AIITS 2016 HCT VI JEEM JEEA/Advanced/PAPER-1/Solutions/Solutions PDF

AIITS-HCT-VI(Paper-1)-PCM(S)-JEE(Advanced)/16
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JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
HALF COURCE TEST VI
(Paper - 1)
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
A, B, C, D
A, B, D
B, C
6.
A, B, D
B, C, D
A, C
7.
A, C
B, C, D
A, B, C
8.
A, B
A, B
A, B
9.
10.
11.
(A) (r)
(A) (p)
(A) (s)
(B) (p)
(B) (s)
(B) (p)
(C) (s)
(C) (q, t)
(C) (r)
(D) (q)
(D) (r)
(D) (q)
(A) (p, q, r)
(A) (r);
(A) (p)
(B) (s, t)
(B) (p, q, t)
(B) (q)
(C) (s, t)
(C) (p, q, s)
(C) (r)
(D) (p, q, r)
(D) (p, t)
(D) (s)
1.
2.
3.
4.
5.
6.
1.
2.
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Physics
PART I
SECTION A
1.
V1 = 4.5 m/s, V2 = 3 m/s
2.
F g L x gL
3.
vp x 5 , v p y 5
d
xu
dt
5 2 = 7.1 m/s approx.

4.
Solve the problem using as the coefficient of kinetic friction. Linear velocity radius to zero
before angular velocity becomes zero.
5.
y = A sin (kx - t + )
at t = 0, x = 0, y = 5 mm
1
at t
, x = 0, y = 0
24
also = 2m, A = 10 mm
Solve to get answer.
6.
Given PT = Constant and PV = nRT

P2V = constant
PV1/2 = K.
From first law of thermodynamics
Q = U + O
Pf Vf PV
i i
CT CV T
1 1
2
C = CV + 2R
R
33.24
2R
Y 1
2
Y = 1.5 and Y 1
f
f = 4.
7.
Impulse = change in momentum
2(v 2 v1 )
2(3i j)
As impulse is in the normal direction of colliding surface

1
tan
3
1
tan1
3
1
90 tan1 .
3
8.
KAd
d
K(2rL)
dr
dr
r2
dr 2KL 2
r H d
r
2KL(2 1 )
dQ
H
80
dt
r
ln 2
r1
dm
L 80
dt
dm 80
80
kg/second.
dt
L
80 4200 4200
Fcos
Fcos2
A / cos
A
9.
Tensile stress
10.
Tensile stress is maximum when cos2 is maximum i.e. at = 0
11.
Shearing stress
F sin
F sin cos F sin 2
A / cos
A
2A
SECTION C
1.
a sin t
(x cos y cos )
represents a wave travelling along a line in x-y plane through origin making an angle with x-axis
and with the y-axis.
2

(x2 x1 )cos (y 2 y1)cos
comparing with the given equation, we get

= 30, = 60, = 1m, = 30/s
Also, = 4.
2.
P = A e (30004 3004) = 2 kW.
3.
v=
50
1 2GM
V =
100 e 2
R
Applying energy conservation
GMm 1
GMm
m v 2
R
2
(R h)
2GM 2GM
v2 =
R
Rh
1 2GM
1
1
.
= 2GM
4 R
R Rh
1
h
=
4R R(R h)
R + h = 4h
h = R/3
N = mg
N = m r 2
2
mg = m. 2 sin
g
2sin
mr2
N
mg
0.1 10
2 sin30
= 1 rad / s.
5.
x = A cos t
dx
v
A sin t
dt
a
d2 x
dt 2
A2 cos t
amax A2
max = I max I
1
A2 1
amax
MR2
MR A2
2
R
2
R
max 4N.m
6.
A1v1 A 2 v 2
v2 =16 m/s
Applying Bernoullis equation
1
1
3
3
P1 v12 P2 v 22 ( = 0.9 10 kg/m )
2
2
Chemistry
PART II
SECTION A
1.
H2 O
Mg2 C3
CH3 C C H
ii CH3 CH2 Cl H3 C C C CH2 CH3
i Na
P 2 - catalyst
Me
Et
C
H
H
( 2Z ) - pent - 2 - ene
Hence (D) is correct.

