Beruflich Dokumente
Kultur Dokumente
5R-92
Milton D. Anderson*
Roger W. Black
John P. Cook
Floyd E. Dimmick
Wolfgang D. Eisenhut
Jack J. Fontana*
Paul R. Hollenbach
Robert W. Gaul*
Subcommittee chairman
Mylcs A. Murray
Secretary
Richard Montani
Joseph M. Plecnik
Hamid Saadatmanesh
W. Glenn Smoak
Joe Solomon
Michael M. Sprinkel
Douglas G. Walters*
David P. Hu
T.Michael Jackson
Troy D. Madeley
Albert Mayer
Joseph A. McElroy*
Paul F. McHale
Peter Mendis*
This guide provides the engineer, contractor, and architect with a description of thevarious types of polymer adhesives (epoxy, polyester,
acrylic, plyurethane, polysulfide, silicone, vinyl acetate, and styrene
butadiene) most frequently used for adhesive bonding of fresh concrete to cured concrete, repair of cracks in concrete, bonding concrete to other materials, and adhesive grouting of bolts and other inserts into concrete.
The guide emphasizes the factors that should be considered where
selecting astructural adhesive, including characteristics during installation and in service.The benefits and limitations of adhesive bonding are discussed for each application.
3.1-Application characteristics
3.2-Properties of cured adhesive
3.3-Distinguishing characteristics
CONTENTS
Chapter 1 - General, pg. 503.5R-2
503.5R-1
503.5R-2
14
Chapter 11 - References, pg. 503.5R-15
11.1-Specified and/or recommended references
11.2-Cited references
11.3-Additional references
CHAPTER 1 - GENERAL
This guide is intended to aid the engineer, contractor, and architect in choosing a proper polymer adhesive for adhesive bonding applications encountered in
joining concrete members in construction, repair, and
rehabilitation of concrete structures.
1.1- Organization of the Guide
Sections 2 and 3 of the guide describe the properties
of the two major classes of polymer adhesives in use
(solvent-free adhesives and water-borne adhesives) and
identifies the distinguishing features of the specific polymers (e.g., epoxy, acrylic, and polyvinyl acetate)
within each class. Section 4 lists the basic criteria that
should be used in all adhesive selections. Sections 5
through 9 provide additional guidance specific to the
selection of adhesives for bonding fresh or hardened
concrete to hardened concrete, repairing cracked concrete, bonding other materials to concrete, and bonding inserts into concrete. Section 10 is a quick reference
guide to help narrow the search for a proper adhesive.
This guide includes more data and information on
epoxy adhesives than on other types because epoxy ad-
When using an adhesive, the manufacturers literature should always be reviewed. Manufacturers recommendations should be followed because the adhesive may differ from other adhesives in its class.
Many adhesives contain hazardous ingredients. Material Safety Data Sheets (MSDS) and labels should always be consulted before using the adhesive.
1.3 - Advantages/disadvantages of adhesive
bonding
The major advantage of adhesive bonding is that it
POLYMER ADHESIVES
503.5R-3
503.5R-4
Working life -The period of time which an adhesive, after mixing with a curing agent or other ingredient, remains sufficiently workable to permit spreading
and application.
CHAPTER 2 - SOLVENT-FREE ADHESIVES
503.5R-5
POLYMER ADHESIVES
psi
Epoxy
5000-9000
4000-13,000
Polyester
600-13,000
Polyurethane
percent
20-70
3-6
2-6
100-1000
psi
4000-14,000
15,000-25,000
13,000-30,000
20,000
NR
300-400
10-100
115-550
140-400
NR
45-65
55-100
100-200
Compressive modulus
10 psi
290-370
degF
165-209
Styrene-butadiene
175-10,000
at 73 F ASTM D 695
Heat deflection
temperature ASTM D 648
Coefficient
of thermal
expansion ASTM D 696
*From Reference 26.
NR: Not reported.
10 /in./in./deg C
48-80
300-800
67-140
503.5R-6
polymer adhesive formulation has a specific HDT. Frequently, manufacturers literature and technical references report physical properties at only one temperature. When this is so, it is important to know the HDT
to be able to anticipate if the physical properties at actual service temperatures will be substantially different
from those strengths reported in the published literature. Modulus of elasticity, adhesive strength, bond
strength, creep resistance, and chemical and radiation
resistance all begin to change at about 18 F (10 C) below the HDT and begin to fall off rapidly in a region
beginning about 18 F (10 C) above the HDT 16-18 (also
see Fig. 1). Heatdeflection temperature is determined
byASTM D 648.
