Excess properties | iy Resioual properties : gas ideal sol 15 Al moleuila fares are thesan® Guy =Z¥e SF KCD +8 Tal) Teeny} RT lage CRIED = 0 ertngyag nig 244-0 Teer ‘deol gos eee MCT 7 +R THM) Fron O: Sie Bale), t Ree) Point Bz Hale esos Zag eR ASH = REM geal atte Fores aceite . a pale | For sok Bee RE ct. agecantiy —Teh Rrg im ste dant 50 phen kendon Mee | a ead autem alle, D+ em pee 2% ret Dane Rr She oe a ay aes fo Sn 28 =O ie” Fete Gre = Zxehe +00 “Fotmcon ay (clea! 7 T< Te C2phase? 9 itty aces key cep Amo A =xC = h)-+ Xo Crh ha) Residual Propertis fer Qi Ted t RATING fl bee} Fen t RT hf filey J tteanclealor irteoe%0"5 core im Excess Properties p— reyerence state Geo Pry er) — GACT Xe J=RTD a Pure w=] diluton'k'=O vnitadatty of | A= | jh FS (c-dilution) — fy T, P fixed yn Saw. Sh (pute 1) otonCreny saan) t 5 (pure 2) < f; fi Aewis Rendall 0 ‘Typical f variation fora miscible 1-2 binary solution = T afuite ilvie referen@ XO i f= Bias Fax Proticy VE) wyeee B= 1PXad, ST hhe MPP SKE 1 he uth, Real Sdea 2 XP conveotion [solve —2'safote eve dlatate fron Hearys tye deviation fron L RC E=HE) Hlolecular Aspectay- Mixing pure i referene stoke eee ee fie] =F pm sot fuged ee a-Yq=¥=8 & = eR Toeal-gos mite | Non ideo|-gac mixture | GIT we soltin i otal = TrCaypdy RTIn Xi = Tt RT fixe fon ida solo" | Gia TTP) + RTMCH: CT be) ERT CYP Cie TiCTs thor) +I HC, PA) Bi STOR THK AAPeB>2A'B € =L2ne-Cumt wos) z- E ron EXo fav E20 Slate else pores! ices Propaties of Solution _ xi) ween mh = Fen eth di® = renee 2 ABT Terepresents “he alewasion Fx GS £. fomihus prichicted by LR aide Lewis/Rondall Rule! £tR = xfs Cs + Angas dan) GFeRTHH Fe 7H)! GP RTInGGiteetnn > lotr =P) 3(%)- Gee eT +2 Bete 48) =4haP- Ear 4 Zhndni o d(45)= Gear heats Z nani Y fp actin) one, C80), 6 CBO) Thasstoge efjaxte Pon GE ” een 2 (ooh HEP BE len “BE yer > ey § wi!) 6. yee EHCRINN) > ETH Binwy slutton: P= Kiln + Haha 8) =o lt eaCrantad= Nasa, Bem) ghee Inv, = In¥o. CAS) (4) Kah Ba i - 9 2D (oa Yolndst Uhy, = Yylarg +¥, ht hy, 2 eee ot In = ayer ~ % SRD ubiconperem sys Ini F- F ve AL), oun “tmp see that bs cs offected ky otha camponenrs ~) "eit" 5 Frat i Ini SE? > SCRA = ind. Adlets 5%dleti.dhts %dhk, Linke x il Ady, Ox, 55 ayy” IR chad diet dits yb dak ainCr 7d wh A A oS xd Gibbs/tuhen ean’ SAT + VP or = Stat +YFAP = RT ZKAlnhi const TPs Sx? = 0 9 ZaetmV =D t " \n ler A xl ° tot Xialy, + Xaetlor, =p BO YI lh a Sa + Hol 0 9A “yonple: tyre’) In benzeoe ci) Comte Ye Apdinenialess ESS in YA HME = 20 AM (-Wahige 2A Coy Ax, We ok te anit +, DAyAY, life Ya Alle) chen Sapes sIntivs ¥y Ing vs. x, ae dey hy) or Inf, 7D portal