Beruflich Dokumente
Kultur Dokumente
26 The weight of the molecules exerts a force on the wall of the container is Ideal gas
cause of exerting pressure by
27 The precipitation of AgCl will occur if ionic product is More than Ksp
28 Number of hydrogen atom presents in one mole of water 1.204 x1024 atoms
29 Charge on one electron 1.6022 x 10-19 C
30 Number of electrons in one coulomb of charge is 6.25 x 1018
31 If Kc for certain reaction is large it indicates that Product concentration
will be high
32 AlCl3 is Lewis acid
33 Forces controlling the reaction are proportional to the product of active The law of mass action
masses
34 Hydrogen bond in possible in NH3
35 Most stable covalent hydride HF
36 At constant temperature when volume of given mass of gas is doubled its Half
density becomes
37 In all reversible process the entropy of the system Increases
38 0.1000 Mole of NaCl is dissolved in 1.000dm3 distilled water at 298K, the 0.1000 M
concentration of resulting solution is
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39 Mosely derives a direct relationship between the frequency of x-rays Atomic number
emitted by an element bombarded with high energy electrons, on what
characteristic of the element does it depend
40 The intensity of x-rays depend upon nature of material of target
41 The charge of electron was determined by R Milliken
42 The e/m ratio of an electron was determined by J.J Thomson(1897)
43 Metals are good conducters because It has free electrons
44 The energy of electron in shell is given by 1312
En =
2
45 The number of electron in one coulomb of charge are 6.25 x 1018
46 The solubility of solute depends upon Pressure, Temperature, nature of And solvent
solute
47 Heat capacity of substance at constant volume is directly related to the Internal energy
48 The number of orbitals in M shell of an orbit is 9
49 H2 most closely represent Ideal gas
50 At constant temperature, the pressure of the gas is doubled its volume One half
becomes
51 Angular acceleration in the body is produced by Torque
52 The span of broad depends upon jumpers Angle of projection
53 Evaporation occurs at All temperature
54 The rate of reaction is defined as Dc/dt
55 According to bronsted and lowery concept SO4-2 cannot function as acid
56 When electron jump from one shell to another it emits energy, it was said by Bohr
57 equal volume of all gases at same temperature and pressure contain same Avogadros law
number of particles
58 NCl3 contain Six bonded electrons
59 An orbital may never be occupied by 3 electrons
60 Glass in an example of amorphous solid which can be characterized as Very viscous fluid
61 Four balloons filled with different gases, hydrogen filled balloon flew High
62 During redox reaction an oxidizing agent Gain electrons
63 The penetrating power of x-rays depends on Operating voltage
64 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p electronic configuration
65 The paramagnetic nature of substance depends on number of Unpaired electrons
66 The value of Kc is different at Different temperature
67 Standard solution are prepared in Volumetric flask
68 Nitrogen has three unpaired electrons according to Hunds rule
69 Standard hydrogen electrode may act as both cathode and anode
70 Stoichiometric calculation based on chemical equation provides us Theoretical yield
estimation about
71 The phenomenon of gas cooling by sudden expansion is called Joule Thomson Effect
72 Both hydrogen and helium is same number of Shells
73 CO2 is iso-structural with C2 H2
74 CaCO3 ,CaC ,KCN are Inorganic
75 (NH2)CO is Organic
76 Molecules of oxygen is diatomic and behaves as paramagnetic
77 HClO4 is strongest Acid from HClO1 , HClO2 , HClO3
78 TiCl4 is use as catalyst for the manufacture of ammonia
79 The shapes or appearance in which crytal grows is called Crystal habit
80 SO2 is responsible for the formation of Acid rain
81 A catalyst is more effectivne when it is in the finally divided state because It increase in surface
area
82 Electronic configuration of an element is ns2 np2 it belongs to group 4th of periodic table
83 CaCl2 anhydrous is use as Drying agent
