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5 authors, including:
Manoj Paneru
Jrg Maier
Universitt Stuttgart
Universitt Stuttgart
14 PUBLICATIONS 54 CITATIONS
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Manoj Paneru*, Zhang Qing, Piotr Plaza, Jrg Maier, Gnter Scheffknecht
*Corresponding author: manoj.paneru@ifk.uni-stuttgart.de
Content
o Introduction
o Fuel Properties
o Experimental Facility
Introduction
Hydrothermal Carbonisation (HTC)
--Biomass Pretreatment/upgrading
http://www.energy-without-carbon.org/SyntheticCoal
Fuel properties
W
Fix-C
Cl
LHV
[%, ad]
[%, db]
[%, daf]
[%, daf]
[%, daf]
[%, daf]
[%, daf]
[%, daf]
[%, daf]
[MJ/kg, an]
Coal (EC)
2.53
12.2
35.8
64.3
80.9
5.30
1.45
0.557
0.009
26.2
Lignite (RL)
9.02
3.90
54.6
45.5
67.4
4.84
0.735
0.462
0.035
22.1
HTC-SG
3.62
5.75
69.6
30.4
68.3
5.83
3.31
0.361
0.003
25.6
HTC-DS
3.34
11.8
67.4
32.6
62.3
4.58
1.79
1.08
0.043
20.3
HTC-BW
6.96
16.4
78.0
21.9
60.8
6.35
1.41
0.183
0.170
18.3
Biomass (WP)
7.95
1.27
80.1
20.5
51.1
4.79
0.628
0.066
0.026
17.4
Fuel
HTC-SG
Spent Grains
HTC-PM
HTC-BW
Municipal Bio-Waste
HTC as Fuel
HTC-SG
HTC-DS
HTC-BW
Coal
Lignite
Wood Pellets
1.4
Biomass
1.2
1
Coal
0.8
0.6
0.4
Coal
Lignite
HTC-Coal 1
Wood
0.2
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
Experimental facility
Fig. 1:
20 kW facility electrically
heated
Fig. 2:
500 kW facility
Focus
Coal (EC)
Lignite (RL)
HTC-SG
HTC-DS
Combustion and
Emission Behaviour
NOx Behaviour
HTC-BW
Biomass (WP)
Co-Combustion
Focus
HTC-SG + EC
Combustion and
Emission Behaviour
NOx behaviour and
Staging
HTC-SG + RL
Combustion behaviour
100
CO [ppm]HTC-SG
90
80
CO [ppm]
CO [ppm]
70
60
50
40
30
20
CO [ppm] HTC-SG+EC
CO [ppm]-EC
30000
25000
20000
15000
10000
5000
0
0.3
10
0.4
0.5
0.6
0.7
0.8
0.9
0
HTC-DS
HTC-Coals
HTC-BW
EC
RL
WP
HTC-SG + HTC-SG +
EC
RL
Coal
Lignite
Wood
Co-Firing
CO [ppm]HTC-SG
CO [ppm]
HTC-SG
CO [ppm] HTC-SG+RL
CO [ppm]-RL
30000
25000
20000
15000
10000
5000
0
0.3
0.4
0.5
0.6
0.7
0.8
0.9
NOx Emission
NOx [mg/m3] @ 6 vol.-% O2
1800
1600
1400
1200
1000
800
600
400
200
0
HTC-SG
HTC-DS
HTC-BW
HTC-Coals
EC
RL
WP
Coal
Lignite
Biomass
1600
1400
1200
1000
800
600
400
200
0
RL
HTC-SG + RL HTC-SG
Co-firing with Lignite
EC
HTC-SG +
EC
HTC-SG
Fuel N to NOx
HTC-DS
HTC-BW
Coal
Lignite
Lignite
Wood Pellets
60
60
50
50
HTC-SG
40
30
20
10
HTC-SG + RL
HTC-SG
Coal
HTC-SG + EC
40
30
20
10
HTC-Coals
0
30
35
40
45
50
55 60 65 70
Volatile [wt-%, daf]
75
80
85
90
30
35
40
45
50
55
60
65
Volatile [daf, wt-%]
70
75
80
NO profile (1200C)
CO [ppm]HTC-SG
750
NO [ppm]
NO [ppm] EC
40000
35000
30000
25000
20000
15000
10000
5000
0
700
650
600
550
500
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
NO [ppm] HTC-SG
900
NO [ppm]
800
CO [ppm]
NO [ppm] HTC-SG
Coal
800
700
Co-firing
600
HTC-SG
500
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
HTC-SG shows:
Destruction of NO in near burner zone
Self-staging effect-correlated with CO profile
dominated by HTC-SG during co-firing
11
SO2 Emission
HTC-SG
HTC-DS
HTC-BW
Coal
Lignite
Wood Pellets
HTC-SG + EC
HTC-SG + RL
3000
2500
2000
1500
1000
500
0
0
0.2
0.4
0.6
0.8
1.2
The SO2 shows a linear relationship with the fuel sulphur content.
Self-capture in ash relevant only for WP and Lignite
Despite of high calcium amount in HTC-SG the self-capture (in ash) was negligible
--Calcium remains as phosphates not available for SO2 capture
12
Mono-Combustion
Focus
Coal (EC)
HTC-SG
Co-Combustion
20th.%, 40%th.
300 kW (Operational)
Furnace end
measurements
13
500
450
400
350
300
250
200
150
100
50
0
Unburned Carbon[%]
2
1.5
1
0.5
100%HTC-SG
40%HTC-SG
20%HTC-SG
10%HTC-SG
CO[ppm]
CO[ppm]
CO[ppm]
2.5
EC-Coal
EC-Coal
CO[ppm]
CO[ppm]
CO [ppm, dry]
Combustion behaviour
Unburned Carbon =
CAs
Flame behaviour
Furnace Temperature [C]
1300
Temperature [C]
1200
1100
1000
900
800
700
600
L4 L8 L26 L4 L8 L26 L4 L8 L26 L4 L8 L26 L4 L8 L26
100%EC-Coal 10%HTC-SG 20%HTC-SG 40%HTC-BT 100%HTC-BT
HTC-Flame
Coal-Flame
EC-Coal Temp. [C]
1500
1400
1300
1200
1100
1000
900
HTC-SG
Coal
800
0
10
11
12
15
NOx Emission
NOx [mg/m3] @ 6 vol-% O2
400
300
200
100
0
HTC-SG
EC
16
NO profile (HTC-SG)
CO[%]
8
500
400
300
200
CO [vol.-%]
NO [ppm]
NO[ppm]
600
0
0
10 11 12 13 14 15 16
Test Summary
Combustion behaviour/flame behaviour
Stable flames and good combustion performance
Slower volatile combustion indicated by longer CO rich zone
Black clouds in flame (probably soot ) in the upper-middle zone
Early stage combustion behaviour--impacts burner and boiler design/operation
well as emission (especially NOx)
18
Test Summary
Emission Behaviour
Lower fuel-N to NOx conversion
Self reduction of NO in flame
--relate to the combustion behaviour
Fuel-N to NO pathway of HTC fuels interesting area of further research
19
Conclusion
Thanks
20
Acknowledgement
The research leading to these results has received funding from the European Union
Seventh Framework Programme (FP7-Energy-2011-1) under grant agreement no.:
282873. (Bioboost: " Biomass based energy intermediates boosting biofuel production ").
http://bioboost.eu/home.php
21