ekad

fok; dksM iqfLrdk dksM

H 2015 (II)
A
jlk;u foKku 1
Lke; : 3:00 ?kaVs
izu i= Ikw.kkZad : 200 vad

vuqnsk

1. vkius fgUnh dks ek/;e pquk gS A bl ijh{kk iqfLrdk esa ,d lkS iSarkyhl (20 Hkkx 'A'esa + 50 Hkkx
'B' + 75 Hkkx 'C' esa ) cgqy fodYi izu (MCQ)fn, x, gSa A vkidks Hkkx 'A' esa ls vf/kdre 15
vkSj Hkkx 'B' esa 35 izuksa rFkk Hkkx 'C' esa Lks 25 izuksa ds mRrj nsus gSa A ;fn fu/kkZfjr Lks vf/kd
izuksa ds mRrj fn, x, rks dsoy Hkkx 'A' Lks 15,Hkkx 'B' ls 35 rFkk Hkkx 'C' ls 25 igys mRrjksa dh
tkap dh tk,xh A
2. vks,evkj mRrj i=d vyx Lks fn;k x;k gS A viuk jksy uEcj vkSj dsUnz dk uke fy[kus Lks igys
;g tkap yhft, fd iqfLrdk esa i`B iwjs vkSj lgh gSa rFkk dgha Lks dVs&QVs ugha gSa A ;fn ,slk gS rks
vki bfUothysVj Lks mlh dksM dh iqfLrdk cnyus dk fuosnu dj ldrs gSa A blh rjg Lks
vks,evkj mRrj i=d dks Hkh tkap ysa A bl iqfLrdk esa jQ dke djus ds fy, vfrfjDr iUus
layXu gSa A
3. vks,evkj mRrj i=d ds i`B 1 esa fn, x, LFkku ij viuk jksy uEcj] uke rFkk bl ijh{kk
iqfLrdk dk ekad fyf[k,] lkFk gh viuk gLrk{kj Hkh vo'; djsa A
4. vki viuh vks,evkj mRrj i=d esa jksy uacj] fok; dksM] iqfLrdk dksM vkSj dsUnz dksM ls
lacaf/kr leqfpr o`rksa dks dkys ckWy isu ls vo; dkyk djsaA ;g ,d ek= ijh{kkFkhZ dh ftEesnkjh gS
fd og vks,evkj mRrj i=d esa fn, x, funsZ kksa dk iwjh lko/kkuh ls ikyu djsa] ,slk u djus ij
dEI;wVj fooj.kksa dk lgh rjhds Lks vdwfVr ugha dj ik,xk] ftlls varr% vkidks gkfu] ftlesa
vkidh vks,evkj mRrj i=d dh vLohd`fr Hkh kkfey gS] gks ldrh gS A
5. Hkkx 'A' rFkk Hkkx 'B' esa izR;sd izu ds 2 vad 'C' esa izR;sd izu 4 vad dk gS A izR;sd xyr mRrj
dk _.kkRed ewY;kad 25 % dh nj ls fd;k tk,xk A
6. izR;sd izu ds uhps pkj fodYi fn, x, gSa A buesa Lks dsoy ,d fodYi gh lgh vFkok loksRZ re
gy gS A vkidks izR;sd izu dk lgh vFkok loksRZ re gy <wa<uk gS A
7. udy djrs gq, ;k vuqfpr rjhdksa dk iz;ksx djrs gq, ik, tkus okys ijh{kkfFkZ;ksa dk bl vkSj
vU; Hkkoh ijh{kkvksa ds fy, v;ksX; Bgjk;k tk ldrk gS A
8. ijh{kkFkhZ dks mRrj ;k jQ iUuksa ds vfrfjDr dgha vkSj dqN Hkh ugha fy[kuk pkfg, A
9. dsydwysVj dk mi;ksx djus dh vuqefr ugha gS A
10. ijh{kk lekfIr ij fNnz fcUnq fpfUgr LFkku ls OMR mRrj i=d dks foHkkftr djsaA bfUothysVj dks
ewy OMR mRrj i=d lkSaius ds ipkr vki bldh dkWcZuySl izfrfyfi ys tk ldrs gSaA
11. fgUnh ek/;e@laLdj.k ds izu esa folaxfr gksus@ik;s tkus ij vaxzsth laLdj.k izekf.kd gksxk A
12. dsoy ijh{kk dh iwjh vof/k rd cSBus okys ijh{kkFkhZ dks gh ijh{kk iqfLrdk lkFk ys tkus dh
vuqefr nh tk,xh A

jksy uacj
vH;FkhZ }kjk Hkjh xbZ tkudkjh dks eSa lR;kfir djrk gw A

uke ................................
bfUothysVj ds gLrk{kj
 2

FOR ROUGH WORK

 3

LIST OF THE ATOMIC WEIGHTS OF THE ELEMENTS

Element Symbol Atomic Atomic Element Symbol Atomic Atomic

Number Weight Number Weight
Actinium Ac 89 (227) Mercury Hg 80 200.59
Aluminium Al 13 26.98 Molybdenum Mo 42 95.94
Americium Am 95 (243) Neodymium Nd 60 144.24
Antimony Sb 51 121.75 Neon Ne 10 20.183
Argon Ar 18 39.948 Neptunium Np 93 (237)
Arsenic As 33 74.92 Nickel Ni 28 58.71
Astatine At 85 (210) Nlobium Nb 41 92.91
Barium Ba 56 137.34 Nitrogen N 7 14.007
Berkelium Bk 97 (249) Nobelium No 102 (253)
Beryllium Be 4 9.012 Osmium Os 76 190.2
Bismuth Bi 83 208.98 Oxygen O 8 15.9994
Boron B 5 10.81 Palladium Pd 46 106.4
Bromine Br 35 79.909 Phosphorus P 15 30.974
Cadmium Cd 48 112.40 Platinum Pt 78 195.09
Calcium Ca 20 40.08 Plutonium Pu 94 (242)
Californium Cf 98 (251) Polonium Po 84 (210)
Carbon C 6 12.011 Potassium K 19 39.102
Cerium Ce 58 140.12 Praseodymium Pr 59 140.91
Cesium Cs 55 132.91 Promethium Pm 61 (147)
Chlorine Cl 17 35.453 Protactinium Pa 91 (231)
Chromium Cr 24 52.00 Radium Ra 88 (226)
Cobalt Co 27 58.93 Radon Rn 86 (222)
Copper Cu 29 63.54 Rhenium Re 75 186.23
Curium Cm 96 (247) Rhodium Rh 45 102.91
Dysprosium Dy 66 162.50 Rubidium Rb 37 85.47
Einsteinium Es 99 (254) Ruthenium Ru 44 101.1
Erbium Er 68 167.26 Samarium Sm 62 150.35
Europium Eu 63 151.96 Scandium Sc 21 44.96
Fermium Fm 100 (253) Selenium Se 34 78.96
Fluorine F 9 19.00 Silicon Si 14 28.09
Francium Fr 87 (223) Silver Ag 47 107.870
Gadolinium Gd 64 157.25 Sodium Na 11 22.9898
Gallium Ga 31 69.72 Strontium Sr 38 87.62
Germanium Ge 32 72.59 Sulfur S 16 32.064
Gold Au 79 196.97 Tantalum Ta 73 180.95
Hafnium Hf 72 178.49 Technetium Tc 43 (99)
Helium He 2 4.003 Tellurium Te 52 127.60
Holmium Ho 67 164.93 Terbium Tb 65 158.92
Hydrogen H 1 1.0080 Thallium Tl 81 204.37
Indium In 49 114.82 Thorium Th 90 232.04
Iodine I 53 126.90 Thulium Tm 69 168.93
Iridium Ir 77 192.2 Tin Sn 50 118.69
Iron Fe 26 55.85 Titanium Ti 22 47.90
Krypton Kr 36 83.80 Tungsten W 74 183.85
Lanthanum La 57 138.91 Uranium U 92 238.03
Lawrencium Lr 103 (257) Vanadium V 23 50.94
Lead Pb 82 207.19 Xenon Xe 54 131.30
Lithium Li 3 6.939 Ytterbium Yb 70 173.04
Lutetium Lu 71 174.97 Yttrium Y 39 88.91
Magnesium Mg 12 24.312 Zinc Zn 30 65.37
Manganese Mn 25 54.94 Zirconium Zr 40 91.22
Mendelevium Md 101 (256)
*Based on mass of C12 at 12.000 . The ratio of these weights of those on the order chemical scale (in which oxygen of natural
isotopic composition was assigned a mass of 16.0000) is 1.000050. (Values in parentheses represent the most stable known
isotopes)
 4

