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enthalpy (in kJ mol ) of a few elements are given

Assignment
Unit:- Periodic Table
Q1a

Fill in the blank of following table

Fill in the blank

1. What is the general configuration of transition element


?
2. Write the atomic number of the element present in the
second period and 14 group of the periodic table
3. Write the statement of modern periodic law
4. Write the electronic configuration and find the number
+2
of unpaired electron in 27 Co
5. Which of the following pairs of elements would have a
more negative electron gain enthalpy and why
(i) O or F
(ii) Cl or F
6. How would you justify the presence of 32 elements in
the 6th period of the Periodic Table?
7. what will be formula of compound formed by formed
element x and y given
2
2
6
2
1
2
2
6
2
5
X 1s ,2s ,2p ,3s ,3p and Y 1s ,2s ,2p ,3s ,3p
8. Arrange the elements with the following electronic
configurations in order of increasing electron affinity
2

9.

10.

11.
12.

13.

14.

i) 1s ,2s ,2p
(ii) 1s ,2s ,2p
2
2
3
2
2
6
2
4
iii) 1s ,2s ,2p
(iv) 1s ,2s ,2p ,3s ,3p
The first ionization enthalpy (iH) values of the second
period elements, N , C and F are respectively 1400,
1
1000 and 1800 kJ mol . Predict whether the first iH
1
value for O will be more close to 1220 or 1660 kJmol
? Justify your answer.
What do you mean by d-block element ? and write
general e- configuration and four important
characteristics of them
What is the group , period and block for the
chromium with atomic no =24
(i)what do you mean by the term covalent radii of
atom for an element given ? (ii) write those factor
which affect atomic rad. Arrange following in
2+,
3 +,
increasing order of size (A)
Mg, Al ,Mg Al
What do you mean by ionisation enthalpy of an
element Arrange the atoms with the following
electronic configurations in order of increasing order
of ionisation enthalpy
2
2
2
2
1
(i) 1s ,2s ,
(ii) 1s ,2s ,2p
2
2
6
2
2
6
2
6
(iii) 1s ,2s ,2p
(iv) 1s ,2s ,2p ,3s ,3p
The first (iH1) and the second (iH) ionization
1
enthalpies (in kJ mol ) and the (egH) electron gain

below:
Which of the above elements is likely to be :
(a) the least reactive element.
(b) the most reactive metal.
(c) the most reactive non-metal.
dthe least reactive non-metal.
(e) the metal which can form a stable binary halide of
the formula MX2, (X=halogen).
(f) the metal which can form a predominantly stable
covalent halide of the formula MX (X=halogen)?
(g) which element form acidic oxide
(h) which elements belongs to first group
16 Show by a chemical reaction with water that
Na2O is a basic oxide and Cl 2 O7 is an acidic oxide.
17 Assign the position of the element having outer
electronic configuration
2
4
(i)
ns np for n = 3
2
2
(n - 1)d ns for n = 4, and
7
1
2
(ii)
(n - 2) f (n - 1)d ns for n = 6, in the periodic
table.
18 Among the second period elements the actual
ionization enthalpies are in the order Li < B < Be < C <
O < N < F < Ne. Explain why
19 (i) Be has higher iH than B (ii) O has lower iH than N
and F?
20 The first ionization enthalpy (iH) values of the second
period elements, P , Si and Cl are respectively 1200,
1
800 and 1600 kJ mol . Predict whether the first iH
1
value for S will be more close to 1020 or 1460 kJmol
21 Arrange following
+
2+
3+
4+
Na , Mg , Al , Si [size ]
Ne, P , S, Cl and Ar[onization enthalpy]
Si, Be, Mg, Na, P [metallic characyer]
O,S,F,Cl [egain enthalpy, electronegativity]
22 How would you justify the presence of 50 elements in
the 8th period of the Periodic Table?
23 Which pair of elements belongs to same group?
(a) Elements with at. no. 17 and 38 (b) at. no. 20 and 40
(c) at. no. 17 and 53d) at. no. 11 and 33
24 General electronic configuration of the transition
elements is given by:
25 What is the symbol as per IUPAC system for an
element with z = 113 ?
26 Write the atomic number of the element present in the
third period and 15 group
27 Write the electronic configuration and find the number
+2
of unpaired electron in 28Ni
28 What is the symbol as per IUPAC system for an
element with z = 113 ?
2
2
6
29 An element having electronic configuration 1s , 2s 2p ,
2
6
1
3s 3p , 4s forms Acidic oxide/basic oxide or neural
2+
30 Find Number of unpaired e- in Fe ion
31 Why second e- gain enthalpy of atoms is +ve