2.3.7 Creep resistance - Polymer adhesives have a
much higher tendency to creep than inorganic materials
such as concrete. Sustained loads at temperatures more
than 18 F (10 C) above the HDT can result in creep to
failure.19 Creep resistance can always be improved by
reducing bond-line thickness, by increasing fiber content of the adhesive as supplied by the manufacturer, or
by adding aggregate in the field. The amount of aggregate that can be added is limited by the degree that
workability is reduced and/or air voids result from too
high an aggregate to adhesive ratio. Physical testing is
required to quantify the effect of filler addition for
each specific adhesive.
2.3.8 Coefficient of thermal expansion - Polymer
adhesives have coefficients of thermal expansion two to
ten times that of concrete (see Table 1). When the adhesive is confined in a narrow [ 1/8 in. (3.2 mm)] or less
bond line between two concrete elements or between
concrete and steel, this difference has not proven to be
a problem. However, when placed in thicker sections or
used to bond materials with a greater thermal expansion and contraction than that of concrete, the difference can cause failure in the concrete if the bonded elements are subjected to low temperatures (below 30 F).
Problems caused by the differences in thermal expansion of the adhesive and concrete can always be
lessened by reducing bond line thickness. Choosing an
adhesive with a lower modulus of elasticity also helps to
minimize stress caused by differences in thermal expansion but increases the danger of creep failure if the
bond line is subjected to sustained loads.
2.3.9 Fire resistance- Polymers are combustible, as
are most organic materials. Incorporation of special
fire-retardent additives and inorganic fillers allows the
formulation of adhesives with fire resistance acceptable
for some applications. The performance of a bonded
concrete structure or of an assembly of concrete adhesively bonded to other materials will depend on the insulation value and thermal conductivity of each of the
bonded materials, as well as the temperature level (see
Section 2.3.6), duration of exposure, and the magnitude and direction of stress on the bond line. An analysis should be performed to estimate the actual temperature that may be reached, and consideration should be
given to the possibility that some of the bonded material may be consumed or removed by the fire. Through
105
4
cn
UY
3
2a
B
lo4
lo3
-50
50
100
150
Temperature, deg C
Fig. 1 - Modulus of amine-cured epoxy (from Reference 38)
appropriate design, including plaster coating of the
concrete member to prevent burn out of the adhesive,
the fire resistance of adhesively bonded concrete structures can be maintained within desired levels. Test data
for a specific application and configuration should be
required when a fire rating is required. 20-21
2.3.10 Age hardening - Most polymer adhesives develop over 90 percent of their strength at normal ambient temperature, 68 to 100 F (20 to 38 C) within 7
days after placement. However, curing continues and
results in higher strength accompanied by higher modulus, or by hardening.22 Age hardening is undesirable
with flexible, low-modulus adhesives that are expected
to maintain their flexibility over a long period of time.
Adhesives are available for which long-term test data
are available. Accelerated aging data using elevated
temperature aging for several days is often used as an
indication of a susceptibility to aging. However, a precise correlation between long-term tests at the expected
service temperature and accelerated tests can be established only by conducting both tests.
2.3.11 Chemical resistance - The degree of chemical
resistance varies greatly, not only between polymer
groups, but also from formulation to formulation
within a polymer group; see Table 2 for comparison of
the polymer groups. Chemical resistance of an adhesive
in a bond line is often better than chemical resistance
tables would indicate because only a very small surface
area (the edges of the bond line) of the entire mass of
adhesive is exposed to the chemical environment.
2.3.12 Water resistance - Cured polymer adhesives
have generally good water resistance. As with chemical
resistance there can be a wide variation both between
polymer groups and within a polymer group for resistance to water. Relative water resistance can be meas-
POLYMER ADHESIVES
xy
65 C
Nonoxidizng acids
Oxidizing acids
Aqueous salt solution
Aqueous alkalies
Polar solvents
Nonpolar solvents
Water
Poly ester
25 c
65 C
S
U
s
S
Polyurethane
25 c
65 C
s
S
Styrenebuta iene
25 C
65 C
s
:
U
s
S
Silicone
65 C
25 C
Polyurethane
I
UTILITY
Incipient to Mild
Mild to Moderate
Often Satisfactory
Moderate to Severe
Not Recommended
I
Silicone Unfilled
Polyester Mineral Filled
Gamma dose Gy
Fig. 2 - Radiation resistance of polymer materials (from Reference 23)
ured by water absorption tests such as ASTM D 570.
