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Module 5: Distillation
Assignment Problems:
Assignment Problem 5.1: The vapor pressure of an alcohol is 10.0 torr at 14.7
C. Calculate the vapor pressure at 52.8 C if its vaporization is 47.2 kJ/mol.
(Ans: 100.2 torr)
Assignment Problem 5.2: Consider a mixture of components A and B obeys
Raults law. Plot the boiling point diagram of the system at 1 atmospheric
pressure. The vapor pressure of A and B are given in the following Table.
Temperature 0C
Vapor pressure of Component
A
Vapor pressure of Component
B
80
760
85
877
90
1016
95
100 105
1168 1344 1532
110
1800
345
405
475
760
557
645
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NB NA
N 0 B N 0 A
1 / AB
354.3
353.6
353.2
353.3
354.5
0.569
0.593
0.682
0.742
0.916
0.350
0.453
0.679
0.769
0.944
= y = 0.685; boiling point of the azeotrope =
K.
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to be obtained. The amount of liquid is fed back to the column at the top is 4
times the distillate product. The average heat capacity of the feed is 159 KJ/kg
mole. K and the average latent heat 32099 kJ/kg mole.
The equilibrium data:
Temp.(K)
353.3 358.2 363.2
366.7
373.2
378.2
383.8
xA (mole fraction) 1.000 0.780 0.580
0.450
0.258
0.13
0
yA(mole fraction)
1.000 0.900 0.777
0.657
0.456
0.261
0
Calculate
(a) The kg moles per hour distillate, kg mole per hour bottoms
(b) No. of theoretical stages at the operating reflux.
(c) The minimum no. of theoretical stages required at total reflux
(d) Overall efficiency at operating conditions
(e) Overall efficiency at total reflux conditions
Ans: (a) 41.2 kg mole/h, 58.8 kg mole/h (b) 7.9 (c) 5.9 (d) 0.79 (e) 0.59
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