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Hydrogen Sulfide

Hydrogen Sulfide /SCF 100


Mass gram 0.01555 Volume of Gas
Molecular Weight H2S a.u.m 32 Molecular Weight H2S

Mole of Gas mol 0.00049 Volume of 1-mole Gas

Volume of 1-mole Gas liter 22.4 Moles of Gas

Volume of Gas liter 0.010885 Mass of Gas


Volume of Gas ft3 0.000384

H2S ppmv 384.2 ppmw

Hydrogen Sulfide /SCF 100


H2S/100SCF 3.84

mass gram 0.0156 mass


density g/l 1.43 density
Volume l 0.01 Volume
Volume ft3 0.0004 Volume
H2S PPMv 383.86 H2S
/100 Scf PPMv 3.84 /100 Scf

Mole of Gas Mol 0.0004573529

%age
Flow lb/hr 173106.8
30.5% MDEA lb/hr 52797.6
7.5% DEA lb/hr 12983.0

62 Water lb/hr 107326.2


/gram 0.01555
SCF 100
a.u.m 32

liter 22.4

mol 126.4

gram 4044.3

3.84

gram 0.9500
g/l 1.43
l 0.66
ft3 0.0235
PPMv 23451.05
PPMv 234.51
100

Comp Mole% Mole Frac. Hysys


CO2 2.22 0.0222 0.0221
N2 7.26 0.0726 0.0717
H2S 0.0462 0.001 0.0010
H2O 0 0 0.0011
Methan 89.19 0.8919 0.8911
Ethan 0.84 0.0084 0.0087
Propane 0.22 0.0022 0.0023
i-Butane 0.04 0.0004 0.0004
n-Butane 0.06 0.0006 0.0006
i-Pentane 0.02 0.0002 0.0001
n-Pentane 0 0 0.0000
Hexane+ 0.1 0.001 0.0011

99.996 1.0005
Pt (Psig) 1950
For Physical Solvent
Reqrd high PP of Acid Gas
100

Mole% Mole Frac. Hysys Error


CO2 2.215 0.0222 0.0221 0.0001 43.1925
N2 7.185 0.0719 0.0716 0.0002 140.1075
H2S 0.0595 0.0006 0.0010 -0.0004 1.16025
H2O 1.11E-03
Methan 89.19 0.8919 0.8907 0.0012 1739.205
Ethan 0.865 0.0087 0.0087 0.0000 16.8675
Propane 0.225 0.0023 0.0023 0.0000 4.3875
i-Butane 0.035 0.0004 0.0004 0.0000 0.6825
n-Butane 0.06 0.0006 0.0006 0.0000 1.17
i-Pentane 0.01 0.0001 0.0001 0.0000 0.195
n-Pentane 0 0 0.0000 0.0000 0
Hexane+ 0.12 0.0012 0.0011 0.0001 2.34

99.9645 0.9996 0.9996 1949.31

PPMv to Mole%

ppm 1000
mole% 0.1
Mole Frac. 0.001

Methan 89.19 0.8919


Ethan 0.865 0.00865
Propane 0.225 0.0023
i-Butane 0.035 0.0004
n-Butane 0.06 0.0006
i-Pentane 0.01 0.0001
n-Pentane 0 0
Hexane+ 0.12 0.0012
CO2 2.215 0.0222
N2 7.175 0.0718
H2S 0.1 0.0010
H2O

99.9950 1.0000
SOUTH-1 SOUTH-2
Mole% Mole Frac. Hysys Difference Mole%
2.22 0.0222 0.0221 0.000 2.21
7.26 0.0726 0.0717 0.001 7.2
0.0462 0.000462 0.0010 -0.001 0.074
0 0 0.0011 0
89.19 0.8919 0.8911 0.001 89.19
0.84 0.0084 0.0087 0.000 0.89
0.22 0.0022 0.0023 0.000 0.23
0.04 0.0004 0.0004 0.000 0.03
0.06 0.0006 0.0006 0.000 0.04
0.02 0.0002 0.0001 0.000 0
0 0 0.0000 0.000 0
0.1 0.001 0.0011 0.000 0.14

99.996 1.0000 1.0000 0.000 100.0040

984.575473

0.0595
SOUTH-2
Mole Frac. Hysys Difference
0.0221 0.0220 0.000
0.0720 0.0719 0.000
0.0007 0.0007 0.000
0.0000 0.0009 -0.001
0.8919 0.8901 0.002
0.0089 0.0089 0.000
0.0023 0.0023 0.000
0.0003 0.0003 0.000
0.0004 0.0004 0.000
0 0.0000 0.000
0 0.0000 0.000
0.0014 0.0011 0.000
0.000
1.0000 0.9985 0.002
Condensate Cut
Final Analysis
Flow BBL/MMSCF
D - 86 C
o o
F Plant Cap MMSCFD

IBP 110 230 Water Flow BBL/day


10 142 288
20 170 338
30 184 363 Water Cut
40 196 385
50 208 406 Flow BBL/MMSCF
60 220 428 Plant Cap MMSCFD
70 230 446
80 244 471 Water Flow BBL/day
90 258 496
95 268 514 Gas
FBP 300 572 Flow MMSCFD
MMSCFH
Sp Garvity 0.84
Condensate Cut

5 Flow BBL/MMSCF 5
15 Plant Cap MMSCFD 6.8

75 2.1875 Water Flow BBL/day 34 0.9916666667

Water Cut

20 Flow BBL/MMSCF 20
15 Plant Cap MMSCFD 6.8

300 8.75 Water Flow BBL/day 136 3.9666666667

Gas
15 Flow MMSCFD 15
0.625 MMSCFH 0.625

Vol % o
F o
C
0 52.016 11.12
1 71.528 21.96
2 82.976 28.32
3 92.822 33.79
5 101.48 38.6
7 132.22 55.68
10 161.11 71.73
12 175.95 79.97
15 197.83 92.13
17 207.36 97.42
20 217.44 103.02
25 235.71 113.17
30 250.65 121.47
35 264.78 129.32
40 280 137.77
45 297.14 147.3
50 317.57 158.65
55 343 172.78
60 375.28 190.71
65 415.36 212.98
70 457.9 236.61
75 499.51 259.73
80 548.74 287.08
85 609 320.57
90 680.81 360.45
92.5 722 383.31
95 767.17 408.43
96.5 797.7 425.39
98 829.8 443.22
99 841.5 449.72
100 841.5 449.72
11.12
21.96
28.32
33.79
38.6
55.68
71.73
79.97
92.13
97.42
103.02
113.17
121.47
129.32
137.77
147.3
158.65
172.78
190.71
212.98
236.61
259.73
287.08
320.57
360.45
383.31
408.43
425.39
443.22
449.72
449.72
Component %age Flow

Solution 100 10000

MDEA 5 500
DEA 40 4000
Water 55 5500

100 10000

Raw Gas Flow Rate MMSCFD 15


Mol% of H2S to be Removed mol% 0.095
Mol% of CO2 to be Removed mol% 0
Molcular Weight Amine Solution a.u.m 105
Amine Solution wt% 0.25
Moles Loading 0.3

Amine Solution Required GPM 411.0


Condensate Cut

Flow BBL/MMSCF 5
Plant Cap MMSCFD 15

Water Flow BBL/day 75 2.1875

Water Cut

Flow BBL/MMSCF 20
Plant Cap MMSCFD 15

Water Flow BBL/day 300 8.75

Gas
Flow MMSCFD 15
MMSCFH 0.625
South - I

Given Comp. Considered (Hysys)


Mole% Mole Frac. Input After Flash Error

CO2 2.22 0.0222 0.0222 0.0221 0.0001


N2 7.33 0.0733 0.0726 0.0725 0.0008
H2S 0.0462 0.000462 0.000462 0.0005 0.0000
H2O 0.0 0.0 0.0 0.0007 -0.0007
Methan 89.19 0.8919 0.8919 0.8905 0.0014
Ethan 0.84 0.0084 0.0084 0.0084 0.0000
Propane 0.22 0.0022 0.0022 0.0022 0.0000
i-Butane 0.04 0.0004 0.0004 0.0004 0.0000
n-Butane 0.06 0.0006 0.0006 0.0006 0.0000
i-Pentane 0.02 0.0002 0.0002 0.0002 0.0000
n-Pentane 0.0 0.0 0.0000 0.0000 0.0000
Hexane+ 0.1 0.001 0.0010 0.0009 0.0001

Total 100.066 1.001 1.0000 0.9990

South - II

Given Comp. Considered (Hysys)


Mole% Mole Frac. Input After Flash Error

CO2 2.21 0.0221 0.0221 0.0220 0.0001


N2 7.178 0.0718 0.0718 0.0717 0.0001
H2S 0.074 0.0007 0.0007 0.0007 0.0000
H2O 0.0 0.0000 0.0 0.0009 -0.0009
Methan 89.19 0.8919 0.8919 0.8903 0.0016
Ethan 0.89 0.0089 0.0089 0.0089 0.0000
Propane 0.23 0.0023 0.0023 0.0023 0.0000
i-Butane 0.03 0.0003 0.0003 0.0003 0.0000
n-Butane 0.06 0.0006 0.0006 0.0006 0.0000
i-Pentane 0.0 0.0000 0.0000 0.0000 0.0000
n-Pentane 0.0 0.0000 0.0000 0.0000 0.0000
Hexane+ 0.14 0.0014 0.0014 0.0012 0.0002

Total 100.002 1.000 1.0000 0.9989

South - I + II

Given Comp. Considered (Hysys)


Mole% Mole Frac. Input After Flash Error

CO2 2.215 0.0222 0.0222 0.0221 0.0000


N2 7.29 0.0729 0.0717 0.0716 0.0013
H2S 0.0595 0.0006 0.0010 0.0010 -0.0004
H2O 0.0 0.0 0.0 0.0007 -0.0007
Methan 89.19 0.8919 0.8919 0.8905 0.0014
Ethan 0.865 0.0087 0.0087 0.0087 0.0000
Propane 0.225 0.0023 0.0023 0.0023 0.0000
i-Butane 0.035 0.0004 0.0004 0.0004 0.0000
n-Butane 0.06 0.0006 0.0006 0.0006 0.0000
i-Pentane 0.01 0.0001 0.0001 0.0001 0.0000
n-Pentane 0 0.0000 0.0000 0.0000 0.0000
Hexane+ 0.12 0.0012 0.0012 0.0010 0.0002

Total 100.070 1.001 1.0000 0.9990

Hypo 0.0010
PPMv to Mole%

ppm 950
mole% 0.095 0.0222
Mole Frac. 0.00095 0.0718
0.0010
0.0
0.8919
0.0087
0.0023
0.0004
0.0006
0.0001
0.0000
0.0012

1.000000
-0.0221
-0.0725
-0.0005
-0.0007
-0.8905
-0.0084
-0.0022
-0.0004
-0.0006
-0.0002
0.0000
-0.0009

-0.0220
-0.0717
-0.0007
-0.0009
-0.8903
-0.0089
-0.0023
-0.0003
-0.0006
0.0000
0.0000
-0.0012

-0.0222
-0.0717
-0.0010
0.0000
-0.8919
-0.0087
-0.0023
-0.0004
-0.0006
-0.0001
0.0000
-0.0012

0.0220821389
0.0715077391
0.0009901438
0.0011121153
0.8890485784
0.0086513394
0.0022756045
0.000392693
0.000586195
9.58702E-005
0
0.0010704
0.9978 14.98715
Rich Amine Loading mole H2S / mole of DEA 0.3

Lean AmineLoading mole H2S / mole of DEA 0.03

Flow of H2S (Feed) mole / hr 1.632

mole / hr 5.44
DEA Required
gm /hr 571.96

Sol Strength (DEA) % 30

Water Required gm /hr 1334.58

Solution Mass gm / hr 1906.54

H2S Flow In DEA 0.16


5.5488
0.331481
DEA
Solvent Parameters Sweet Gas A
Flow Temperature Pressure DEA MDEA H2S CO2
USGPM F psig wt% wt% mol frac mol frac
60 110 1245 30 0 0.000000066 0.000404744
65 110 1245 30 0 0.000000039 0.000401496
70 110 1245 30 0 0.000000032 0.000408853
75 110 1245 30 0 0.000000028 0.000414065
65 105 1245 30 0 0.000000040 0.000476346
65 110 1245 30 0 0.000000041 0.000402889
65 115 1245 30 0 0.000000045 0.000341886
65 120 1245 30 0 0.000000049 0.000292238
65 125 1245 30 0 0.000000055 0.000250899
65 115 1245 25 0 0.000000092 0.000519190
65 115 1245 26 0 0.000000072 0.000460054
65 115 1245 27 0 0.000000061 0.000418584
65 115 1245 28 0 0.000000054 0.000387623
65 115 1245 29 0 0.000000048 0.000362437
65 115 1245 30 0 0.000000045 0.000342419
65 115 1245 31 0 0.000000042 0.000326103
65 115 1245 32 0 0.000000040 0.000312352
65 115 1245 33 0 0.000000038 0.000300583
65 115 1245 34 0 0.000000037 0.000290416
65 115 1245 35 0 0.000000036 0.000281364
Sweet Gas Analysis
H2S CO2 H2O Acid Gas
ppmv ppmv mol frac Loading
0.07 404.74 ###
0.04 401.50 ###
0.03 408.85 ###
0.03 414.07 ###
0.04 476.35 ###
0.04 402.89 ###
0.04 341.89 ###
0.05 292.24 ###
0.06 250.90 ###
0.09 519.19 ###
0.07 460.05 ###
0.06 418.58 ###
0.05 387.62 ###
0.05 362.44 ###
0.04 342.42 ###
0.04 326.10 ###
0.04 312.35 ###
0.04 300.58 ###
0.04 290.42 ###
0.04 281.36 ###
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
MDEA
Solvent Parameters Sweet Gas Analysis
Temperatur H2S CO2 H2O
Flow Pressure MDEA
e
USGPM psig wt% PPMV mol % mol frac
F
30 110 1250 40 0.9164 1.3180
30 115 1250 40 1.0020 1.3110
30 120 1250 40 1.0970 1.3040
35 110 1250 40 0.8615 1.2530
35 115 1250 40 0.9944 1.2410
35 120 1250 40 1.1400 1.2300
35 115 1250 45 0.8037 1.1790
35 115 1250 35 1.5070 1.2900
40 110 1250 40 0.6460 1.2220
40 115 1250 40 0.7835 1.2040
40 120 1250 40 0.9653 1.1860
40 115 1250 35 1.0980 1.2590
40 115 1250 45 0.6023 1.1450
45 110 1250 40 0.4091 1.2390
45 115 1250 40 0.5044 1.2080
45 120 1250 40 0.6291 1.1800
50
50
50
lysis
Acid
Gas H2S (PPMV)
Loading
0.9164

0.8037

0.6023

0.4091
DEA+MDEA
Solvent Parameters Sweet Gas Analy
Flow Temperature Pressure DEA MDEA H2S CO2
USGPM F psig wt% wt% mol frac mol frac
A
Sweet Gas Analysis
H2S CO2 H2O Acid
Gas
ppmv ppmv mol frac Loading
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
MMBtu/Gal 0.000161906 LHV BTU/SCF

Btu/Gal 161.91 Spec. Gravity -


Temperature oF
Btu/Scf 1211.1
950

1
115

16.5217391304