However, water resistance in service also depends on
the degree of exposure of the adhesive to water, either
through the substrates or at the edge of the bond line
(Table 2 gives a comparison of polymer groups).
2.3.13 Radiation resistance - Polymer materials are
much more susceptible to radiation than inorganic materials such as concrete. Within a polymer type formulation, variations can greatly influence radiation resistance. See Fig. 2 for relative radiation resistance for
polymer type groups.23-26
2.4 - DISTINGUISHING CHARACTERISTICS
2.4.1 Epoxy adhesives - Epoxy adhesives are generally composed of an epoxy resin, an amine or polyamid
curing agent, reactive diluents and, in some cases, inorganic fillers and thixotroping agents. They are the
most commonly used polymeric adhesives.
Epoxy adhesives generally have excellent adhesion
because of relatively low curing shrinkage, with low
surface tension and molecular properties that enhance
their attraction to a wide variety of substrates. They are
503.5R-8
POLYMER ADHESIVES
Type II latex adhesives are usually made with nonionic surfactant systems such as alkyl phenols reacted
with various levels of ethylene oxide. Often, low levels
of anionic surfactants are incorporated to assist in polymerization or to result in specific latex properties.
This type of latex gives a dried film that is not redispersible. Polyacrylic esters and styrene-butadiene copolymers are included in this category.
3.1 - Application characteristics
3.1.1 Surface preparation - For both Type I and II
adhesives, the surface should be damp, but without any
standing water. This damp condition is conducive to
penetration by the polymer particles of the adhesives
into the hardened concrete.
3.1.2 Working life -Type I latex adhesives have
a virtually unlimited working life because of their
redispersible characteristic. The adhesive is usually applied by brush or roller, and the fresh, unhardened
concrete can be applied whether the latex is still wet or
has dried. In the latter occurrence, water from the
fresh, unhardened concrete causes redispersion of the
latex polymer. Although it is recommended that the
fresh, unhardened concrete be placed within 24 hr of
applying the latex, satisfactory bonds have been obtained when the fresh, unhardened concrete was placed
up to 7 days after latex application. Note that the dried
film of the Type I latex adhesive must be kept clean
from dust and other contaminants between the times of
film forming and the application of the fresh concrete.
Type II adhesives have a limited working life, the
length of which wiIl depend on the type of latex, the
type of hydraulic cement, and the environmental conditions. Typically, the working life of the slurry, in a
relatively closed container, will be from one to several
hours; however, in an open environment, drying can
occur quickly and shorten working life to less than 30
min. It is important that the fresh concrete be placed
while the latex-cement slurry is still wet. If the slurry
has dried, it may act as a bond breaker rather than an
adhesive.
3.1.3 Curing -Curing of Type I adhesives depends
on the cure of the fresh concrete because Type I adhesives cure by drying. The drying occurs as water is removed either by evaporation or by hydration of the cement in the fresh concrete.
Curing of Type II adhesives depends on the rate of
hydration of the cement in the slurry and also on evaporation of the water.
3.1.4 Methods of application - Type I and Type II
adhesives are usually applied by brush or roller, although other techniques such as spraying and troweling
have also been used. It is essential that the surface being coated be thoroughly damp, and that the application technique be such that the adhesive completely
wets the surface.
3.1.5 Application conditions - It is essential that the
latex adhesive, whether Type I or II, coalesces to form
a polymer film. Consequently, application temperatures must either be above the minimum film-forming
503.5R-9
503.5R-10
This chapter describes the factors that can be important in choosing an adhesive for a specific application.
4.1 - Type and magnitude of loads
For permanent adhesive bonds the adhesive should
be able to transfer loads to the same degree as the
structural elements that are bonded together. For each
load a determination should be made of:
l Direction (tension, compression, shear, flexure)
l Rate (static, dynamic)
l Duration
l Frequency
Most often data are available only for a single load
rate while information on creep, fatigue, or dynamic
loading is not available. For very critical adhesive applications, if adequate test data are not available, a test
program should be conducted that simulates the load
POLYMER ADHESIVES
5.1.2 Working life -The working life should be adequate to allow placing, positioning, and aligning the
concrete elements to be bonded. In bonding large segments, especially where several segments are assembled
at one time, a working life of many hours is necessary.