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123 Reason for alkali metals to be soft is that, they have Not closed packed
structure
124 If the pressure and temperature of 2 litres of CO2 are doubled, the volume 2 litres
will become
125 Atoms present in one mole of Ca(OH)2 are 5 x 6.023 x 1023 atoms
126 Aluminum is resistant to Corrosion
127 CH4 &SiH4 have same Structure
128 A mixture of 50g H2 and 50 He has a total pressure of 1.5atm. partial 1.0 atm
pressure of H2 gas is
129 Calculate the volume occupied by 2.8g of nitrogen gas at STP is 22.4dm3
130 A piece of wood and iron seen to lose the same weight when completely Volume
submerged in liquid. The two pieces must have the same
131 A solution of 2,0g NaOH dissolved in 1000 g of water has concentration 0.05M
132 Bohrs theory explains He+, Li++, Be+++
133 The oxidation number of hydrogen in metal hydrides -1
134 In discharge tube Neon gas will produce Pink colour
135 The value of principle quantum number l=1,the value of magnetic quantum -1,0,+1
number(m) are
136 The study of heat changes accompanying a chemical reaction is known as Thermo-chemistry
137 On complete oxidation , one mole of an organic compound gave four moles Propane
of water which is
137 Water is not used as thermometric liquid because it does not Expand linearly
138 Number of moles of NaCl in 75,0g of table salt 1.28
139 Oxygen atom has two unpaired electrons it is there fore Paramagnetic
140 The sample of compound contain 0.100g of hydrogen and 4.20g of nitrogen NH3
, the compound is
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209 Velocity of NH3/velocity of HCl= 1.5
210 Rate of diffusion of NH3/ Rate of diffusion of HCl= 1.5
211 The temperature above which a gas can not be liquefied by pressure alone is Critical temperature (Tc)
called
212 Pressure at critical temperature is Critical Pressure (Pc)
213 The volume occupied by one mole of a gas at T c and Pc is Critical Volume (Vc)
214 H2 O2H+O H=920 k J mol
215 H2O(l)H2O(g) H=40.7 k J mol
216 Intramolecular forces are stronger then Intermolecular forces
217 Covalent bond, Co-ordinate covalent bond Intramolecular forces
218 Hydrogen bond > Dipole-Dipole interaction > London dispersion forces Intermolecular forces or
Van der Waals forces
219 Thermodynamic properties (Boiling point, Boiling point, heat of Dipole-dipole forces
vaporization and heat of sublimation) depends upon
220 Hydrogen bond is present between hydrogen and F, O And N
221 HF is weaker acid than HCl, HBr and HI
222 Ethyl alcohol(C2 H5 OH) is miscible in water in All proportion
223 London dispersion forces (short-range forces) are also called Dipole-induced dipole
interaction
224 London forces are present in Polar and Non polar
225 The strength of London forces depends upon Size of electronic clouds
226 The boiling point increase down the group from Helium to radon
227 Boiling point of neon -245.90 C
228 Boiling point of xenon -107.10 C
229 Boiling point of neon is less than xenon because neon has Smaller size than xenon
230 Boiling point of fluorine -188.10 C
231 Boiling point of iodine 184.40 C
232 Boiling point of fluorine is less than iodine because fluorine has Smaller size than iodine
233 Butane(C4 H10) has linear structure and long chain compound its boiling 272.5 K
point is
234 2-Methyl propane(C4 H10) has branched structure and short chain compound 261.3 K
its boiling point is
235 Ethane (C2 H6 ) is non-polar and its boiling point is 184.5 K (London forces)
236 Fluoro-methane (CH3 F ) is polar and its boiling point is 194.7 K (dipole-dipole
interaction)
237 Carbon tetrachloride (CCl4) is non-polar and its boiling point is 61.20 C (London forces)
238 Trichloro-methane (CHCl3) is polar and its boiling point is 76.80 C (dipole-dipole
interaction)
239 Rate of evaporation of water is slower than Ether
240 Vapour pressure of ether 250 C
241 V.P = P+h
242 The temperature at which vapour pressure of liquid becomes equal to Boiling point
atmospheric pressure is called
243 The pressure exerted by the vapours in equilibrium with a liquid at a given Vapour pressure
temperature is called
244 Glycerine boils at 2900 C
245 Glycerine decrease to 2100 C at 50 mm of Hg
246 At higher altitude, atmospheric pressure is Less than 1 atm