m
s s 0s
h s 0s
e
s s

k s 0s
c s s
IeV
amu
G
R
y 0s
NA s
0s

R 0s

USEFUL FUNDAMAENTAL CONSTANTS

m Mass of electron
h Planck's constant
e Charge of electron
k Boltzmann constant
c Velocity of Light
IeV
amu
G
Ry Rydberg constant
NA Avogadro's number

R Molar Gas constant

 5

Hkkx \PART 'A'

1.
3.
1(0.9)4
1(10.9)4
2.
4.
(10.9)4
(0.9)4

1. 0s s s
3. The probability that a ticketless traveler is
caught during a trip is 0.1. If the traveler
s0s0s s
makes 4 trips , the probability that he/she will
0 ss, s be caught during at least one of the trips is:
ss -ss? 1. 1(0.9)4 2. (10.9)4
1. X 2. II 3. 1(10.9)4 4. (0.9)4
3. III 4. IX
4.
1. The clue is hidden in this statement, read the
note handed to Sherlock by Moriarty, who hid
the stolen treasure in one of the ten pillars.
Which pillar is it?
1. X 2. II
3. III 4. IX
s0 0
s s
2. s s0s 0s : s : 0 s

,s
00 s

s
0s s0 0s ?
1. 3 2. 4
s 21 s0s ,
3. 5 4. 6
27
s 30
s s 4.
s s s
0s 0
s
0s
?
1. 18
2. 24
3. 26
4. sss0ss The minimum number of straight lines
s required to connect the nine points above
without lifting the pen or retracing is
1. 3 2. 4
2. Suppose three meetings of a group of
3. 5 4. 6
professors were arranged in Mumbai, Delhi
and Chennai. Each professor of the group
attended exactly two meetings. 21 professors 5. s
attended Mumbai meeting, 27 attended Delhi A, B A B
meeting and 30 attended Chennai meeting.
0 s0s ?
How many of them attended both the Chennai
1. 2.
and Delhi meetings?
1. 18 3. 4. 3
2. 24
3. 26 5. Let A, B be the ends of the longest diagonal of
4. Cannot be found from the above the unit cube. The length of the shortest path
information from A to B along the surface is
1. 2.
3. s 0ss s, s 3. 4. 3
s s s0s 0.1 0
6.
0s316 0 ss0
0 s 4 s 0ss s

0s ?
,0ss s s
1. 2.
s0s0s:
3. s 4.
 6

6. How many digits are there in 316 when it is 9. The base diameter of a glass is 20% smaller
expressed in the decimal form? than the diameter at the rim. The glass is
1. Three 2. Six filled to half the height. The ratio of empty to
3. Seven 4. Eight filled volume of the glass is
1. 2.
7. x-y s s 0s

s , x s y 3. 4.

s0s :8 7 ss

s 10.
0s ss
1. (8, 7) 2. (8, 7) s0s s s 0s 10.
3. (4, 3.5) 4. (4, 3.5) ,s0 sss

7. A circle drawn in the x-y coordinate plane 0 sss

passes through the origin and has chords of 1. 0 2. 10
lengths 8 units and 7 units on the x and y axes, 3. 4.
respectively. The coordinates of its centre are
1. (8, 7) 2. (8, 7) 10. A wheel barrow with unit spacing between its
wheels is pushed along a semi-circular path of
3. (4, 3.5) 4. (4, 3.5)
mean radius 10. The difference between
distances covered by the inner and outer
8. s0
s s s wheels is
- s0s0s s0
1. 0 2. 10
ss
0s ? 3. 4.

11. 0 d =1 , r = 1 0,sg = 1 ss
s0,
-s ?
(100 = )
1. cos d < cos r < cos g
2. cos r < cos g < cos d
1. 2. 3. cos r < cos d < cos g
3. 4. 4. cos g < cos d < cos r

8. There is an inner circle and an outer circle 11. Write d =1 degree, r = 1 radian and g = 1 grad.
around a square. What is the ratio of the area Then which of the following is true?
of the outer circle to that of the inner circle? (100 grad = a right angle)
1. cos d < cos r < cos g
2. cos r < cos g < cos d
3. cos r < cos d < cos g
4. cos g < cos d < cos r

12. s 0 100 0 0 0 s
ss
1. 2.
0
0 s ss , s s
3. 4.
s s ss
9. s s 0s s 0
0 s s
0s 20% s s s


0ss 0
0s 0s s s s 20%
ss ss
0s 0s 0
00s ?
1. 2. 1. 122 2. 144
3. 150 4. 160
3. 4.
 7

12. A vendor sells articles having a cost price of

Rs.100 each. He sells these articles at a
premium price during first eight months, and
at a sale price, which is half of the premium
price, during next four months. He makes a
net profit of 20% at the end of the year.
Assuming that equal numbers of articles are
sold each month, what is the premium price of
the article?
1. 122 2. 144
3. 150 4. 160
15. Three circles of equal diameters are placed
such that their centres make an equilateral
13. 'sss triangle as in the figure
s
s '
1. s
2. s
3. s
4. s

13. The statement: The father of my son is the

only child of your parents
1. can never be true
Within each circle, 50 points are randomly
2. is true in only one type of relation
scattered. The frequency distribution of
3. can be true for more than one type of
distances between all possible pairs of points
relations
will look as
4. can be true only in a polygamous family

14. s

0s , s
0 ?
1. (6-gon) 2. (8-gon)
3.
(10-gon) 4. s
(12-gon)

14. One is required to tile a plane with congruent

regular polygons. With which of the following
polygons is this possible?
16. s -
1. 6-gon 2. 8-gon
3. 10-gon 4. 12-gon s

0ss ?
15. s0s ss 1. s0ssssss
0s , 2. sss
s0 3. ss
0

4. ss s

s

16. Most Indian tropical fruit trees produce fruits

in April-May. The best possible explanation

50
0s: for this is
1. optimum water availability for fruit
sss - 0
production.
s ss
 8

2. the heat allows quicker ripening of fruit.

