Material Safety Data Sheet

According to Commission Regulation (EC) No 1907/2006 (REACH)

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
Product Name:
Specific use(s):

XYLAN 4090/F0931 RED OXIDE

Optional primer for use under Xylan 1000 series to improve the
corrosion resistance.

Contact manufacturer
Whitford Ltd.
10 Christleton Court, Manor Park
Runcorn, Cheshire WA7 1ST
England
Telephone: [44] (0) 1928-571000 or 598100
Telefax: [44] (0) 1928-571010
E-Mail: salesuk@whitfordww.com

Supplier
Whitford Ltd.
10 Christleton Court, Manor Park
Runcorn, Cheshire WA7 1ST
England
Telephone: [44] (0) 1928-571000 or 598100
Telefax: [44] (0) 1928-571010
E-Mail: salesuk@whitfordww.com

Emergency telephone number (24/7): [44] (0) 1928-571000 (Whitford)

2. HAZARDS IDENTIFICATION
Classification
Flammable.
Harmful.
Most important hazards
Flammable. Irritating to skin. Risk of serious damage to eyes.
Harmful by inhalation, in contact with skin and if swallowed.
Symptoms of Exposure
Inhalation
Cough. Irritating to respiratory system.
Skin contact
Redness. May be absorbed through the skin in harmful amounts.
Eye contact
Severe eye irritation. Redness. Excessive watering.
Ingestion
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Unconsciousness.
Specific hazards
Inhalation of high vapour concentrations can cause CNS-depression and narcosis.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

Revision Date: 09 December 2009
Revision Number: 2

Page 1 of 9

English (UK)

Material Safety Data Sheet

Chemical nature of the preparation
Chemical Name
N-METHYLPYRROLIDONE (NMP)
XYLENE

XYLAN 4090/F0931 RED OXIDE

CAS RN
872-50-4

Weight %
20 - 40%

EC-No.
212-828-1

Classification
Xi;R36/38

1330-20-7

10 - 20%

215-535-7

96-48-0
100-41-4

10 - 20%
1 - 5%

202-509-5
202-849-4

R10
Xn;R20/21
Xi;R38
Xn;R22-41
F;R11
Xn;R20

GAMMA-BUTYROLACTONE (BLO)
ETHYL BENZENE

For the full text of the R phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice
If you feel unwell, seek medical advice (show the label where possible). Take off contaminated clothing and shoes
immediately. Wash contaminated clothing before re-use. Show this safety data sheet to the doctor in attendance.
Inhalation:
Move to fresh air in case of accidental inhalation of vapors or decomposition products. Lie down in the recovery position,
cover and keep warm. Apply artificial respiration only if patient is not breathing or under medical supervision.
Skin contact:
Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If skin irritation persists,
call a physician.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15
minutes. Keep eyes wide open while rinsing. If eye irritation persists, consult a specialist.
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting: contains petroleum distillates and/or
aromatic solvents. If a person vomits when lying on his back, place him in the recovery position. Obtain medical attention.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use dry chemical, CO2, water spray or "alcohol" foam.
Extinguishing media which must not be used for safety reasons
Do not use a solid water stream as it may scatter and spread fire.
Specific hazards
Flammable. The vapour is invisible, heavier than air and spreads along the ground. Can form explosive mixture with air
particularly in empty uncleaned containers. Heating may cause pressure rise with risk of bursting and subsequent explosion.
Flash back possible over considerable distance.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.
Specific methods
In the event of fire, cool containers/tanks with water spray.

Revision Date: 09 December 2009

Page 2 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Remove all sources of ignition. Pay attention to flashback. Use appropriate personal protective equipment. Avoid contact with
skin, eyes and clothing. Wear personal protective equipment.
Environmental precautions
Should not be released into the environment. Do not allow material to contaminate ground water system. Do not flush into
surface water or sanitary sewer system. Prevent product from entering drains. Avoid subsoil penetration. Local authorities
should be advised if significant spillages cannot be contained.
Methods for cleaning up
Sweep up and shovel into suitable containers for disposal. Soak up with inert absorbent material and dispose of as
hazardous waste.

