Innovene PE products: full market

coverage now and in the future

Dr. Fabian Siberdt

PE Product Manager

SPE conference, Houston

February 2015
Sustainability

New
Products
 Sneak peek at

Growth through strategic partnerships Entrepreneurial & Innovative

JV with PetroChina for

refining and trading

Former JV with BASF (now fully

owned) for the styrene/PS chain

Proposed JV with Solvay for INOVYN

the chlorine/PVC chain
Our polyolefins licensing successes

384
56

The new leading licensor of

polyolefins technology

More than 20 million tonnes of

polyolefins capacity awarded
since 2005
 Our polyolefins technologies
Innovene G Innovene S Innovene PP
Clean loop gas phase Bimodal slurry loops Plug flow gas phase
Swing LLDPE/HDPE HDPE/Bimodal HDPE PP (homo, RCP, ICP)

G S PP
Superior mLL and HAO Superior bimodal HDPE
Superior ICPs
LL products products
Highest product
Unique C4-C6-C8 Unique swing
consistency
comonomer versatility monomodal/bimodal/Cr
operations Unique plug flow
Clean Loop Process
process
High reliability / Low Quick transitions
Short transitions
Maintenance No wax generation
Our future.
The challenge of our
age must be to
decouple human
progress from
resource use &
environmental
deterioration

KMPG: expect the unexpected, building business

value in a changing world, 2012
Our future with polyolefins

Light weight &

durable

Recycling
solutions

Energy recovering
Polyolefins end-use application
 Trends in polyethylene

Metallocene LLDPE Bimodal HDPE

2 x AAGR of LLDPE 1.5 x AAGR of HDPE

Based on POPS data Based on POPS and Towsend Solutions data

 Innovene G product coverage
Application Type 2007 2015
Film LL C4
LL C6
LL C8 Extension of
mLL C6 or C8 mLL grade slate
HDPE New Cr catalyst
Blow Molding Medium Mw Cr Extended offer
High Mw Cr New Cr catalyst
Injection Molding LLDPE
HDPE
Pipe & Conduits Non pressure
PE80 ISO certified black PE80
Textile Monofilament
Tape
Improved tenacity

Rotomolding MDPE
mMDPE
Others W&C
Geomembrane
Extrusion coating Metallocene & Ziegler
Commercial New/improved and delivered Development
 HPLL metallocene product line
25

2007
20
MI2.16 (g 10/min)

15

10

0
910 915 920 925 930 935 940 945
Density (kg/m)
 HPLL metallocene product line
25

2015
20

Injection
MI2.16 (g 10/min)

15

Extrusion
10
coating Roto
5
Film

0
910 915 920 925 930 935 940 945
Density (kg/m)
 HPLL, a unique metallocene product

Reverse Comonomer
LCB
Distribution

Conventional Ziegler Conventional Metallocene INEOS HPLL

Broad MWD Very narrow MWD Narrow MWD
Comonomer decreases with Mw Comonomer evenly distributed Comonomer increases with Mw

High
Comonomer content
Low
Low High Low High Low High
 HPLL, a unique metallocene product

Extrudability

Best processability
Best ESCR
Mechanicals Bubble Stability

INEOS HPLL
Best optics
Solution C8 Metallocene High impact
Conventional Gas Phase
Metallocene
Excellent sealability
Optics Sealability
HPLL, downgauging in film applications

Better processability with

HPLL
Mono Bubble stability comparable
to conventional LLDPE
HPLL was run at 20% higher
Formulation : monolayer 50m output
95% mLLDPE + 5% LDPE

Higher stiffness: Outstanding Optics:

PF6212KJ
formulation HPLL Competitive mPE
formulation formulation

Best balance of mechanical, optical and sealing

Competitive
Haze (%) 7.9
gas phase 9.7
Gloss () 71
metallocene
formulation
66
properties available now with unmatched
processability and lower energy costs
Secant Modulus Dart impact
HPLL, low SIT film based on mVLDPE

HPLL6012 (912)
HPLL6212 (920)
C8 ULDPE (902)

HPLL @ 912 kg/m matches solution 902 kg/m ULDPEs

is very close to metallocene plastomers
but is exhibiting better
Extramechanical
low SITproperties
film
still with superior processability and toughness
HPLL, enhanced extrusion coating

Lower seal temperature - broader

processing window
Tougher seal - higher seal integrity
Highly increased ESCR

Seal strength ESCR

Broader processing window and better package

integrity & ESCR still with superior
processability
 Innovene S Product Coverage
Application Type 2007 2015
Film LLDPE LL C4
HDPE INcrease
Bimodal HDPE High processability
Blow Molding Medium Mw Cr INcrease
High Mw Cr INcrease
Bimodal High stiffness, ESCR & swell
Injection Molding Monomodal
Bimodal High ESCR
Pipe & Conduits Non pressure
PE80
INcrease

PE100 bimodal Low sag PE100
PE100RC PE100RC
Textile Monofilament
Tape
Bimodal High tenacity
Others W&C
Geomembrane
Rotomolding Roto C6
Commercial New/improved Development
 Trends in pressure pipes market

1987: INEOS invented PE100RC

the 1st generation of PE100
Performance level

Low Sag
2.5 m
PE100

PE100
PE80
PE63

1970 1980 1990 2000 2010

 PE100RC

PE100 designed
for alternative
installation
PE100
techniques
Requires sand bed PE100RC
protection Sandless
Laying

Sand protection might represent

up to 50 % of the total cost !
INpipe100SR a new PE100RC reference

1 000 000
Superstress
INEOS INpipe100SR
Limit of testing PE100RC PE100RC
100 000 No break!!
NO BREAK ! PE100
FNCT, time to failure (h)

10 000
PE100RC
ESCR

PE 100
1 000 PE100
Eltex

PE 80
100
PE80

10 Blow
General moulding
Purpose
HDPE
1
0.1 1 10 100 1000 10000

Innovene S is a solution provider for all piping

systems including PE100RC, todays most
performing HDPE grade
Bimodal Blow Moulding

B
 ZBM58-30HS, a new reference

ZBM58-30HS
Bimodal comp. A
Bimodal comp. B
Chromium reference

Superior ESCR and processability multiplying

opportunities for downgauging
 Innovene G Innovene S
Clean loop gas phase Bimodal slurry loops
Swing LLDPE/HDPE HDPE/Bimodal HDPE
Premire platforms

G Bimodal HDPE
mLLDPE / mVLDPE
for all market
S
segments
 Solutions for the new millenium

INEOS 2015 - Innovene, INcat, INcrease, INpipe, HPLL are trademarks of INEOS Technologies