Using of Allium Ampeloprasum Extract As

International
Journal of Mechanical
Engineering
and Technology (IJMET),
ISSN 0976 6340(Print),
INTERNATIONAL
JOURNAL
OF MECHANICAL
ENGINEERING
AND
ISSN 0976 6359(Online), Volume 6, Issue 1, January (2015), pp. 34-41 IAEME
TECHNOLOGY (IJMET)
ISSN 0976 6340 (Print)

ISSN 0976 6359 (Online)
Volume 6, Issue 1, January (2015), pp. 34-41
IAEME: www.iaeme.com/IJMET.asp
Journal Impact Factor (2014): 7.5377 (Calculated by GISI)
www.jifactor.com
IJMET
IAEME
USING OF ALLIUM AMPELOPRASUM EXTRACT AS

CORROSION INHIBITOR
Hussein H. Ibrahim1,
Abd- Alwahab A.Sultan2,
Intisar A. Abdulkareem4,
Abdulkareem M. Jewad3,
Asaad H. Majeed5
South Oil Company, Basrah, Iraq

Petrochemical Engineering Department, Basrah Engineering Technical Collage, Basrah, Iraq
3
Healthy Technical Collage, basrah, Iraq
4
Petrochemical Industries Department, Technical Institute, Basrah, Iraq
5
Technical Institute, Basrah, Iraq
ABSTRACT
The inhibition of carbon steel corrosion by extract of Allium Ampeloprasum was studied by
weight loss method. The inhibition efficiency of the inhibitor was found to increase with increasing
content of the extract. Inhibition efficiency of 98.3% was achieved with 40% v/v of the extract in 1M
hydrochloric acid during 3 hours at 25. Effect of temperature was also investigated and activation
parameters were evaluated. The results showed that the extract adsorb on the surface of carbon steel
through physical adsorption and the adsorption of the inhibitor obeys the Langmuir adsorption
isotherm.
Keywords: Allium Ampeloprasum, Corrosion inhibition, Carbon steel, acidic media, adsorption
1. INTRODUCTION
Corrosion is the destructive attack of a metal by chemical or electrochemical reaction with
the environment.
The basic cause of the corrosion of the metals is their tendency to return to their stable state.
Nearly all metals are inherently unstable and it is their natural tendency to seek self-destruction by
reacting with their environment to attain a state of lower energy by forming a metal compound. This
is the state in which the majority of metals are found in nature [1].
34
International Journal of Mechanical Engineering and Technology (IJMET), ISSN 0976 6340(Print),
The three main reasons for the importance of corrosion are: economics, safety, and
conservation. The cost of corrosion in industrialized countries has been estimated to be about 34%
of the gross national product [2, 3].
Corrosion can compromise the safety of operating equipment by causing failure of, for
example, pressure vessels and boilers, metallic containers for toxic chemicals, turbine blades and
rotors. Loss of metal by corrosion is a waste not only of the metal, but also of the energy, the water,
and the human effort that was used to produce and fabricate the metal structures in the first place [2].
Corrosion of metallic surfaces can be reduced or controlled by the addition of chemical
compounds to the corrodent. This form of corrosion control is called inhibition and the compounds
added are known as corrosion inhibitors. These inhibitors will reduce the rate of either anodic
oxidation or cathodic reduction, or both. The inhibitors themselves form a protective film on the
surface of the metal [4]. There are numerous inhibitor types and compositions. Most inhibitors have
been developed by empirical experimentation [5]. Most synthetic corrosion inhibitors are expensive,
toxic and hazardous compounds. The toxic effect of these inhibitors does not only affect living
organisms but also poison the environment. Therefore, the use of natural products has gained
popularity. Plants extracts constitute several organic compounds those act as antioxidants could be
considered to generate cost effective source of corrosion inhibitor actives being renewable, widely
available and they offer the advantage of imposing no hazard to the environment. In this study,
extract of Allium Ampeloprasum was used as natural corrosion inhibitors.
2. EXPERIMENTAL
2.1 Specimen Preparation
Carbon steel specimens of size 6.5 cm x 2.5 cm x 0.3 cm containing a small hole of 3 mm
diameter near the upper edge were employed for the weight loss test. Before each test, each
specimen was polished with emery papers of 60, 1000, 1200 grades, washed with tap water followed
by distilled water, dried with tissues, degreased with acetone and dried with tissues again.
2.2 Preparation of Plant Extract
Fresh Allium Ampeloprasum which was used in this study was collected from Al-Sarragi in
Basrah city. The plant was washed with tap water several times followed by distilled water and put
on the tissue to dry. Two grams of Allium Ampeloprasum was immersed in 100 ml of ethanol for
three days. After three days the solution was filtered and used as natural corrosion inhibitor.
3. RESULTS AND DISCUSSION
3.1 Effect of Inhibitor Concentration
Various corrosion parameters such as corrosion rate and inhibition efficiency were obtained
from weight loss measurements for different inhibitor content (2%, 10%, 20%, 30% and 40%) for
the corrosion of carbon steel in 1M HCl solution duration 3 hours at 25 (Table 1). Fig. 1 shows the
variation of corrosion rate (mg cm hr
) with content of extract in 1M HCl solution. From the plot
it can be seen that corrosion rate of carbon steel was significantly lowered down in presence of
extract and with the increase in content of the extract the corrosion rate decreased gradually.
Corrosion rate of carbon steel in 1M HCl solution decreased from 0.8896 mg/cm^2.hr to 0.0151
mg/cm^2.hr in the presence of 40% of the extract.
Fig. 2 shows the variation of percentage corrosion inhibition efficiency against content of the
extract. The results revealed that corrosion inhibition efficiency increases with increasing the extract
content. The inhibition efficiency reached to 98.3026 in the presence of 40% v/v of the extract. This
behavior can be attributed to the increase of surface covered and adsorption of natural compounds
35
on the surface of the carbon steel as the inhibitor content increases. Due to adsorption the corrosion
sites of carbon steel get blocked and adsorbed film acts as barrier between carbon steel surface and
corrosion medium.
Table 1: Corrosion parameters obtained from weight loss measurements
Content
weight loss (mg)
C.R (mg/cm^2.hr)
I.E %
0%
30.00
0.8896
---2%
10.10
0.3066
65.5350
10%
9.20
0.2792
68.6151
20%
7.50
0.2225
74.9887
30%
1.30
0.0377
95.7621
40%
0.51
0.0151
98.3026
Corrosion rate (mg/cm^2.hr)
1
0.8
0.6
0.4
0.2
0
0%
10%
20%
30%
40%
Inhibitor content
Fig 1: Variation of corrosion rate of carbon steel without and with extract in 1M HCl solution at
25
Inhibition efficiency %
100
95
90
85
80
75
70
65
0%
10%
20%
30%
40%
Inhibitor content
Fig 2: Variation of percentage corrosion inhibition efficiency with the content of the extract in 1M
HCl solution at 25
36
3.2 Effect of Temperature

