Specimen
Si
Mn
Ni
Cr
Mo
Cu
Fe
CD4MCUMn0
CD4MCUMn1
CD4MCUMn2
0.04
0.03
0.04
0.86
0.75
0.86
0.0
0.8
2.0
0.027
0.029
0.027
0.006
0.004
0.006
5.32
5.36
5.32
25.19
25.37
25.19
1.84
1.99
1.84
2.8
2.8
2.8
0.13
0.13
0.13
Balance
Balance
Balance
Fig. 1. Typical optical micrographs of CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively.
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Fig. 2. SEM micrographs of CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively, showing the second
precipitates of fine austenitic phase.
3. Experimental results
Fig. 1 represents the typical optical micrographs of
CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively. This figure demonstrates that the microstructure of CD4MCU cast
duplex stainless steel varied significantly with different Mn
contents. In CD4MCUMn0 alloy, for example, the colonies
of austenitic phase with the volume fraction of 44% and
the diameter ranging from 80 to 200 m were observed.
With increasing Mn content to 0.8%, the volume fraction of
austenitic phase was reduced to 40%. The shape of austenitic
phase became a needle-shape with the Mn addition of 0.8%.
With the addition of Mn up to 2%, the volume fraction of
austenitic phase was further reduced to 35%, and the size
of austenitic phase became slightly larger than that of the
0.8% Mn added counterpart. The aspect ratio of austenitic
phase in CD4MCUMn2 was noted to become slightly larger
compared to that in CD4MCUMn1 alloy. Regardless of Mn
content, a substantial amount of the second precipitates of
fine austenitic phase were observed in the ferritic matrix.
Fig. 2 shows the SEM micrographs of CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b)
0.8% and (c) 2%, respectively, showing the second precipitates of fine austenitic phase. It was shown that the shape and
the size of these precipitates were substantially different in
CD4MCUMn1 from those observed in the other two alloys.
Most of these precipitates in CD4MCUMn1 alloy were, for
example, needle-shaped, while they were fine globular shape
in the other two alloys.
Fig. 3 shows the effect of Mn content on the tensile property of CD4MCU cast duplex stainless steels. Each data point
represents the average of at least five test results. This figure shows that the yield strength of CD4MCU cast duplex
stainless steel tended to increase slightly with increasing Mn
content from 0 to 2%. The ultimate tensile strength, on the
other hand, decreased from 777 to 753 MPa with increasing
Mo content from 0 to 0.8%, while it increased to 768 MPa
with the addition of 2% Mn. The tensile elongation decreased
from 33.0 to 19.8% with increasing Mn content from 0 to
0.8%. With the addition of 2% Mn, the tensile elongation became greatly improved to the level of CD4MCUMn1. Fig. 4
represents the typical SEM fractographs of tensile-tested
CD4MCU cast duplex stainless steels with different Mn con-
Y.H. Jang et al. / Materials Science and Engineering A 396 (2005) 302310
305
Fig. 4. SEM fractographs of tensile-tested CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively.
tents of (a) 0%, (b) 0.8% and (c) 2%, respectively. Depending
on the Mn content, the tensile fracture mode of CD4MCU alloy showed a subtle difference. In CD4MCUMn0 alloy, for
example, relatively large dimples with an average diameter
of 18 m were observed with throughout the matrix. The
specimens with 0.8 and 2% Mn, on the other hand, showed
a bimodal distribution of 3.7 m diameter fine and 19 m
diameter large dimples, while the overall size of dimples
in CD4MCUMn2 alloy appeared to be approximately 1 m
larger than that in CD4MCUMn1 alloy.
In order to understand the effect of Mn addition on the
corrosion behavior of CD4MCU alloy, the polarization tests
were conducted in 3.5% NaCl + 5% H2 SO4 aqueous solution. Fig. 5 shows the representative polarization curves
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Fig. 6. SEM micrographic observations of the corroded surfaces of CD4MCU alloys with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively,
after polarization test in 3.5% NaCl + 5% H2 SO4 .
less steel was significantly altered with exposure to the aggressive environment. It was noted that the tensile fracture
mode of CD4MCIMn0 was almost unaffected with exposure to 3.5% NaCl + 5% H2 SO4 aqueous solution at an anodically applied potential of 1100 mV versus Ag/AgCl. In
CD4MCUMn1 alloy, on the other hand, the dimpled rupture mode in air changed to the quasi-cleavage mode in an
SCC-causing environment. CD4MCUMn2 alloy also showed
a substantial portion of cleavage mode along with the dimpled rupture mode. Fig. 10 represents the SEM micrographs
of the surface area of SSRTed CD4MCU alloys with differ-
Fig. 8. Percent change in tensile elongation of CD4MCU cast duplex stainless steels with different Mn contents.