7. HANDLING AND STORAGE

Handling
Use only in area provided with appropriate exhaust ventilation. Avoid contact with skin and eyes. Change out of working
clothes and wash hands before breaks and at the end of the working day.
Storage
Keep away from open flames, hot surfaces and sources of ignition.
Packaging material
Store in original container.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational exposure controls
Engineering measures
As required by the COSHH regulations, the user (employer) must "monitor and maintain the concentration of all hazardous
substances in the air below their occupational exposure limits." Ensure spray booth filters are changed, cleaned and
serviced regularly. Provide adequate ventilation. Equipment used to apply and cure this product must be adequately
exhausted. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general
extraction.
Chemical Name
N-METHYLPYRROLIDONE
(NMP)
XYLENE

ETHYL BENZENE

Exposure Limit Values

EUROPEAN IOELVS
UNITED KINGDOM OELS
= 309 mg/m3 STEL
= 75 ppm STEL
TWA (IOELV): 221 mg/m3
100 ppm STEL; 441 mg/m3
TWA (IOELV): 50 ppm
STEL = 100 ppm STEL
STEL (IOELV): 442 mg/m3
100 ppm STEL; 441 mg/m3
STEL (IOELV): 100 ppm
STEL = 441 mg/m3 STEL
TWA (IOELV): 100 ppm
125 ppm STEL; 552 mg/m3
TWA (IOELV): 442 mg/m3
STEL = 552 mg/m3 STEL
3
STEL (IOELV): 884 mg/m
125 ppm STEL; 552 mg/m3
STEL (IOELV): 200 ppm
STEL = 125 ppm STEL

IRISH OELS
TWA: 25 ppm
TWA: 101 mg/m3
TWA: 221 mg/m3
TWA: 50 ppm
STEL: 100 ppm
STEL: 442 mg/m3
TWA: 100 ppm
TWA: 435 mg/m3
STEL: 545 mg/m3
STEL: 125 ppm

Personal protective equipment

Revision Date: 09 December 2009

Page 3 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. The use of
a suitable mask with particle filter P3 (BS EN 143) and a respirator with an organic vapour filter A2 (BS EN 143) is
recommended.
Hand protection
Solvent-resistant gloves. For prolonged use the gloves should meet the requirements of EN374 preferably with a Class 6
performance level which indicates a breakthrough time of >480 minutes e.g butyl rubber gloves - 0.7mm coating thickness.
For short-term contact the gloves should meet the requirements of EN374 preferably with at least Class 2 performance level
which indicates a breakthrough time of >30 minutes e.g nitrile rubber - 0.4 mm coating thickness. Gloves should be replaced
immediately if signs of degradation are observed.
Eye protection
Safety glasses. If extra protection is required wear a face-shield over the safety glasses or splash goggles. Face-shields are
only effective if worn in addition to safety glasses or splash goggles. Eye wash bottle with pure water.
Skin and body protection
Lightweight protective clothing. Safety showers should be readily available.
Hygiene measures
It is good practice in industrial hygiene to avoid contact with organic solvents by using appropriate protective measures
whenever possible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form:
Appearance:
Odour:
Colour:
pH:

Liquid.
Viscous red liquid.
Amine-like.
Red brown.
7 - 8

Flash point:
Explosion limits:
- lower (LEL):
- upper (UEL):

>39.5C

Specific gravity (g/cc):

1.19 0.02

Boiling point/range:
Melting point/range:
Decomposition temperature:
Auotignition temperature:

>136C
<-24C
>285C
>245C

Vapour Pressure:
Evaporation rate:

<2.31 mmHg @20C

Slower than butyl acetate.

Water solubility:
Solubility in other solvents:

Immiscible.
Only compatible with limited range of solvents. Use of non-compatible solvent may
make product unusable. Please contact Whitford Technical department for advice.

Viscosity:

40 - 45 seconds BS 4 viscosity cup at 23C

Percent volatile by volume:

Volume of vapour from 1 kilo of
product:

79%
<151 litre(s)

Revision Date: 09 December 2009

1.0
15.6

Page 4 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

10. STABILITY AND REACTIVITY

Stability
Stable under recommended storage conditions.
Materials to avoid
Bases. Oxidizing agents. Acids.
Hazardous decomposition products
Combustion produces oxides of carbon (COx) including highly poisonous carbon monoxide. Nitrogen oxides (NOx).
Polymerisation
Hazardous polymerization does not occur.
Conditions to avoid
Keep away from open flames, hot surfaces and sources of ignition.