The effect of temperature on the various corrosion parameters such as weight loss, corrosion
rate, inhibition efficiency were studied for the corrosion of carbon steel in 1M HCl solution duration
3 hours at temperatures 25, 45 and 65. The results indicated that the corrosion rate of carbon steel
in the absence and presence of the extract increases with rise in temperature, although corrosion rate
is lowered in the presence of the extracts compared to blank solution. Fig. 3 represents this behavior
clearly. The values of corrosion inhibition efficiency of the extract decreased with increasing
temperature. Fig. 4 shows the relation between corrosion inhibition efficiency of the extract with
temperature. As explained previous these results can be attributed to the physical adsorption of the
extract on the carbon steel surface in 1M HCl solution [6, 7].
Table 2: Corrosion parameters obtained from weight loss test for carbon steel immersed in 1M HCl
in the absence and presence of 40% of the extract at different temperatures
Tem.
weight loss (mg)
C.R (mg/cm^2.hr)
I.E %
30
0.8896
----
0.51
0.0151
98.3026
49.6
1.3279
----
9.4
0.2516
81.0472
79.3
2.3045
----
31.6
0.7264
68.4774
25
45
65
Corrosion rate (mg/cm^2.hr)
2.5
2
1.5
without inhibitor
with inhibitor
0.5
0
20
30
40
50
60
70
Temperature (C)
Fig 3: Plot of corrosion rate of carbon steel in 1M HCl without and with 40% of the extract against
temperature obtained from weight loss measurements
37
Inhibition efficiency %
100
95
90
85
80
75
70
65
20
30
40
50
60
70
Temperature (C)
Fig 4: Plot of inhibition efficiency of the extract (40%) in 1M HCl against temperature
3.3 Activation Parameters of Inhibition Process
The activation energy (E ) and enthalpy of activation for the corrosion of carbon steel in the
absence and presence of 40% v/v of the extract in 1M hydrochloric acid were calculated using
Arrhenius equation and Arrhenius transition state equation [8, 9]:
log C. R =
log
E
+ log A (1)
2.303RT
C. R
R
S
H
= log
+
!
(2)
2.303RT
T
Nh 2.303R
A plot of logarithm corrosion rate of carbon steel obtained from weight loss measurements
versus the reciprocal of absolute temperatures 25, 45 and 65, gives a straight line as shown in Fig.
5 with slope E 2.303R . On the other hand, a plot of log C. RT versus 1T gives a straight line
(Fig. 6) with a slope equal to H2.303R from which the values of H were calculated. The
values of E and H are listed in Table 3.
The results showed that the activation energy increases in the presence of the extract. Higher
activation energy for the corrosion process in the presence of inhibitor leads to conclusion that
probably the inhibitor is found to be adsorbed on the surface of carbon steel by specific physical
adsorption process [10, 11]. The positive signs of enthalpies reflect the endothermic nature of
dissolution process.
Table 3: Activation parameters for the dissolution of carbon steel in 1M HCl in the absence and
presence of 40% of the extract
Content
%&
'&
(KJ/mol)
(KJ/mol)
0.0
19.8364
18.4789
40%
81.7583
80.3988
38
0.5
log C.R
0
y = -1036.x + 3.411
R = 0.983
-0.5
Blank
-1
40%
y = -4270.x + 12.61
R = 0.952
-1.5
-2
0.0029
0.003
0.0031
0.0032
1/T (K^-1)
0.0033
0.0034
Fig 5: Plot of log C.R against 1/T for carbon steel in 1M HCl in the absence and presence of 40% of
the extract
-2
log C.R/T
-2.5
y = -965.1x + 0.699
R = 0.982
-3
Blank
40%
-3.5
-4
y = -4199.x + 9.899
R = 0.951
-4.5
0.0029
0.003
0.0031
0.0032
1/T (K^-1)
0.0033
0.0034
Fig 6: Plot of log C.R/T against 1/T for carbon steel in 1M HCl in the absence and presence of 40%
of the extract
3.4 Adsorption Isotherm
Addition of extract molecules which adsorbed on the carbon steel surface and the interaction
between them can be described by adsorption isotherm. The data were tested graphically by fitting to
Langmuir model. This model is given by [12]:
C()* 1
= + C()* (3)
K
,
By plotting values of -./