2.
NaBH4
140 C
BCl3 3NH4 Cl
B3N 3H3 Cl3
reduction
(A )
trichloroborazine
BNH
3 3 6
Borazine or
Inorganic benzene
H2 O
NH3 H3BO3 H2
Hence (C) is correct.

CH3
3.
H
H 2C
Cl
H 2C
CH 2
Cl
Cl2
hv
Cl
H 2C
CH3
(S)-2-chloropentane
CH3
CH2
Cl
CH3
(optically active (1)
H 2C
CH3
Cl
CH2
H
CH3
(optically inactive)
CH3
Cl
CH
H 2C
Cl
CH3
(optically
active (2)
CH3
Cl
CH 2
CH
Cl
CH2
Cl
CH3
(one optically
active and one
optically
inactive)
CH2
H2 C
Cl
(optically
active (1)
Hence (A) is correct.

4.
The limiting reagent here is HCl. So calculating with the limiting reagent, the total number of
products is 7.5.
5.
Symmetrical alkenes give same products.
6.
&
,
have (4n + 2) electrons.
7.
CCl4 does not undergo hydrolysis.
8.
KEmax of photoelectrons ejected depends only on frequency and not on its intensity.
Also, photoelectric effect is a direct evidence for the particle nature of light not of dual nature.
Hence (A), (B) is correct.
9.
CH3
H2C
O
CH
i O
CH2
H3C
ii Zn / H O HCHO
3
CHO HCHO
10.
O
i O
ii Zn / H O
3
11.
Oxidative ozonolysis
SECTION B
1.
F
F
S
Xe
O
2.
F
O
F
(D)
O
(B)
Trigonal bipyramidal
CH3
(A)
i O3
H C
ii Zn/H O 2 2
2
CH3
(B)
i O
2HCHO
CH CH CH CH3
ii Zn / H O
H2C
H3C
(C)
i O3
CH CH CH2
ii Zn / H O
(H3C)2C
H3C
(D)
CHO
i O3
H3C
CH CH2
ii Zn / H O
H3C
CHO
CHO
H3C
CHO
HCHO
CHO
CHO HCHO
SECTION C
1.
AgSCN
Ag SCN
AgBr
Ag Br
K
K
sp AgSCN
sp AgBr
2.
a b a 1.0 1012
a b b 5.0 1013
N2
3H2 2NH3
Initial
2
5
0
(after N2 reacted50%) 1
2
2
Total moles of N2, H2 and NH3 = 5 mol (after reaction)
Initial mol = 7
Pressure at start = 7 atm.

Hence pressure at equilibrium = 5 atm.
2
Partial pressure of NH3 = 5 = 2 atm.
5
4.
4.9 B.M, 4.9 n n 2

Number of unpaired electorn in Mnx+ = 4, x = 3
5.
Volume withdrawn = (20 2) 20 = 20 L

20
Numer of balloons =
4
5
6.
Maximum number of electron in 3rd orbit = 18

electrons with spin quantum number m s = 1/2 = 9
Mathematics
PART III
SECTION A
1.
Put x = 1 and x = 1 and adding

25
325 1 1 2 1
2
2
25
25
25
2
25
C0 C1 2 C2 2 ... C25 225 1
a0 + a2 + + a50 =
2
2 1 25 C1 25 C2 2 ... 25C25 224
2
2 13 25 C2 ... 25C25 225 even.
2.
3.
4.
Circle touching y = x at (0, 0) can be taken as x 2 + y2 + (x y) = 0