11. TOXICOLOGICAL INFORMATION

LETHAL CONCENTRATION & LETHAL DOSE TOXICITY FOR PRODUCT COMPONENTS
N-METHYLPYRROLIDONE (NMP), CAS NO 872-50-4
= 2000 mg/kg Dermal LD50 Rabbit
= 2500 mg/kg Dermal LD50 Rat
= 3.1 mg/L Inhalation LC50 Rat 4 h
= 3598 mg/kg Oral LD50 Rat
XYLENE, CAS NO 1330-20-7
= 4300 mg/kg Oral LD50 Rat
= 5000 ppm Inhalation LC50 Rat 4 h
> 1700 mg/kg Dermal LD50 Rabbit
GAMMA-BUTYROLACTONE (BLO), CAS NO 96-48-0
= 1540 mg/kg Oral LD50 Rat
> 2.68 mg/L Inhalation LC50 Rat 4 h
ETHYL BENZENE, CAS NO 100-41-4
= 15354 mg/kg Dermal LD50 Rabbit
= 17.2 mg/L Inhalation LC50 Rat 4 h
= 3500 mg/kg Oral LD50 Rat
Sensitization
No sensitization reponses were observed.
Local effects
Exposure to component solvent vapour concentrations in excess of stated national occupational exposure limits may result
in adverse health effects. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Chronic toxicity
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic
contact dermatitis and absorption through the skin.

Revision Date: 09 December 2009

Page 5 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

12. ECOLOGICAL INFORMATION

Persistence and degradability
Not inherently biodegradable.
Ozone depletion potential
No ozone depleting chemicals are present or used in manufacture.
ECOTOXICITY EFFECTS FOR PRODUCT COMPONENTS
N-METHYLPYRROLIDONE (NMP), CAS NO 872-50-4
Ecotoxicity effects:
832 mg/L LC50 96
4000 mg/L LC50 96
1400 mg/L LC50 96
1072 mg/L LC50 96
4897 mg/L EC50 48
3135 mg/L EC50 96
500 mg/L EC50 72
XYLENE, CAS NO 1330-20-7
Ecotoxicity effects:

8.05 mg/L LC50 96

16.1 mg/L LC50 96
26.7 mg/L LC50 96
13.4 mg/L LC50 96
0.0084 mg/L EC50 24
0.6 mg/L LC50 48
3.82 mg/L EC50 48

GAMMA-BUTYROLACTONE (BLO), CAS NO 96-48-0

Ecotoxicity effects:
220 - 460 mg/L LC50 96
10000 mg/L EC50 17
500 mg/L EC50 48
79 mg/L EC50 96
360 mg/L EC50 72
ETHYL BENZENE, CAS NO 100-41-4
Ecotoxicity effects:
150.0 mg/L LC50 96
9.6 mg/L LC50 96
9.09 mg/L LC50 96
48.5 mg/L LC50 96
32 mg/L LC50 96
14.0 mg/L LC50 96
4.2 mg/L LC50 96
96 mg/L EC50 24
9.68 mg/L EC50 30
1.8 - 2.4 mg/L EC50 48
438 mg/L EC50 96
4.6 mg/L EC50 72

13. DISPOSAL CONSIDERATIONS

Revision Date: 09 December 2009

Page 6 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

Waste from residues / unused products

Classified as hazardous waste according to (national equivalent of EC-Dir. 91/689; disposal of toxic and hazardous waste).
Should not be released into the environment. It must undergo special treatment, e.g. at suitable disposal site, to comply with
local regulations. Use a registered waste disposal company and supply accurate information about the nature of the hazard.
Waste disposal number - 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances.
Contaminated packaging
Contaminated packaging is classified as hazardous waste. Empty containers should be transported/delivered using a
registered waste carrier for local recycling or waste disposal. Waste disposal number - 15 01 08* Packaging containing
residues of our contaminated by dangerous substances.
Fully drained containers which are drop- and scrape-free can be treated as industrial waste, and can possibly be recycled.

