Series ONS SET-1

U .
Code No. 56/1/S
U . U U U-S -cU
Roll No. U
Candidates must write the Code on the
title page of the answer-book.

U - cU 16
- U U U U U-S -cU U
U - 26
U M U ,
- 15 U - U q
10.15 10.15 10.30 U - U
U -S U U
Please check that this question paper contains 16 printed pages.
Code number given on the right hand side of the question paper should be written
on the title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before attempting
it.
15 minute time has been allotted to read this question paper. The question paper
will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will
read the question paper only and will not write any answer on the answer-book
during this period.

U (h)
CHEMISTRY (Theory)

3 U
U 70
Time allowed : 3 hours Maximum Marks : 70

56/1/S 1 P.T.O.


(i)

(ii) 1 5 -U U 1

(iii) 6 10 -U U 2

(iv) 11 22 -U U 3

(v) 23 U U 4

(vi) 24 26 -U U 5

(vii) , U U UU

General Instructions :

(i) All questions are compulsory.

(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.

(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.

(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.

(v) Question number 23 is a value based question and carry 4 marks.

(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.

(vii) Use log tables, if necessary. Use of calculators is not allowed.

56/1/S 2
1. CH25CH 2 CH2Cl U CH32CH22CH2Cl SN1
?
Out of CH25CH 2CH2Cl and CH32CH22CH2Cl, which is more reactive
towards SN1 reaction ?

2. HNO3 U U U U
U U U mU
On heating Zn granules with conc. HNO3, a brown gas is evolved which
undergoes dimerization on cooling. Identify the gas.

3. U U UU S U
?
What type of magnetism is shown by a substance if its domains are arranged
in equal number and in opposite directions ?

4. .....

Write the IUPAC name of the given compound :

56/1/S 3 P.T.O.
5. U SU U ?
What is the reason for the stability of colloidal sols ?

6.
U SUU , U , U U
U
(i) ?
(ii) S ?
(iii) U U UU ?
(iv) ?
For the given cells :
Lead storage cell, Mercury cell, Fuel cell and Dry cell
Answer the following :
(i) Which cell is used in hearing aids ?
(ii) Which cell was used in Apollo space programme ?
(iii) Which cell is used in automobiles and inverters ?
(iv) Which cell does not have long life ?

7. UU S MnO2 KOH S
U (A)
U (B)
(i) (A) U (B)
(ii) (B) ?
When pyrolusite ore MnO2 is fused with KOH in presence of air, a green
coloured compound (A) is obtained which undergoes disproportionation reaction
in acidic medium to give a purple coloured compound (B) :
(i) Write the formulae of the compounds (A) and (B).
(ii) What happens when compound (B) is heated ?

56/1/S 4
8. PdCl2.4NH3 AgNO3
2 AgCl U

(i) U
(ii) .....
When a coordination compound PdCl2.4NH3 is mixed with AgNO3, 2 moles of
AgCl are precipitated per mole of the compound. Write :
(i) Structural formula of the complex
(ii) IUPAC name of the complex

9. Pt
N 2 (g ) 13H2 (g )
2NH3 (g)

U5k
(i) U U
(ii) k U
Pt N g 13H g .
For a reaction : 2NH3 (g) 2( ) 2( )

Rate5k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.

10. U U
(i)
(ii) -U S

MU U
(i) U UU
(ii) UU

56/1/S 5 P.T.O.
 Write the chemical equations involved in the following reactions :

(i) Clemmensen reduction

(ii) Hell-Volhard Zelinsky reaction

OR

How do you convert

(i) Toluene to benzaldehyde

(ii) Ethanoyl chloride to ethanal

11. U f.c.c. SU
400 pm
7g cm23 280 g U l ?

An element crystallizes in a f.c.c. lattice with cell edge of 400 pm. The density
of the element is 7g cm23. How many atoms are present in 280 g of the
element ?