versus C()* (Fig. 9) a linear plot was obtained indicating that the
adsorption of the inhibitor is consistent with the assumption of Langmuir adsorption isotherm and
the slope obtained is close to unity.
39
0.5
C inh/
0.4
R = 0.970
0.3
0.2
0.1
0
0
0.1
0.2
0.3
0.4
C inh
Fig 9: Langmuir isotherm for the adsorption of the inhibitor on the surface of the carbon steel in 1M
HCl solution at 25
4. CONCLUSION
1. Allium Ampeloprasum extract acts as efficient corrosion picking inhibitor on carbon steel in 1M
hydrochloric acid.
2. The extract showed maximum inhibition efficiency of 98.3% at the presence of 40% in v/v
during 3 hours at 25.
3. The corrosion inhibition efficiency of the extract decreases with increasing temperature.
4. Activation energy increases in the presence of the inhibitor which indicates the physisorption of
the extract on the carbon steel surface.
5. Allium Ampeloprasum extract adsorbs on the carbon steel surface according to the Langmuir
isotherm.
SYMBOLS
A: Constant
C. R: Corrosion rate (mg. cm . hr
)
C()* : Content of the inhibitor
E : Apparent activation energy (KJ.mol
)
h: Planks constant (6.626*1001 J. s)
H : Enthalpy of Activation (KJ.mol
)
K: Binding constant of the adsorption reaction
N: Avogadros number (6.022*100 mol
)
R: Gas constant (8.314 J. mol
. K
)
S : Entropy of activation (J. mol
. K
)
T: Temperature (K)
: Surface coverage
40
REFERENCES
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
Haward R. (1968), Marine Corrosion, G. Newnes, London.

