Sie sind auf Seite 1von 22

The energy content of the universe is constant, just as its mass content is.

Yet at
times of crisis we are bombarded with speeches and articles on how to conserve
energy. As engineers, we know that energy is already conserved. What is not
conserved is exergy, which is the useful work potential of the energy. Once the
exergy is wasted, it can never be recovered. When we use energy (to heat our
homes, for example), we are not destroying any energy; we are merely converting it
to a less useful form, a form of less exergy.

Exergy and the Dead State

The useful work potential of a system is the amount of energy we extract as useful
work. The useful work potential of a system at the specified state is called exergy.
Exergy is a property and is associated with the state of the system and the
environment. A system that is in equilibrium with its surroundings has zero exergy
and is said to be at the dead state. The exergy of the thermal energy of thermal
reservoirs is equivalent to the work output of a Carnot heat engine operating between
the reservoir and the environment.

For more information and animations illustrating this topic visit the Animation Library
developed by Professor S. Bhattacharjee, San Diego State University, at this link.

test.sdsu.edu/testhome/vtAnimations/index.html 1
Exergy Forms

Now lets determine the exergy of various forms of energy.

Exergy of kinetic energy

Kinetic energy is a form of mechanical energy and can be converted directly into
work. Kinetic energy itself is the work potential or exergy of kinetic energy
independent of the temperature and pressure of the environment.
Exergy of kinetic energy: V2
xke ke (kJ/kg)
Exergy of potential energy 2
Potential energy is a form of mechanical energy and can be converted directly into
work. Potential energy itself is the work potential or exergy of potential energy
independent of the temperature and pressure of the environment.
Potential energy itself is the work
potential or exergy of potential energy
independent of the temperature and
pressure of the environment.

Exergy of potential energy:


xpe pe gz (kJ/kg) 2
Useful Work

The work done by work producing devices is not always entirely in a useable form.
Consider the piston-cylinder device shown in the following figure.

The work done by the gas expanding in the piston-cylinder device is the boundary work
and can be written as

W P dV ( P P0 ) dV P0 dV
Wb, useful P0 dV
3
The actual work done by the gas is W Wb, useful P0 dV
Wb, useful P0 (V2 V1 )
The word done on the surroundings is Wsurr P0 dV P0 (V2 V1 )
Any useful work delivered by a piston-cylinder device is due to the pressure above the
atmospheric level.

Wu W Wsurr
Reversible Work

Reversible work Wrev is defined as the maximum amount of useful work that can be
produced (or the minimum work that needs to be supplied) as a system undergoes a
process between the specified initial and final states. This is the useful work output
(or input) obtained when the process between the initial and final states is executed
in a totally reversible manner.

Irreversibility

The difference between the reversible work Wrev and the useful work Wu is due to the
irreversibilities present during the process and is called the irreversibility I. It is
4
equivalent to the exergy destroyed and is expressed as
Reversible Work

Reversible work Wrev is defined as the maximum amount of useful work that can be
produced (or the minimum work that needs to be supplied) as a system undergoes a
process between the specified initial and final states. This is the useful work output
(or input) obtained when the process between the initial and final states is executed
in a totally reversible manner.

Irreversibility

The difference between the reversible work Wrev and the useful work Wu is due to the
irreversibilities present during the process and is called the irreversibility I. It is
equivalent to the exergy destroyed and is expressed as

I X destroyed T0 Sgen Wrev, out Wu, out Wu, in Wrev, in


where Sgen is the entropy generated during the process. For a totally
reversible process, the useful and reversible work terms are identical and
thus irreversibility is zero.

5
Irreversibility can be viewed as the wasted work potential or the lost opportunity to do
work. It represents the energy that could have been converted to work but was not.

Exergy destroyed represents the lost work potential and is also called the wasted
work or lost work.
Exergy of change of a system

Consider heat transferred to or from a closed system whenever there is a


temperature difference across the system boundary. The exergy for a system may be
determined by considering how much of this heat transfer is converted to work
entirely. Lets take a second look at the following figure.

7
Taking the heat transfer to be from the system to its surroundings, the conservation of
energy is
Ein Eout dEsystem
0 Q W dU
The work is the boundary work and can be written as
W P dV ( P P0 ) dV P0 dV
Wb, useful P0 dV
Any useful work delivered by a piston-cylinder device is due to the pressure above the
atmospheric level.