12. H2O2 U U U SU U mU

1.0 3 10 4 K
log k 5 14.2 2
T

Ea U U SU k U -
200 U ( R58.314 JK21 mol21)

The rate constant for the first order decomposition of H2O2 is given by the
following equation :

1.0 3 10 4 K
log k 5 14.2 2
T

Calculate Ea for this reaction and rate constant k if its half - life period be
200 minutes. (Given : R58.314 JK21 mol21)

56/1/S 6
13. (i) U CaCl2 c U?
(ii) S U H2SO4 U H3PO4
? U
(iii) U U U U U ?
(i) Out of silica gel and anhydrous CaCl2, which will adsorb the water
vapours ?
(ii) Out of H2SO 4 and H 3PO4, which one is more effective in causing
coagulation of positively charged sol ? Give reason.

(iii) Out of sulphur sol and proteins, which one forms macromolecular
colloids ?

14. (i) UcU

(ii) h Al2O3 Al c Al2O3 NaOH U
U h U UU
?
(iii) U S U c U ?
(i) Name the method of refining Zirconium.
(ii) In the extraction of Al, impure Al2O3 is dissolved in conc. NaOH to form
sodium aluminate and leaving impurities behind. What is the name of
this process ?
(iii) What is the function of limestone in the extraction of iron from its
oxides ?

15. 298K U E0cell U

2Cr(s)13Fe21(0.01M) 2Cr31(0.01M)13Fe(s)

: Ecell50.261 V

56/1/S 7 P.T.O.
 Calculate E0cell for the following reaction at 298K :

2Cr(s)13Fe21(0.01M) 2Cr31(0.01M) 13Fe(s)

Given : Ecell50.261 V

16. U
(i) Mn 17 U () S
U U 14 U S
(ii) Zn Cr UU
(iii) Eu21 U U
Give reasons :
(i) Mn shows the highest oxidation state of 17 with oxygen but with fluorine
it shows the highest oxidation state of 14.
(ii) Zn is soft whereas Cr is hard.
(iii) Eu21 is a good reducing agent.

17.
(i) 2, 4, 6 UUU U
(ii) 2-UU KOH U
(iii) U S Na UU U

U U
What happens when :
(i) 2, 4, 6 - trinitrochlorobenzene is treated with warm water.
(ii) 2-chlorobutane is treated with alcoholic KOH.
(iii) ethyl chloride is treated with Na metal in presence of dry ether.
Write the equation involved in the above reactions.

56/1/S 8
18. U

(a) U (R-CO-R)
UU (R-CHO)

(b) UU U

(c) U-U

Give reasons for the following :

(a) Aldehydes (R-CHO) are more reactive than ketones (R-CO-R) towards
nucleophilic addition reaction.

(b) Benzaldehyde does not undergo aldol condensation reaction.

(c) Benzoic acid does not give Friedal-Crafts reaction.

19.

Br2 / KOH CH3COCl / pyridine

(i) C6 H5 2 COO2NH41 A B C

NaNO2 / Cu CHCl3 1 alc. KOH

Sn / HCl B
(ii) C6 H5N 21BF42 A C

Complete the following reactions :

Br2 / KOH CH3COCl / pyridine

(i) C6 H5 2 COO2NH41 A B C

NaNO2 / Cu CHCl3 1 alc. KOH

Sn / HCl B
(ii) C6 H5N 21BF42 A C

56/1/S 9 P.T.O.
20. (i) U t - U UU ?
(ii)

(iii) S
PVC, -6, -N

UU U
(i) What is the role of t-butyl peroxide in the polymerization of ethene ?

(ii) Identify the monomers in the following polymer :

(iii) Arrange the following polymers in the increasing order of their

intermolecular forces :

PVC, Nylon-6, Buna-N

OR

Write the mechanism of free radical polymerization of ethene.

56/1/S 10
21. (i) U U U UU
(ii) U
(iii) UU U U U U - U
(i) Write the name of two monosaccharides obtained on hydrolysis of maltose
sugar.
(ii) Name the vitamin whose deficiency causes convulsions.
(iii) Write one example each for Fibrous protein and Globular protein.

22. (a) [CoF6]32 U, U U S

(.. Co527)
(b) [Co(en)2Cl2]1 U

(a) For the complex [CoF6]32, write the hybridization, magnetic character
and spin of the complex. (At. number : Co527)
(b) Draw one of the geometrical isomers of the complex [Co(en)2Cl2]1 which
is optically active.