3. animals have no other source of food in 1. GENT STUDENTS CAUSE LITTLE
summer. HEART BURNS
4. the impending monsoon provides 2. STUDENTS ARE INTELLIGENT BUT
optimum conditions for propagation. PROBLEM IS NOT SOLVABLE
3. THIS PROBLEM IS UNSOLVABLE
17. s (12-gon) BY ANY STUDENT
4. THIS PROBLEM IS SOLVABLE BY

0s
INTELLIGENT STUDENTS
1. 66 2. 54
3. 55 4. 60
20. ss0s
17. The number of diagonals of a convex
deodecagon (12-gon) is
1. 66 2. 54
3. 55 4. 60

18. s, s : s

s , s s
1. 19 2. 5
s ? 3. 9 4. 9
1. 1 2. 2
3. 3 4. 4 20. The missing number is

18. Three boxes are coloured red, blue and green

and so are three balls. In how many ways can
one put the balls one in each box such that no
ball goes into the box of its own colour?
1. 1 2. 2
3. 3 4. 4

19. s
1. 19 2. 5
3. 9 4. 9
0s 0
0s
s s
Hkkx \PART 'B'
s

1.
0s0 0ss 21. sP450 ss0s0
2.
0s0s0 s ,:
3.
0s0s 1.
s
sO2 s
4. 0sss0s0 2. O2 ssO2 s
s 3. O2 sss0
4. s0sO2 s
19. Decode
21. The biological functions of cytochrome P450
G E N T S T U
and myoglobin are, respectively
I S S O L V D
1. oxidation of alkene and O2 storage
L I I S P A E
2. O2 transport and O2 storage
L M H T R B N
3. O2 storage and electron carrier
E E L B O L T
4. electron carrier and O2 transport
T N I Y B E S
 9

22.
-s0 25. The WW bond order in [W(5-C5H5)(-
Cl)(CO)2]2 is
1.

0
1. three 2. two
2. 0 3. one 4. zero
3. O2 s0
4. s0 26. [Mn(H2O)6]2+ MnO
s

22. Deoxy-hemocyanin is 1.
s
1. heme protein and paramagnetic
2. s
s
2. colorless and diamagnetic
3. O2 transporter and paramagnetic 3.

ss
4. blue colored and diamagnetic 4. [MnO4]MnO s0

23. [CrO4]2, [MnO4] 2s [FeO4]2

ss
26. The correct statement for MnO bond
, lengths in [Mn(H2O)6]2+ is
1. [CrO4]2 < [MnO4]2 < [FeO4]2 1. All bonds are equal
2. [FeO4]2 < [MnO4]2 < [CrO4]2 2. Four bonds are longer than two others
3. [MnO4]2 < [FeO4]2 < [CrO4]2 3. Two bonds are longer than four others
4. [CrO4]2 < [FeO4]2 < [MnO4]2 4. They are shorter than the MnO bond in
[MnO4]
23. The oxidizing power of [CrO4]2, [MnO4] 2,
and [FeO4]2 follows the order 27. [Fe(5-C5H5)(CH3)(CO)2] PMe3,
1. [CrO4]2 < [MnO4]2 < [FeO4]2 0s

0
0
2. [FeO4]2 < [MnO4]2 < [CrO4]2 5
1. [Fe( -C5H5)(CH3)(CO)2(PMe3)]
3. [MnO4]2 < [FeO4]2 < [CrO4]2 2. [Fe(5-C5H5)(COCH3)(CO)]
4. [CrO4]2 < [FeO4]2 < [MnO4]2 3. [Fe(3-C5H5)(CH3)(CO)2]
4. [Fe(3-C5H5)(COCH3)(CO)(PMe 3)]
24.
s
s
0 s 27. For the reaction of [Fe(5-C5H5)(CH3)(CO)2]
with PMe3, the main intermediate is
eff () sss
1. [Fe(5-C5H5)(CH3)(CO)2(PMe3)]
(A) [CoF6]3,
(B) [IrCl6]3, 2. [Fe(5-C5H5)(COCH3)(CO)]
(C) [Fe(H2O)6]2+, 3. [Fe(3-C5H5)(CH3)(CO)2]
4. [Fe(3-C5H5)(COCH3)(CO)(PMe 3)]
1. A s B 2. B s C
3. A s C 4. A, B, s C 28. 0(II) 0 s s
0 ,
24. Using crystal field theory, identify from the
following complex ions that shows same eff 0 s0
(spin only) values (phen = 1,10-phenathroline)
(A) [CoF6]3, (B) [IrCl6]3, (C) [Fe(H2O)6]2+, 1. [Fe(phen)3]2+ s [Fe(phen)3]3+
1. A and B 2. B and C 2. [Fe(phen)3]3+ s [Fe(phen)3]2+
3. A and C 4. A, B, and C 3. [Fe(CN)6]4 s [Fe(CN)6]3
4. [Fe(CN)6]3 s [Fe(CN)6]4
25. [W( -C5H5)(-Cl)(CO)2]2 WW
5

28. Identify the complex ions in sequential order

1. 2. when ferroin is used as an indicator in the
titration of iron(II) with potassium dichro-
3. 4. 0
mate. (phen = 1,10-phenathroline)
1. [Fe(phen)3]2+ and [Fe(phen)3]3+
2. [Fe(phen)3]3+ and [Fe(phen)3]2+
 10

3. [Fe(CN)6]4 and [Fe(CN)6]3 32. The order of increasing Brnsted acidity for
4. [Fe(CN)6]3 and [Fe(CN)6]4 boron hydrides is
1. B5H9 < B6H10 < B10H14
29. XeF2 s XeO2F2 s ,: 2. B10H14 < B5H9 < B6H10
3. B6H10 < B10H14 < B5H9
1. ,0
4. B10H14 < B6H10 < B5H9
2. ,0
3. , 33.

s
4. , sss
0s ,
0),
A. [NiCl4]2 (
29. The structures of XeF2 and XeO2F2
respectively are B. IF7 (ss0),
1. bent, tetrahedral 0),
C. [CoF6]3 (
2. linear, square planar
D. Fe(CO)5 (ss0)
3. linear, see-saw
4. bent, see-saw 1. B s C 2. B s D
3. C s D 4. A s D
30.

