ALL INDIA SENIOR SECONDARY BOARD PRACTICAL 2017

SUB : CHEMISTRY
I. Volumetric Analysis 10 Marks

a) Estimation of Potassium permanganate using standard FAS

1. Simple procedure
Pipette solution : 20 ml of standard FAS
Burette solution : Potassium permanganate
Medium : Equal volume of 4 N sulphuric acid
Temperature : Room temperature
Indicator : Self (Potassium permanganate)
End point : Appearance permanent pale pink colour
N-factor
i. FAS (a) :1
ii. KMnO4 (b) :5
Molecular weight of KMnO4 : 158
2. (a) Calculation of molarity of standard FAS solution
Weight of FAS : _____________
w
Molarity of Std. FAS =
M v
= ______________M
3. Principle
Reduction half
MnO-4 + 8H+ + 5e- Mn2+ + 4H2O
Oxidation half
Fe2+ Fe3 + + e- 5

Over all reaction
MnO-4 + 5Fe2+ + 8H+ 5Fe3 + + Mn2 + + 4H2O
4. Tabular column

S. No Volume standard Burette reading Volume of

Concordant value
FAS Initial final KMnO4

5. Calculation of Molarity
Volume of Std. FAS (V1) : 20 ml
Molarity of std. FAS (M1) : ____M
Volume of KMnO4 (V2) : ____ml
Molarity of KMnO4 (M2) :?
According to law of volumetric analysis
V1 x a x M1 = V2 x b x M2
 V1 a M 1
M2 =
V2 b
= ______________M.
Molarity of KMnO4 = ________________M.
6. Calculation of strength
Strength of the given KMnO4 solution = Molarity x Molecular weight
= ____________ gram/litre
7. Result
i. Molarity of given KMnO4 solution = ___________ M.
ii. Strength of the given KMnO4 solution = ___________ g.

b) Estimation of Potassium permanganate using standard Oxalic acid

1. Simple procedure
Pipette solution : 20 ml of standard Oxalic acid
Burette solution : Potassium permanganate
Medium : Equal volume of 4 N sulphuric acid
Temperature : 60 to 70 C
Indicator : Self (Potassium permanganate)
End point : Appearance permanent pale pink colour
N-factor
i.Oxalic acid (a) :2
ii. KMnO4 (b) :5
Molecular weight of KMnO4 : 158

2. (a) Calculation of molarity of standard Oxalic acid solution

Weight of Oxalic acid : _____________
w
Molarity of Std. Oxalic acid =
M v
= ______________M
3. Principle
Reduction half
MnO-4 + 8H+ + 5e- Mn2 + + 4H2O2

Oxidation half
C2 O24- 2CO2 + 2e- 5

Over all reaction
2MnO-4 + 5C2 O24- + 16H+ 10CO2 + 2Mn2 + + 8H2O
4. Tabular column

S. No Volume standard Burette reading Volume of

Concordant value
Oxalic acid Initial final KMnO4
 5. Calculation of Molarity
Volume of Std. Oxalic acid (V1) : 20 ml
Molarity of std. Oxalic acid (M1) : ____M
Volume of KMnO4 (V2) : ____ml
Molarity of KMnO4 (M2) :?
According to law of volumetric analysis
V1 x a x M1 = V2 x b x M2
V1 a M 1
M2 =
V2 b
= ______________M.
Molarity of KMnO4 = ________________M.
6. Calculation of strength
Strength of the given KMnO4 solution = Molarity x Molecular weight
= ____________ gram/litre
7. Result
i. Molarity of given KMnO4 solution = ___________ M.

ii. Strength of the given KMnO4 solution = ___________ g.

II. Content based experiment: 6 Marks

As given in record note

III. Salt analysis 8 Marks

a. Preliminary test
(i) Colour /appearance
(ii) Smell
(iii) Solubility
(iv) Action of heat
(v) Flame test
(vi) Ash test
b. Identification of acid radical
(i) Action of dil. HCl
(ii) Action of Con.H2SO4
(iii) Copper turnings test
(iv) Chromyl chloride test
(v) MgSO4 test
c. Sodium carbonate extract preparation
(i) AgNO3 test

(ii) BaCl2 test

 (iii) Brown ring test
d. Identification of basic radical
Preparation of original salt solution
Few grams of salt is dissolved in 15 ml of water/ dil.HCl and taken as original salt solution
(i) Group separation. (upto the group)
(ii) Confirmatory test for basic radical
e. Result
(i) The given acid radical is _________.
(ii) The given basic radical is _________.
(iii) The given simple inorganic salt is _________.
IV Project 2 Marks
V Viva-voce 2 Marks
VI Record 2 Marks