(i)
This bisects the circumference of the circle x 2 + y2 + 2y 3 = 0
(ii)
Hence radical axis between (i) and (ii) must pass through the centre of (ii) which is (0, 1)
Radical axis is (x y) 2y + 3 = 0, hence x = 5 put x = 5 in (i) to get the result.
Number of positive integral solution of x + y + z + w = 50 is 50C3
Number of positive integral solution of x + y + z + w = 19 is 19C3
For equilateral triangle
z2 z1 z3 z2 z1 z3 a
Also
z z3
z2 z3
a 3
z1 will be the length of median as well as altitude i.e. 2
z1
2
2
2
2
Hence, sin
z 2 z1 z 3 z1
2
z 2 z 3 2z1 z 3 z 2
5.
6.
7.
1
2
.
4
Any conic having its foci same as the given ellipse will have equation
variable now if the curve passes through (3, 2), we get
= 6
Putting value of , we get the required answer.
For real roots 4a2 4b (a 1) 0
a2 ba + b 0
Now for above inequality to hold for all values of a,
b2 4b 0 or 0 b 4.
We have AE = EP = AP = 1 AP = PT = 1
APT is isosceles
This makes AET a 30 60 90 triangle,
So AT = 3 and ATX = 150
since TX = 2
E
By applying cosine rule in ATX, we get
2
(AX) = 3 + 4 4 3 cos 150
= 7 + 6 = 13
AX 13
13 1 16
2
1
cos XAE
.
2 13 1 2 13 13
x2
y2
1 , x is
9 4
A
1
1
13
30
60
30
1
150
2
8.
Let A be (h, k), then altitude = k

2
2
Also AB : AC = 2 : 1, hence AB = 4AC
2
2
2
2
2
2
Now, AB = h + k and AC = (6 h) + k
2
9-11.
AC2 12
4AC
10
4
20 96 AC 20 96
2
Slope of AB
5
7
, hence slope of PQ
7
5
C C
Let equation of PQ be 7x + 5y = C, then coordinates of P & Q will be ,0 & 0, . Now
7 5
x 5y
7x y
equation of AQ and BP will be
0&
1
7 c
C 5
2
2
Eliminating C from these two equations gives the locus of R as the circle x + y 7x + 5y = 0.
Now, T will be the point on the diameter through origin of this circle at a distance 74 i.e.
distance of centre from origin + radius. Hence coordinate of T is (7, 5). Equation of the requires
parabola (y + 5)2 = 2(x 7). The line y = - 3 meets the parabola at (9, - 3). As the line is parallel to
15
the axis so any ray incident along it will pass through focus , 5 of the parabola after getting
2
15
reflected. Hence the reflected ray will be travelling along the line joining (9, 3) & , 5 .
2
Hence equation of reflected ray will be 4x 3y = 45.

SECTION B
Required numbers of
Required numbers of
Required numbers of
Required numbers of
ways = 2C1 2C1 7! 2!

ways = 8!
ways = 6! 2! 2C1 2C1
ways = 9! 8C2 6C2 4C2 2C2
1.
(A)
(B)
(C)
(D)
2.
(A) 2 sinx, sin 2x & 2cosx are in A.P., hence sin 2x = sin x + cos x
Now, let sin x + cos x = t, then sin 2x = t2 1, then the above equation gives t2 t 1 = 0 or
1 5
t sin x cos x
2
(B) Let C be the sides angles, then angles will be
c c
, ,
3 3 3 3 3
c

c c , hence angles are , , .
3 3
2
6 3 2
a
b
c
a
b
c
Now

1
3 2
sin
sin
sin
6
2
2

Hence angles are , , .
6 3 2
a
b
c
Now
sin
sin
sin
6
3
2
10
a
b
c
.
1
3 2
(C) Let AB = a, BC =
3 a, CA = 3a & AD = 3 3 a
a2 27a2 BD2 3a2 9a2 BD2
Now cos A + cos C = 0
0
3 3a2
3 3a2
BD
BD2 = 20a2
20 2 5
AB
2a2c 2
8a2c 2
(D) a + c = 2b & b2 = 2
(a + c)2 = 2
2
a c
a c2
4
2
2 2
(a + c) 2ac(a + c) 8a c = 0
a c 2
2,4
ac
But 4 gives a = c, hence taking 2
a
a2 + 4ac + c2 = 0 3 2 .
c
SECTION C
1.
R
3
2 ABC must be equilateral