0
33. Among the following, species expected to
show fluxional behaviour are
A. s; B. s; C. 0
s
A. [NiCl4]2 (tetrahedral),

B. IF7 (pentagonal bipyramidal),
1. A sB 2. B s C C. [CoF6]3 (octahedral),
3. A s C 4. A, Bs C D. Fe(CO)5 (trigonal bipyramidal)
1. B and C 2. B and D
3. C and D 4. A and D
30. Spin motion of which of the following gives
magnetic moment
A. Electron; B. Proton; C. Neutron 34. [Si6O18]12 0sss
Correct answer is 0


0s ,:
1. A and B 2. B and C 1. 6 s 6 2. 12 s 6
3. A and C 4. A, B and C
3. 12 s12 4. 6 s 12

31.
34. The ring size and the number of linked
1. 00-s0
tetrahedra present in [Si6O18]12 are,
s respectively,
2. 0sss
1. 6 and 6 2. 12 and 6
3. 00s
3. 12 and 12 4. 6 and 12
4. 0ss
0 35. C3O2 s 0
1. 4 s4

31. Correct statement for coulometry is
2. 3 s 2
1. it is based on Faradays law of
electrolysis 3. 2 s 3
2. it is a type of voltammetry 4. 3 s 4
3. it is based on Ohms law
4. it uses ion selective electrode 35. The molecule C3O2 has a linear structure.
This compound has
32. sss
s 1. 4 and 4 bonds
s 2. 3 and 2 bonds
1. B5H9 < B6H10 < B10H14 3. 2 and 3 bonds
2. B10H14 < B5H9 < B6H10 4. 3 and 4 bonds
3. B6H10 < B10H14 < B5H9
4. B10H14 < B6H10 < B5H9
 11

36.
0 s
1. 2.
0s0ss
0?
1. Eu, Yb 2. Sm, Tm
3. Gd, Lu 4. Nd, Ho
3. 4.
36. The metallic radii are abnormally high for
which of the following pairs?
1. Eu, Yb 2. Sm, Tm
3. Gd, Lu 4. Nd, Ho
38. The major product formed in the following
reaction is
37. 0
s

1. 2.

3. 4.

39. 0s 0s
1. A s B 2. A s C
3. B s D 4. C s D

37. Identify two enantiomers among the following

compounds.
1. 2.

3. 4.

39. The major product formed in the following

reaction is

1. A and B 2. A and C
3. B and D 4. C and D

38. 0s
0
s 1. 2.

3. 4.
 12

40. 0s 0s 41. The major product formed in the following

reaction is

1. 2.

1. 2.

3. 4.

3. 4.

40. The major product formed in the following

reaction is

42. 0s 0sA s
B

1. 2.

3. 4.

41. 0s 0s
1.

2.

3.

1. 2. 4.
1.

3. 4.
 13

42. The major products A and B in the following 43. D-Mannose upon refluxing in acetone with
reactions are CuSO4 and H2SO4 gives

1.

1. 2.

2.
3.

3.

4.
4.

43. CuSO4 sH2SO4 sD-(D-Mannose) 44. (2E,4Z,6E)-sssss0

ss s 0s

0
s

1. 1. 2.

3. 4.
1.

2. 44. The major product formed by photochemical

reaction of (2E,4Z,6E)-decatriene is

3.
1. 2.

4.
3. 4.
 14

45. 0s
3.

4.

0s s
1. 0 ss
46. 001H NMR 0
s
0s s 1
H NMR (DMSO-d6): 7.75 (dd, J = 8.8, 2.4 Hz,
1H), 7.58 (d, J = 2.4 Hz, 1H), 6.70 (d, J = 8.8 Hz,
2. 0 ss
1H), 6.50 (broad s, 2H), 3.80 (s, 3H).

1. 2.
0s
s-II ss

3.

3. 4.

0s
s-I ss

4.
46. The structure of the compound that matches
the 1H NMR data given below is
1
H NMR (DMSO-d6): 7.75 (dd, J = 8.8, 2.4
Hz, 1H), 7.58 (d, J = 2.4 Hz, 1H), 6.70 (d, J =
8.8 Hz, 1H), 6.50 (broad s, 2H), 3.80 (s, 3H).
45. The correct statement about the following
reaction is that

1. 2.

1. 3. 4.

2.
 15

47. sss 48. The number of chemical shift non-equivalent

protons expected in 1H NMR spectrum of -
ss ,
pinene is
A B

P. X. 1750 cm-1

1. 7 2. 8
Q. Y. 1770 cm-1
3. 9 4. 10

49. 1,2-s s , m/z s

R. Z. 1800 cm -1
98, 100s 102 s
ss
1. 3:1:1 2. 9:6:1
3. 1:1:2 4. 1:2:1
1. P-Y, Q-Z, R-X 2. P-Y, Q-X, R-Z
3. P-Z, Q-Y, R-X 4. P-X, Q-Z, R-Y
49. In the mass spectrum of 1,2-dichloroethane,
47. Correctly matched structure and carbonyl approximate ratio of peaks at m/z values 98,
stretching frequency set is 100, 102 will be
Column A Column B 1. 3:1:1 2. 9:6:1
3. 1:1:2 4. 1:2:1

P. X. 1750 cm-1 50. 0s 0s

Q. Y. 1770 cm-1

R. Z. 1800 cm-1

1. P-Y, Q-Z, R-X 2. P-Y, Q-X, R-Z

3. P-Z, Q-Y, R-X 4. P-X, Q-Z, R-Y
1.
48. -s(-pinene)1H NMR

0sss0 -0s

0s

2.

1. 7 2. 8
3. 9 4. 10
 16

3.

1. 2.

4.
3. 4.

51. The major product formed in the following reaction

50. The major product formed in the following is
reaction is

1. 2.

1. H

3. 4.
H
MeO2C

52. 0s

0
s
2.

3.
1.

2.

4.
3.

51. 0s 0s 4.

 17

52. The major product formed in the following

reaction is

The orders of these two reactions I and II,

respectively, are
1. 1. zero and one
2. one and zero
3. zero and two
4. two and zero
2.

54. 0
s s

3.
0 ,
1.
2. s
0
4. 3. s
0
4.

54. For a simple cubic crystal lattice, the angle

53.
0s R
between the plane and the plane is
s
s 0ss
1. less than
, s0s0s : 2. between and
3. between and
4. greater than

55.
0s,

0sI s II, 0s,

:

1.
0s
s ,
2. s0
3.
0s 1.
2.
4. s0
3.
4.
53. The concentration of a reactant R varies with
time for two different reactions as shown in
55. For the following reaction,
the following plots:
 18

is given by 59. p ()0sp (s0)

1. sss0s0s
1.
2. 2. s0sss0s
3. s0ss0ss ,
3.
s0ss0s0
4.
4. s0
s

56. s, 59. If the pressure p (system) is greater than the

00s s, p (surroundings), then
1. work is done on the system by the
s0ss surroundings
2. work is done on the surroundings by the
system
1.
3. work done on the system by the
2. surroundings is equal to the work done
on the surroundings by the system
3. 4. internal energy of the system increases
4.
60.

0 s

56. If the reduced mass of a diatomic molecule is

doubled without changing its force constant,
the vibrational frequency of the molecule ,
will be
1. s
1. times the original frequency
2.
s
2. times the original frequency 3.
3. twice the original frequency 4.
4. unchanged
60. Two different non-zero operators and
57. ss satisfy the relation

s , , when
1. and
1. 2. 2.
3. 4. 3. and are arbitrary
4.
57. The standard deviation of speed for
Maxwells distribution satisfies the relation 61. 0s0s s

1. 2.
ss3
3. 4.

s s
1. 3 2. 2
58. 0s 3. 1 4. 4

ss 61. The degeneracy of an excited state of a

1. 2. particle in 3-dimensional cubic box with
3. 4. energy 3 times its ground state energy is
1. 3 2. 2
58. The value of for the reaction 3. 1 4. 4
is
62. 0s s
1. 2.