Y.H. Jang et al. / Materials Science and Engineering A 396 (2005) 302310
307
Fig. 9. SEM fractographs of CD4MCU alloys with different Mn contents of (a) 1%, (b) 0.8% and (c) 2%, respectively, after slow strain rate tests in 3.5%
NaCl + 5% H2 SO4 .
ent Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively, in 3.5% NaCl + 5% H2 SO4 aqueous solution, documented in the vicinity of fracture location. This figure shows
that the crack morphology of SSRTed specimens in 3.5%
NaCl + 5% H2 SO4 was quite different with each other depending on the Mn contents. In CD4MCUMn1 alloy, for example, relatively well-developed sharp cracks were observed
throughout the surface with the long axis perpendicular to
Fig. 10. SEM micrographs of surface areas of CD4MCU alloys with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively, close to the fractured
surfaces documented after slow strain rate test in 3.5% NaCl + 5% H2 SO4 .
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Fig. 11. SEM cross-sectional micrographs of CD4MCU cast duplex stainless steels with different Mn contents of (a) 0%, (b) 0.8% and (c) 2%, respectively,
after slow strain rate test in 3.5% NaCl + 5% H2 SO4 .
4. Discussion
In the present study, a notable microstructural evolution in
CD4MCU cast duplex stainless steel was observed with different Mn contents, including the volume fraction, the size
and the shape of austenitic phase. There is a controversy on
which phase Mn stabilizes [19,20]. The present study suggests that Mn is a ferrite stabilizing element in CD4MCU
cast duplex stainless steel, since the volume fraction of ferritic phase increased from 56 to 65% with increasing Mn content from 0 to 2%. The size and shape of austenitic phase also
varied with different Mn contents, as shown in Fig. 1. With
increasing Mn content from 0 to 0.8%, the size of austenitic
phase was substantially reduced giving a needle-shaped appearance. With the addition of Mn up to 2%, the volume frac-
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309
5. Conclusions
The tensile and corrosion behaviors of CD4MCU cast duplex stainless steels with different Mn contents of 0, 0.8 and
2%, respectively, were examined, and the following conclusions are drawn.
(1) A substantial microstructural evolution in CD4MCU cast
duplex stainless steel was observed with different Mn
contents, including the volume fraction and the size and
shape of both primary and secondary austenitic phase.
(2) With increasing Mn contents from 0 to 2%, the improvement in YS and the UTS values was not significant. The
tensile elongation was, on the other hand, greatly impaired with the addition of 0.8% Mn. The trend observed
in the present study was believed to be due to the change
in shape of austenitic phase, the change in volume fraction of ferritic phase and the intrinsic hardening effect of
Mn solute.
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(3) The addition of 0.8% Mn to CD4MCU alloys greatly degraded the resistance to both pitting corrosion and stress
corrosion cracking in 3.5% NaCl + 5% H2 SO4 solution,
which appeared to be due to the increase in contact area
between the less-noble ferritic and the noble austenitic
phases as a result of the shape change in austenitic phase.
(4) Even though the SCC resistance of CD4MCU cast duplex stainless steel was improved with the addition of
2% Mn, as compared to that of CD4MCU1 alloy, it was
still greatly inferior to that of the 0% Mn counterpart.
The inferior resistance to SCC in CD4MCUMn2 alloy
was believed to be due to higher volume fraction of ferrite and higher contact area between noble ferritic phase
and less-noble austenitic phase compared to those of
CD4MCUMn0 alloy.
Acknowledgement
This work was supported by the Korea Research Foundation Grant (KRF-2003-042-D00201).
References
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[2] J.R. Davis (Ed.), ASM Specialty Handbook Stainless Steels, ASM
International, Materials Park, OH, 1996, p. 32.
[3] H.D. Solomon, T.M. Devine Jr., in: R.A. Lula (Ed.), Duplex Stainless
Steels, ASM, Metals Park, OH, 1983, p. 693.
[4] J. Charles, Proceedings of the Fourth International Conference on
Duplex Stainless Steels, vol. 1, Paper KI, Glasgow, Scotland, 1994.