247 Water boils at lower temperature at Higher altitude
248 The amount of heat absorbed when one mole of solid converted into liquid Molar heat of
at its melting point is called fusion(Hf)
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260 Molten sulphur at 2400 C with ring shape S molecules are less viscous than 1900C
long chain entangled Sn molecules at
261 The viscosity of water(H2O) is more than ethyl-alcohol due to Hydrogen bonding of
water (H2O)
262 The ratio of viscosity of liquid to the viscosity of water taken as standard is Relative viscosity
called
263 Viscosity ()=dt here d is Density
264 The viscosity of water is taken as 1 Centipoise at 250C
265 To measure the relative viscosity of liquid , we use Ostwalds Viscometer
266 The force required to maintain a difference of velocity of 1 ms -1 between Co-efficient of Viscosity
two parallel layers of liquid one meter apart ()
267 The unit of Co-efficient of Viscosity () is Kgm-1s-1
268 1 poise = 10-1 Kgm-1s-1
269 Stearin from52.10C to 62.60C behaves like a Liquid crystal
270 Cholesteryl benzoate from 1450C to 1790C behaves like a Liquid crystal
271 Crystalline solids are also called True solids
272 Amorphous solids are also called Super cooled liquids
273 Crystalline solids have definite Geometrical shape and their particles are Arranged properly
274 Amorphous solids have no definite shape and its particles are packed Proper arrangement
together without
275 NaCl, CaCO3 , CaO, CuSO4 .5H2 O , Graphite and Diamond etc are Crystalline solids
276 Glasses, Plastics, Rubber,Coal, Tar and Gemstone are Amorphous solids
277 Plane of symmetry can be More than 1
278 Axis of symmetry can be More than 1
279 Centre of symmetry can be Only 1
280 Grinding to a very fine powder, crystalline solids still retain their specific Geometrical shape
281 The temperature of crystalline solids remain constant until all particles Become mobile
282 The magnitude of interfacial angles after cleavage has taken place is always Different for different
solids
283 NaCl has a Cubic Habit
284 NaCl will grow in one dimension (needle like) if % of urea present is 10%
285 Crystalline solids have anisotropic behavior because of Regular particles
arrangment
286 Physical properties of isomorphs are Different from each
other
287 Structure of NaCl and Mgo is Cubic
288 Structure of ZnO and CdS is Hexagonal
289 Structure of KNO3 ,NaNO3 ,CaCO3 is Rhombohedral
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290 Existence of more than two compounds in one crystalline form Isomorphism
291 Existence of one compound in more than one crystalline form Polymorphism
292 Existence of one element in more than one crystalline form Allotrophy
293 Sulphur exist in two allotropic forms Rhombohedral and
monoclinic
294 Oxygen exist in two allotropic forms O2 and O3
295 Tin Diamond, Graphite and Bucky balls Gray tin(cubic) and
White tin(tetragonal)
296 KNO3 exist in two allotropic forms Rhombohedral and
Orthorhombic
297 Carbon exist in three allotropic forms Diamond, Graphite and
Bucky balls
298 The temperature at which one crystalline form changes to another Transition Temperature
299 Crystalline forms of same substance coexist in equilibrium at Transition Temperature
300 Transition Temperature of Sulphur is 98.50C
301 Transition Temperature of Tin is 13.20C
302 Transition Temperature of KNO3 is 128.50C
303 , , , a, b, c are unit cell dimensions or Crystallographic
elements
304 Energy required(+) to break one mole ionic crystal to its ions in the gas Lattice energy
phase or energy released(-) when one mole of ionic crystal is formed from
its opposite gaseous atoms
305 Lattice energy for NaF is 895 kJ mol-1
306 Lattice energy for NaCl is 787 kJ mol-1
307 Lattice energy for NaBr is 728 kJ mol-1
308 Lattice energy for NaI is 690 kJ mol-1
309 NaCl, MgO and NaBr are Ionic crystals
310 Diamond, Carborundum and Silicon carbide are Covalent crystals
311 Copper, Alluminium, Silver, Iron and Sodium are Metallic crystals
312 Ice and Sugar are Polar molecular crystals
313 Carbondioxide, Sulphur, Phosporus, Solidified noble gases and Iodine are Non-polar molecular
crystals