0s
3. 4.
1. versus
2. versus
 19

3. versus 65. The correct expression for the product

4. versus [ and are the number-
average and weight average molar masses,
62. of a reaction is equal to slope of the plot of respectively, of a polymer] is
1. versus
2. versus 1. 2.
3. versus 3. N M i i 4. N M i i
2

4. versus i i

66. 0.1M Na2SO4 0s0s

63. 0 s MgSO40ss
1. 1. 0.05 M 2. 0.067 M
2. 3. 0.075 M 4. 0.133 M
3.
4.
66. The concentration of a MgSO4 solution
having the same ionic strength as that of a
63. The correct form for a simple Langmuir 0.1M Na2SO4 solution is
isotherm is 1. 0.05 M 2. 0.067 M
1. 3. 0.075 M 4. 0.133 M
2.
3.
67. sp ss
4.
s
ss
0)
64. ss0 sp ss
0
s s
1. 0 1.
2. 0-0 2.
s 3.
3.
0-0s 4.


4.
0:0
0 67. sp hybrid orbitals are of the form
ss0 are normalised
individually). The coefficients of the norma-

lized form of the above sp hybrid orbitals are
1.
64. In Kohlrausch law ,
and
2.
1. depend only on stoichiometry
2. depend only on specific identity of the 3.
electrolyte
3. are independent of specific identity of the 4.
electrolyte
4. are mainly dependent on specific identity
of the electrolyte and stoichiometry, 68.

respectively 1. N2+ sN2s

:N2

sN2+
65.
0
s
[ s: 0s-
2. N2 sN2+s

ss0s ]
:N2+

sN2
1. 2.
s
3. Ni M i
i
4. Ni M i2
i
 20

3. N2+ sN2s
1. P-Y, Q-Z, R-X 2. P-Z, Q-X, R-Y
3. P-Z, Q-Y, R-X 4. P-X, Q-Z, R-Y
:N20sN2+s

70. The correct match for compounds in column A
4. N2+sN2s
with the description in column B is
:N20sN2+s Column A Column B

Oil of
68. The correct statement among the following is P. X.
Wintergreen
1. N2 has higher bond order than N2+ and
hence has larger bond length compared
to N2+
Q. Y. Aspirin
2. N2+ has higher bond order than N2 and
hence has larger bond length compared
to N2
3. N2 has higher bond order than N2+ and
R. Z. Ibuprofen
hence has higher dissociation energy
compared to N2+
4. N2 has lower bond order than N2+ and
hence has lower dissociation energy 1. P-Y, Q-Z, R-X 2. P-Z, Q-X, R-Y
compared to N2+ energy 3. P-Z, Q-Y, R-X 4. P-X, Q-Z, R-Y

69. M+ (M = Li, Na, K and Cs) cryptand, C222

ss
1. Li+ < Cs+ < Na+ < K+
Hkkx \PART 'C'
2. Li+ < Na+< K+ < Cs+
3. K+ < Cs+ < Li+ < Na+
71. O2 ss (OO, cm1
4. Cs+ < K+ < Li+ < Na+
) 1580
- O2
69. The formation constant for the complexation of OO ,
M+ (M = Li, Na, K and Cs) with cryptand, 1. 1600 2. 1900
C222 follows the order 3. 800 4. 1100
1. Li+ < Cs+ < Na+ < K+
2. Li+ < Na+< K+ < Cs+ 71. The resonance Raman stretching frequency
3. K+ < Cs+ < Li+ < Na+ (OO, in cm1) of O2 is 1580. The OO for O2
4. Cs+ < K+ < Li+ < Na+ in bound oxy-hemoglobin is close to
1. 1600 2. 1900
3. 800 4. 1100
70. A 0 B
s 72. A s
0 B 0
0sss
s
A B
A B
Oil of (a) i. s0s0
P. X.
Wintergreen (b) sb ii. s0s s
(c) sB12 iii. O2 ss
(d) s0 iv.
ss-
Q. Y. Aspirin
0sss

v. O2 ss

R. Z. Ibuprofen vi. O2 s0

s
 21

1. (a)-(vi); (b)-(i); (c)-(iv) s (d)-(iii) C. Non-metals cannot be determined with

AAS
2. (a)-(v); (b)-(i); (c)-(iv) s (d)-(iii)
D. AAS is better than ICP-AES for simul-
3. (a)-(vi); (b)-(v); (c)-(i) s (d)-(ii) taneous determination of metal ions
4. (a)-(v); (b)-(vi); (c)-(ii) s (d)-(iv) Correct answer is
1. A, B and C 2. B, C and D
72. Match the metalloprotein in column A with 3. C, D and A 4. D, A and B
its biological function and metal center in
column B 74.
s00s
0s
Column A Column B 1. 9Be (, n) 8Be
(a) Hemoglobin i. Electron carrier and 2. 23Na (n, ) 24Na
iron 3. 63Cu (p, p 3n 9) 24Na
(b) Cytochrome b ii. Electron carrier and 4. 107Ag (n, n) 107Ag
copper
(c) Vitamin B12 iii. O2 transport and
74. Identify radioactive capture from the
copper
following nuclear reactions
(d) Hemocyanin iv. Group transfer
1. 9Be (, n) 8Be
reactions and cobalt
v. O2 storage and 2. 23Na (n, ) 24Na
cobalt 3. 63Cu (p, p 3n 9) 24Na
vi. O2 transport and 4. 107Ag (n, n) 107Ag
iron
75.



The correct match is
1. (a)-(vi); (b)-(i); (c)-(iv) and (d)-(iii) ss
2. (a)-(v); (b)-(i); (c)-(iv) and (d)-(iii) 1.
0
3. (a)-(vi); (b)-(v); (c)-(i) and (d)-(ii) 2. s
s
4. (a)-(v); (b)-(vi); (c)-(ii) and (d)-(iv) 3.
0
s
s

4.
0s

73. s
0(AAS)

ss 75. The calibration curve in spectrofluorimetric
AASHg0 analysis becomes non-linear when
A.

1. molecular weight of analyte is high
2. intensity of light source is high
B. AASs 3. concentration of analyte is high
s 4. molar absorptivity of analyte is high
C. AASss
76. [MnO4] s s [ReO4 ]

sss
D. s 0 s
0s ,
ICP-AES sAAS

1. Mn 0sRe0 dd



1. A, B s C 2. B, C s D
2. Re0sMn0 dd
3. C, D s A 4. D, A s B

73. Pick the correct statements about Atomic 3. O Mn s ORe

Absorption Spectrometry (AAS) from the
ss

following 4. O Re
s OMn
A. Hg lamp is not a suitable source for
AAS
ss

B. Graphite furnace is the best atomizer for
AAS
 22

76. [MnO4] is deep purple in color whereas Me2NHHCl.

