Warning over tanks for chemicals,

water, wastewater
2 Sep 2009

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Tanks for use in the chemical storage and processing and the water & waste treatment industries
must not be taken as a commodity. Tanks must be safe, as the liability & risk to personnel & the
environment is extremely high. To the engineer without experie
Careful study is essential ahead of specifying plastic tanks, wrties Lee Forbes chairman of BS
4994-1987 & a member of BSI committee for EN 13121. He is co-founder of Forbes Group with
49 years' experience in the thermoplastic & GRP chemical tank, vessel & gas scrubber industry:

London - Tanks for use in the chemical storage and processing and the water & waste treatment
industries must not be taken as a commodity. Tanks must be safe, as the liability & risk to
personnel & the environment is extremely high. To the engineer without experience in the
selection of materials and design, tanks seem to be simple structures, almost bought from a
product catalogue.

This approach can easily lead to failures within the lifetime of the tank. It is essential the design,
materials of construction and type of manufacture are carefully assessed to meet the application
and design life required, at the same time producing the most economic solution. Often an
inadequate tank is selected by the purchaser purely on economic grounds to meet a demanding
budget.

Virtually all tanks are regarded as a long-term capital investment. In particular the Water
Industries often demand at least 20 years design life. Therefore selection of the design
Standards & materials of construction must follow suit.

No matter what the application is, it is essential the purchaser fully engages with the
manufacturer to ensure a safe, correctly designed tank, is selected. Part of this initial selection
process involves the critical factor relating to the materials of construction. Do not be misled by
the manufacturer who can only offer very limited choice of materials.

Look at the potential long-term effect of the contents on the materials of construction. This is
particularly important when handling liquids in thermoplastic tank where the thermoplastic is not
only the chemical resistor but also the load bearing structure. All plastics suffer from a small
degree of permeation and many engineers discount this long-term effect on the polymeric
structure, which can lead to environmental stress cracking or softening of the material.

Always insist on certified design Standard with full design calculation thus ensuring the tank will
meet requirements. Despite what some people think, materials can have a relatively short life
due to degradation when the tank shell is under load. Long-term exposure to a number of
chemicals when under stress can induce environmental stress cracking. .

Material selection is always a difficult area for the purchaser to consider, with various claims
being made in relation to expected service life, by different manufacturers. The safest approach
is to fully engage with an experienced manufacturer who can demonstrate successful long-term
applications. The next safeguard is the requirement for detailed design. The product must be fully
compliant to a recognised British or EU Standard without exceptions.

The suggested selection process includes:

Material selection
 a) Thermoplastic as the chemical resistor and load bearing structure

b) Glassfibre reinforced vinylester & polyester (GRP or FRP) laminate with a composite inner
corrosion barrier

c) Thermoplastic inner shell corrosion barrier being the chemical resistor with the external GRP
laminate being load bearing structure, this being fully protected from the effects of the contents.
Examples of such tanks, in continual service for over 35 years, can be demonstrated by Forbes.

The area, which is not always addressed by the manufacturer, is proven expected long-term life.
All materials have a degree of degradation over time, particularly in chemical environments.
There are reduction factors published in EN 1771 for a number of chemicals in contact with
thermoplastics, where permeation does have an affect on the physical properties of the material.

For GRP tanks & pressure vessels, long term experience to be demonstrated by the
manufacturer or apply the guidance notes in BS 4994 - 1987 which will give the appropriate
safety factor.

Typical examples of points to raise with the manufacturer

1. The long term chemical resistance is confirmed, with examples. Whilst the corrosion
resistance charts indicate satisfactory resistance, if the thermoplastic is also acting as the load
bearing structure, ensure the design gives a low level of strain as environmental stress cracking
can occur long term. Many chemical resistance charts are based on short term testing only.

2. Ensure the grade of thermoplastic is correct for the application..

3. Confirm there is no risk of temperature excursions beyond the design temperature. The
mechanical strength of thermoplastics rapidly reduces with relatively small increases in
temperature of the contents.