Once the working life has expired but before cure has
taken place, the concrete elements cannot be realigned
or adjusted without significantly reducing the bond
strength that would be realized on full cure.
5.1.3 Cure time - When choosing an adhesive for its
curing time, the working life requirements described in
Section 5.1.2 must be considered since cure time and
working life for polymer adhesives are related.
5.1.4 Bond-line thickness - Recommended bond-line
thickness requirements vary from one adhesive to another. In general, however, the strength of unreinforced joints decreases as the bond line thickness increases.
5.2 - Important bond-strength considerations
Although the published bond strengths for polymer
adhesives may appear to be adequate for a specific
hardened concrete to hardened concrete application,
the effects of high ambient temperatures (Sections 2.3.6
and 2.3.7) must be considered, especially if reinforcement does not pass through the adhesive joint.
CHAPTER 6 - ADHESIVES FOR BONDING
PLASTIC CONCRETE TO HARDENED
CONCRETE
Polymer adhesives provide a better bond of plastic
concrete to hardened concrete than can be obtained by
relying on the cement itself or on a cement slurry, because polymer adhesives shrink less than cement paste
upon curing, and because they tolerate a wider range of
moisture conditions in the plastic concrete and the
hardened substrate.
The primary use of all types of water-borne adhesives with concrete is to bond plastic concrete to hardened concrete. The only solvent-free adhesives used for
bonding plastic concrete to hardened concrete are epoxy adhesives because, unlike other solvent-free adhesives, they can be readily formulated to cure and bond
in the presence of water.
6.1 - Important application considerations
6.1.1 Viscosity and thixotropy - Most applications
of bonding fresh concrete to existing concrete are on
relatively large areas.
To place the adhesive economically, it is desirable to
use an adhesive that is sufficiently low in viscosity to be
sprayed or applied by a roller or squeegee. However, if
the surface is rough, as it would be from only rough
trowelling or chipping, the adhesive must have enough
thixotropy to maintain a uniform bond line thickness
without draining away from the high spots and into the
low spots. For vertical surfaces, the adhesive must be
able to stand without running off.
6.1.2 Working life - The working life of an adhesive used for bonding fresh concrete must be long
enough to allow workers time to place the concrete before the adhesive gels. This is especially important in
503.5R-11
503.5R-12
cracks by injection. High-molecular-weight methacrylates are also used on some flat surface applications by
flooding the surface with adhesive, and they have been
used occasionally to inject into fine cracks because of
their low viscosity. Polyesters and latex-cement slurries
have been used very infrequently with either application method18,21
7.1 - Important application considerations
7.1.1 Viscosity and thixotropy - Low viscosity is required for adhesives to penetrate cracks without using
high injection pressure. Typical viscosities for liquid
epoxy injection adhesives range from 100 to 500 cps at
77 F (25 C). High-molecular-weight methacrylates have
viscosities in the range of 15 to 20 cps at 77 F (25 C).
However, if injection adhesives with viscosities lower
than 100 cps are used the adhesive can penetrate into
the concrete so far that it leaves a starved bond line. In
this case, there must be a continual reservoir of adhesive available to the crack until the adhesive gels fill to
the bond line. Liquid adhesives without thixotropic
properties will also drain out of a crack, even into
subgrades, if all faces of the crack are not sealed prior
to filling the crack. For cracks where all faces cannot be
sealed, a thixotropic or psuedoplastic adhesive should
be used which will stay in the crack without constraint.
7.1.2 Water sensitivity during cure - All cracks in
concrete that is outdoors should be assumed to have
water in them unless there is evidence to the contrary.
An adhesive that will bond in the presence of water
should be used whenever water is present in the crack.
Conformance with ASTM C 881 Type IV or ASTM C
1059 will assure that a satisfactory adhesive is chosen.
For adhesive injection into cracks underwater, no standard tests exist. Special laboratory or field tests should
be conducted to qualify an adhesive for underwater injection. ASTM C 882 has been used for this purpose by
fabricating the test specimens underwater.
7.1.3 Concrete temperature - Cracks in concrete
open and close as the temperature of the concrete
changes. If a crack cannot be injected while it is in its
widest position, an injection adhesive should be chosen
that cures fast enough to resist the tensile forces that
result when the crack widens from temperature change.