CHEMISTRY BY MUKESH SHARMA

PERIODIC TABLE MCQ

1 Consider the isoelectronic ions, K+, S2-, Cl- and Ca2+.


The radii of these ionic species follow the order:
2+
+
22+
2+
(a) Ca > K > Cl > S (b) Cl > S > K > Ca
2+
2+
+
2+
2(c) S > Cl > K > Ca (d) K > Ca > S > Cl
2The first ionistion potentials of Na, Mg, Al and Si are such
that:
(a) Na < Mg < Al > Si (b) Na < Al < Mg < Si
(c) Na > Mg > Al > Si
(d) Na < Mg < Al > Si
3The electronic configuration 1s2, 2s2, 2p6, 3s2, 3p6, 3d10,
2
6
10
2
4s , 4p , 4d , 5s is for:
(a) S-block element
(b) d-block element
(c) p-block element
(d) F-block element
4 The electron affinities of N, O, S and Cl are such
that:
(a) N < O < S < Cl
(b) O < N < Cl < S
(c) O Cl < N S
(d) O < S < Cl < N
5
The correct order of electro-negativity is:
+
+
(a) O > O > O
(c) O > O > O
+
+
(c) O > O > O
(d) O > O > O
6 Which of the following is the correct order of electro
negativity?
(i) B >Al <Ga < ln<Tl (ii) C >Si Ge < Sn < Pb
(iii) F > O > N > Cl > Br (iv) F > Cl > Br > I
Correct option is:
(a) i, ii (b) i, ii, iii (c) i, ii iv (d) All of these
7 Element with atomic number 56 belong to which block
(a) s
(b) p
(c) d
(d) f
8 The element with the highest second ionization potential
is:
(a) Boron (b) Carbon (c) Nitrogen(d) Oxygen
9 General electronic configuration of the transition
elements is given by:
1-2
1-10
2
6
1-10
(a) ns nd
(b) ns np nd
1-10
6
1-10
1-2
(c) (n - 1) d np
(d) (n - 1) d ns
10 The lowest ionization energy would be associated with
the electronic structure :
2
2
6
1
2
2
5
(a) 1s , 2s 2p , 3s
(b) 1s , 2s 2p
2
2
6
2
2
6
2
2
(c) 1s , 2s 2p (d) 1s , 2s 2p , 3s , 3p
11 Which pair of elements belongs to same group?
Elements with at No(a) 17 and 38 (b).20and 40(c)17and53 (d)11and 33
12 The correct order of decreasing first ionization potential
is:
(a) C > B > Be > Li
(b) C > Be > B > Li
(c) B > C > Be > Li
(d) Be > Li > B > C
13 A sudden jump between the values of second and third
ionization energies of an element would be
associated with the electronic configuration:
2
2
6
1
2
2
6
2
1
(a) 1s , 2s 2p , 3s (b) 1s , 2s 2p , 3s 3p
2
2
6
2
2
2
2
6
2
(c) 1s , 2s 2p , 3s 3p (d) 1s , 2s 2p , 3s
14 Ionic radii of :
4+
2+
35 37 (a) Ti < Mn (b) Cl < Cl
+
3+
5+
(c) K > Cl
(d) P > P
15 The process requiring the absorption of energy is :
(a) F
(b) H
F
H
-(c) Cl
(d) O
Cl
O

16The statement Incorrect for f-block elements:


(a) they belong to group3rd (III B) of periodic table
(b) their outer most three shells are Incomplete
(c) they are collectively known as transuranic elements
(d) 4f elements are called rare earths or Lanthanons

17.Diagonal relationships are/is shown by:


(a) Si and Al(b) Mg and Al(c) Be and Al(d) B and P
18
The species isoelectronic with Ne is/are:
3+
2+
3+
2+
(a) N (b) Sn
(c) Al (d) Ca
19.The increasing of electron affinities in accordance
with electronic configurations given below are:
2
2
6
2
5
2
2
3
(1) 1s , 2s , 2p , 3s , 3p (ii) 1s , 2s , 2p
2
2
5
2
2
6
1
(iii) 1s , 2s 2p (iv) 1s , 2s , 2p 3s
(a) (ii) (iv) (iii) (i) (b) (i) (ii) (iii) (iv)
(c) (i) (iii) (ii) (iv)(d) (iv) (iii) (ii) (i)
20.Which of the following statements are in correct ?
(a) EA of 15th (5A) gp elements is more than that of
corresponding elements of 16 gp (VIA)
(b) Electronegativity of halogens decreases from F
to I(c) EA of Cl is higher than that of F though their
electronegativities are reverse in order
(d) EA of noble gases is almost zero
21.The statement which is incorrect about effective
nuclear charge, will be:
(a) Zeff = Z - eff. Z- (a is Slaters screening
constant)
(b) Zeff increase as we move across the period
(c) Z eff decreases from top to bottom in a group
(d) Zeff is constant or almost constant for f-block
elements
22 What is the symbol of element with Z=112
(a) Uub(b) Uut (c) Oub
(d) Hot
23 Which statement is correct?
+
(a) X ion is larger than X ion
(b) X ion is larger in size than X atom
+
(c) X and X have the same size
(d) X ion is larger in size than X atom
24.Among the following series of transition metals ions, the
2
one where all metal ions have 3d electronic
configuration is:
3+
2+
3+
4+
+
4+
6+
7+
(a) Ti , V , Cr , Mn (b) Ti , V , Cr , Mn
4+
3+
2+
3+
2+
3+
4+
5+
(c) Ti , V , Cr , Mn
(d) Ti , V , Cr , Mn
25 The 3d transition series contains elements having
atomic number from :
(a) 22 to 30(b) 21 to 30 (c) 21 to 31(d) 21 to 29
26.One would expect proton(H+) to have very large:
(a) Ionization potential (b) Radius
(c) Charge
(d) Hydration energy
27.Elements of which group forms anions most readily?
(a) Oxygen group
(b) Nitrogen group
(c) Halogens
(d) Alkali metals
28.Which one of the following is an amphoteric oxid
(a) SO2 (b) B2O3 (c) ZnO
(d) Na2O
29.Which is not arranged in the correct sequence?
5
3
1
4
(a) d , d , d , d increasing magnetic moment
(b) Mo, M2O3,MO2,M2O5 decreasing.basic
strength
(c) Sc, V, Cr, Mn increasing number of unpe2+
2+
+
2+
(d) Cr , Mn , Cu , Zn increasing I. E

CHEMISTRY BY MUKESH SHARMA