r 1.5
so a = b = c = 2R sin
=R 3
3
2
1
Now a cot2 A + b2 cot3 B + c3 cot4 C R 3
R 3
3
R R 2 R3 3 32 33 39
13 3
3
3
3
3
3
m n 16
m = 13, n = 3
8.
2
2
2.
3.
R 3
3
5
5
5
5
5
5
210 sin 11 cos 11 cos 10 cos 9 ...cos 3 cos 2
2
2
2
2
2
2
210
5
sin
1
102
4 5
1024
2
hx ky
1
2
3
Homogenising equation of hyperbola by equation of chord of contact gives
Let P be (h, k), then chord of contact will be

2
x2 y2 hx ky
1 h2 1 k 2
1 . If these are perpendicular lines, then

0
2
3 2
3
2 4 3 a
x2 y2 1
hence required locus is
4
9
6
4.
For equilateral triangle r
R
, hence R = 8
2
11
Now in radius r of ABC is the circum radius for second triangle. Hence x1
r R
2 4
x1 R
R
, x3
2
8
16
R R R
x1 + x2 + x3 + =
...
4 8 16
R
R
Hence sum of all these radii is 4 R 8 .
R 2
1
2
Similarly x 2
5.
R.M.S. A.M.
2
z3 z z3
3
z 3 z z 3
3
Also |z 3| + |z| + |z + 3| = 2(|z| + 9), hence z 10 a = 3

where as z 3 z z 3 z 3 2 2 3 |z| 4
b = 4.
a + b = 7.
6.
Let us form that equation having roots y = g(x i)

i.e. y = x2 2 x y 2
y2
5
y2
1 0
y + 20y + 40y + 79y2 + 74y + 23 = 0

g(x1) g(x2) g(x5) = product of roots
= 23
x1x2x3x4x5 = 1 g(x1x2x3x4x5) = 1
g(x1)g(x2) g(x5) 30g(x1x2 x5) = 7.

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AIITS-HCT-VI(Paper-1)-PCM(S)-JEE(Advanced)/16

V1 = 4.5 m/s, V2 = 3 m/s

5 2 = 7.1 m/s approx.

Given PT = Constant and PV = nRT

Impulse = change in momentum

As impulse is in the normal direction of colliding surface

Tensile stress is maximum when cos2 is maximum i.e. at = 0

comparing with the given equation, we get

P = A e (30004 3004) = 2 kW.

Hence (D) is correct.

Hence (C) is correct.

(optically active (1)

Hence (A) is correct.

Symmetrical alkenes give same products.

CCl4 does not undergo hydrolysis.

Pressure at start = 7 atm.

4.9 B.M, 4.9 n n 2

Volume withdrawn = (20 2) 20 = 20 L

Maximum number of electron in 3rd orbit = 18

Put x = 1 and x = 1 and adding

2 13 25 C2 ... 25C25 225 even.

Circle touching y = x at (0, 0) can be taken as x 2 + y2 + (x y) = 0

Let A be (h, k), then altitude = k

Hence equation of reflected ray will be 4x 3y = 45.

ways = 2C1 2C1 7! 2!

2 ABC must be equilateral

Let P be (h, k), then chord of contact will be

1 . If these are perpendicular lines, then

For equilateral triangle r

Also |z 3| + |z| + |z + 3| = 2(|z| + 9), hence z 10 a = 3

Let us form that equation having roots y = g(x i)

y + 20y + 40y + 79y2 + 74y + 23 = 0

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