14. TRANSPORTATION INFORMATION

UN-No:
Proper shipping name:
Hazard Class:
Packing group:

European Road/Rail (ADR/RID)

1139
COATING SOLUTION contains xylene (Flashpoint 23 - 61C)
3
III

International Air Transport Association (IATA); International Civil Aviation Organization (ICAO)
Proper shipping name:
COATING SOLUTION contains xylene (Flashpoint 23 - 61C)
Hazard Class:
3
UN/ID Number:
1139
Packing group:
III
International Maritime Dangerous Goods (IMDG); International Maritime Organization (IMO)
Proper shipping name:
COATING SOLUTION contains xylene (Flashpoint 23 - 61C)
Hazard Class:
3
UN/ID Number:
1139
Packing group:
III
IMDG Page:
3321
Emergency Schedule (EMS) - Fire:
F-E
Emergency Schedule (EMS) - Spill:
S-E

15. REGULATORY INFORMATION

Contains:

XYLENE
N-METHYLPYRROLIDONE (NMP)

Indication of danger:
Xn - Harmful.

R-phrase(s)
R10 - Flammable.
R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Revision Date: 09 December 2009

Page 7 of 9

Material Safety Data Sheet

XYLAN 4090/F0931 RED OXIDE

S-phrase(s)
S23 - Do not breathe fumes or vapour.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S38 - In case of insufficient ventilation, wear suitable respiratory equipment.
S42 - During fumigation/spraying wear suitable respiratory equipment.
S51 - Use only in well ventilated areas.
S21 - When using do not smoke.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.

United States TSCA:

Canada DSL:
Canada NDSL:
EC-No.
Europe ELINCS:
Korea ECL:
China Inventory:
Australia AICS:
Japan ENCS:
Phillipines PICCS:

International Inventories
One or more chemicals in this product are not listed in the inventory.
All chemicals in this product are listed in the inventory.
One or more chemicals in this product are not listed in the inventory.
One or more chemicals in this product are not listed in the inventory.
One or more chemicals in this product are not listed in the inventory.
All chemicals in this product are listed in the inventory.
All chemicals in this product are listed in the inventory.
All chemicals in this product are listed in the inventory.
One or more chemicals in this product are not listed in the inventory.
All chemicals in this product are listed in the inventory.

Legend
TSCA: Toxic Substance Control Act
DSL: Domestic Substance List
NDSL: Non-Domestic Substance List
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: EU List of Notified Chemical Substances
ECL: Existing Chemicals List aka Existing and Evaluated Chemical Substances
AICS: Inventory of Chemical Substances
ENCS: Existing and New Chemical Substances
PICCS: Phillipines Inventory of Chemicals and Chemical Substances

16. OTHER INFORMATION

Shelf life
12 month(s). Turn container(s) upside down or high speed / shear mix the material(s) every month to maintain quality and
minimise settling. Significant increase in viscosity and / or lower dry film gloss indicates that the coating has exceeded its
shelf life.
Text of R phrases mentioned in Section 2
R10 - Flammable.
R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
R22 - Harmful if swallowed.
R11 - Highly flammable.
R20 - Harmful by inhalation.
R36/38 - Irritating to eyes and skin.
R20/21 - Harmful by inhalation and in contact with skin.
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
MSDS INFORMATION
Revision Date:
Revision Number:
Prepared By:

Revision Date: 09 December 2009

09 December 2009
2
Campbell Wilson, Regulatory Affairs, Whitford Ltd.
cwilson@whitfordww.com

Page 8 of 9

Material Safety Data Sheet

Further information:

XYLAN 4090/F0931 RED OXIDE

Request a product data sheet for further information on properties and application
techniques. Data sheets more than 36 months old may not be reliable: Obtain an up-todate version to be sure information is current.
Note: This material safety data sheet does not constitute an assessment of workplace
risk as required by the Health & Safety at Work Act and the Control of Substances

NON-WARRANTY: The information presented in this publication is based upon the research and experience of Whitford. No
representation or warranty is made, however, concerning the accuracy or completeness of the information presented in this
publication. Whitford makes no warranty or representation of any kind, express or implied, including without limitation any
warranty or merchantability or fitness for any particular purpose, and no warranty or representation shall be implied by law or
otherwise. Any products sold by Whitford are not warranted as suitable for any particular purpose to the buyer. The
suitability of any products for any purpose particular to the buyer is for the buyer to determine. Whitford assumes no
responsibility for the selection of products suitable to the particular purposes of any particular buyer. Whitford shall in no
event be liable for any special, incidental, or consequential damages.

Revision Date: 09 December 2009

Page 9 of 9