To assure the reversibility of the process, the heat transfer occurs through a
reversible heat engine.
T0 Q
WHE th Q (1 ) Q Q T0
T T
Qnet Q
dS
T T
WHE Q T0 dS
Q WHE T0 dS
8
WHE T0 dS Wb, useful P0 dV dU
Wtotal useful Wb, useful WHE
dU P0 dV T0 dS
Integrating from the given state (no subscript) to the dead state (0 subscript), we have
Wtotal useful (U 0 U ) P0 (V0 V ) T0 ( S0 S )
(U U 0 ) P0 (V V0 ) T0 ( S S0 )
This is the total useful work due to a system undergoing a reversible process from a
given state to the dead state, which is the definition of exergy.

Including the kinetic energy and potential energy, the exergy of a closed system is

V2
X (U U 0 ) P0 (V V0 ) T0 ( S S0 ) m mgz
2
on a unit mass basis, the closed system (or nonflow) exergy is

V2
(u u0 ) P0 (v v0 ) T0 ( s s0 ) gz
2
(e e0 ) P0 (v v0 ) T0 ( s s0 ) 9
Problem: Evaluating the exergy of exhaust gas

A cylinder of an internal combustion engine contains 2450 cm3 of gaseous


combustion products at a pressure of 7 bar and a temperature of 867 oC just
before the exhaust valve opens. Determine the specific exergy of the gas, in
kJ/kg. Ignore the effects of motion and gravity, and model the combustion
products as air as an ideal gas. Take T0 300 K (27 oC) and p0 1.013 bar.

Answer: 368.91 kJ/kg

10
Exergy change

Here, u0, v0, and s0 are the properties of the system evaluated at the dead state. Note
that the exergy of the internal energy of a system is zero at the dead state is zero
since u = u0, v = v0, and s = s0 at that state.

The exergy change of a closed system during a process is simply the difference
between the final and initial exergies of the system,
X X 2 X 1 m(2 1 )
( E E0 ) P0 (V V0 ) T0 ( S S0 )
V22 V12
(U U 0 ) P0 (V V0 ) T0 ( S S0 ) m mg ( z2 z1 )
2
On a unit mass basis the exergy change of a closed system is
(2 1 )
(e e0 ) P0 (v v0 ) T0 ( s s0 )
V22 V12
(u u0 ) P0 (v v0 ) T0 ( s s0 ) g ( z2 z1 ) 11
2
Exergy of flow

The energy needed to force mass to flow into or out of a control volume is the flow
work per unit mass given by (see Chapter 3).

wflow Pv

The exergy of flow work is the excess of flow work done against atmospheric air at P0
to displace it by volume v. According to the above figure, the useful work potential
due to flow work is

wflow, energy Pv P0v

12
Thus, the exergy of flow energy is

xflow energy Pv P0v (P P0 )v


Flow Exergy

Since flow energy is the sum of nonflow energy and the flow energy, the exergy of
flow is the sum of the exergies of nonflow exergy and flow exergy.
x flowing fluid xnonflowing fluid xflow exergy
V2
(u u0 ) P0 (v v0 ) T0 ( s s0 ) gz ( P P0 )v
2
V2
(u Pv) (u0 P0v0 ) T0 ( s s0 ) gz
2
V2
(h h0 ) T0 ( s s0 ) gz
2
The flow (or stream) exergy is given by

V2
(h h0 ) T0 ( s s0 ) gz
2
13
The exergy of flow can be negative if the pressure is lower than atmospheric
pressure.

The exergy change of a fluid stream as it undergoes a process from state 1 to state 2
is 2
V2 V1
2
2 1 (h2 h1 ) T0 ( s2 s1 ) g ( z2 z1 )
2
Exergy Transfer by Heat, Work, and Mass

Exergy can be transferred by heat, work, and mass flow, and exergy transfer
accompanied by heat, work, and mass transfer are given by the following.

Exergy transfer by heat transfer

By the second law we know that only a portion of heat transfer at a temperature above
the environment temperature can be converted into work. The maximum useful work is
produced from it by passing this heat transfer through a reversible heat engine. The
exergy transfer by heat is

T0
Exergy transfer by heat: X heat 1 Q
T
14
Note in the above figure that entropy generation is always by exergy destruction and
that heat transfer Q at a location at temperature T is always accompanied by entropy
transfer in the amount of Q/T and exergy transfer in the amount of (1-T0/T)Q.

