Beruflich Dokumente
Kultur Dokumente
Prof. Ke Xu
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Questions
Q1: For AA, why is it not ideal to use a broadband
white light source + monochromator?
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Ionization equilibria
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Ionization suppressor
Adding potassium to measure strontium
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Standard addition
Actual concentration
Compensates for many of the interferences by adding known quantities of analyte to the
unknown in its complex matrix
Adding small amount of standards keeps the matrix nearly identical
Background removal is critical
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Atomic emission spectroscopy (AES)
Setup
Principle
Luminescence PL
Thermal
energy
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Advantages of AES
(Qualitative)
I = ac (Ideal; low c)
Slope
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For better reproducibility
Internal-standard!
Add into samples a component that
is not present in the test samples
produces a signal similar to, but
distinguishable from that of the analyte
is added in a constant amount to all
samples and standards
Use ratio of the measured signal of the
analyte to the measured signal of the
internal standard!
Inductor L
~50 V, EDC V G
30 A
R
A
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Plasma sources - Inductively Coupled Plasma (ICP)
Torch of plasma:
Plasma: electrically conductive gaseous mixture
containing cations and electrons
High temperature up to 10,000 K
Energy from the coupling of induction coil:
powered by a radio-frequency generator (10 kW)
Plasma isolated from the quartz by Ar flow
Quartz
tube
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Characteristics of ICP torch
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The many lines in AES
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Spectral overlap is a real problem for AE
AA: Analyzes a single element at one time; one HCL light source only generates a
few very narrow lines use one single, narrow line for AA at a time
AE: Multiple elements in the sample emitting at the same time no way to only excite
only one element at a time.
Use non-overlapping lines
Often need to use multiple lines to confirm the existence of one element
High-resolution monochromator helps
Echelle grating:
High-resolution spectra
in 2D format
Directly recording
with a camera (CCD)
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Single-channel + scanning!
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