[ReO4 ] is colorless. This is due to greater The number of possible isomers for [A] is
energy required for 1. 4 2. 3
1. dd transitions in the Re compound 3. 2 4. 5
compared to the Mn compound
2. dd transitions in the Mn compound 80. [C2B5H7]sssWades0
compared to the Re compound
s0s
3. charge transfer from O to Re compared
1. nido 2. closo
to O to Mn
3. arachno 4. hypho
4. charge transfer from O to Mn
compared to O to Re
80. Using Wades rules predict the structure type
of [C2B5H7].
77. [(3-C3H5)Mn(CO)4] sss 1. nido 2. closo
0s-s 3. arachno 4. hypho
s ,s 1H NMR
81.
/, /
ss
A. [Co(ox)3]3, B. trans-[CoCl2(en)2]+,
1. C. [Cr(EDTA)]
2. 4:1 ss 1. A s B 2. C s B
3. 2:2:1 s
s 3. C 4. A s C
4. s ss
81. Among the following complexes
77. 3
[( -C3H5)Mn(CO)4] shows fluxional A. [Co(ox)3]3, B. trans-[CoCl2(en)2]+,
behaviour. The 1H NMR spectrum of this C. [Cr(EDTA)] the chiral one(s) is/are,
compound when it is in the non-fluxional 1. A and B 2. C and B
state shows 3. C only 4. A and C
1. one signal
2. two signals in the intensity ratio of 4:1 82. s


3. three signals in the intensity ratio of ss
,
2:2:1
4. five signals of equal intensity A. s
s

s
78. [BrF4] , XeF6 s [SbCl6]
3
0s B. s
0 ss
s0 0s : C. s
s0
s
1. 2, 0 s1 2. 1, 0 s 0 D. s0s
3. 2, 1 s 1 4. 2, 1 s 0

1. A sC 2. B s C
78. The number of lone pair(s) of electrons on
A, B s D B s D
the central atom in [BrF4] , XeF6 and 3. 4.
[SbCl6]3 are, respectively,
1. 2, 0 and 1 2. 1, 0 and 0 82. Mssbauer spectrum of a metal complex
3. 2, 1 and 1 4. 2, 1 and 0 gives information about
A. oxidation state and spin state of metal
B. types of ligands coordinated to metal
79.
0ss[A]
C. nuclear spin state of metal
s0 0
s : D. geometry of metal
N3P3Cl6 + 6 HNMe2 N3P3Cl3(NMe2)3 + 3 Correct answer is
[A] 1. A and C 2. B and C
Me2NHHCl. 3. A, B and D 4. B and D
1. 4 2. 3
3. 2 4. 5
83. 0 /:
79. Consider the following reaction: (A) 0 0

s+4
N3P3Cl6 + 6 HNMe2 N3P3Cl3(NMe2)3 + 3 (B) s
s ss

[A]
 23

(C) 0ss
3. it follows the SN1CB mechanism
4. its rate is dependent only on the concen-
0
tration of [OH]
(D) 2

86. [Co(NH3)5Cl]2+ s0Cr2+ s
1. A s B 2. B s C 0 0 Y s 0 Y s
3. A s D 4. B
-s Y ,
1. [Co(NH3)5]2+ 2. [Co(NH3)5(OH)]+
83. For uranocene, the correct statement(s) 3. [Co(NH3)4(OH)2] 4. [Cr(H2O)5Cl]2+
is/are:
(A) oxidation state of uranium is +4. 86. Aqueous Cr2+ effects one electron reduction of
(B) it has cyclooctatetraenide ligands [Co(NH3)5Cl]2+ giving compound Y. Compo-
(C) it is a bent sandwich compound und Y undergoes rapid hydrolysis. Y is,
(D) it has 2 charge. 1. [Co(NH3)5]2+ 2. [Co(NH3)5(OH)]+
Correct answer is 3. [Co(NH3)4(OH)2] 4. [Cr(H2O)5Cl]2+
1. A and B 2. B and C
3. A and D 4. B only
87. BCl3 NH4Cl 0s
sA

84. s [V(CO)6] s [Co(CO)4] NaBH4 0

sB s

H3PO4, 0s

sB HCl 0s0C

s: s ,
1. Cl3B3N3H9 2. [ClBNH]3
1. V(CO)6 s HCo(CO)4 3. [HBNH]3 4. (ClH)3B3N3(ClH)3
2. HV(CO)6 s Co2(CO)8
3. [H2V(CO)6]+ s HCo(CO)4 87. The reaction of BCl3 with NH4Cl gives
product A which upon reduction by NaBH4
4. V(CO)6 s Co2(CO)8 gives product B. Product B upon reacting
with HCl affords compound C, which is
84. The final products of the reaction of carbonyl 1. Cl3B3N3H9 2. [ClBNH]3
metalates [V(CO)6] and [Co(CO)4] with 3. [HBNH]3 4. (ClH)3B3N3(ClH)3
H3PO4, respectively, are
1. V(CO)6 and HCo(CO)4 88. [Ru(CO)3] ,

0s
2. HV(CO)6 and Co2(CO)8
s
0ss ,
3. [H2V(CO)6]+ and HCo(CO)4 1. 1 2. 14
4. V(CO)6 and Co2(CO)8 3. 6 4. 2

85. [Co(CN)5Cl]3 OH s0s, 88. The number of valence electrons provided by

[Ru(CO)3] fragment towards cluster bonding
[Co(CN)5(OH)] , ,
3
is
1. 0s 1. 1 2. 14
3. 6 4. 2
2. s
s
89. -(Tanabe-Sugano)
s
s
ss
3. 0SN1CB 0ss
A. 0E/B so/B

4. [OH]s
s
B.
s
0s

C. s
s
85. The correct statement about the substitution
reaction of [Co(CN)5Cl]3 with OH to give D. s

[Co(CN)5(OH)]3 is,
ss

1. it obeys first order kinetics
2. its rate is proportional to the concentr- s
ation of both the reactants

 24

1. A sB 2. A sC 91. Zs

0s
3. A, B s D 4. A, B, C s D

0
s

89. Choose the correct statements about Tanabe-

Sugano diagrams:
A. E/B is plotted against o/B.
B. The zero energy is taken as that of the
lowest term.
C. Terms of the same symmetry cross each
other.
D. Two terms of the same symmetry upon

increase of ligand field strength bend
apart from each other.
Correct answer is
1. A and B 2. A and C
3. A, B and D 4. A, B, C and D

90.
s
0?
(A) sEu3+ s
0,-0

ssss
(B)
ss

0
1. A s D 2. B s D
(C) Sm(II) sss
3. B s C 4. A s C


(D)
s(III) 0 00 91. The intermediate and the final major product
s
of photolysis of Z



1. A s D 2. A s B
3. A s C 4. B s C

90. Which of the following statements are TRUE

for the lanthanides?
(A) The observed magnetic moment of
Eu3+ at room temperature is higher from the following:
than that calculated from spin-orbit
coupling
(B) Lanthanide oxides are predominantly
acidic in nature
(C) The stability of Sm(II) is due to its
half-filled sub-shell
(D) Lanthanide(III) ions can be separated
by ion exchange chromatography
Correct answer is
1. A and D 2. A and B
3. A and C 4. B and C

are
1. A and D 2. B and D
3. B and C 4. A and C
 25

92. [Mn2(CO)10] I2 0s s CO 1. (2020, 1980, 1800) and one

2. (2020, 1980, 1800) and two
A 0 A 120 C
3. (2020, 1980) and one
CO
B s , 4. (2143) and one
MnMn
s
0 B 0s C 2
0s 94. ZSM-5 ss
s

