PPDI-Terminated Polycarbonate Prepolymer

ADIPRENE LFP 3940A

PRODUCT DATA

Urethane
Prepolymers

ADIPRENE LFP 3940A is a PPDI-terminated polycarbonate prepolymer

having very low free PPDI content (typical < 0.1%) for easier management
of health and safety during handling. ADIPRENE LFP 3940A yields high
performance 93-96 Shore A hardness elastomers when cured with
VIBRACURE A 250 or HQEE.
The high performance features of ADIPRENE LFP 3940A are due to PPDI
(p-phenylene diisocyanate), a special building block that imparts
exceptional properties to cast polyurethane elastomers. The unique
combination of properties exhibited by PPDI-based prepolymers is superior
to those available from standard prepolymers based on TDI or MDI.
Features of ADIPRENE LFP 3940A include:

Low Free PPDI Content

Excellent hydrolytic stability, oil stability and thermal stability
Long Pour Life
Excellent Dynamics
Good Tensile/Tear Strength
Excellent Resilience

Hygiene
Although ADIPRENE LFP 3940A has a very low level of free PPDI
monomer, this does not eliminate the need to manage health and safety
issues responsibly when handling this product. Impervious gloves and
goggles should be worn. Avoid contact with eyes, skin, and clothing, and
wash thoroughly after handling. Avoid breathing vapor. Use only with
adequate ventilation. In the absence of good ventilation or under
emergency situations, self-contained or air-supplied respiratory protection
is recommended. Before use consult MSDS for ADIPRENE LFP 3940A
for additional information on potential hazards and handling precautions.

ADIPRENE LFP 3940A

TYPICAL PHYSICAL SPECIFICATIONS
Liquid Prepolymer Specifications
% NCO...................................................................................3.40-3.80
AE ..........................................................................................1105 1236
Appearance @ 25C ..............................................................Solid, free from
contamination
Color, Gardner .......................................................................0-2

Typical Properties
Viscosity, Centipoise (Pas)
@ 86F (30C) .................................................................(Solidifies)
@ 140F (60C) ...............................................................(Solidifies)
@ 176F (80C) ...............................................................6000 (60)
@ 212F (100C) .............................................................2500 (25)

ADIPRENE LFP 3940A

PROCESSING CONDITIONS
PROCESSING CONDITIONS
Vibracure A250

HQEE

ADIPRENE LFP 3940A Temperature, F (C).........................212 (100)....................212 (100)

CURATIVE Temperature, F (C) ..............................................75 (24)......................230 (110)
% Theory..........................................................................................95................................98
pph CURATIVE (AE = 1167) ........................................................ 3.7 .............................. 8.3
Mold Temperature, F (C)........................................................260 (127)....................260 (127)
Pour Life, Minutes ............................................................................5....................>10 w/out catalyst
Demold Time, Minimum Minutes ...................................................60................. 30-60 w/out catalyst
Postcure Cycle, Hrs./F (C)................................................... 16/260 (127) .............. 16/260 (127)

Notes:
1. Chemtura VIBRACURE A 250 is specially formulated for PPDI prepolymers to improve
mixing of prepolymer and curative during processing.
2. For best results, the mold should be pre-heated to the recommended temperature. If
the mold cools during handling and casting, it is desirable to preheat it enough above
the cure temperature to allow for its cooling.
3. Allow cast parts to condition for four weeks at room temperature before use.

ADIPRENE LFP 3940A

TYPICAL PHYSICAL PROPERTIES

Vibracure A 250

HQEE

Hardness, Shore A .......................................................................94 96.........................93-95

100% Modulus, psi (MPa) .........................................................1580 (11)....................1670 (12)
300% Modulus, psi (MPa) .........................................................2600 (18)....................2560 (18)
Tensile, psi (MPa)......................................................................7600 (53)....................7260 (50)
Elongation, % .................................................................................550..............................550
Tear Strength, pli [kN/m] Split (D-470) ....................................150 (27)......................150 (27)
Bashore Rebound ............................................................................50................................48
Compression Set, Method B, 22 Hrs.
@ 158F (70C) ........................................................................33................................28
@ 212F (100C) ......................................................................55................................39

Dynamic Mechanical Properties

Storage Modulus (G), Mdynes/cm2 sec.
@ 86F (30C) ..........................................................................325..............................266
@ 302F (150C) ......................................................................260..............................244
Tangent Delta
@ 86F (30C) ........................................................................ 0.022 .......................... 0.034
@ 302F (150C) .................................................................... 0.019 .......................... 0.016

All materials tested after conditioning at room temperature for four weeks.
Property values reported in this bulletin are for the specific composition shown. Additional colorants or
additives of any kind may alter some or all of the properties. The data listed fall within the normal range
of product properties, but they should not be used to establish specification limits nor used alone as the
basis of design.

Disclaimer
Except as otherwise provided by law outside the USA, the following information should be noted.
The information set forth herein is furnished free of charge and is based on technical data that Chemtura
believes to be reliable. It is intended for use by persons having technical skill, at their own discretion and
risk. The handling precaution information contained herein is given with the understanding that those
using it will satisfy themselves that their particular conditions of use present no health or safety hazards.
Since conditions of product use are outside our control, we make no warranties, express or implied, and
assume no liability in connection with any use of this information. Nothing herein is to be taken as a
license to operate under or a recommendation to infringe any patents.
Rev. ZZ/ROR:mc\4/99:1/02/02/jbk:11/02dd:6/04jh:7/05dd:ZZ/pl4/06: