RESULTS

Tube Tube Tube Tube Tube Tube Tube Tube

No.1 No.2 No.3 No.4 No.5 No.6 No.7 No.8
Initial 0.0 0.6 8.9 2.5 6.59 0.3 22.6 0.9
Final 8.33 9.22 22.45 13.75 28.61 24.45 30.75 7.8
Total 8.33 9.06 13.55 11.25 22.02 24.15 8.15 6.9

Test tube No. 1 & 2 : 6 M HCl + 5 ml distilled water

Test tube No. 3 & 4 : 6 M HCl + 5 ml pure CH3COOC2H5

Test tube No. 5 & 6 : 6 M HCl + 3 ml glacial CH3COOH + 2 ml absolute C2H5OH

Test tube No. 7 & 8: 6 M HCl + 2 ml glacial CH3COOH + 3 ml absolute C2H5OH

Weight of Samples:

SAMPLE VOLUME WEIGHT

6 N HCl 5 ml 5.14 g
CH3COOC2H5 5 ml (0.898 g/ml)(5 ml) = 4.49 g
CH3COOH 2 ml (1.05 g/ml)(2 ml) = 2.1 g
C2H5OH 2 ml (0.789 g/ml)(2 ml) = 1.578 g
CH3COOH 3 ml (1.05 g/ml)(3 ml) = 3.15 g
C2H5OH 3 ml (0.789 g/ml)(3 ml) = 2.367 g

Test tube 1 & 2: N = 0.238 N

V of H2O = 5ml 2 H2O H3O + + OH-

Mass of H2O = 5 g
Vsoln = 25 ml NaOH + 5 ml H2O + 5 ml I 55.56 0 0
HCl = 35 ml solution C -2x x x
E 55.26 2x x x
1 mol
5 g( )
NH2O = 18 g = 55.56 M H2O
0.005 L [ H 3 O ] [OH ] [ x ][ x ]
K1 = [ H 2 O]2 = [55.26 2 x ]2

Test tube 1: [0.238] 2

K1 = [55.26 2(0.238)]2 = 1.87 x 10 -5
NVsoln = NVNaOH
N (35 ml) = 1(8.33 ml)
NVsoln = NVNaOH
Test tube 2: N (35 ml) = 1(9.06 ml)
N = 0.259 N

[0.259]2
K2 = [55.26 2(1.259)]2 = 2.21 x 10 -5

Test tube 3 & 4:

CH3COOC2H5 + H2O C2H5OH + CH3COOH

1 mol
4.49 g ( )
MCH3COOC2H5 = 88 g = 10.215 M CH3COOC2H5
0.005 L

Mass of HCl = 6 mol / L soln (36.45 g/mol)(0.005 L) = 1.0935 g HCl

Mass of H2O = 5.14 g 1.0935 g = 4.0465 g H2O
1 mol
4.0465 g ( )
MH2O = 18 g = 44.96 M
0.005 L

CH3COOC2H5 + H2O C2H5OH + CH3COOH

I 10.215 44.96 0 0

C -x -x x x

E 10.215-x 44.96-x x x

Test tube 3: Test tube 4:

NVsoln = NVNaOH NVsoln = NVNaOH

N (35 ml) = 1(13.55 ml) N (35 ml) = 1(11.25 ml)
N = 0.387 N N = 0.3214 N

[0.3214]2
[ C 2 H 5 OH ][CH 3COOH ] K1 = [ 10.2150.3214 ] [44.960.3214 ]
K1 = [CH 3 COOC 2 H 5][ H 2O]
= 2.43x10 -4
[0.238]2
K1 = [ 10.2150.387 ] [44.960.387] =

3.42 x 10 -4