alvbiity wera certain rangeok T ye der a, <) (GRE tke. H bonding) shaw Complex turctiqnalines wined SH ont Many Lig, mixtores compssitin —» Group codtribut ions SE ag mixity are plotted VS ° ss He Actuy wetticient Madels wy 0 HL Zedlex=0 Caro ssuce gh peo ssuber| (20 Fae fs ebteain SE, = Av ees) 4s} OC ¢ A > % g Marques E49» omit forms atte: I: Sere, = AaiXit Ata X Ine That 20a Aad)X) ini Aa ne =¥P LA 2CA-Aay) Xo) Ind =Aae 14 the 2 components are alice Ara = Az GF = Ara RTVi% = ACD YAS lramen/asvilie 47 Von Law Gy" e saa? At BCX-X2) Side A ERCX)—%) = CAB IK TCAYD Se 5 : ; ler gig =A) pom = Ae Rk Kath Xo > ay oy 82 Inte AC ABLES? Insane tet) Yi 20 tO ven faor user dof Sal wit hp Ottevtve F AsslnnCeSEBY? Agt= tne ple)” Therrodiynamic LOnsistenoy oF > y Xu ae “alo ea 0 AER) ink o-@ 0! SCE Miaa= Ine dat” 5 yale” dee if @-@=0 "" ‘ of + 45h Marques 92,=CA Kae 8K) — DX m2Applicarions a 2, ant 7 in Plase Eq liberia Val eqplorions a Gis by pater el a) ig FoR: Murex PB Fer For Low FB) 21 Puaxik PM AU = UF2QU git > tn DU ignin pice 2 = Ky + 2X6 BOE HOR por Xs 2X2 Xb) + 62 a = wa ABE)? Lg 0S °= 0% =0) TL eapilbn — LE RP a ee ote sda Gea - L epilibriom Ags asc) tov solebil'ty in Solvent C1) a §, = PH = Haga om Yar0 G9] opie ct constbatT omy © Gi = 1p C1+ RTIn Bi aGyey, VaaP= RTaIng; po Ee Ha Sib vt Ptah) We» (THEE inks vata) Se he > Se =e RT TE Tat K Tega? 2” dp FP since stot a ely Is onoked GP ap Be ae InHa,= (0 Be Infrhlast Bro fos on a Ips Rt 3 nba Hil Sf BaP p “es 5 stent QQ) inl Vapour prESUE oy solver Renens te slope a i AA, PF cones Ao nye + Svrer ge e bn Sebia t vee B= In sol I) The ae drm wh a> 5 wer FD CORT Hay = Henny Theoretie| made eb activity (pedticients Wells Expoasin dar Excess Erercy ; Es g2 est Bur BB HOES dash Gone aria oh, Bae mslenuls vl Sphe< 2 Bue, BaEa ie, as ineracction parameter & Chat M2275 8222 +3022.) 5 [C dee + BaysdKi, +C24 2 t Bamd%ete] AA AgeiC 202 + 3am); Aer = C242 + 30.0) [i SE acnater ae Ma HEALS] aay lab = Dem dean Ine Zo Rast 2&\C Ane, ~ An) Iyyed 2%. Aeg, ~Aa)) Conporlson with Von Lor Ayiz2ante | Ary= 2842 Fheamtial implication af von L sar Mele! Degube sol assumption CS*2Y°=D) > uF =g® roth BDlkinerc prgerteslescbed by VOW an (3 ) =f “a3 G) Ener mig ten OneCXA 4 Yo BY bi con/mel ) QV misiyton beex8 + Xabe @) ep Aula =f Sane ion i niet ny uc icf con dentin a Pseudo ~iAeol HS (wir 41g] Mine vie [i solution & Alisa, Nis +75 Ba 2 Usiy nts C2CRAE ay, >A -%) Oo kee Oe an Cw ey inne Boel Se) “at nto Bir 9) ; dna = AraC AOL)? Tyg Aa? Cin fete) Aa: GR, Aa obit. Yl G71 Remy 6. BHI Crete il 9 b%aba eerie!) — bi cui/ee) By 22 baal aCe) Uccni/mel) 3 sudex