4. Ensure the chemical resistance for GRP is compatible for the resin selected and a low level of
strain is maintained, thus avoiding the risk of strain corrosion.

Design Selection To achieve long term safe working product, it is imperative the tank is
designed to a recognised Standard. This will reduce the purchasers Healthy & Safety liability in
the event of anything going wrong during the working life of the tank. It is important that all
aspects of the chosen Standard are met, with statements such as covered by the relevant parts
of the Standard to be treated with a high degree of suspicion.

Prior to specifying & manufacturing items to the relevant Standard the following information must
be agreed & documented between the purchaser & manufacturer & confirmed by the
manufacturer prior to design & manufacture:

1. Details of the liquids to be handled including any trace contaminants

2. Confirmation of chemical resistance of the thermoplastic & the agreed reduction factor for
the long-term effect of the contents on the material of construction as detailed in EN 1771. For
GRP structures where the inner corrosion barrier is a chemical resistant laminate such as
vinylester, long-term test results for the particular application.
3. Maximum operating temperature
4. Design temperature
5. Safety factor
For thermoplastics - BS EN 12573 - for guidance see EN 1771 (example below)

Type of loading & application Safety

 Factor

Static load at room temperature and constant conditions. No possible

1.3
danger to persons, objects & the environment in the event of failure

Loading under alternating conditions (e.g. temperature, filling levels).

Possible danger to persons, objects & environment in the event of a 2.0
failure,

The factors of safety in above table are for two loading cases depending
on the potential hazard posed by the tank. In each individual case, the
designer / engineer shall decide which classification is appropriate for
the tank being designed & what level of safety factor is to be used.

For GRP and GRP with inner corrosion barrier of thermoplastic, the safety factor is calculated
within BS 4994 -1987 & EN 13121-2/3.

6. Configuration & detailed dimensions (i.e. flat base, conical or dished base, sloping base,
conical. Dished or flat top. The less preferred configuration of a horizontal or rectangular tank).
7. Operating pressures
8. Design pressures
9. Site conditions temperatures, wind & snow loadings.
10. Hazardous area requirements
11. Imposed loads personnel, equipment, brackets holding external equipment, agitator
supports and access ladders and platforms.
12. Operating conditions including filling & emptying velocities or agitation, which may cause
vibrations and tank moment.
13. Method of support (i.e. flat full plinth or platform or skirt specially designed cradles for
horizontal configurations) & holding down design
14. Nozzle connections, size, standard & layout, including how safe access can be gained
when is service.
15. Seismic loadings (if applicable)
16. Site access & layout
17. Transportation, installation & handling.
The operating requirements specified by the tank owner and the calculations by the supplier to
determine the design life and critical features of the tank should form the basis of the
documentation retained for the life of the tank.

For thermoplastics for demanding duties, use the extensive German Standard DVS 2205. A less
demanding Standard EN12573 (which many engineers consider is lacking in a number of areas)
will give you basic design parameters but does not address many areas covered in DVS2205.

For GRP /FRP and thermoplastic / GRP reinforced products apply the very comprehensive BS
4994:1987. The recent issue of EN 13121-3 has caused much consternation within the industry.
This standard is primarily a pressure vessel code for GRP vessels up to 10-bar pressure rating to
meet the European Pressure Equipment Directive (PED)

Due to the sheer complicated nature of EN 13121-3 code, coupled with an estimate of over forty
errors within the document, there are suggestions from the industry that EN 13121-3 is
withdrawn and the well proven BS 4994-1987 remains the mainstay for the design and
manufacture of safe and reliable tanks and vessels which can exceed 200 cubic metres in
capacity.
The most important message is to fully engage with the manufacturer to build a confident
working relationship. Where the major problems have occurred in the past and are still being
seen in the current financially restricted market - Do not buy purely on price.

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chemicals-water-wastewater