A, B, s C 0s

: s

1. ss0s
CO I CO CO py
ss0s
O CO I CO
C
Mn CO OC Mn CO
I
Mn CO
2.
OC Mn OC Mn
OC
I
C
O CO
OC
CO
OC
py
I
CO 3.
(C6H5)+ ss
ss
I II III
CO CO CO
4.
I CO
I
OC Mn py OC Mn Mn CO
OC
CO
OC
CO
I
CO
94. Protonated form of ZSM-5 catalyzes the
IV V reaction of ethene with benzene to produce
ethylbenzene. The correct statement for this
1. II, V s IV 2. II, III s IV catalytic process is
3. V, III s IV 4. II, V s III 1. alkyl carbocation is formed
2. carbanion is formed
92. Reaction of [Mn2(CO)10] with I2 results in A 3. benzene is converted to (C6H5)+ group
without loss of CO. Compound A, on heating 4. vinyl radical is formed
to 120 C loses a CO ligand to give B, which
does not have a MnMn bond. Compound B 95. [CrF6]3

reacts with pyridine to give 2 equivalents of s 14900, 22700 s 34400
C. Compounds A, B, and C from the cm1 o s (cm1 ) s
following respectively, are
CO O I
CO
CO
I
CO py
CO

C I
OC Mn
C
Mn CO OC Mn CO OC Mn
I
Mn CO
1. 7800 s4A2g 4T2g
OC OC OC
14900 s4A2g 4T2g
I O CO CO py CO
I II III 2.
14900 s 4T2g 4T1g(F)
CO CO CO
I
I
CO 3.
7800 s 4T2g 4T1g(F)
OC Mn py OC Mn Mn CO
OC OC
I 4.
CO CO CO
IV V
95. Three electronic transitions at 14900, 22700
1. II, V and IV 2. II, III and IV and 34400 cm1 are observed in the
3. V, III and IV 4. II, V and III absorption spectrum of [CrF6]3. The o
value (in cm1) and the corresponding
93. [Fe(5-C5H5)(-CO)(CO)]2 (-
0) transition are
s 0 1. 7800 and 4A2g 4T2g
2. 14900 and 4A2g 4T2g

CO
(cm1) s
s
3. 14900 and 4T2g 4T1g(F)
sFeFe
: 4. 7800 and 4T2g 4T1g(F)
1. (2020, 1980, 1800) s
2. (2020, 1980, 1800) s 96. 0s

0
s
3. (2020, 1980) s
4. (2143) s

93. The approximate positions of CO bands

(cm1) in the solid-state infrared spectrum
and the FeFe bond order in [Fe(5-C5H5)(-
CO)(CO)]2 (non-centrosymmetric)
respectively, are
 26

1. 2.

1. Claisen rearrangement Cope

rearrangement ene reaction
2. Cope rearrangement Claisen
3. 4. rearrangement ene reaction
3. Cope rearrangement ene reaction
Claisen rearrangement
4. ene reaction Claisen rearrangement
Cope rearrangement
96. The major product formed in the following
reaction is
98.
0s



0s

1. 2.

1. 2.
3. 4.

97. s 3. 4.

98. The major product formed in the following

reaction sequence is

1. 0s
0s
0s
2. 0s0s
0s
3.
0s 0s
0s 1. 2.
4. 0s0s
0s

97. The following transformation involves 3. 4.

sequential
 27

99.
0s0sA
sB 4.

100. 0s

0
s

1.

2.
1. 2.

3.

3. 4.

4.

100. The major product formed in the following

99. The major products A and B in the following reaction is
reaction sequence are

1. 2.

1.

2. 3. 4.

3.
 28

101. 0s 0sA
sB

1.

1. A = D-; B = D-

2.
2. A = D-; B = D-
+ D-
3. A = D-; B = D- + D-
4. A = D-s ; B = D-
3.
101. The major products A and B in the following
reaction sequences are

4.

1. A = D-threose; B = D-glucose 103. 0s

0
sA
2. A = D-erythrose; B = D-glucose + D-
s B
mannose
3. A = D-threose; B = D-glucose + D-
mannose
4. A = D-tartaric acid; B = D-glucose

102. 0s
0s A
s B

1.

1.

2.

2.

3.
3.

4.
4.

102. The major products A and B in the following

reaction sequence are
 29

103. The major products A and B in the following

reaction sequence are 4.

104. The major products A and B in the following

reaction sequence are

1.

2.

1.

3.

2.

4.
3.

4.
104.
0s
0
s
A s B

105. 0s0sA
s B

1.

2. 1.

3. 2.
 30

106. The major product formed in the following

3. reaction is

4.

1. 2.
105. The major products A and B in the following
reaction sequence are

3. 4.

107. 0ss0s

1.

2.

1. 2.
3.

4. 3. 4.

106.
0ss
0s
107. The major product formed in the following
reaction is

1. 2.
1. 2.

3. 4. 3. 4.
 31

108.
0s0
s A 109. 0s0sA
s B s B

1.

2. 1.

3. 2.

4. 3.

108. The major products A and B in the following 4.

reaction sequence are

109. The major products A and B in the following

reaction sequence are

1.

2.

1.
3.

2.
4.
 32

3.

4.

1.

110. s
s0
2.

1. A = NaBH4, BF3OEt2; B = MeMgBr (2.5 3.

equiv.), THF s H3O+
2. A = BH3THF; B = MeLi (2.5 equiv.), THF
s H3O+
3. A = BH3THF; B = (i) aq. NaOH then H3O+,
(ii) MeLi (2.5 equiv.), THF s H3O+ 4.
4. A = (i) Me3Al, MeNHOMe, (ii) MeMgBr,
THF s H3O+; B = LiAlH4, THF

110. The correct reagent combination to effect the

following transformation is 111. The mechanism and the product formed in the
following reaction, respectively, are

1. A = NaBH4, BF3OEt2; B = MeMgBr

(2.5 equiv.), THF then H3O+
2. A = BH3THF; B = MeLi (2.5 equiv.),
THF then H3O+ 1.
3. A = BH3THF; B = (i) aq. NaOH then
H3O+, (ii) MeLi (2.5 equiv.), THF then
H3O+
4. A = (i) Me3Al, MeNHOMe, (ii)
MeMgBr, THF then H3O+; B = LiAlH4,
THF 2.

111.
0s0ss

0
s,:
 33

113. 0s0sA s
B
3.

4.

1.

112. s00s 0[1,3]-ss

0ss
ss

2.

3.
1. 2.

4.
3. 4.

113. The major products A and B in the following

reaction sequence are
112. A concerted [1,3]-sigmatropic rearrangement
took place in the reaction shown below. The
structure of the resulting product is

1.

1. 2.

2.
3. 4.
 34

3.
1. 2.

4.
3. 4.

114.
0s

0

s 115. The major product formed in the following
reaction is

1. 2.

3. 4.

1. 2.

114. The major product formed in the following

reaction sequence is

3. 4.

1. 2. 116. 0s

0
sA
s B

3. 4.

115. 0s 0s

1.

2.
 35

117. The major product of the following reaction is

3.

4.

116. The major products A and B in the following 1.

reaction sequence are

2.

1. 3.

2. 4.

3.
118. 0s0s A s B

4.

117.
0ss0s
1.

2.

1.
3.

2.

4.

3.

4.
 36

118. The major products A and B in the following 119. The major products A and B in the following
reaction sequence are reaction sequence are

1.
1.

2.
2.

3.
3.

4. 4.

120. 0ss0s
119. 0s0sA s
B

1. 2.

1. 3. 4.

2. 120. The major product of the following reaction is

3.