Morguies Gan fer #2) 2-44 [ny = Xe Any #2%1Aar-Ara)) = Axe 8 In¥y = X2CAait 2XQCAr2 ~ Aa) = CAE KA BX Scortchinek Hildebranel 240a+i0q % In =22 (Ayr 22 Asie) | Mg=2i Aa t 22aC Aree Ay) wa Aa 1-53)? Ae bey BEI 5; > soidiy promoter VBE (5,-8.5 Inty> AES -Ba)™ bie - hv =(42 92 a oe ern ve Theory * reyilarsol: sS=y7=D tebiitin’ C= SU (' 7) vor Grey chaige per tsotherma) voparization of the AU: SCR Bagi so she ideal ges state. CVD Obes Cem Behe Poa va xe c= chesive aensity VETTE. = yelomed ae = = CMM Xo Va )ECyh4 2E0H A + Gai 3 NAVaes Toleal gesture Wa RE Va. Liquid mst & | ood, Xe Use? Kec? = Ut) ¥ICUs ut) + Dusk +cus Ud) = ORY AYO MMB LEnt Cane Ze) 2 UE Dub =Oa trl HA, [a Be) ~CM Ph BALES jor : aka (2 8, 96a> rs prema ogre | 89 a ta robe apvet | 2 a yt gE Ube Cay tale) HLS. 21? a Rthr=V47LE-S2)> RT = va#708.-82) red Gia -EaGas S52 Wrilathamic Bh 70 Si S.C4et) = feikg, con veoh ek lente vnterocisest Cle ty 2 feta + 2ki2 Luce J 18 [c5,-5, 2c] Fhe genetic man Cia Cart kn ea Tel QF = Oh Wa eI 6 Orca ~ Ind = SB Sa) 228] Inde [hittwe Ven Laat 30.Exxcess Furenion ant Partial Misco lity AGpax °2Unact PAV TAS AAU = TAS “Spon mis | yen beng, Elo ace Pe = FAG > Bux 719+ Kae +A Dove Gout Te Ahmix 20 Cara blmy witiyee , 2 pore compacens Bni< O 4&4 RTD sInKi IE TH Ini thor toe CX INR FXDIOYA) 15 a X= 0. Moghes= int eS uznees vu Bas Se ae ee) Sears [ee ey) ee EZ titi, SESIA ret TF at seortn chat insti ty Ab ome Po Cri) attr & Baa decvntie SO . te ess! ; sr mupoamy oh 2% 2 8 C2 Tan Boor Binodle) 2,eass at 6B om Bouraa ez) J Dh IBA 344, los Aly - C41 2] "7 Sie lten’ le ten Hl ret Gputedel = 9 Sune che iol pwtetial otol once wptenis70 Bimodet ° ° a Teng n & r 2 Hence g ¢ Bo and é ‘meani Reglen lot cumeiscible (f 229qp'S, Bee ® 1 Bee er Sot alas orb 2 pasts E+ RTCK IK Fea bxa)]- © 1 FAG Fm. yf Lt ees 229% 7 axe aKF RR HE) Br 5470 5 6 nomiigif Qo 961 [Te criticeisol Tr 7 TS > come toh Pp compretely miSaeie PAG, y 229 fr< Te partsi mise 42098) | deri Te SHE) Mae lo tren 6), MASP a Cees) ae Inaclagthx, J etlnt? 2) inne BeXEHInX By 7), bas Ma ad min ud rh conditions A bar Loy ot cating 33.20. Ge) aE) OF 93 70 Jara e vasfiatin o bitaryorgmic rtios = OE oF ase ook ore * ne eae Osntis Equation LL LE or equi fern) MEP EM LCA) xT PACT PET) a [= oPexplYVRTD >-In Lear ctlte sos isdnioa in A Phase Hohe 94 yy winks= Bee = In = IMC |-¥3) Sa vies Xa 9D Bees Ye My BER MARTE TINY = MS HY" Tvs ERT OER, Comin) entroy diving force Asseption (© dilute solution @ Incompressible soe fe con rewrite the nial ea) fron Gite ow uy cB + Go) ste ve ve a ese, BION Fae) cownlag, DRT te Cet) OB 2 G Sin Bat Celt) > fain 178K 1st