23. S U . S U U
U UU
M U . S . U
mU h U U U U . S
U U U U U
U
U U U U
(i) . U mU ( ) ?
(ii) UUU ?
(iii) U$U ? U

56/1/S 11 P.T.O.
 Due to hectic and busy schedule, Mr. Awasthi made his life full of tensions and
anxiety. He started taking sleeping pills to overcome the depression without
consulting the doctor. Mr. Roy, a close friend of Mr. Awasthi, advised him to
stop taking sleeping pills and suggested to change his lifestyle by doing Yoga,
meditation and some physical exercise. Mr. Awasthi followed his friends advice
and after few days he started feeling better.

After reading the above passage, answer the following :

(i) What are the values (at least two) displayed by Mr. Roy ?

(ii) Why it is not advisable to take sleeping pills without consulting doctor ?

(iii) What are tanquilizers ? Give two examples.

24. (a) U

(i) H2S H2Te

(ii) PCl3 PCl5

(iii) h

(b) (i) HClO4 (ii) XeOF4 U U

(i) S
H3PO3, H3PO4, H3PO2

(ii) He U Xe U U ?

(iii) U U S ?

(iv) U

(v) SO2 U?

56/1/S 12
 (a) Account for the following :
(i) H2 Te is more acidic than H2S.
(ii) PCl5 is more covalent than PCl3.
(iii) Boiling points of interhalogens are little higher as compare to pure
halogens.
(b) Draw the structures of :
(i) HClO4 (ii) XeOF4
OR
(i) Arrange the following in the increasing order of their reducing
character :
H3PO3, H3PO4, H3PO2
(ii) Out of He and Xe, which one can easily form compound and why ?
(iii) Write the conditions to maximize the yield of ammonia in Habers process.
(iv) Write two uses of Chlorine gas.
(v) How can you detect the presence of SO2 gas ?

25. (a)
(i)

(ii)

(iii)

56/1/S 13 P.T.O.
 (b) -
Conc.H2SO4 / 413K
2CH3CH2OH CH3CH2 2 O2 CH2CH3

(a) U
(i) CS2
(ii) NaOH S U U
(iii) HI
(b)
(i) U U U
(ii) U t-U
(a) Write the product(s) in each of the following reactions :

(i)

(ii)

(iii)

(b) Write the mechanism of the following reaction :

Conc.H2SO4 / 413K
2CH3CH2OH CH3CH2 2 O2 CH2CH3

56/1/S 14
 OR

(a) Write equations of the following reactions :

(i) Bromine in CS2 with phenol

(ii) Treating phenol with chloroform in the presence of aq.NaOH

(iii) Anisole reacts with HI

(b) Distinguish between :

(i) Ethanol and Diethyl ether

(ii) Propanol and t-butyl alcohol

26. (a) U 50 g Na2SO4 (M5142

g mol21) 2 g U Na2SO4

(Kb 50.52 K kg mol21)

(b) U

(i) U (ii) U

(a) CS2 100 g 2.56 g U 0.383 K

U (Sx) U

(Kf CS2 53.83 K kg mol21 U . 532 g mol21)

(b) 0.9% U UU U U
U ?

(i) 1.2% U UU

(ii) 0.4% U UU

56/1/S 15 P.T.O.
 (a) Calculate the boiling point of solution when 2 g of Na 2 SO 4
(M5142 g mol21) was dissolved in 50 g of water, assuming Na2SO4
undergoes complete ionization.

(Kb for water50.52 K kg mol21)

(b) Define the following terms :

(i) Colligative properties (ii) Ideal solution

OR

(a) When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point
lowered by 0.383 K. Calculate the formula of sulphur (Sx).

(Kf for CS253.83 K kg mol21 Atomic mass of Sulphur532 g mol21)

(b) Blood cells are isotonic with 0.9% sodium chloride solution. What happens
if we place blood cells in a solution containing ?

(i) 1.2% sodium chloride solution

(ii) 0.4% sodium chloride solution

56/1/S 16