Uhlig, Herbert H. and Revie, R. Winston (2008), Corrosion and Corrosion Control, John
Wiley and Sons, Hoboken New Jersey.
Bardal Einar (2004), Corrosion and Protection, Springer, London.
Schweitzer, Philip A. (2007), Corrosion Engineering Handbook, Taylor and Francis Group,
Boca Raton.
Fontana, Mars G. (1987), Corrosion Engineering, McGraw-Hill, New York.
El-Etre A. Y. (2003), Inhibition of aluminum corrosion using Opuntia extract, Corrosion
Science, Vol.45, No.11, pp. 2485-2495.
Ameh P. O., Magaji L. and Salihu, T. (2012), Corrosion inhibition and adsorption behavior
for mild steel by Ficusglumosa gum in H SO1 solusion, African Journal of Pure and Applied
Chemistry, Vol.6, pp. 100-106.
Dahmani M., Et-Touhami A., Al-Deyab S. S., Hammouti B., Bouyanzer A. (2010),
Corrosion Inhibition of C38 Steel in 1M HCl: A Comparative Study of Black Pepper Extract
and Its Isolated Piperine, International Journal of Electrochemical Science, Vol.5, pp. 10601069.
Singh A., Singh V. K., Quraishi M. A. (2010), Effect of fruit extracts of some
environmentally benign green corrosion inhibitors on corrosion of mild steel in hydrochloric
acid solution, J. Mater. Environ. Sci., Vol.1, No.3, pp. 162-174.
Rajalakshmi R., et al. (2008), Efficiency of sprouted seed extracts of Phaseolus aureus on
the corrosion inhibition of mild steel in 1M HCl, Oriental Journal of Chemistry, Vol. 24, No.
3, pp. 1085-1090.
Odiongenyi A. O., Odoemelam S. A. and Eddy N. O. (2009), Corrosion Inhibition and
Adsorption Properties of Ethanol Extract of Vernonia Amygdalina for the Corrosion of Mild
Steel in H SO1 , PortugaliaeElectrochemicaActa, Vol. 27, pp. 33-34.
Lebrini M., Robert F., Roos C. (2011), Alkaloids Extract from Palicourea guianensis Plant
as Corrosion Inhibitor for C38 Steel in 1M Hydrochloric Acid, International Journal of
Electrochemical Science, Vol. 6, pp. 847-859.
Vishnu Pratap Singh, Abhishek Gaikwad, Mohammad Zahid Rayaz Khan and Kamlesh
Tiwari, Development of Dual Phase Steel and Determination of It's Mechanical Properties
and Comparison With Low Carbon Steel International Journal of Mechanical Engineering &
Technology (IJMET), Volume 5, Issue 7, 2014, pp. 151 - 159, ISSN Print: 0976 6340,
ISSN Online: 0976 6359.
Hameed Hussein Alwan, Adsorption Mechanism For Corrosion Inhibition of Carbon Steel
on Hcl Solution by Ampicillin Sodium Salt International Journal of Advanced Research in
Engineering & Technology (IJARET), Volume 4, Issue 7, 2012, pp. 236 - 246, ISSN Print:
0976-6480, ISSN Online: 0976-6499.
Nadir Mohamed Abdulreda, Corrosion Inhibition of Carbon Steel In Nacl and Hcl Solutions
by Vitamin C International Journal of Advanced Research in Engineering & Technology
(IJARET), Volume 5, Issue 4, 2014, pp. 38 - 45, ISSN Print: 0976-6480, ISSN Online: 09766499.
41

Using of Allium Ampeloprasum Extract As

Hochgeladen von

Dokumentinformationen

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Using of Allium Ampeloprasum Extract As

Hochgeladen von

Copyright:

Verfügbare Formate

International

ISSN 0976 6340 (Print)

USING OF ALLIUM AMPELOPRASUM EXTRACT AS

Abd- Alwahab A.Sultan2,

South Oil Company, Basrah, Iraq

Corrosion rate (mg/cm^2.hr)

3.2 Effect of Temperature

weight loss (mg)

Corrosion rate (mg/cm^2.hr)

By plotting values of -./

Haward R. (1968), Marine Corrosion, G. Newnes, London.

Das könnte Ihnen auch gefallen