314 The melting point of Ionic crystals, Covalent crystals, Metallic crystals are High meting point
high while Molecular crystals have
315 The Ionic crystals, Covalent crystals, Metallic crystals are hard while Soft
Molecular crystals are
316 The Ionic crystals are soluble in Polar
317 The Covalent crystals are soluble in Non-polar
318 The Molecular crystals are soluble in Non-polar
319 Ionic crystals are Do not conduct heat and
electricity
320 Covalent crystals are Poor conductors of heat
and electricity
321 Metallic crystals are Good conductors of heat
and electricity
322 Metallic crystals Ductile and Malleable
323 Because of the polar nature of molecule and presence of strong hydrogen Heat of fusion
bonding, ice has high value of
324 The law of mass action was proposed by C.M. Guldberg and P. Waage in 1864
325 Mathematical representation of law of mass action []2[]2
Kc=[]2[]2
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373 Weight in grams of solute necessary to saturate 100 grams of solvent at Solubility
given temperature and pressure
374 At constant temperature the solubility is directly proportional to the Pressure
375 Number of moles of solute/number of kg of solvent Molality (m)
376 Number of moles of solute/volume of solution(dm3) Molarity (M)
377 To temperature, solubility is Dependent
378 To temperature, lowering of vapour pressure of solute dissolved in solvent Inependent
is
379 To temperature, molality is Independent
380 To temperature, mole friction is Independent
381 Parts per million (ppm) = wt. or vol. of solute / wt. or vol. of solution x 106
382 Parts per billion (ppb) = wt. or vol. of solute / wt. or vol. of solution x 109
383 Parts per trillion (ppt) = wt. or vol. of solute / wt. or vol. of solution x 1012
384 The solubility of NaCl and KBr is not affected by change in Temperature
385 A dissolved dissolve in liquid ,its vapour pressure is Decreased
386 Pressure of solution is always less than Solvent pressure
387 Lowering of vapour pressure depends upon nature of solvent, concentration Nature of solute
of solute but not on
388 The partial vapour pressure of any volatile component of solution is equal to Raoults Law
the vapour pressure of the pure component multiplied by the mole friction
of that component of solution
389 Elevation of boiling point of dilute solution is directly proportional to Temperature
390 Types of colloidal suspension are 8
391 = RTC/M Osmotic pressure
392 One gram of matter to energy yields 2.2 x 1013 cal
393 Loss of mass of coal is 3 x 10-9
394 Increase in internal energy of system can results in a chemical reaction or Temperature and phase
change in
395 First law of thermodynamics q=E + w
396 The only type of work in thermodynamics is Pressure-volume work
397 In pressure-volume work q=E + pv
398 The unit of work and heat is Nm-2 x m3 =Nm or J
399 H=E+PV , here H is Enthalpy of a system
400 Heat evolved or absorbed during a reaction is equal to enthalpy of system H = qp
401 Enthalpy of a system is State function
402 Chang in enthalpy at 298K and 1 atm when reactants and product are un Standard Enthalpy
their natural state Change ( H0)
403 Unit of heat capacity JK-1
404 Chang in enthalpy at 298K and 1 atm when one mole of compound is Standard Enthalpy of
formed from its components Formation (Hf 0)
405 Chang in enthalpy at 298K and 1 atm when one mole of compound is burnt Standard Enthalpy of
in excess of air or oxygen Combustion (Hc 0)
406 Chang in enthalpy at 298K and 1 atm when one mole of water is formed
from H+ from acid react with OH-
407 Chang in enthalpy at 298K and 1 atm when one mole of substance is Standard Enthalpy
dissolved in excess solvent so that further heat change are not detect Solution (Hs 0)
408 To measure enthalpy change, we use direct calorimeter or Hesss Law
409 Sum of energy change of closed cycle is zero Born Haber Cycle
410 Oxidation is addition of oxygen or removal of hydrogen while Classical concept of
Reduction is removal of oxygen and addition of hydrogen Oxidation-reduction
411 Oxidation loss of electrons while Reduction is gain of electrons Electron transfer concept
412 Oxidation number of oxidizing agent Increases
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