Note that exergy transfer by heat is zero for adiabatic systems.


15
Exergy transfer by work

Exergy is the useful work potential, and the exergy transfer by work can simply be
expressed as
W Wsurr (for boundary work)

Exergy transfer by work: X
work
W (for other forms of work)

where Wsurr P0 (V2 V1 ), P0 is atmospheric pressure, and V1 and V2 are the initial and
final volumes of the system. The exergy transfer for shaft work and electrical work is
equal to the work W itself.

Note that exergy transfer by work is zero for systems that have no work.
Exergy transfer by mass

Mass flow is a mechanism to transport exergy, entropy, and energy into or out of a
system. As mass in the amount m enters or leaves a system the exergy transfer is
given by

Exergy transfer by mass: X mass m


Note that exergy transfer by mass is zero for systems that involve no flow. 16
Exergy Destruction

Irreversibilities such as friction, mixing, chemical reactions, heat transfer


through finite temperature difference, unrestrained expansion, non-quasi-
equilibrium compression, or expansion always generate entropy, and
anything that generates entropy always destroys exergy. The exergy
destroyed is proportional to the entropy generated as expressed as

X destroyed T0 Sgen
The decrease of exergy principle does not imply that the exergy of a system cannot
increase. The exergy change of a system can be positive or negative during a
process, but exergy destroyed cannot be negative. The decrease of exergy principle
can be summarized as follows:
0 Irreversible proces

X destroyed 0 Reversible process
0
Impossible process
17
Problem: A gear box operates at steady state with known values for power input,
out put and heat transfer rate as shown in diagram. The temperature on the outer
surface is given. Take To = 293 K. Find exergy and exergy destruction.

18
Exergy Balances

Exergy balance for any system undergoing any process can be expressed as
Total Total Total Change in the

exergy
exergy
exergy
total exergy
entering leaving destroyed of the system

General: X in X out X destroyed X system


Net exergy transfer Exergy Change
by heat, work, and mass destruction in exergy

General, rate form:

X in X out X destroyed X system


Rate of net exergy transfer Rate of exergy Rate of change
by heat, work, and mass destruction of exergy

19
General, unit-mass basis: ( xin xout ) xdestroyed xsystem
T0
X heat 1 Q
where T
X work Wuseful
X mass m
X system dX system / dt
For a reversible process, the exergy destruction term, Xdestroyed, is zero.

Considering the system to be a general control volume and taking the positive
direction of heat transfer to be to the system and the positive direction of work
transfer to be from the system, the general exergy balance relations can be
expressed more explicitly as
T0
1 T Qk W P0 (V2 V1 ) mi i me e X destroyed X 2 X 1
k

T0 dVCV dX CV
1 T
k
Q

W P0 i i e e

m m X destroyed
k dt dt
20
where the subscripts are i = inlet, e = exit, 1 = initial state, and 2 = final state of the
system. For closed systems, no mass crosses the boundaries and we omit the terms
containing the sum over the inlets and exits.

Problem: Determining the exergy destruction in a Throttling valve

Superheated water vapor enters a valve at 500 oF, 500 Ibf/in2 and exits at a pressure
of 80 Ibf/in2. The expansion is a throttling process. Determine the exergy destruction
per unit mass flowing in Btu/Ib. Let T0 = 77 oF and P0 = 1 atm.

21
Problem: Determining the exergy destruction in a heat exchanger

Compressed air enters a counterflow heat exchanger operating at steady state at 610
K, 10 bar and exits at 860 K, 9.7 bar. Hot combustion gas enters as a separate
stream at 1020 K, 1.1 bar and exits at 1 bar. Each stream has a mass flow rate of 90
kg/s. Heat transfer between the outer surface of the heat exchanger and the
surroundings can be ignored. Kinetic and potential energy effects are negligible.
Assuming the combustion gas stream has the properties of air, and using the ideal
gas model for both streams, determine for the heat exchanger
(a) the exit temperature of the combustion gas, in K.
(b) the net change in the flow exergy rate from inlet to exit of each stream, in MW.
(c) the rate exergy is destroyed, in MW.
Let T0 = 300 K, p0 =1 bar.

22

Das könnte Ihnen auch gefallen