7.2 - Important strength considerations
7.2.2 Limitations- Adhesive bonding of cracked
concrete may not be permanent if the original cause of
the crack is not eliminated. For example, if overloads
continue to exist or if foundations continue to settle,
the concrete structure will probably crack again in the
vicinity of the original crack. Factors such as these
should be considered before repairing the original
cracks.
7.2.2 Flexibility -The use of a low modulus flexible
adhesive in a crack will not allow any significant movement of the concrete structure for the reasons cited in
Section 2.3.2. The effective modulus of elasticity of a
flexible adhesive in a crack is substantially the same as
that of a rigid adhesive.15
POLYMER ADHESIVES
503.5R-13
503.5R-14
(lz!R!&
E
ifZh
2000 psi
(13.8 MPa)
E,S&;;
E.P,iif ,PP,
E,P,M
S
E,P,M,SB
PAE
E,P,M,PP
S
E,P,M
E,P,M
Temperature
resistance
Water resistance
B3e:oFw
%r;
(0 C)
(49 C)
Moisture
E,PAE,SB,
VAE
Submerged
E
E,P,M,PP,
PP
E,P,M,
PP
E,P,M
PP,S
E,P,M
E,P,M
E,P,M
E,P,M
E,M
E,P,M
E,P,M
%$A
z$*
E
E,PP
E,PP,S
E,PP
E,PP
E,PP
E,PP
E,P,M
E,P,M
E,P,M
E,P,M
E,P,M
E,P,M
E,PAE,SB,PVA,VAC
Submerged
substrate
-
7zw
(0 C)
-
;kii
(38 C)
-
Ability to
flow into
narrow voids
-
E.M
E,P,M
E,SB,PAE
E
E
E
E,M
E,M
E,P,M
E,P,M
E,P,M
-
E,PP
E,PP
E,M
E,P,M
Moist
substrate
~BBREVV;TlONS:
K
PP
S
PAE
SB
PVA
FXE
VAC
Polyester
Methylmethacrylate monomer
Polysulfide and polyurethane
Silicone
Acrylic latex
Styrene-butadiene latex
Polyvinyl acetate latex
Coefficient of thermal expansion
Elastic modulus
Vinyl acetate copolymer latexes
E,PP
E,P,M
CAUTION:
POLYMER ADHESIVES
CHAPTER 11 - REFERENCES
11.1 - Specified and/or recommended
references
The documents of the various standards-producing
organizations referred to in this document are listed
with their serial designation, including year of adoption or revision. The documents listed were the latest
effort at the time this document was revised. Since
some of these documents are revised frequently, generally in minor detail only, the user of this document
should check directly with the sponsoring group if it is
desired to refer to the latest revision.
503.2-79
(Revised 1986)
ASTM
C 192-88
503.5R-15
503.5R-16
Renovated by Post Reinforcement and Thin Bonded Concrete Overlay, Concrete Construction, Aug. 1984, pp. 705-709.
37. Seymor, Raymond B.; Plastics Versus Corrosives, John Wiley
& Sons, New York, 1982, pp. 147-262.
38. May, Clayton A., and Tanaka, Yoshio, Epoxy Resins, Chemistry and Technology, Marcel Dekker, Inc., New York, 1973, p. 347.
Calder, A. J. J., Exposure Tests on Externally Reinforced Concrete Beams - First Two Years, Supplementary Report 529 Transport and Road Research Laboratory, Crowthorne, 1979.
Cook, John Philip, and Panek, Julia R., Construction Sealants and
Adhesives, 2nd Ed., John Wiley & Sons, New York, 1984, pp. 295297.
Hugenschmidt, F., Epoxy Adhesives for Concrete and Steel,
Proceedings, First International Congress on Polymer Concretes,
London, May 1975.
Luke, Philip Chi Chung, Strength and Behavior of Rebar Dowels
Epoxy-Bonded in Hardened Concrete, thesis, Graduate School of
Engineering, University of Texas at Austin, 1984.
Plecnick, Joseph M.; Gaul, Robert W.; Pham, Mai; Cousins,
Thomas; and Howard, Jeff, Epoxy Penetration, Concrete International, V. 8, No. 2, Feb. 1986, pp. 46-50.
Tii, A., and Krokosky, E. M., Effect of Radiation on Some
Mechanical Properties of an Epoxy System, Journal of Materials,
JMCSA, V. 6, No. 2, June 1971, pp. 465481.