4. 1. 2.
 37

which are assigned to and [1 1 1]

3. 4. planes, respectively. The ratio is
1. 1.5 2. 1.22
3. 0.82 4. 0.67

124. ss
121. -s-s
s0
,
s
s 1. s
0
s

s , ( s0ssh ss

s0s) 2. s
0
s
ss
1. 2.
3. s
0
3. 4. ss
s
4. s
0s
121. According to the transition state theory, one of ss
the vibrations in the activated complex is a
loose vibration. The partition function for this 124. Stability of lyophobic dispersions is determined
loose vibration is equal to ( is the by
Boltzmanns constant and h is the Plancks
constant) 1. inter-particle electric double layer repulsion
and intra-particle van der Waals attraction
1. 2. 2. inter-particle electric double layer attraction
and intra-particle van der Waals repulsion
3. 4. 3. inter-particle excluded volume repulsion
and intra-particle van der Waals attraction
4. inter-particle excluded volume attraction
122. s s
0s
and intra-particle van der Waals repulsion
,
s
s /
125. 2-
0 s0
s
1. 2
S1/2 2. 2
P3/2 s P1/2
2
s0 s
3. 1
S0 s 1P1 4. 3
P0 s3P1 ss
0 : s

s
s 0 s s
122. Possible term symbol(s) of the excited states of
atom with the electronic configuration s
is/are 1. 2.
2 2 2
1. S1/2 2. P3/2 and P1/2
1
3. 4.
3. S0 and 1P1 4. 3
P0 and 3P1
125. A certain 2-level system has stationary state
123. 0 X- energies and with
, s s normalized wave functions and
respectively. In the presence of a
ss s [1 1 1] perturbation , the second-order correction
:s0s
s to the energy for the first state will be
1. 1.5 2. 1.22 1. 2.
3. 0.82 4. 0.67
3. 4.
123. For a simple cubic crystal, X-ray diffraction
shows intense reflections for angles and
 38

126. 42.4 MHz 1. 2. 1

3. 4.
s 0
0
s
: s ,
0s?
1. 10.6 MHz 2. 169.6 MHz
3. 42.6 MHz 4. 21.3 MHz 129. s
sEMF
126. The frequency at is 42.4
MHz. If the gyromagnetic ratios of and 1. Tss
are and , 2. Tss
respectively, what will be the frequency 3. Ts
at ?
4. [HCl]ss
1. 10.6 MHz 2. 169.6 MHz
3. 42.6 MHz 4. 21.3 MHz
129. The standard EMF of the cell
127. s 10 mL s
ss:s 0.1M s
1. increases with T
0.1M - 0s 0s 2. decreases with T
s-0 : s 3. remains unchanged with T
s
s 0 4. decreases with [HCl]
s,
130.
s
0s
1. 2.
0 (s
),
3. 4.
1. 2.
127. 10 mL aliquots of a mixture of and 3. 4.
are titrated conductometrically using a
0.1M and a 0.1M separately. 130. The molecule with the smallest rotational
The titre volumes are and constant (in the microwave spectrum) among
respectively. The concentration of in the following is
the mixture is obtained from the combination 1. 2.
1. 2. 3. 4.
3. 4.
131. trans-1,2- sscis-1,2-
128. 0s s s
,s
at 25 C,

0s
,

0s
1. s

, 2. UV-0

1. 2. 1 3. X-ss
3. 4.
4.
-

131. The spectroscopic technique that can distin-

guish unambiguously between trans-1,2-
128. Given that and
dichloroethylene and cis-1,2-dichloroethylene
at 25 C, without any numerical calculation is
corresponding to the electrode reaction 1. Microwave spectroscopy
2. UV-Visible spectroscopy
3. X-ray photoelectron spectroscopy
is 4. -ray spectroscopy
 39

132. s s0C2 1. 2.
3. 4.

ss0s

1. 135. The molecule diborane belongs to the

2. symmetry point group
3. 1. 2.
4. 3. 4.

132. The ground state electronic configuration of 136. s0s

0,
C2 using all electrons is s s
1. ,
2. 1. s,
ss
sss
3. 2. ss
s
4. 3. sssss
4.
ssss
133.
s 0s
136. Though a constant shift of energy levels of a
s , : s
system changes the partition function, the
s
s properties that do not change are
0s 1. average energy, entropy and heat capacity
1. 2. 2. average energy and entropy
3. 4. 3. average energy and heat capacity
4. entropy and heat capacity
133. for an enzyme catalyzed
137.
0
0 s

reaction are and


s
respectively. The rate of the
0 s

s
reaction when the substrate concentration is
is 0
, s
1. 2.
1. 2.
3. 4.
3. 4.
137. The vibrational frequency of a homonuclear
134.
s 0s s s diatomic molecule is . The temperature at
s
ss 0s
s which the population of the first excited state
will be half that of the ground state is given by
s0s atm
1. 2.
s atm 3. 4.
00s
1. 2. 138.
0 s
3. 4. trans- 0ss0
-
0 ,
134. The first order rate constant for a unimole-
cular gas phase reaction products that 1. s 2. s
follows Lindemann mechanism is at 3. s 4. s
atm and at atm.
The rate constant for the activation step is
138. The irreducible representations of
1. 2.
are and . The Raman active
3. 4.
modes of trans- -butadiene belong to the
irreducible representations
135. s s , 1. and 2. and
3. and 4. and
 40

139.
s 143. -s-:

1. 2. 1. ss1 atm s
3. 4. s
2. ss
139. The symmetry-allowed atomic transition 3. s1 atm s
among the following is

1. 2.
4. 1 atm ss s
3. 4.

140. 10
6

143. The non-spontaneous process among the

( following is
ss0 ) 1. vapourisation of superheated water at
1. 106 2. 105
and 1 atm pressure
3. 104 4. 103 2. expansion of a gas into vacuum
3. freezing of supercooled water at
140. The average end-to-end distance of a random and 1 atm pressure
coil polymer of 106 monomers (in units of 4. freezing of water at and 1 atm
segment length) is pressure

1. 106 2. 105 144. s 0

3. 104 4. 103
s s 0s)
141. s0s s ,
1.0 mol s01.0 L 4.0 1. 2s 2. 3p
3. 4d 4. 5f
L 0s
1. 2. 144. The radial part of a hydrogenic wave function
3. 4. is given as are constants).
This function is then identifiable as
141. A reversible expansion of 1.0 mol of an ideal 1. 2s 2. 3p
gas is carried out from 1.0 L to 4.0 L under 3. 4d 4. 5f
isothermal condition at . for this
process is 145. ss0 s s s
1. 2. s
3. 4. s
s
s0 :1/2 s3/2 s,s
142. s s s s s
0 0s 0s 0 s
,
s 7/6
s
s0s
ss
1. 1/2 2. 1/3
1. 200 K 2. 300 K 3. 1/4 4. 1/5
3. 400 K 4. 500 K
145. A normalized state is constructed as a
142. The temperature-dependence of the vapour linear combination of the ground state
pressure of solid can be represented by and the first excited state of some
, and that of liquid by harmonic oscillator with energies 1/2 and 3/2
units, respectively. If the average energy of
. The temperature of the
the state is 7/6, the probability of finding
triple point of is in will be
1. 200 K 2. 300 K 1. 1/2 2. 1/3
3. 400 K 4. 500 K 3. 1/4 4. 1/5
 41

FOR ROUGH WORK

 42

FOR ROUGH WORK